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Results for “Rare Isotopes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

CNO isotope production in nova outbursts

A current model of novae is presented which explains their outbursts assuming that the progenitor of a common nova is a carbon-oxygen dwarf. This white dwarf accretes H-rich material from its companion which produces strong shock waves at its surface; as the amount of accreted material increases later, its bottom ignites. The nova outburst is then triggered by CNO-Ne reactions which favor the formation of rare isotopes with proton-rich radioactive parents such as C-13, N-15, O-17, and Ne-21. The production of such nuclear species is examined in different nova models, and conclusions are drawn concerning the importance of novae in models of chemical evolution of the galaxy.

Audouze, J.↗
NASA NTRS1974

Nuclear composition of solar cosmic rays

Experimental observations of the elemental and isotopic composition of solar flare particles are discussed. Sources and characteristics of particle-emitting solar flare events are reviewed, and techniques for separating particle species are briefly described. Data are presented for the elemental composition of the solar atmosphere, and the possibility of determining the solar helium abundance from solar cosmic-ray observations is explored. The main experimental determinations of heavy element abundances at energies greater and less than 10 MeV/nucleon are summarized, and techniques for measuring the ionic charge composition of solar cosmic rays are outlined. Models explaining heavy element enhancements are described along with processes leading to gamma-ray emission during solar flare events. Observations of the rare isotopes of hydrogen and helium during solar flare events are noted, and a lower atmospheric limit is derived for nuclear reactions leading to positron decay. The possibility of investigating low-energy solar cosmic rays by measuring the relative abundances of different elements is evaluated.

Hovestadt, D.↗
NASA NTRS1980

DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2lasers

A parametric analysis of DIAL sensitivity with heterodyne detection is presented and comparisons with direct detection are discussed. Examples are given for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system. Results indicate that maximum sensitivity at minimum laser energy per measurement requires multiple pulse operation with the energy per pulse selected so that the measured photon rate is approximately equal to the detector IF bandwidth. Measurement sensitivities can be maximized and interference effects minimized by fine adjustment of measurement frequencies using the tunability of high pressure lasers. The use of rare isotope lasers minimizes loss due to CO2 atmospheric absorption.

Brockman, P.↗
NASA NTRS1981

Radio observations of molecules in the interstellar gas

Since 1968, radio astronomy has made it possible to identify nearly 50 molecules in the dense concentrations of the interstellar gas now generally termed molecular clouds. Most interstellar molecules are familiar stable compounds. However, one-fifth of the discovered species are ions, radicals, and acetylenic carbon chains so reactive in the laboratory that before being detected in space they had rarely been observed or were entirely unknown. The heavy atom backbone of the known interstellar molecules is a linear chain of C, N, O, or S. Si is found in two diatomic molecules. Rings and branched chains are missing. The most readily observed spectral lines of most interstellar molecules correspond to rotational transitions at millimeter wavelengths. These are generally excited by H2 collisions. A number of rare isotopic species are observed in interstellar molecules. Isotopic ratios differing from those on Earth exist, and can in almost all cases be attributed to stellar nucleosynthesis since the formation of the solar system.

Thaddeus, P.↗
NASA NTRS1981

Unusual properties of particle events associated with solar flare gamma ray events

An attempt to establish a link between gamma rays observed at the earth with solar flare areas highly enriched with electrons is presented. Two hour averages of the counting rates of 5-100 MeV electrons and 25-145 MeV protons performed on the ISEE-3 spacecraft were correlated with solar flares with a maximum intensity of 6-11 MeV electrons and 25-44 MeV protons recorded by other observers. The coverage was part of the Solar Maximum Mission, which attained a 50 percent coverage. Gamma ray associated events showed high ratios of electrons to protons, about 0.2, and electrons with energies greater than 80 MeV were observed, which are values high enough to produce the highest gamma rays observed, 40 MeV. The available data for electron, proton, and rare isotope fluxes and the time histories of the fluxes are noted to provide a data base for further information on solar flares and particle acceleration mechanisms.

Evenson, P.↗
NASA NTRS1983

CO2 DIAL sensitivity studies for measurements of atmospheric trace gases

An analysis is presented of the accuracy of infrared differential absorption lidar (DIAL) measurements of trace constituents in the atmosphere. Expressions are derived for the signal-to-noise ratios applicable in the detection of a signal from a scattering cell for the cases of single-detection heterodyne detection and direct detection. Results of computer simulations of the expectation value of the measured return for various measurement conditions are presented which illustrate the sensitivities of plume measurements for horizontal range-resolved and vertical content measurements of NH3 in heterodyne and direct detection. Advantages for long-range measurements of the use of rare isotope laser frequencies, tuning by collision broadening, and closely spaced on and off frequencies are pointed out.

