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Upper and lower bounds have been calculated for the energy levels of a rigid rotator in an electric field, in order to study the problems associated with the use of the partitioning method for bracketing an eigenvalue of the Schrödinger equation. Results of arbitrarily high accuracy are possible in this example.
Strengths and Stark-effect widths of the Sn I and Sn II lines prominent between 3200 and 7900 A are measured with a spectroscopic shock tube. Absolute strengths of 17 ionic lines are obtained with estimated (22-50)% accuracy and conform to appropriate quantum-mechanical sum rules. Relative transition probabilities for nine prominent neutral tin lines, normalized to radiative-lifetime data, are compared with other experiments and theoretical predictions. Parameters for Stark-effect broadening are measured over a range of plasma electron densities. Broadening data (with accuracies of 15-35%) for one neutral and ten ionic lines of tin are compared to theoretical predictions.
Stark effect on hydrogen spectral line wings
Symmetric-top molecular beam focused and dipole moment oriented in electric six-pole field via Stark effect
An agile electronically configurable optical beam steering device for use in directional free-space transmission of optical signals is described. The device design employs an array of tunable resonant transmissive modulators constructed from multi-layered stacks of electro-optically active dielectric materials. Each modulator may be individually configured to transmit an optical signal with a specific amount of phase and group velocity modulation. The resulting diffractive interactions between modulator outputs provide a method for directional optical signal transmission. Of particular focus within this presentation is the optimized design of the individual modulator. It is widely known that periodic multi-layered stacks of dielectric materials exhibit reflective and transmissive resonances as described by the stack's transmission function. If an electric field is applied normal to the stack's layers, phenomena such as the electro-optic effect and/or the quantum-confined Stark effect may be employed to change the effective refractive index within the stack. This refractive index change alters the stack's transmission function and modulates the phase and group velocity of the transmitted optical signal. By varying the parameters that describe the stack's specific construction and operation, such as number of layers within the stack, refractive indexes of stack materials, layer thicknesses, and combinations of periodic verses non-periodic layer repetitions, custom transmittance functions may be generated. The transmitted optical signal carrier frequency and bandwidth must be carefully selected to maximize transmission and to minimize absorption. A computational optimization of the variables describing the stack's construction strives to maximize the amount of optical signal modulation verses applied voltage. Trade-offs between methods of increasing device performance verses the limitations of fabrication technologies are considered.
Electric field measuring methods, showing Stark effect in rotational spectra of gases as most promising
Stark effect /broadening/ on high balmer series lines emitted by solar flares
Differential Stark effect in second excited state of alkali metal atoms described, using electric field level crossing spectroscopy
Procedure to replace electron correlation effects with Debye shielded interaction including classical path broadening functions for Stark effects
The evolution of the field entropy in the two-photon JCM in the presence of the Stark shift is investigated, and the effects of the dynamic Stark shift on the evolution of the field entropy and entanglement between the atom and field, are examined. The results show that the dynamic Stark shift plays an important role in the evolution of the field entropy in two-photon processes.
Broadening of H alpha and H beta lines due to intrinsic pressure and Stark effect
Some theories of solar flares predict strong electric fields during the pre-flare energy buildup. These might well be observable with existing techniques by measuring the linear polarization in spectral lines that are split due to the Stark effect.
An optoacoustic detector for gas analysis is implemented with Stark effect cell modulation for switching a beam in and out of coincidence with a spectral line of a constituent gas in order to eliminate the heating effect of laser energy in the cell as a source of background noise. By using a multiline laser, and linearly sweeping the DC bias voltage while exciting the cell with a multiline laser, it is possible to obtain a spectrum from which to determine the combinations of excited constituents and determine their concentrations in parts per million.
Active Q switching in a GaAs/AlGaAs multiquantum well laser with an intracavity electroabsorption monolithic loss modulator is demonstrated. In this device, an efficient loss modulation is achieved through the quantum confined Stark effect in a modulator section and the enhanced carrier induced band shrinkage effect in an optical amplifier section. It is found that a picosecond pulse as narrow as 18.6 ps full width at half-maximum is generated and a high repetition rate of more than 3 GHz is obtained.
The electron density was determined for a number of quiescent prominences at various positions from the Stark effect. It was found that the intensity ratio of Mg I emission lines to SrII lines is independent of the observed electron density in the range of ten to the 10.2 power to 10 to the 11.4 power cm-3. This contrasts with Landman's (1984) theoretical expectation that the ratio is proportional to the electron density. From the intensity of Balmer lines and the electron density, it is inferred that the true diameter of a thread in prominence of high electron density may be smaller than 0.2". The averaged total number density of hydrogen N sub H sub of was found to be 3-6 times 10 to the 11th power cm-3, leading to a total gas pressure P =0.6 dyn cm-2 and a total density of approx. 10 to the minus twelth power g cm-3. Landman's large value of N sub H approx. 6 times 10 to the 12th power and P sub g approx. 6 may have resulted either from the fact that he has treated very bright prominences and/or from the derivation of the high electron density for all prominences he studied.
High-speed (1 Gbit/x) dual-wavelength demultiplexing and detection in a monolithic linear array of superlattice p-i-n photodetectors in a waveguide configuration is demonstrated. A crosstalk attenuation of 28 dB was achieved between two digital transmission channels with an interchannel wavelength spacing of 30 nm. The device performance is a result of an enhanced electroabsorption due to the quantum-confined Stark effect in the superlattice p-i-n diodes.
The microwave spectra of five isotopic species of bicyclo (1.1.1) pentanone have been investigated. The rotational constants along with various centrifugal distortion constants for each species have been determined. From the rotational constants, a complete r(s) structure has been determined for the heavy atoms. Analysis of Stark effect measurements has shown the dipole moment to be along the a principal inertial axis with a magnitude of 3.164 (5) D. These results are compared with those obtained by four current theoretical methods: molecular mechanics (MM2), MNDO, and Hartree-Fock ab initio theory with STO-3G and 3-21G basis sets.
The permanent electric dipole moments for the X 5Pi and B 5pi states of gas-phase CrO have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 + or - 0.13 and 4.1 + or - 1.8 D for the X and B states, respectively. The theoretical values determined for the X state using multireference CI iterative-natural-orbital and finite-field calculations are in excellent agreement with the experimental value.