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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Stratospheric N2O5 profiles at sunrise and sunset from further analysis of the ATMOS/Spacelab 3 solar spectra

Data obtained by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment during the Spacelab 3 (SL3) mission (April 29 to May 6, 1985) indicated the presence of N2O5 in the stratosphere. This paper presents additional analyses of the ATMOS/SL3 spectra carried out to obtain quantitative information on stratospheric N2O5. Results of this analysis include the detection and measurement of weak N2O5 absorption at sunset in the lower stratosphere, the inversion of a precise (about 10 percent) N2O5 sunrise vertical distribution between 25.5 and 37.5 km altitude, and the identification and measurement of absorption by the N2O5 743/cm band at sunrise. Results confirm model predictions that not all of the N2O5 is photodissociated during the day, except in polar regions during the extended daylight of summer.

Rinsland, C. P.↗
NASA NTRS1990

The sunrise and sunset variation of ClO in the lower stratosphere

The abundances of ClO have been measured, in situ, in the lower stratosphere during sunrise and sunset. Measurements were made with an instrument mounted on the NASA ER-2 aircraft, which was flown at an altitude of 20 km and latitudes between 35 and 47 deg N during a morning and an evening flight. The abundances of ClO were observed over a dynamic range of 20 from a detection threshold of 1 part per trillion volume (pptv). These data confirm the sunrise variation of the photolysis of chlorine nitrate that is predicted by a zero-dimensional photochemical model. They also suggest that the absolute photolysis and termolecular formation of chlorine nitrate occur at rates consistent with nominal ClONO2 and NO2 concentrations.

Brune, W. H.↗
NASA NTRS1994

An examination of global variations of sunset NO2 as measured by SAGE II

Global variations of sunset NO2 are examined for the period October 24, 1984 through May 28, 1991 using Stratospheric Aerosol and Gas Experiment (SAGE) II data. Between 60 deg S and 60 deg N declining trends are observed at all latitudes and at all altitudes above 25 km. For the column NO2 above 25 km, the area-weighted integrated trend between these latitudes is -2.5%/year. The largest rates of decline (5%/year) are at mid to high latitudes in each hemisphere. Different temporal behavior is observed with latitude and in the two hemispheres. The largest percentage changes of NO2 from year to year are observed near 40 km at high latitudes and can be as large as 160%. These results and previously reported simulations suggest that a modulating polar source of NO(y) and variations in atmospheric temperature and advective transport both contribute to the observed NO2 variations.

Callis, L. B.↗
NASA NTRS2018

Synoptic Ozone, Cloud Reflectivity, and Erythemal Irradiance from Sunrise to Sunset for the Whole Earth as Viewed by the DSCOVR Spacecraft from the Earth-Sun Lagrange 1 Orbit

EPIC (Earth Polychromatic Imaging Camera) on board the DSCOVR (Deep Space Climate Observatory) spacecraft is the first earth science instrument located near the earth-sun gravitational plus centrifugal force balance point, Lagrange 1. EPIC measures earth-reflected radiances in 10 wavelength channels ranging from 317.5 to 779.5 nm. Of these channels, four are in the UV range 317.5, 325, 340, and 388 nm, which are used to retrieve O3, 388 nm scene reflectivity (LER: Lambert equivalent reflectivity), SO2, and aerosol properties. These new synoptic quantities are retrieved for the entire sunlit globe from sunrise to sunset multiple times per day as the earth rotates in EPIC's field of view. Retrieved ozone amounts agree with ground-based measurements and satellite data to within 3 %. The ozone amounts and LER are combined to derive the erythemal irradiance for the earth's entire sunlit surface at a nadir resolution of 1818 km2 using a computationally efficient approximation to a radiative transfer calculation of irradiance. The results show very high summertime values of the UV index (UVI) in the Andes and Himalayas (greater than 18), and high values of UVI near the Equator at equinox.

Cloud reflectivity↗
NASA NTRS1986

Direct computation of orbital sunrise or sunset event parameters

An analytical method is developed for determining the geometrical parameters which are needed to describe the viewing angles of the Sun relative to an orbiting spacecraft when the Sun rises or sets with respect to the spacecraft. These equations are rigorous and are frequently used for parametric studies relative to mission planning and for determining instrument parameters. The text is wholly self-contained in that no external reference to ephemerides or other astronomical tables is needed. Equations are presented which allow the computation of Greenwich sidereal time and right ascension and declination of the Sun generally to within a few seconds of arc, or a few tenths of a second in time.

