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At least 37 records · Page 2

The South Ray Crater age paradox

Relative exposure ages based on agglutinate content are calculated for 26 Apollo 16 surface and core samples. These ages increase from the northern part of the traverse to the southern part and are in general agreement with cosmogenic gas ages and particle track ages. An apparent paradox exists in which presumed ray soil from South Ray Crater is much older than the age of South Ray Crater itself as determined by a variety of methods. The most likely explanation for the paradox is that the presumed South Ray Crater soil is not ejecta from South Ray Crater but is pre-existing regolith upon which blocks and fragments from South Ray Crater are scattered.

Mckay, D. S.↗

The Shergottite Age Paradox and the Relative Probabilities of Ejecting Martian Meteorites of Differing Ages

The apparent paradox that the majority of impacts yielding Martian meteorites appear to have taken place on only a few percent of the Martian surface can be resolved if all the shergottites were ejected in a single event rather than in multiple events as expected from variations in their cosmic ray exposure and crystallization ages. If the shergottite-ejection event is assigned to one of three craters in the vicinity of Olympus Mons that were previously identified as candidate source craters for the SNC (Shergottites, Nakhlites, Chassigny) meteorites, and the nakhlite event to another candidate crater in the vicinity of Ceraunius Tholus, the implied ages of the surrounding terranes agree well with crater density ages. EN,en for high cratering rates (minimum ages), the likely origin of the shergottites is in the Tharsis region, and the paradox of too many meteorites from too little terrane remains for multiple shergottite-ejection events. However, for high cratering rates it is possible to consider sources for the nakhlltes which are away from the Tharsis region. The meteorite-yielding impacts may have been widely dispersed with sources of the young SNC meteorites in the northern plains, and the source of the ancient orthopyroxenite, ALH84001, in the ancient southern uplands. Oblique-impact craters can be identified with the sources of the nakhlites and the orthopyroxenite,, respectively, in the nominal cratering rate model, and with the shergottites and orthopyroxenite, respectively, in the high cratering rate model. Thus, oblique impacts deserve renewed attention as an ejection mechanism for Martian meteorites.

Borg, L. E.↗

Avoiding Braess' Paradox Through Collective Intelligence

In an Ideal Shortest Path Algorithm (ISPA), at each moment each router in a network sends all of its traffic down the path that will incur the lowest cost to that traffic. In the limit of an infinitesimally small amount of traffic for a particular router, its routing that traffic via an ISPA is optimal, as far as cost incurred by that traffic is concerned. We demonstrate though that in many cases, due to the side-effects of one router's actions on another routers performance, having routers use ISPA's is suboptimal as far as global aggregate cost is concerned, even when only used to route infinitesimally small amounts of traffic. As a particular example of this we present an instance of Braess' paradox for ISPA'S, in which adding new links to a network decreases overall throughput. We also demonstrate that load-balancing, in which the routing decisions are made to optimize the global cost incurred by all traffic currently being routed, is suboptimal as far as global cost averaged across time is concerned. This is also due to "side-effects", in this case of current routing decision on future traffic. The theory of COllective INtelligence (COIN) is concerned precisely with the issue of avoiding such deleterious side-effects. We present key concepts from that theory and use them to derive an idealized algorithm whose performance is better than that of the ISPA, even in the infinitesimal limit. We present experiments verifying this, and also showing that a machine-learning-based version of this COIN algorithm in which costs are only imprecisely estimated (a version potentially applicable in the real world) also outperforms the ISPA, despite having access to less information than does the ISPA. In particular, this COIN algorithm avoids Braess' paradox.

Wolpert , David H.↗

Elevated Tropospheric Ozone Over the South Tropical Atlantic in January-February 1999: An Ozone Paradox Due to Interhemispheric Transport, Lightning, or Stratospheric Exchange?

On this first North American to southern African oceanographic cruise with ozonesonde launches (January and February 1999 on board the NOAA Research Vessel Ronald H Brown between Norfolk, VA, and Cape Town, South Africa) we found: (1) high ozone, CO, and aerosols off northern equatorial Africa from biomass burning, but even higher ozone concentrations off southern Africa which was not burning - an "ozone paradox"; (2) TOMS satellite evidence that south Atlantic elevated ozone in January-February 1999 was a regional feature similar in extent to the well-known September-October ozone maximum. Several mechanisms are considered to explain the "ozone paradox." Convection transporting air from the lower troposphere rich in ozone and/or ozone precursors to the upper troposphere through the ITCZ (intertropical Convergence Zone) may lead to cross-hemisphere transport of pollution. This is supported by trajectory linkage of lower-tropospheric ozone maxima with smoke seen by the TOMS satellite. Lightning-generated NO (nitric oxide) leading to ozone peaks of > 100 ppbv observed at 7-10 km altitude is another explanation. The TRMM (Tropical Rainfall Measuring Mission) Lightning Imaging Sounder shows many lightning flashes over southern Africa, which trajectories link to the high-ozone layers south of the ITCZ. The highest ozone peaks in the middle troposphere correspond to very low water vapor, which may point to photochemical destruction of ozone or subsidence from the upper troposphere which had interacted with stratospheric ozone.

