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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Mapping the Path Forward to Next Generation Algal Technologies: Workshop on Understanding the Rules of Life and Complexity in Algal Systems

Algal technology offers enormous potential as a source of renewable biomass and bioproducts for fuels, biochemicals, nutrients, and numerous other applications. While tremendous opportunities exist, significant challenges are also present in harnessing and utilizing this valuable and potentially sustainable bioproduction platform. Funded by a joint partnership between the Bioenergy Technologies Office (BETO) at the Department of Energy (DOE) and the National Science Foundation (NSF), the recent virtual workshop, "Understanding the Rules of Life: Complexity in Algal Systems Workshop," was organized to bring together thought leaders from academia, national laboratories and other government agencies, and industry to identify key challenges and propose research strategies to overcome these barriers. Two parallel sessions were undertaken: 1) algae strain and toolkit development and 2) algal ecosystem and microbiome dynamics, in order to advance algae engineering and cultivation efforts. In each session, attendees discussed the most pressing challenges from the perspective of model systems and omics analysis. Themes such as genetic engineering toolboxes, translation from the laboratory to outdoor cultivation, functional genomics, metabolomics, algal ecology, consortial design, microbiome dynamics, mathematical models, and data analytics emerged from the discussion. Overall, this workshop has served to elucidate the key hurdles and many opportunities present as we continue to advance algal science and technology from the laboratory and into the commercial realm.

09 BIOMASS FUELS↗

Towards the development of a standardized testing protocol for overhead island kitchen exhaust devices: Procedures, measurements and paths forward

Cooking is one of the most important sources of airborne pollutants in the indoor environments of residential buildings. Elevated concentrations of NO 2 due to cooking have been reported widely (Garret et al. 1998; Garrett et al. 1999; Mullen et al. 2016; Ryan et al. 1988; Schwab et al. 1994; J. Spengler et al. 1994; J. D. Spengler et al. 1983; Wilson et al. 1995). Many researchers have attributed elevated particulate concentrations to cooking, and some have attributed extremely high short-term concentrations of fine particles (>300 μg/m3) and ultrafine particles (>105 μg/m3) to cooking events (Abdullahi et al. 2013; Abt et al. 2000; Afshari et al. 2005; Buonanno et al. 2009; He et al. 2004; Kearney et al. 2011; Lance A. Wallace et al. 2004; See and Balasubramanian 2008; Stieb et al. 2008; Wallace and Ott 2011; Wheeler et al. 2011; Zhang et al. 2010). Cooking is also a source of other gas-phase pollutants including carbon monoxide, formaldehyde, acrolein, and other volatile organic compounds (Garret et al. 1998; Garrett et al. 1999; Logue et al. 2013; Mullen et al. 2016; Ryan et al. 1988; Schwab et al. 1994; J. Spengler et al. 1994; J. D. Spengler et al. 1983; V. Seaman et al. 2007; Wilson et al. 1995). Lastly, cooking can be a significant source of water vapor, and the water vapor produced from cooking can eventually lead to moisture-related problems (Parrott and Emmel 2003)

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Membrane design for non-aqueous redox flow batteries: Current status and path forward

Redox flow batteries are promising technologies for large-scale, long-duration energy storage applications. Among them, non-aqueous redox flow batteries (NARFB) represent a transformative flow battery system since NARFBs potentially offer a higher energy density than aqueous flow batteries. However, many technical challenges remain for NARFBs, including the lack of high-performance membranes, low solubility of redox materials, and poor cycling efficiencies. Membranes serve a vital function in NARFBs, as they allow for selective ion transport while providing separation between the anolyte and catholyte. NARFB membrane development is an emerging research area, and this article reviews their design and critical factors that influence membrane properties, including solvent uptake, ion transport, and redox species permeability. A greater understanding of membrane behavior in non-aqueous solutions provides design principles for developing next-generation membranes for NARFB. In conclusion, we summarize the challenges, target metrics, and future perspectives for NARFBs.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Modified alkaline peroxide pretreatment: An efficient path forward for bioethanol production from bamboo

