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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

The Cabauw Intercomparison Campaign for Nitrogen Dioxide Measuring Instruments (CINDI): Design, Execution, and Early Results

From June to July 2009 more than thirty different in-situ and remote sensing instruments from all over the world participated in the Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI). The campaign took place at KNMI's Cabauw Experimental Site for Atmospheric Research (CESAR) in the Netherlands. Its main objectives were to determine the accuracy of state-ofthe- art ground-based measurement techniques for the detection of atmospheric nitrogen dioxide (both in-situ and remote sensing), and to investigate their usability in satellite data validation. The expected outcomes are recommendations regarding the operation and calibration of such instruments, retrieval settings, and observation strategies for the use in ground-based networks for air quality monitoring and satellite data validation. Twenty-four optical spectrometers participated in the campaign, of which twenty-one had the capability to scan different elevation angles consecutively, the so-called Multi-axis DOAS systems, thereby collecting vertical profile information, in particular for nitrogen dioxide and aerosol. Various in-situ samplers and lidar instruments simultaneously characterized the variability of atmospheric trace gases and the physical properties of aerosol particles. A large data set of continuous measurements of these atmospheric constituents has been collected under various meteorological conditions and air pollution levels. Together with the permanent measurement capability at the CESAR site characterizing the meteorological state of the atmosphere, the CINDI campaign provided a comprehensive observational data set of atmospheric constituents in a highly polluted region of the world during summertime. First detailed comparisons performed with the CINDI data show that slant column measurements of NO2, O4 and HCHO with MAX-DOAS agree within 5 to 15%, vertical profiles of NO2 derived from several independent instruments agree within 25% of one another, and MAX-DOAS aerosol optical thickness agrees within 20-30% with AERONET data. For the in-situ NO2 instrument using a molybdenum converter, a bias was found as large as 5 ppbv during day time, when compared to the other in-situ instruments using photolytic converters.

Atmospheric composition↗
NASA NTRS2008

Sensor-Web Operations Explorer

Understanding the atmospheric state and its impact on air quality requires observations of trace gases, aerosols, clouds, and physical parameters across temporal and spatial scales that range from minutes to days and from meters to more than 10,000 kilometers. Observations include continuous local monitoring for particle formation; field campaigns for emissions, local transport, and chemistry; and periodic global measurements for continental transport and chemistry. Understanding includes global data assimilation framework capable of hierarchical coupling, dynamic integration of chemical data and atmospheric models, and feedback loops between models and observations. The objective of the sensor-web system is to observe trace gases, aerosols, clouds, and physical parameters, an integrated observation infrastructure composed of space-borne, air-borne, and in-situ sensors will be simulated based on their measurement physics properties. The objective of the sensor-web operation is to optimally plan for heterogeneous multiple sensors, the sampling strategies will be explored and science impact will be analyzed based on comprehensive modeling of atmospheric phenomena including convection, transport, and chemical process. Topics include system architecture, software architecture, hardware architecture, process flow, technology infusion, challenges, and future direction.

observation↗
NASA NTRS2002

WIND Validation Cases: Computational Study of Thermally-perfect Gases

The ability of the WIND Navier-Stokes code to predict the physics of multi-species gases is investigated in support of future high-speed, high-temperature propulsion applications relevant to NASA's Space Transportation efforts. Three benchmark cases are investigated to evaluate the capability of the WIND chemistry model to accurately predict the aerodynamics of multi-species chemically non-reacting (frozen) gases. Case 1 represents turbulent mixing of sonic hydrogen and supersonic vitiated air. Case 2 consists of heated and unheated round supersonic jet exiting to ambient. Case 3 represents 2-D flow through a converging-diverging Mach 2 nozzle. For Case 1, the WIND results agree fairly well with experimental results and that significant mixing occurs downstream of the hydrogen injection point. For Case 2, the results show that the Wilke and Sutherland viscosity laws gave similar results, and the available SST turbulence model does not predict round supersonic nozzle flows accurately. For Case 3, results show that experimental, frozen, and 1-D gas results agree fairly well, and that frozen, homogeneous, multi-species gas calculations can be approximated by running in perfect gas mode while specifying the mixture gas constant and Ratio of Specific Heats.