Thompson, Anne M.↗

Patent foramen ovale and paradoxical systemic embolism: a bibliographic review

A patent foramen ovale (PFO) has been reported to be an important risk factor for cardioembolic cerebrovascular accidents through paradoxical systemic embolization, and it provides one potential mechanism for the paradoxical systemic embolization of venous gas bubbles produced after altitude or hyperbaric decompressions. Here, we present in a single document a summary of the original findings and views from authors in this field. It is a comprehensive review of 145 peer-reviewed journal articles related to PFO that is intended to encourage reflection on PFO detection methods and on the possible association between PFO and stroke. There is a heightened debate on whether aviators, astronauts, and scuba divers should go through screening for PFO. Because it is a source of an important controversy, we prefer to present the findings in the format of a neutral bibliographic review independent of our own opinions. Each cited peer-reviewed article includes a short summary in which we attempt to present potential parallels with the pathophysiology of decompression bubbles. Two types of articles are summarized, as follows. First, we report the original clinical and physiological findings which focus on PFO. The consistent reporting sequence begins by describing the method of detection of PFO and goal of the study, followed by bulleted results, and finally the discussion and conclusion. Second, we summarize from review papers the issues related only to PFO. At the end of each section, an abstract with concluding remarks based on the cited articles provides guidelines.

NASA Discipline Environmental Health↗

New Perspectives from Satellite and Profile Observations on Tropospheric Ozone over Africa and the Adjacent Oceans: An Indian-Atlantic Ocean Link to tbe "Ozone Paradox"

In the past few years, tropospheric ozone observations of Africa and its adjacent ocenas have been greatly enhanced by high resolution (spatial and temporal) satellite measurements and profile data from aircraft (MOZAIC) and balloon-borne (SHADOZ) soundings. These views have demonstrated for the first time the complexity of chemical-dynamical interactions over the African continent and the Indian and Atlantic Oceans. The tropical Atlantic "ozone paradax" refers to the observation that during the season of maximum biomass burning in west Africa north of the Intertropical Convergence Zone (ITCZ), the highest tropospheric ozone total column occurs south of the ITCZ over the tropical Atlantic. The longitudinal view of tropospheric ozone in the southern tropics from SHADOZ (Southern Hemisphere Additional Ozonesondes) soundings shown the persistence of a "zonal-wave one" pattern that reinforces the "ozone paradox". These ozone features interact with dynamics over southern and northern Africa where anthropogenic sources include the industrial regions of the South African Highveld and Mideastern-Mediterranean influences, respectively. Our newest studies with satellites and soundings show that up to half the ozone pollution over the Atlantic in the January-March "paradox" period may originate from south Asian pollution. Individual patches of pollurion over the Indian Ocean are transported upward by convective mixing and are enriched by pyrogenic, biogenic sources and lightning as they cross Africa and descend over the Atlantic. In summary, local sources, intercontinental import and export and unique regional transport patterns put Africa at a crossroads of troposheric ozone influences.

Thompson, Anne M.↗

Crystallization Age of NWA 1460 Shergottite: Paradox Revisited

We have determined the Rb-Sr age of basaltic shergottite NWA 1460 to be 312 +/- 3 Ma, and the Sm-Nd age to be 352 +/- 30 Ma. The initial Sr and Nd isotopic compositions of NWA 1460 suggest it is an earlier melting product of a Martian mantle source region similar to those of the Iherzolitic shergottites and basaltic shergottite EETA79001, lithology B. The new ages of NWA 1460 and other recently analyzed Martian meteorites leads us to reexamine the paradox that most of the Martian meteorites appear to be younger from the majority of the Martian surface. This paradox continues to pose a challenge to determining a reliable Martian chronology.