Brockman, P.↗
NASA NTRS1985

Cosmic ray He-3 measurements

The rare isotopes H-2 and He-3 in cosmic rays are believed to be of secondary origin produced by nuclear interactions of primary H-1 and He-4 with the interstellar medium. There has recently been renewed interest in these isotopes as a result of indications from high energy antiproton, positron, and He-3 observations that the origin of some primary H and He nuclei may differ from that of heavier cosmic rays. A new observation of low energy He-3 is examined. Previously reported He-3 and He-4 measurements at both low and high energies are examined and compared with calculations of the expected He-3 and He-4 ratio at 1 AU. No evidence for an excess of low energy He-3 such as that reported at high energies was found.

Mewaldt, R. A.↗
NASA NTRS1986

Variations in the HCN/HNC abundance ratio in the Orion molecular cloud

Observations of the rare isotopes of HCN and HNC have been used to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio HCN/HNC decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. The kinetic temperature in the regions studied is determined from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways that those in the general instellar cloud material.

Goldsmith, Paul F.↗
NASA NTRS1990

LaRC-developed catalysts for CO2 lasers

Pulsed CO2 lasers have many remote sensing applications from space, airborne, and ground platforms. The NASA Laser Atmospheric Wind Sounder (LAWS) system will be designed to measure wind velocities from polar earth orbit for a period of up to three years. Accordingly, this and other applications require a closed-cycle pulsed CO2 laser which necessitates the use of an efficient CO-O2 recombination catalyst for these dissociation products which otherwise would degrade the laser operation. The required catalyst must not only operate at low temperatures but also must operate efficiently for long time periods. The research effort at NASA LaRC has centered around development and testing of CO oxidation catalysts for closed-cycle, pulsed, common and rare-isotope CO2 lasers. Researchers examined available commercial catalysts both in a laser and under simulated closed-cycle laser conditions with efforts aimed toward a thorough understanding of the fundamental catalytic reaction. These data were used to design and synthesize new catalyst compositions to better meet the catalyst requirements for closed-cycle pulsed CO2 lasers. Syntheses and test results for catalysts developed at Langley Research Center which have significantly better long-term decay characteristics than previously available catalysts and at the same time operate quite well under lower temperature conditions are discussed.

Upchurch, Billy T.↗
NASA NTRS1989

Recent advances in efficient long-life, eye-safe solid state and CO2 lasers for laser radar applications

The key problems in the development of eye-safe solid-state lasers are discussed, taking into account the energy transfer mechanisms between the complicated energy level manifolds of the Tm, Ho, Er ion dopants in hosts with decreasing crystal fields such as YAG or YLF. Optimization of energy transfer for efficient lasing through choice of dopant concentration, power density, crystal field and temperature is addressed. The tailoring of energy transfer times to provide efficient energy extraction for short pulses used in DIAL and Doppler lidar is considered. Recent advances in Pt/SnO2 oxide catalysts and other noble metal/metal oxide combinations for CO2 lasers are discussed. Emphasis is given to the dramatic effects of small quantities of H2O vapor for increasing the activity and lifetime of Pt/SnO2 catalysts and to increased lifetime operation with rare isotope (C-12)(O-18)2 lasing mixtures.

Hess, R. V.↗
NASA NTRS1990

The nu-process

As the core of a massive star collapses to form a neutron star, the flux of neutrinos in the overlying shells of heavy elements becomes so great that, despite the small cross section, substantial nuclear transmutation is induced. Neutrinos excite heavy elements and even helium to particle unbound levels. The evaporation of a single neutron or proton, and the back reaction of these nucleons on other species present, significantly alters the outcome of traditional nucleosynthesis calculations leading to a new process: nu-nucleosynthesis. Modifications to traditional hydrostatic and explosive varieties of helium, carbon, neon, oxygen, and silicon burning are considered. The results show that a large number of rare isotopes, including many of the odd-Z nuclei from boron through copper, owe much of their present abundance in nature to this process.

Woosley, S. E.↗
NASA NTRS1990

Pt/SnO2-based CO-oxidation catalysts for CO2 lasers

The activity of Pt/SnO2-based CO-oxidation catalysts has been maximized by optimizing pretreatment conditions and catalyst formulation. The role of H2O in activating these catalysts and of CO2 retention in deactivating them has been determined as has the interaction of these catalysts with rare-isotope C(0-18) and (O-18)2.