Buglia, J. J.↗
NASA NTRS1994

Infrared Astronomy with Arrays: The Next Generation; Sunset Village, Los Angeles, CA, Oct. 1993

Conference papers on infrared array techniques and methods for infrared astronomy are presented. Topics covered include the following: infrared telescopes; infrared spectrometers; spaceborne astronomy; astronomical observatories; infrared cameras; imaging techniques; sky surveys; infrared photography; infrared photometry; infrared spectroscopy; equipment specifications; data processing and analysis; control systems; cryogenic equipment; adaptive optics; image resolution; infrared detector materials; and focal plane arrays.

Mclean, Ian S.↗
NASA NTRS1996

The 1988 Arctic Survey, Diurnal Study (Sunrise and Sunset) and Peak Altitude (22 km) Flights for the In Situ Detection of ClO and BrO from the NASA ER-2 Aircraft

Two critical areas of research were addressed successfully by this research. The first involves NASA ER-2 airborne observations of ClO and BrO radical destruction of ozone within the arctic vortex. The second involves the analysis of diurnal variations in ClO, to test the production and loss rates of ClO that constitutes the test for coupling reactions between the chlorine and nitrogen systems. We discuss results from this research in order.

Anderson, James G.↗
NASA NTRS1978

Identification of the nu-2 vibration-rotation band of ammonia in ground level solar spectra

Comparison of infrared solar spectra in the 750 to 950 kayser region obtained during sunrise and sunset shows that a number of features due to the nu-2 NH3 band are present on the sunset spectra but are indicated by only a trace on the sunrise spectra. The sunset path shows approximately 0.007 atm-cm NH3, and the reason for the discrepancy between sunrise and sunset spectra is not known. The ground-based measurements at Denver were obtained with a 0.06 kayser resolution.

Murcray, D. G.↗
NASA NTRS1991

Spectroscopic measurement of HO2, H2O2, and OH in the stratosphere

Stratospheric concentrations of HO2, H2O2, and OH have been retrieved simultaneously from the far-infrared emission spectra obtained with a balloon-borne Fourier transform spectrometer in June 1983 at 32 deg N latitude. Retrieved concentrations of HO2 and H2O2 are reported, along with vertical distributions of OH which were reported in an earlier paper for the afternoon, sunset, and nighttime periods for altitudes from 26 to 38 km. HO2 distributions are obtained with uncertainties that are about the same as OH for the same vertical range and for the afternoon and sunset periods. H2O2 concentration is obtained at an altitude of 30 km for the period that covers afternoon and sunset hours. The retrieved concentrations of these HO(x) species agree well with other individually measured results and the steady state photochemical predictions. The ratio HO2/OH at around 32 km seems to increase from the afternoon period to the sunset period.

Park, J. H.↗
NASA NTRS2011

Covariant C and O Isotope Trends in Some Terrestrial Carbonates and ALH 84001: Possible Linkage Through Similar Formation Processes

Carbonate minerals found on the surface of Mars and in martian meteorites indicate that liquid water has played a significant role in the planet's history. These findings have raised questions regarding the history of the martian hydrosphere and atmosphere as well as the possibility of life. Sunset Crater, Arizona is a dry environment with relatively high evaporation and brief periods of precipitation. This environment resembles Mars and may make Sunset Crater a good analog to martian carbonates. In this study we sought to identify discrete micro-scale isotopic variation within the carbonate crusts in Sunset Crater to see if they resembled the micro-scale isotope variation found in ALH 84001 carbonates. Sunset Crater carbonate formation may be used as a martian analog and ultimately provide insight into carbonate formation in ALH 84001.

Volk, Kathryn E.↗
NASA NTRS1983

Solar control of winter mesospheric echo occurrence at Poker Flat, Alaska

Winter mesospheric echoes are observed between about 55 and 80 km when auroral absorption is present during daylight hours. Relatively steady auroral absorption during sunrise and sunset periods causes a distinct onset and decay signature in mesospheric echo occurrence. The echo onset and disappearance time are shown versus height by the inclined lines for four different dates. The more vertical lines give the visible sunlight height/time curves for both sunrise (SR) and sunset (SS). The data is combined and replotted to give the morning onset height and the afternoon disappearance height as a function of solar zenith angle. Echoes are not observed at the lowest heights in the morning until the solar zenith angle is less than 90 deg. The afternoon echoes at the lowest heights also start to disappear as soon as the solar zenith angle exceeds 90 deg, implying that the solar component which sustains the mesospheric echo is screened by a layer extending up to about 60 km. The morning echo at 73 km onsets near the time of visible sunrise, but in the afternoon the 73 km echo lasts well past visible sunset.