To overcome the typical delignification saturation point of alkaline peroxide pretreatment and further facilitate lignin removal, a novel modified alkaline hydrogen peroxide pretreatment (MAHP) was proposed by introducing ethanol into the reaction system. The dosages of H 2 O 2 , ethanol, and pretreatment temperature were optimized, and the results revealed that a maximum lignin removal as high as 79.25% could be achieved at only 100 °C, 3 wt% H 2 O 2 concentration and 1 wt% ethanol concentration. Meanwhile, 76.5% of glucan and 56.0% of xylan were preserved at this pretreatment condition. By overcoming the delignification saturation point, enzymatic hydrolysis efficiency was remarkably enhanced, achieving 96.76% and 97.38% of glucan and xylan conversion, respectively, which are 7.4 and 11.4 times as compared to that of the untreated bamboo. Furthermore, the simultaneous saccharification and fermentation (SSF) result indicated an identical ethanol yield of ~75% when elevating the SSF solid loading from 5% to 30%. Based on the sequential SSF and xylose fermentation results, about 5.6 tons of bamboo would be consumed to produce 1 ton of ethanol. Finally, the energy balance revealed that a positive balance of 1255.4 KJ could be generated via processing 1 kg bamboo. Here, the results demonstrate that the MAHP is a promising high-efficiency pretreatment technology for bamboo due to the mild pretreatment severity and robust ethanol yield.

30 DIRECT ENERGY CONVERSION↗

Laser-direct-drive program: Promise, challenge, and path forward

Along with laser-indirect (X-ray)-drive and magnetic-drive target concepts, laser direct drive is a viable approach to achieving ignition and gain with inertial confinement fusion. In the United States, a national program has been established to demonstrate and understand the physics of laser direct drive. The program utilizes the Omega Laser Facility to conduct implosion and coupling physics at the nominally 30-kJ scale and laser–plasma interaction and coupling physics at the MJ scale at the National Ignition Facility. This article will discuss the motivation and challenges for laser direct drive and the broad-based program presently underway in the United States.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Subscale maturation of advanced reactor technologies (SMART): A path forward for nuclear thermal propulsion fuel and reactor development

Nuclear Thermal Propulsion (NTP) systems are actively being developed for future crewed missions to Mars. NTP systems excel in missions where both high thrust and high specific impulse are required, but modern NTP systems currently do not have a Technology Readiness Level (TRL) high enough for use in crewed space exploration. TRLs are used to demonstrate the level of rigor with which a component/system has been tested/demonstrated for its intended use. While space systems technology in general must be qualified as a unit, nuclear technology must be first demonstrated to meet qualification level requirements both at the fuel (component) level and the reactor (subsystem) level. Here, in this paper, historic NTP development programs are surveyed to identify a testing and development strategy that can be effectively implemented to allow for NTP reactor development. Based on this strategy, required facilities to enable such activities are identified. Current domestic experimental capabilities to support NTP qualification are limited to separate effects testing of individual components. Separate effects testing is found extensively in historic NTP development efforts but is not sufficient for full fuel and reactor qualification. Combined effects testing allows for an accurate assessment of fuel performance but is not achievable for NTP conditions in existing facilities. Assessment of historic development programs suggests that an intermediate, subscale test facility is necessary to advance NTP TRLs. A solution to meet this need is proposed, namely the Subscale Maturation of Advanced Reactor Technologies (SMART) facility. SMART will mitigate risk to NTP development by enabling performance and reactor physics demonstrations of NTP subsystems. A SMART facility could be built by modifying existing nuclear test facilities, which may potentially enable schedule and cost savings. To pursue reactor qualification beyond the subscale, a new ground test facility will be necessary. This ground test facility should be developed concurrently with SMART to allow for the facility to be operational in time for expedited NTP engine demonstration.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Advances in vat photopolymerization: early-career researchers shine light on a path forward

Vat photopolymerization (VP) has emerged as a promising additive manufacturing technique to allow rapid light-based fabrication of 3D objects from a liquid resin. Research in the field of vat photopolymerization spans across multiple disciplines from engineering and materials science to applied chemistry and physics. This perspective brings together early-career researchers from various disciplines in academia and national laboratories around the world to summarize the most recent advancements with special emphasis on the research highlighted as part of the Gordon Research Conference (GRC) 2024 meeting on Additive Manufacturing of Soft Materials. We provide an outlook on next-generation polymer processing methods from synthesis of novel materials to multimodality manufacturing and performance engineering. Further, this article combines the ideas of many of these junior researchers to present a vision for the future of the field by highlighting the challenges and opportunities that lie ahead.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Compact and efficient elastocaloric heat pumps—Is there a path forward?