Upchurch, Billy T.↗
NASA NTRS1996

Signal Processing and Calibration of Continuous-Wave Focused CO2 Doppler Lidars for Atmospheric Backscatter Measurement

Two continuous-wave(CW)focused C02 Doppler lidars (9.1 and 10.6 micrometers) were developed for airborne in situ aerosol backscatter measurements. The complex path of reliably calibrating these systems, with different signal processors, for accurate derivation of atmospheric backscatter coefficients is documented. Lidar calibration for absolute backscatter measurement for both lidars is based on range response over the lidar sample volume, not solely at focus. Both lidars were calibrated with a new technique using well-characterized aerosols as radiometric standard targets and related to conventional hard-target calibration. A digital signal processor (DSP), a surface acoustic and spectrum analyzer and manually tuned spectrum analyzer signal analyzers were used. The DSP signals were analyzed with an innovative method of correcting for systematic noise fluctuation; the noise statistics exhibit the chi-square distribution predicted by theory. System parametric studies and detailed calibration improved the accuracy of conversion from the measured signal-to-noise ratio to absolute backscatter. The minimum backscatter sensitivity is approximately 3 x 10(exp -12)/m/sr at 9.1 micrometers and approximately 9 x 10(exp -12)/m/sr at 10.6 micrometers. Sample measurements are shown for a flight over the remote Pacific Ocean in 1990 as part of the NASA Global Backscatter Experiment (GLOBE) survey missions, the first time to our knowledge that 9.1-10.6 micrometer lidar intercomparisons were made. Measurements at 9.1 micrometers, a potential wavelength for space-based lidar remote-sensing applications, are to our knowledge the first based on the rare isotope C-12 O(2)-18 gas.

Rothermel, Jeffry↗
NASA NTRS2011

A Laboratory and Theoretical Study of Silicon Hydroxide SiOH

The rotational spectrum of the triatomic free radical SiOH in its X 2A' ground electronic state has been observed in a supersonic molecular beam by Fourier transform microwave spectroscopy. The fundamental (10,1 yields 00,0) transition has been detected for normal SiOH and for three rare isotopic species: (30)SiOH, Si(18)OH, and SiOD. The same transition has also been observed in two of three excited vibrational states, v2 and v3, for the most abundant species. Precise spectroscopic constants, including those that describe the effective spin doubling and hydrogen hyperfine structure, have been derived for each isotopic species or vibrational state. To complement the laboratory work, theoretical calculations of the structure, dipole moment, and energies of the X 2A' and low-lying 1 2A'' states have also been undertaken at the coupled cluster level of theory. In agreement with theoretical predictions, we conclude from the hyperfine constants that SiOH is a best described as a pi-type radical, with the unpaired electron localized on a p orbital on the silicon atom. Assuming a bond angle of 118.5 deg, the Si-O bond length is 1.647(2) Angstroms and the O-H bond length is 0.969(4) Angstrom.

McCarthy, M. C.↗
NASA NTRS1987

Isotope Exchange in Oxide Catalyst

Replacement technique maintains level of CO2/18 in closed-cycle CO2 lasers. High-energy, pulsed CO2 lasers using rare chemical isotopes must be operated in closed cycles to conserve gas. Rare isotopes operated in closed cycles to conserve gas. Rare isotopes as CO2/18 used for improved transmission of laser beam in atmosphere. To maintain laser power, CO2 must be regenerated, and O2 concentration kept below few tenths of percent. Conditions achieved by recombining CO and O2.

Hess, Robert V.↗
NASA NTRS2013

Oxygen Isotope Measurements of a Rare Murchison Type A CAI and Its Rim

Ca-, Al-rich inclusions (CAIs) from CV chondrites commonly show oxygen isotope heterogeneity among different mineral phases within individual inclusions reflecting the complex history of CAIs in both the solar nebula and/or parent bodies. The degree of isotopic exchange is typically mineral-specific, yielding O-16-rich spinel, hibonite and pyroxene and O-16-depleted melilite and anorthite. Recent work demonstrated large and systematic variations in oxygen isotope composition within the margin and Wark-Lovering rim of an Allende Type A CAI. These variations suggest that some CV CAIs formed from several oxygen reservoirs and may reflect transport between distinct regions of the solar nebula or varying gas composition near the proto-Sun. Oxygen isotope compositions of CAIs from other, less-altered chondrites show less intra-CAI variability and 16O-rich compositions. The record of intra-CAI oxygen isotope variability in CM chondrites, which commonly show evidence for low-temperature aqueous alteration, is less clear, in part because the most common CAIs found in CM chondrites are mineralogically simple (hibonite +/- spinel or spinel +/- pyroxene) and are composed of minerals less susceptible to O-isotopic exchange. No measurements of the oxygen isotope compositions of rims on CAIs in CM chondrites have been reported. Here, we present oxygen isotope data from a rare, Type A CAI from the Murchison meteorite, MUM-1. The data were collected from melilite, hibonite, perovskite and spinel in a traverse into the interior of the CAI and from pyroxene, melilite, anorthite, and spinel in the Wark-Lovering rim. Our objectives were to (1) document any evidence for intra-CAI oxygen isotope variability; (2) determine the isotopic composition of the rim minerals and compare their composition(s) to the CAI interior; and (3) compare the MUM-1 data to oxygen isotope zoning profiles measured from CAIs in other chondrites.

Matzel, J. E. P.↗