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At least 37 records · Page 2

Three-dimensional measurements of plasma parameters in an inductively coupled plasma processing chamber

Inductively coupled plasmas (ICPs) are extensively used for materials processing and microelectronics fabrication. However, their electromagnetic properties have not been fully characterized. In this regard, we have performed fully three dimensional (3D), time dependent measurements of the magnetic field, electron density, and electron temperature for an ICP sustained in argon in an industrial reactor designed for plasma etching in microelectronics fabrication. These measurements were compared to modeling results. The plasma was generated using pulsed power delivered at 2 MHz by a planar coil. The magnetic field was measured using a three axis magnetic probe at 15 366 locations throughout the plasma volume during the H-mode portion of the pulse at temporal intervals of 2 ns. A swept Langmuir probe was used to measure plasma parameters at the same locations. The plasma density measurement was calibrated with line-integrated densities obtained using a 96 GHz interferometer. During a single radio frequency (RF) cycle, the 3D current density [derived from B(r→,t)]is initially maximum just below the coil and moves downward toward the center of the chamber. Isosurfaces of current are nearly symmetric toroids. The total electric field, space charge field, and inductive electric field were derived and used to calculate the dissipated power, plasma current, and Poynting flux. Computer modeling of the experiment reproduces the phase dependent behavior. Animations showing the time dependent 3D measurements are presented in the supplementary material.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Plasma Processing to Mitigate Field Emission in LCLS-II 1.3 GHz SRF Cavities

A collaboration between Fermilab, SLAC and ORNL is working to develop plasma processing for 1.3GHz TESLA shaped SRF cavities. Hydrocarbon (C x H y ) contaminations and adsorbates lower the cavity surface work function (Φ) increasing Field Emission (FE). Plasma processing removes C x H y allowing the cavity to operate at higher E acc .

43 PARTICLE ACCELERATORS↗

Crystallization kinetics of rapid spray plasma processed multiple cation perovskites in open air

Rapid Spray Plasma Processing (RSPP) is a high throughput, scalable, and open-air route toward manufacturing perovskite solar modules. The plasma exposure is dosed such that the perovskite precursor solution is cured in milliseconds using a combination of rapid heating, reactive species, and UV photons. We implemented in situ wide angle X-ray scattering (WAXS) to characterize the crystal growth in multiple cation, mixed halide perovskite thin films—Cs x (MA z FA 1-z ) 1-x Pb(Br 0.17 I 0.83 ) 3 for 0.05 ≤ x ≤ 0.25—fabricated in open air. The use of synchrotron radiation and high detector speeds resolved the formation and dissolution of a transient intermediate crystalline phase during the tens of milliseconds when the perovskite crystallized. Increasing the mole fraction of cesium and methylammonium resulted in a decrease in the intermediate phase and an increase in the average grain diameter. Increasing the cesium fraction suppressed phase segregation, as observed in photoluminescence. Calculations showed the refractive index decreased and the extinction coefficient increased with cesium fraction. Based on the rapid crystallization kinetics, RSPP perovskite films exhibit residual stress values >5× lower than spin coated films. Understanding the kinetics of perovskite formation enables the design of perovskite films with improved thermomechanical and operational stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Plasma processing of SRF cavities at Jefferson Lab: Experiment results and simulation insight

Plasma processing of superconducting radio frequency (SRF) cavities has been an active research effort at Jefferson Lab (JLab) since 2019, aimed at enhancing cavity performance by removing hydrocarbon contaminants and reducing field emission. In this experiment, processing using argon-oxygen and helium-oxygen gas mixtures to find minimum ignition power at different cavity pressure was investigated. Ongoing simulations are contributing to a better understanding of the plasma surface interactions and the fundamental physics behind the process. These simulations, combined with experimental studies, guide the optimization of key parameters such as gas type, RF power, and pressure to ignite plasma using selected higher-order mode (HOM) frequencies. This paper presents experimental data from argon-oxygen and helium-oxygen gas mixture C75 and C100 cavity plasma ignition studies, as well as simulation results for the C100-type cavity based on the COMSOL model previously applied to the C75 cavity.

Accelerator Physics↗

Plasma Processing to Reduce Field Emission in LCLS-II 1.3 GHz SRF Cavities

Plasma cleaning for LCLS-II 9-cell 1.3 GHz cavities is under study at Fermilab. Starting from ORNL method, we have developed a new technique for plasma ignition using HOMs. Plasma processing is being applied to contaminated and field emitting cavities, here are discussed the first results in terms of Q and radiation vs E measured before and after treatment. Further studies are ongoing to optimize plasma parameters and to acquire statistics on plasma cleaning effectiveness.