DalBello, Teryn↗
NASA NTRS1982

Importance of heterogeneous processes to tropospheric chemistry - Studies with a one-dimensional model

A one-dimensional, time-dependent model of tropospheric air composition is developed which incorporates several heterogeneous physical and chemical processes. The model includes the interaction of gases, aerosols, and hydrometeors through the physical mechanisms of nucleation, condensation, evaporation, coagulation, coalescence, and deliquescence. Precipitation, sedimentation, and dry deposition act to remove material from the atmosphere, while chemical transformations occur both in the vapor and the condensed phases. The model also incorporates the sources and vertical diffusion of gases and particles, as well as changes in the solar intensity caused by light-scattering from aerosols and clouds. Preliminary simulations made using this model indicate that rainout and washout processes strongly influence the distributions of tropospheric gases and aerosols under certain conditions.

Turco, R. P.↗
NASA NTRS1981

Momentum and energy exchange collision terms for interpenetrating bi-Maxwellian gases

For application to aeronomy and space physics problems involving strongly magnetized plasma flows, we derived momentum and energy exchange collision terms for interpenetrating bi-Maxwellian gases. Collision terms were derived for Coulomb, Maxwell molecule, and constant collision cross-section interaction potentials. The collision terms are valid for arbitrary flow velocity differences and temperature differences between the interacting gases as well as for arbitrary temperature anisotropies. The collision terms had to be evaluated numerically and the appropriate coefficients are presented in tables. However, the collision terms were also fitted with simplified expressions, the accuracy of which depends on both the interaction potential and the temperature anisotropy. In addition, we derived the closed set of transport equations that are associated with the momentum and energy collision terms.

Barakat, A. R.↗
NASA NTRS1977

Galatry profile convolved with the Fabry-Perot instrument function

The physical conditions in laboratory gases and in the upper atmosphere of the planets, including earth, can be deduced from a measurement of the intensity and line profile of different radiating molecules. Because of the low pressures in the upper atmospheres, many molecular lines with small pressure-broadening coefficients are collisionally narrowed. These lines are resolvable with a Fabry-Perot interferometer. Analytical expressions are given relating the measured line intensity and profile to the true line intensity and profile. A deconvolution of the measured profile gives the parameters A, beta, and K characterizing the collisionally narrowed Galatry profile. General expressions for the nonideal interferometer are discussed, and, specifically, mirror defects and a limited detector aperture are treated.

Goorvitch, D.↗
NASA NTRS1981

Effect of type of explosives and physical-mechanical properties of explosive rock on formation of toxic gases in atmosphere of shafts

The quality of toxic gases formed during explosive work in underground shafts depends upon the type of explosives and the conditions of explosion. Several types of explosives and rocks were examined. All remaining conditions were maintained the same (sandy-argillaceous stemming, electrical method of explosions, diameter of blast holes, and the direct triggering of charges).

Mindeli, E. O.↗
NASA NTRS2006

Is Q for Quantum? From Quantum Mechanics to Formation of the Solar System

The realization in 1985 that fullerenes exist in nature [1] as a third form of carbon-carbon clustering, continues to inspire new areas of research. In particular, the study of closed-cage endohedral fullerenes [2-6] is of scientific interest because of its potential application in a number of promising fields from medical imaging to astrophysics. One of these is to provide a possible chronometer for studying the age and origin of certain astromaterials in the solar system. Fullerenes are closed carbon cages that are fundamentally related to a long-standing debate over the "Q-Phase" origin of planetary noble gases in carbonaceous chondrites [7]. Although Q-phase has been identified as the carrier of planetary noble gases [8- 10], its physical nature has not been explained. Our limited understanding of it is based primarily on the laboratory chemical processing which it survives as well as the fact that it must have been widely distributed in the solar nebula [11]. Yet as important as it might be while preoccupying some 30 years of research, the question of what actually is Q-phase remains unresolved.

Wilson, T. L.↗
NASA NTRS2009

Identifying the Molecular Origin of Global Warming

We have investigated the physical characteristics of greenhouse gases (GHGs) to assess which properties are most important in determining the efficiency of a GHG. Chlorofluorcarbons (CFCs), hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), nitrogen fluorides, and various other known atmospheric trace molecules have been included in this study. Compounds containing the halogens F or Cl have in common very polar X-F or X-Cl bonds, particularly the X-F bonds. It is shown that as more F atoms bond to the same central atom, the bond dipoles become larger as a result of the central atom becoming more positive. This leads to a linear increase in the total or integrated XF bond dipole derivatives for the molecule, which leads to a non-linear (quadratic) increase in infrared (IR) intensity. Moreover, virtually all of the X-F bond stretches occur in the atmospheric IR window as opposed to X-H stretches, which do not occur in the atmospheric window. It is concluded that molecules possessing several F atoms will always have a large radiative forcing parameter in the calculation of their global warming potential. Some of the implications for global warming and climate change are discussed.