Elastocaloric cooling holds promise for energy-efficient heat pumping near room temperature with low environmental impact. Its adoption is, however, impeded by disproportionally large sizes of actuators compared with the active material volume. Taking magnetocaloric cooling as the baseline, the value of no more than 10:1 actuator volume to active material volume should lead to both size- and cost-effective solutions that may potentially be competitive with vapor-compression devices. With the goal to establish performance metrics that can lead to informed actuator selection for specific regenerator requirements, we analyze a wide range of elastocaloric materials and actuator technologies to find the best matches. We find that actuation with magnetic shape memory alloys meets all requirements; however, this technology is currently in early developmental stages and such actuators are not widely commercially available. Another promising and easily accessible option is standard rotary electric motors in combination with rotary-to-linear transduction mechanisms. A theoretical analysis of two case studies of elastocaloric systems using rotary electric motors with a Scotch yoke mechanism demonstrates the usefulness of our approach. Actuator requirements are based on two different regenerator configurations: one starting from zero strain without any mechanical energy recovery and another with 2% pre-strain and mechanical energy recovery to reduce the power and torque required from the motor. Our results indicate that the 10:1 target actuator to active material volume ratio can be met and feasibly lowered further, demonstrating that the proposed method for selecting actuators makes compact and efficient elastocaloric systems possible.

42 ENGINEERING↗

Artificial spin ice: Paths forward

Artificial spin ice systems are lithographically prepared arrays of interacting nanoscale magnetic moments with collective behavior resulting from the chosen array geometry. These many-body systems are unusual in that their simple constituent elements can be configured to design their interactions with exquisite control. They can then be probed experimentally over a remarkably large range of time scales and length scales, including imaging of the individual moments. The study of artificial spin ice has broadened well beyond the original focus on systems with connection to spin ice and ice models, and now the term is used in reference to many other structures that exhibit a much wider range of physical phenomena. Here in this perspective, we review progress in the field of artificial spin ice since its inception more than a decade ago. We then discuss prospects for future directions – continuing the exploration of nanomagnetism, statistical spin models, and the potential for technological devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Package Performance Study: A Historical Perspective and Planning for a Path Forward

The topic of spent nuclear fuel (SNF) transportation often draws public attention and concerns regarding safety, and with large-scale shipping campaigns expected in the future, public interest is anticipated to substantially increase. In 1999, the U.S. Nuclear Regulatory Commission (NRC) began an initiative called the Package Performance Study (PPS) that initially focused on SNF transportation cask responses to severe transportation accidents. A public participation approach was to be used to help guide the scope and parameters of the study, which was also to consider using full-scale physical testing of a SNF transportation cask, where appropriate. In 2010, the NRC decided not to go forward with physical testing as proposed. In 2006, the National Academy of Sciences (NAS) conducted a study on SNF and high-level radioactive waste transportation in the United States. The NAS study recommended that full-scale cask testing, as well as other accepted methodologies, continue to be used as part of the package performance evaluation. In 2012, the Blue Ribbon Commission on America’s Nuclear Future (BRC) recommended conducting the PPS with a full-scale rail transportation cask for the purpose of building public trust and confidence in the safety of SNF transport. In 2021, the U.S. Department of Energy (DOE) restarted a consent-based siting process, focusing on how to site federal facilities for the interim consolidated storage of SNF using a consent-based approach. Large-scale SNF transportation would be necessary for any such interim storage facility. As the planning activities begin for future large-scale shipping campaigns, the DOE is considering options for conducting a DOE-led PPS to help build public trust and confidence in the transportation of SNF. Therefore, the DOE is gathering information related to the previous NRC-led PPS efforts, as well as applicable international experience with the testing of SNF packages. This paper discusses previous NRC efforts, as well as the current status of a DOE-led PPS, which is in the early planning stages.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hydrodynamic instabilities and mix studies on NIF: predictions, observations, and a path forward