43 PARTICLE ACCELERATORS↗

Update on Plasma Processing R&D for LCLS-II

SRF cavities performance preservation is crucial, from vertical test to accelerator operation. Field emission is still one of the main problems to overcome and plasma cleaning has been proven successful by SNS, in cleaning field emitters and increasing the work function of Nb. A collaboration has been established between FNAL, SLAC and ORNL with the purpose of applying plasma processing to LCLS-II cavities, in order to minimize and overcome field emission without affecting the high Q of N-doped cavities. The recipe will follow the neon-oxygen active plasma adopted at SNS, allowing in-situ processing of cavities and cryomodules from hydrocarbon contaminants. A novel method for plasma ignition has been developed at FNAL: a plasma glow discharge is ignited using high order modes to overcome limitations imposed by the fundamental power coupler. The results of experiments on 9-cell LCLS-II cavity are presented, along with plasma ignition studies. In addition the RF system is shown and N-doped Nb samples studies are discussed.

43 PARTICLE ACCELERATORS↗

Open‐Air Combustion Synthesis with Rapid Plasma Processing of Large‐Area Transparent Conducting Oxides

A vacuum-free, high-throughput synthesis of indium tin oxide (ITO) via Combustion Oxidation with Rapid Plasma Processing (CORP) utilizes a solution-based exothermic combustion reaction to generate the oxide with tunable control of either amorphous or crystalline phases. A subsequent open-air, forming gas plasma treatment is used to introduce oxygen vacancies and promote crystallization. Here, the evolution of the oxide structure is elucidated by extended X-ray absorption spectroscopy fine structure analysis. Using CORP, fabrication of 300 cm 2 of ITO possessing a champion sheet resistance of 38 Ω sq. −1 , visible transmission of 89%, conductivity stability for over 250 days, roughness < 2nm, and Haacke figure of merit (%T 550nm 10 /R s ) of 0.012 Ω −1 is achieved. Cost modeling of CORP demonstrates up to a 67% reduction in price for TCOs using fully continuous, in-line unit operations compared with vacuum sputtering. The work shows a path toward a low-cost, vacuum-free manufacturing method for TCOs at commercial scales.

42 ENGINEERING↗

Rapid scalable plasma processing of thin-film Li–La–Zr–O solid-state electrolytes

Solid-state electrolytes, such as lithium lanthanum zirconium oxide (LLZO), show promise as technologies for next-generation high-energy-density batteries, but commercial development has been hindered by a lack of scalable processing methods. Current fabrication methods are costly or require long annealing steps to create dense films. We report an atmospheric pressure blown-arc nitrogen plasma jet process to rapidly form sub-micrometer-thick, dense amorphous LLZO (a-LLZO) films from sol-gel precursors. Films are processed in less than 2 min, an order of magnitude faster than what has previously been reported. We demonstrate 500-nm-thick a-LLZO films processed at 350°C with an ionic conductivity of 2 × 10 −6 S/cm at 30°C and 2 × 10 −3 S/cm at 100°C and a conductance of 19 S at 100°C, the highest conductance of any LLZO phase to date. Here, the films exhibit outstanding smooth surface morphology with low defectivity, advancing atmospheric plasma processing as a scalable processing method for solid-state electrolytes.

25 ENERGY STORAGE↗

Study of the niobium oxide structure and microscopic effect of plasma processing on the Nb surface

A study of the niobium oxide structure is presented here, focusing on the niobium suboxides. Multiple steps of argon sputtering and XPS measurements were carried out until the metal surface was exposed. Subsequently, the sample was exposed to air for different time intervals and the oxide regrowth was studied. In addition, three Nb samples prepared with different surface treatments were studied before and after being subjected to plasma processing. The scope is investigating the microscopic effect that the reactive oxygen contained in the glow discharge may have on the niobium surface. This study suggests that the Nb 2 O 5 thickness may increase. Nevertheless, since the Nb 2 O 5 is dielectric, its thickening would not negatively affect the cavity performance.

36 MATERIALS SCIENCE↗

Study of the Niobium Oxide Structure and Microscopic Effect of Plasma Processing on the Nb Surface

A study of the niobium oxide structure is presented here, focusing on the niobium suboxides. Multiple steps of argon sputtering and XPS measurements were carried out until the metal surface was exposed. Subsequently, the sample was exposed to air for different time intervals and the oxide regrowth was studied. In addition, three Nb samples prepared with different surface treatments were studied before and after being subjected to plasma processing. The scope is investigating the microscopic effect that the reactive oxygen contained in the glow discharge may have on the niobium surface. This study suggests that the Nb 2 O 5 thickness may increase. Nevertheless, since the Nb 2 O 5 is dielectric, its thickening would not negatively affect the cavity performance.