Bera, Partha P.↗
NASA NTRS2020

Line shape parameters of PH3 transitions: Theoretical studies of self-broadened widths and line mixing effects

Line mixing effects have been calculated in various parallel and perpendicular bands of self-broadened PH3 lines and compared with recent experimental data. The theoretical approach is an extension to symmetric tops with high inversion barrier of the formalism previously developed for NH3 [Q. Ma and C. Boulet, J. Chem. Phys. 144, 224303 (2016)]. The model takes into account the non-diagonality of the scattering operator within the line space as well as, in a correct way, the double degeneracy of the j, k levels when k ≠ 0. Transitions between such levels should be considered as doublets whose components may be coupled by the line mixing process. It has been shown that, at low pressure, the inversion of the experimental data will strongly depend on the splitting between the two components of a doublet. When it is significant, one can measure independently both the width of one component and the intra-doublet coupling matrix element. Otherwise, one can only measure the sum of these two elements. Comparisons with measurements show that the present formalism leads to accurate predictions of the experimental line shapes.

Remote sensing↗
NASA NTRS1974

Application of wave mechanics theory to fluid dynamics problems: Fundamentals

The application of the basic formalistic elements of wave mechanics theory is discussed. The theory is used to describe the physical phenomena on the microscopic level, the fluid dynamics of gases and liquids, and the analysis of physical phenomena on the macroscopic (visually observable) level. The practical advantages of relating the two fields of wave mechanics and fluid mechanics through the use of the Schroedinger equation constitute the approach to this relationship. Some of the subjects include: (1) fundamental aspects of wave mechanics theory, (2) laminarity of flow, (3) velocity potential, (4) disturbances in fluids, (5) introductory elements of the bifurcation theory, and (6) physiological aspects in fluid dynamics.

Krzywoblocki, M. Z. V.↗
NASA NTRS2011

Physical Properties and Seasonal Behavior of H2O, HDO, CO2 and Trace Gases on Mars: Quantitative Mapping from Earth-Based Observatories

Since 1997, we have used high-resolution (R greater than 40000) spectrometers on ground based-telescopes to study molecules that have astrobiological significance in Mars' atmosphere. We have used the NASA-IRTF, Keck II, and VLT telescopes in the 1.0-5.0 micron range. The spectrometer is set at a wavelength to detect specific molecules. Spectral/spatial images are produced. Extracts from these images provide column densities centered at latitude/longitude locations (resolution ~400km at sub-Earth point). We have mapped the O2 singlet-Delta emission (a proxy for ozone), HDO, and H2O for seasonal dates throughout the Martian year. Previously undiscovered isotopic bands of CO2 have been identified along with isotopic forms of CO. We are searching for other molecules that have astrobiological importance and have successfully measured methane in Mars' atmosphere.

Novak, Robert E.↗
NASA NTRS1994

Recycling of volatiles at subduction zones: Noble gas evidence from the Tabar-Lihir-Tanga-Feni arc of papua New Guinea

Convergent margin processes play an important but poorly understood role in the distribution of terrestrial volatile species. For example, subduction processes filter volatiles from the subducting package, thereby restricting their return to the mantle. In addition, once extracted from the downgoing slab, volatiles become an essential component in the petrogenesis of island arc magmas. The noble gases, with their systematic variation in physical properties and diversity of radiogenic isotopes, should carry a uniquely valuable record of these processes. However, thus far studies of noble gases in arc volcanics have achieved only limited success in this regard. Subduction-related lavas and geothermal fluids carry (3)He/(4)He ratios equal to or slightly lower than those found in the depleted upper mantle source of mid-ocean ridge basalts. Apparently slab-derived helium (which should have (3)He/(4)He much less than MORB) is extensively diluted by MORB-like helium from the mantle wedge, making it difficult to use helium as a tracer of convergent margin processes. Interpretation of the heavier noble gases (Ne-Ar-Kr-Xe) in arc lavas has also proven difficult, because the lavas carry low noble gas concentrations and hence are subject to pervasive atmospheric contamination. The low noble gas concentrations may be a consequence of degassing in the high level magma chambers characteristic of arc stratovolcanos. We have recently initiated a project to better constrain the behavior of volatiles in subduction zones through geochemical studies of the tectonically unusual volcanoes of the Tabar-Lihir-Tanga-Feni (TLTF) arc in the Bismarck Archipelago, Papua New Guinea.