The goals of the Mix Campaign are to determine how mix affects performance, locate the "mix cliff", locate the source of the mix, and develop mitigation methods that allow performance to be increased. We have used several different drive pulse shapes and capsule designs in the Mix Campaign, to understand sensitivity to drive peak power, level of coast, rise time to peak power, adiabat, and dopant level in the capsule. Ablator material mixing into the hot spot has been shown conclusively with x-ray spectroscopy. The observed neutron yield drops steeply when the hot spot mix mass becomes too large. The mix appears to be driven by ablation- front Rayleigh-Taylor instabilities. A high foot, higher adiabat drive has a more stable ablation front and has allowed the mix mass in the hot spot to be reduced significantly. We found two recent high foot shots achieved neutron yields > 10 15 and measured neutron yield over clean 1D simulation (YOC) > 50%, which was one of the central goals of the Mix Campaign.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

EVOLUTION OF SPACE REACTOR QUALIFICATION METHODS AND A PATH FORWARD FOR NEW SPACE REACTORS UNDER CONSIDERATION

These slides outline the evolution of space reactor system qualifications and provide a potential framework for qualification of current space reactor concepts. Qualification approaches for SNAP 10A, SP-100, TOPAZ II, and Prometheus reactor systems will be discussed. Several qualification approaches from past reactors will be reviewed including: a component qualification approach demonstrated in the SNAP reactor program, a system level approach in the SP-100 program, adding additional features to an existing design in the TOPAZ program, and a combination of a computational and basic testing approach for the Prometheus reactor. Past and present test facilities will also be discussed and the impact of test facility availability (or existence) is discussed. A suggested approach that complies with the updated Presidential Directive (NSPM-20, August 2019) that is derived from previous program approaches will be discussed for qualification of future space reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Running Ensemble Workflows at Extreme Scale: Lessons Learned and Path Forward

The ever-increasing volumes of scientific data combined with sophisticated techniques for extracting information from them have led to the increasing popularity of ensemble workflows which are a collection of runs of individual workflows. A traditional approach followed by scientists to run ensembles is to rely on simple scripts to execute different runs and manage resources. This approach is not scalable and is error-prone, thereby motivating the development of workflow management systems that specialize in executing ensembles on HPC clusters. However, when the size of both the ensemble and the target system reach extreme scales, existing workflow management systems face new challenges that hamper their efficient execution. In this paper, we describe our experience scaling an ensemble workflow from the computational biology domain from the early design stages to the execution at extreme scale on Summit, a leadership class supercomputer at the Oak Ridge National Laboratory. We discuss challenges that arise when scaling ensembles to several million runs on thousands of HPC nodes. We identify challenges with composition of the ensemble itself, its execution at large scale, post-processing of the generated data, and scalability of the file system. Based on the experience acquired, we develop a generic vision of the capabilities and abstractions to add to existing workflow management systems to enable the execution of ensemble workflows at extreme scales. We believe that the understanding of these fundamental challenges will help application teams along with workflow system developers with designing the next generation of infrastructure for composing and executing extreme-scale ensemble workflows.

Mehta, Kshitij↗

Tritium Control and Capture in Salt-Cooled Fission and Fusion Reactors: Status, Challenges, and Path Forward

Three advanced nuclear power systems use liquid salt coolants that generate tritium and thus face the common challenges of containing and capturing tritium to prevent its release to the environment. The fluoride salt–cooled high-temperature reactor (FHR) uses clean fluoride salt coolants and the same graphite-matrix coated-particle fuel as high-temperature gas-cooled reactors. Molten salt reactors (MSRs) dissolve the fuel in a fluoride or chloride salt with release of fission product tritium into the salt. In most FHR and MSR systems, the baseline salts contain lithium where isotopically separated 7 Li is proposed to minimize tritium production from neutron interactions with the salt. The Chinese Academy of Sciences plans to start operation of a 2-MW(thermal) molten salt test reactor by 2020. For high-magnetic-field fusion machines, the use of lithium enriched in 6 Li is proposed to maximize tritium generation—the fuel for a fusion machine. Advances in superconductors that enable higher power densities may require the use of molten lithium salts for fusion blankets and as coolants. Recent technical advances in these three reactor classes have resulted in increased government and private interest and the beginning of a coordinated effort to address the tritium control challenges in 700°C liquid salt systems. In this paper, we describe characteristics of salt-cooled fission and fusion machines, the basis for growing interest in these technologies, tritium generation in molten salts, the environment for tritium capture, models for high-temperature tritium transport in salt systems, alternative strategies for tritium control, and ongoing experimental work. Several methods to control tritium appear viable. Finally, limited experimental data are the primary constraint for designing efficient cost-effective methods of tritium control.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