Nyquist, L. E.↗

The Solar Curtailment Paradox

This presentation summarizes work recently published in a Joule article, "The Curtailment Paradox in the Transition to High Solar Power Systems." Rising penetrations of variable renewable energy (VRE) in power systems are expected to increase the curtailment of these resources because of oversupply and operational constraints. We evaluate the effect on curtailment from various flexibility approaches, including storage, thermal generator flexibility, operating reserve eligibility rules, transmission constraints, and temporal resolution, by using a highly resolved realistic system. Results reveal two aspects of a curtailment paradox as the system evolves to higher solar penetration levels. First, thermal generator parameters, especially in restricting minimum operating levels and ramp rates, affect VRE curtailment more in mid-PV penetration levels (~25%–40%) but much less at lower (~20%) or higher (~45%) PV penetration levels. Second, although allowing VRE and storage to provide operating reserve results in significant operating costs and curtailment benefits, the price suppression effect from these resources reduces incentives for PV to provide operating reserves with curtailed energy.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Impact of Thermal Plant Operational Flexibility on VRE Curtailment: The Curtailment Paradox

This presentation provides an overview of a previously published paper in Joule "The curtailment paradox in the transition to high solar power systems." The adoption of PV and battery storage has accelerated globally in recent years, driven by rapid cost declines. A corresponding increase in curtailment is anticipated as PV growth continues. This study explores the effect of system flexibility options on curtailment across increasing PV penetration levels. Results highlight a paradox where thermal generator flexibility matters most only at mid-PV penetration levels (25%-40%), and a misalignment exists where PV provides system value by providing operating reserves without sufficient opportunity for monetary compensation.

capacity expansion modeling↗

Tunneling between Multiple Histories as a Solution to the Information Loss Paradox

The information loss paradox associated with black hole Hawking evaporation is an unresolved problem in modern theoretical physics. In a recent brief essay, we revisited the evolution of the black hole entanglement entropy via the Euclidean path integral (EPI) of the quantum state and allow for the branching of semi-classical histories along the Lorentzian evolution. We posited that there exist at least two histories that contribute to EPI, where one is an information-losing history, while the other is an information-preserving one. At early times, the former dominates EPI, while at the late times, the latter becomes dominant. By doing so, we recovered the essence of the Page curve, and thus, the unitarity, albeit with the turning point, i.e., the Page time, much shifted toward the late time. In this full-length paper, we fill in the details of our arguments and calculations to strengthen our notion. One implication of this modified Page curve is that the entropy bound may thus be violated. We comment on the similarity and difference between our approach and that of the replica wormholes and the islands’ conjectures.

79 ASTRONOMY AND ASTROPHYSICS↗

Overcoming the Damping–Elasticity Paradox via 3D‐Printed NiTiSn Nanocomposite

Abstract Developing high damping alloys (HDAs) with large elastic strain has attracted growing attention due to the increasing demand for energy absorption with overload reliability and reusability. However, damping capacity inherently conflicts with elasticity, because the former requires a liable movement of crystal defects while the latter opposite. To deal with the damping‐elasticity paradox, the advantage of pseudobinary eutectic reaction and rapid cooling of laser powder bed fusion is taken to fabricate a bulk NiTiSn nanocomposite with a two‐level hierarchical structure. The first‐level architecture is composed of martensitic NiTi nanolamellae and reinforced Ti 3 Sn nanolamellae. In addition to lattice strain matching and lamellar boundary strengthening, a novel mechanism of martensite reorientation mediated by reversible stress‐induced detwinning‐twinning is activated to generate large elastic strain. A high density of nanotwins and nanodomains within NiTi nanolamellae constitute the second‐level architecture, which provides pronounced internal friction for high damping capacity. As a result, our NiTiSn nanocomposite exhibits a record‐high integration of damping capacity (tanδ > 0.10) and elastic strain (exceeding 4.5%), as well as superb stability under cyclic overload. This research not only represents a major breakthrough in achieving HDAs with outstanding damping and elastic strain but also offers a novel paradigm for high‐performance functional and structural materials.