Farley, Kenneth↗
NASA NTRS1976

Infrared band absorptance correlations and applications to nongray radiation

Various mathematical models for infrared radiation absorption spectra for atmospheric gases are reviewed, and continuous correlations for the total absorptance of a wide band are presented. Different band absorptance correlations were employed in two physically realistic problems (radiative transfer in gases with internal heat source, and heat transfer in laminar flow of absorbing-emitting gases between parallel plates) to study their influence on final radiative transfer results. This information will be applied to the study of atmospheric pollutants by infrared radiation measurement.

Tiwari, S. N.↗
NASA NTRS1987

Current issues in atmospheric change

In response to questions about the effects of long-term, global-scale changes in the atmosphere raised in congressional hearings, a group of leading experts held a two-day workshop to survey the state of current knowledge about atmospheric changes and their implications. The review focuses on the sources, concentrations, and changes of those gases most directly linked to human activities, i.e., carbon dioxide, ozone, and the chlorofluorocarbons; the direct physical effects of rising concentrations of trace gases. The review discusses the uncertainties associated with the knowledge of current trends and possible future changes, including ozone trends and the Antarctic ozone hole, and the impacts of rising concentrations of trace gases.

Source record↗
NASA NTRS2014

Mass Dependency of Isotope Fractionation of Gases Under Thermal Gradient and Its Possible Implications for Planetary Atmosphere Escaping Process

Physical processes that unmix elements/isotopes of gas molecules involve phase changes, diffusion (chemical or thermal), effusion and gravitational settling. Some of those play significant roles for the evolution of chemical and isotopic compositions of gases in planetary bodies which lead to better understanding of surface paleoclimatic conditions, e.g. gas bubbles in Antarctic ice, and planetary evolution, e.g. the solar-wind erosion induced gas escaping from exosphere on terrestrial planets.. A mass dependent relationship is always expected for the kinetic isotope fractionations during these simple physical processes, according to the kinetic theory of gases by Chapman, Enskog and others [3-5]. For O-bearing (O16, -O17, -O18) molecules the alpha O-17/ alpha O-18 is expected at 0.5 to 0.515, and for S-bearing (S32,-S33. -S34, -S36) molecules, the alpha S-33/ αlpha S-34 is expected at 0.5 to 0.508, where alpha is the isotope fractionation factor associated with unmixing processes. Thus, one isotope pair is generally proxied to yield all the information for the physical history of the gases. However, we recently] reported the violation of mass law for isotope fractionation among isotope pairs of multiple isotope system during gas diffusion or convection under thermal gradient (Thermal Gradient Induced Non-Mass Dependent effect, TGI-NMD). The mechanism(s) that is responsible to such striking observation remains unanswered. In our past studies, we investigated polyatomic molecules, O2 and SF6, and we suggested that nuclear spin effect could be responsible to the observed NMD effect in a way of changing diffusion coefficients of certain molecules, owing to the fact of negligible delta S-36 anomaly for SF6.. On the other hand, our results also showed that for both diffusion and convection under thermal gradient, this NMD effect is increased by lower gas pressure, bigger temperature gradient and lower average temperature, which indicate that the nuclear spin effect may not be the significant contributor as the energies involved in the hyperfine effect are much smaller than those with molecular collisions, especially under convective conditions.

Sun, Tao↗
NASA NTRS1974

Advanced acoustic cavity technology

A series of rocket motor firings was performed in a modified linear aerospike thrust chamber with the H2/O2 propellant combination to allow determination of the physical properties of the combustion gases in acoustic cavities located in the chamber side walls. A preliminary analytical study was first conducted to define theoretically both the appropriate cavity dimensions and the combustion gas flow field adjacent to the cavity openings. During the subsequent motor firings, cavity gas temperature profiles were measured and gas samples were withdrawn from the bottom of the cavities for compositional analysis by measurement of pressure/temperature variation and gas chromatography. Data were obtained with both radially and axially oriented cavities and with and without hydrogen bleed flow through the cavities. A simplified procedure was developed for predicting gas cavity and acoustic velocity for use in acoustic cavity design analyses.

Hines, W. S.↗
NASA NTRS1975

Spacecraft high-voltage power supply construction

The design techniques, circuit components, fabrication techniques, and past experience used in successful high-voltage power supplies for spacecraft flight systems are described. A discussion of the basic physics of electrical discharges in gases is included and a design rationale for the prevention of electrical discharges is provided. Also included are typical examples of proven spacecraft high-voltage power supplies with typical specifications for design, fabrication, and testing.

Sutton, J. F.↗