lmprovements and Path Forward for Regulatory Acceptance of SAS4A/SASSYS-1

In the U.S., a key component of the commercialization of advanced reactors is completion of a license application, which must ultimately be approved by the Nuclear Regulatory Commission (NRC). The NRC’s approval of the license application is contingent on, among other things, satisfactory demonstration of the design basis and response to transient and accident scenarios using accepted codes and methods. This effort seeks to improve the regulatory acceptability of the SAS4A/SASSYS-1 advanced reactor design and safety analysis system software by identifying and addressing gaps in the SAS4A/SASSYS-1 documentation basis that support software qualification and dedication. The software’s unique capabilities to assess inherent fast spectrum feedback effects and passive safety features, which facilitate assessment of key safety metrics, position it as a key licensing tool in the field of sodium-cooled fast reactors (SFR).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

A Proposed Path Forward for Transportation of High-Assay Low-Enriched Uranium

Many of the advanced reactors that are being designed will use high-assay low-enriched uranium (HALEU) as the reactor fuel. HALEU is fuel that is enriched between 5% – 20% uranium-235. With the change to higher enriched material, the industry will have new challenges with the development and regulatory approval of enrichment and fuel fabrication facilities and suitable transportation packages to support the economic use of HALEU materials. One area of concern relates to ensure sub-criticality of the material during transportation as identified by the Nuclear Energy Institute (NEI). To evaluate the relevant work, experts, and industry perspectives on HALEU, a workshop was organized to share relevant experience and insights into HALEU transportation, handling, and management. At the August 30 and 31, 2018 workshop, NEI and industry provided the following recommendations to DOE and the national lab complex. 1. DOE and the lab complex should communicate and educate the Nuclear Regulatory Commission (NRC) on criticality issues related to HALEU. 2. Idaho National Laboratory (INL) should support work needed to certify package design for the transportation of HALEU. a. Suggest amending the Certificate of Compliance of an existing package used for the shipment of commercial quantities. b. Suggest DOE provide funding to package designer(s) for analysis and engineering work for a package to be submitted to NRC for approval. 3. INL should provide specific, or a range, of the expected impurities that will be present in recycled naval fuel. 4. In the longer term, DOE and the lab complex should increase the availability of criticality benchmark data to further reduce conservatism in package design. In addition, a couple key takeaways were identified, including: 1. Although the labs can provide additional criticality experiments, industry has enough data to license facilities, overpacks, and cylinders. Validation from additional critical experiments to establish less uncertainty in the benchmarks will be helpful. 2. A collective effort from industry is needed to express consistency on how much information exists or is needed related to criticality. Based on interactions with industry, DOE, and national laboratories, it appears that large-volume transportation of fresh HALEU appears feasible from a criticality perspective. Specifically, an initial review of applicable criticality benchmark experiments identified numerous applicable experiments. However, a more thorough review of a realistic transportation package design is suggested. Therefore, the following next steps are proposed: 1. Evaluate a large volume package with uranium dioxide enriched to 20%. Specifically, the GNF-A NPC package was proposed as a potentially viable option. 2. Based on the results of (1), determine if additional package designs and fuel material should be evaluated. 3. Based on the results of (1), determine if additional criticality experiments would be beneficial to improve the margins for criticality due to uncertainties. 4. Determine DOE transportation needs (packages sizes, shielding requirements, handling/operational requirements, and timing of availability) related to HALEU. 5. Continue to interface with NEI and interested industry companies to determine the appropriate time to engage the NRC.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