Chemistry↗

Entanglement wedge reconstruction and the information paradox

When absorbing boundary conditions are used to evaporate a black hole in AdS/CFT, we show that there is a phase transition in the location of the quantum Ryu-Takayanagi surface, at precisely the Page time. The new RT surface lies slightly inside the event horizon, at an infalling time approximately the scrambling time β/2 π logS BH into the past. We can immediately derive the Page curve, using the Ryu-Takayanagi formula, and the Hayden-Preskill decoding criterion, using entanglement wedge reconstruction. Because part of the interior is now encoded in the early Hawking radiation, the decreasing entanglement entropy of the black hole is exactly consistent with the semiclassical bulk entanglement of the late-time Hawking modes, despite the absence of a firewall.By studying the entanglement wedge of highly mixed states, we can understand the state dependence of the interior reconstructions. A crucial role is played by the existence of tiny, non-perturbative errors in entanglement wedge reconstruction. Directly after the Page time, interior operators can only be reconstructed from the Hawking radiation if the initial state of the black hole is known. As the black hole continues to evaporate, reconstructions become possible that simultaneously work for a large class of initial states. Using similar techniques, we generalise Hayden-Preskill to show how the amount of Hawking radiation required to reconstruct a large diary, thrown into the black hole, depends on both the energy and the entropy of the diary. Finally we argue that, before the evaporation begins, a single, state-independent interior reconstruction exists for any code space of microstates with entropy strictly less than the Bekenstein-Hawking entropy, and show that this is sufficient state dependence to avoid the AMPSS typical-state firewall paradox.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Deciphering the Olefin Isomerization-Polymerization Paradox of Palladium(II) Diimine Catalysts: Discovery of Simultaneous and Independent Pathways of Olefin Isomerization and Living Polymerization

This work elucidates a long-standing unexplained paradox commonly observed within the polymerization of α-olefin using palladium (Pd)(II)–diimine catalysts, in which isomerization and living polymerization of α-olefins are both observed. With a classical mechanistic understanding of these complexes, this behavior is often dismissed and interpreted as experimental error. Herein, we present a comprehensive mechanistic investigation into this phenomenon that supports the existence of a novel mechanistic pathway for Pd(II)–diimine complexes. Part one of the mechanistic study lays the foundation of the proposed mechanism, in which neutral Pd(II)–diimine complexes were found to exhibit a moderate to good catalytic activity for olefin isomerization of α-olefins despite the established notion that catalyst activation is required. Extensive experimental and computational studies reveal the possibility of a partial dissociation of the diimine ligand, which frees up one coordination site and enables coordination–insertion. This finding is significant as the coexistence of two reactive coordination sites at the palladium center becomes a valid proposal for the activated cationic Pd(II)–diimine complexes. In part two, we examined and validated the simultaneously observed α-olefin isomerization and living polymerization using the cationic Pd(II)–diimine catalyst, which supports the presence of two independent reaction pathways of isomerization and polymerization, respectively. Furthermore, the addition of a strong Lewis acid, such as AlCl 3 , accelerates the ligand dissociation and the consequential isomerization as it weakens the palladium–nitrogen bond through competitive binding. In part three, Lewis acid-triggered olefin isomerization-polymerization is employed to prepare living olefinic block copolymers and further synthesize novel polyolefin-polar block copolymers with unique architectures, distinct levels of branching, crystallinity, and polar functionality in a one-pot manner.

Catalysts↗

From Theory to Large-Scale Simulations, or Living Without “The Paradox of Choice”

Navigating the challenges we face at work and in life is often difficult, and can even make us question our past decisions. This dilemma is even worse nowadays because of the many options available to us, leaving us not enough time to explore them all: the paradox of choice. My life experience offers another perspective on how to make choices; wherein I had to rely more on serendipity, coincidence, and embracing risks. This paper presents a brief description of my career path in space science—from a small village in the countryside to one of the top science Laboratories in the world—and lessons learned through the process of becoming a more resilient scientist. I came to the United States from Bulgaria about 30 years ago, seeking a better education and job opportunities. Navigating a career of research scientist, not only did I find jobs that motivated me every day, I also met amazing people to work with along the way. As a woman in science, I hope my story can inspire and attract young researchers (girls and boys alike) to our community, helping to grow and diversify the next generation of space scientists.

99 GENERAL AND MISCELLANEOUS↗

Resolving the ultracollinear paradox with effective field theory

Naive intuition about scale decoupling breaks down in the presence of fermion masses. Kinematic enhancements can greatly extend the range where one needs to keep a finite mass in calculations to obtain a correct result at even the O ( 1 ) level. Treating a light fermion as massive though, leads to a known but somewhat obscure paradox, a seeming leading-order sensitivity to an arbitrarily small mass. We show how a proper formulation in effective field theory not only resolves the physical conundrum but also answers the very practical question of when fermion masses are required. This has important implications for the development of shower Monte Carlo event generators above the weak scale. Published by the American Physical Society 2024

Astronomy & Astrophysics↗

Aharonov-bohm paradox.

Aharonov-bohm paradox involving charge particle interaction with stationary current distribution showing that vector potential term in canonical momenta expression represents electromagnetic field momentum

QUANTUM ELECTRODYNAMICS↗