36 MATERIALS SCIENCE↗

Operando XPS for Plasma Process Monitoring: A Case Study on the Hydrogenation of Copper Oxide Confined under h-BN

Here, we demonstrate that ambient pressure x-ray photoelectron spectroscopy (APXPS) can be used for in situ studies of dynamic changes in surface chemistry in a plasma environment. This opens a new and vast application space for XPS and greatly complements modern spectroscopy techniques to probe plasma-solid/liquid interactions relevant to process monitoring in the semiconductor industry, bio-medical plasma applications and plasma remediation technologies. Hexagonal boron nitride (h-BN) grown on Cu was used in this study as a well-defined model system for plasma process monitoring and because of its unique chemical, optical and electrical properties that make it a prospective material for advanced electronics. To better understand the stability and surface chemistry of h-BN during plasma assisted processing, we track in real time the plasma-induced chemical state changes of B, N and the underlying Cu substrate using APXPS equipped with an AC discharge plasma source operating at 13 Pa. Residual gas analysis (RGA) mass-spectra were concurrently collected during plasma-XPS to track reaction products formed during plasma exposure. A clear reduction of Cu x O is seen, while an h-BN layer remains intact, suggesting hydrogen radical (H • ) species can attack the exposed and h-BN covered Cu oxide patches and partially reduce the underlying substrate without significantly damaging the overlaying h-BN, which is of practical importance for development of h-BN encapsulated devices and interfaces. In addition to demonstration of plasma-XPS capabilities we discuss the observed challenges (e.g., parasitic plasma-chamber walls reactions and charging effects) and propose potential solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Atmospheric pressure plasma processing of polymeric materials utilizing close proximity indirect exposure

A plasma treatment method that includes providing treatment chamber including an intermediate heating volume and an interior treatment volume. The interior treatment volume contains an electrode assembly for generating a plasma and the intermediate heating volume heats the interior treatment volume. A work piece is traversed through the treatment chamber. A process gas is introduced to the interior treatment volume of the treatment chamber. A plasma is formed with the electrode assembly from the process gas, wherein a reactive species of the plasma is accelerated towards the fiber tow by flow vortices produced in the interior treatment volume by the electrode assembly.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

In Situ Plasma Processing of Superconducting Cavities at Jefferson Lab

Jef­fer­son Lab began a plasma pro­cess­ing pro­gram start­ing in the spring of 2019. Plasma pro­cess­ing is a com­mon tech­nique for re­mov­ing hy­dro­car­bons from sur­faces, which in­creases the work func­tion and re­duces the sec­ondary emis­sion co­ef­fi­cient. Un­like he­lium pro­cess­ing which re­lies on ion bom­bard­ment of the field emit­ters, plasma pro­cess­ing uses free oxy­gen pro­duced in the plasma to break down the hy­dro­car­bons on the sur­face of the cav­ity. The resid­u­als of the hy­dro­car­bons in the form of water, car­bon monox­ide and car­bon diox­ide are re­moved from the cry­omod­ule as part of the process gas flow. The ini­tial focus of the ef­fort is pro­cess­ing C100 cav­i­ties by in­ject­ing RF power into the HOM cou­pler ports. We will then start in­ves­ti­gat­ing pro­cess­ing of C50 cav­i­ties by in­tro­duc­ing RF into the fun­da­men­tal power cou­pler. The plan is to start pro­cess­ing cry­omod­ules in the CEBAF tun­nel in the mid-term fu­ture, with a goal of im­prov­ing the op­er­a­tional gra­di­ents and the en­ergy mar­gin of the linacs. This work will de­scribe the sys­tems and meth­ods used at JLAB for pro­cess­ing cav­i­ties using an argon oxy­gen gas mix­ture. Be­fore and after plasma pro­cess­ing re­sults will also be pre­sented.

Powers, T.↗

Plasma Processing of SRF Cavities for the Next Generation of Particle Accelerators

What are the major goals of the project? Goal 1: Optimize interactively processing of the single-cell cavity by combining plasma treatment and vertical cold bath testing. Continue using single cell cavity as the test bed for new applications. Goal 2: Work on upgrading the plasma etching technology for multi-cell SRF cavities. Goal 3: Develop and adapt discharge configurations to critical cavity regions including the electron beam weld (EBW) and iris areas. Goal 4: Develop tailored methods to prepare surface properties for a specific function prior to any additional modification, such as (but not limited to) surface passivation in preparation of other superconducting materials and structures.

43 PARTICLE ACCELERATORS↗

Lithographically patterned metallic conduction in single-layer MoS2 via plasma processing

Tailoring the electrical transport properties of two-dimensional transition metal dichalcogenides can enable the formation of atomically thin circuits. In this work, cyclic hydrogen and oxygen plasma exposures are utilized to introduce defects and oxidize MoS 2 in a controlled manner. This results in the formation of sub-stochiometric MoO 3-x , which transforms the semiconducting behavior to metallic conduction. To demonstrate functionality, single flakes of MoS 2 were lithographically oxidized using electron beam lithography and subsequent plasma exposures. This enabled the formation of atomically thin inverters from a single flake of MoS 2 , which represents an advancement toward atomically thin circuitry.

36 MATERIALS SCIENCE↗