Ecklund, W. L.↗
NASA NTRS1989

New observations of stratospheric N2O5

The unequivocal detection of N2O5 in the stratosphere was reported by Toon et al. based on measurements of the absorption by the N2O5 bands at 1246 and 1720/cm in solar occulation spectra recorded at sunrise near 47 S latitude by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment during the Spacelab 3 (SL3) shuttle mission. Additional measurements and analysis of stratospheric N2O5 derived from the ATMOS/SL3 spectra are reported. The primary results are the detection and measurement of N2O5 absorption at sunset in the lower stratosphere, the inversion of a precise (approximately 10 percent) N2O5 sunrise vertical distribution between 25.5 and 37.5 km altitude, and the identification and measurement of absorption by the N2O5 743/cm band at sunrise. Assuming 4.32 x 10(sup -17) and 4.36 x 10(sup -17)/cm/molecule/sq cm respectively for the integrated intensities of the 1246 and 743/cm bands at stratospheric temperatures, retrieved volume mixing ratios in parts per billion by volume (ppbv) at sunrise (47 S latitude) are 1.32 + or - 0.34 at 37.5 km, 1.53 + or - 0.35 at 35.5 km, 1.63 + or - 0.36 at 33.5 km, 1.60 + or - 0.34 at 31.5 km, 1.43 + or - 0.30 at 29.5 km, 1.15 + or - 0.24 at 27.5 km, and 0.73 + or - 0.15 at 25.5 km. Retrieved VMRs in ppbv at sunset (30 N latitude) are 0.13 + or - 0.05 at 29.5 km, 0.14 + or - 0.05 at 27.5 km, and 0.10 + or - 0.04 at 25.5 km. Quoted error limits (1 sigma) include the error in the assumed band intensities (approximately 20 percent). Within the error limits of the measurements, the inferred mixing ratios at sunrise agree with diurnal photochemical model predictions obtained by two groups using current photochemical data. The measured mixing ratios at sunset are lower than the model predictions with differences of about a factor of 2 at 25 km altitude.

Rinsland, C. P.↗
NASA NTRS1994

Mesospheric ozone measurements by SAGE II

SAGE II observations of ozone at sunrise and sunset (solar zenith angle = 90 deg) at approximately the same tropical latitude and on the same day exhibit larger concentrations at sunrise than at sunset between 55 and 65 km. Because of the rapid conversion between atomic oxygen and ozone, the onion-peeling scheme used in SAGE II retrievals, which is based on an assumption of constant ozone, is invalid. A one-dimensional photochemical model is used to simulate the diurnal variation of ozone particularly within the solar zenith angle of 80 deg - 100 deg. This model indicates that the retrieved SAGE II sunrise and sunset ozone values are both overestimated. The Chapman reactions produce an adequate simulation of the ozone sunrise/sunset ratio only below 60 km, while above 60 km this ratio is highly affected by the odd oxygen loss due to odd hydrogen reactions, particularly OH. The SAGE II ozone measurements are in excellent agreement with model results to which an onion peeling procedure is applied. The SAGE II ozone observations provide information on the mesospheric chemistry not only through the ozone profile averages but also from the sunrise/sunset ratio.

Chu, D. A.↗
NASA NTRS1994

Comparison of SBUV and SAGE II ozone profiles: Implications for ozone trends

Solar backscattered ultraviolet (SBUV) ozone profiles have been compared with Stratospheric Aerosol and Gas Experiment (SAGE) II profiles over the period October 1984 through June 1990, when data are available from both instruments. SBUV measurements were selected to closely match the SAGE II latitude/longitude measurement pattern. There are significant differences between the SAGE II sunrise and the sunset zonal mean ozone profiles in the equatorial zone, particularly in the upper stratosphere, that may be connected with extreme SAGE II solar azimuth angles for tropical sunrise measurements. Calculation of the average sunset bias between SBUV and SAGE II ozone profiles shows that allowing for diurnal variation in Umkehr layer 10, SBUV and SAGE II agree to within +/- 5% for the entire stratosphere in the northern midlatitude zone. The worst agreement is seen at southern midlatitudes near the ozone peak (disagreements of +/- 10%), apparently the result of the SBUV ozone profile peaking at a lower altitude than SAGE. The integrated ozone columns (cumulative above 15 km) agree very well, to within +/- 2.3% in all zones for both sunset and sunrise measurements. A comparison of the time dependence of SBUV and SAGE II shows that there was less than +/- 5% relative drift over the 5.5 years for all altitudes except below 25 km, where the SBUV vertical resolution is poor. The best agreement with SAGE is seen in the integrated column ozone (cumulative above 15 km), where SAGE II has a 1% negative trend relative to SBUV over the comparison period. There is a persistent disagreement of the two instruments in Umkehr layers 9 and 10 of +/- 4% over the 5.5-year comparison period. In the equatorial zone this disagreement may be caused in part by a large positive trend (0.8 K per year) in the National Meteorologica Center temperatures used to convert the SAGE II measurement of ozone density versus altitude to a pressure scale for comparison with SBUV. In the middle stratosphere (30-40 km), SBUV shows a 2-4% negative drift relative to SAGE II. If the actual ozone trends are considered, SBUV and SAGE II agree in showing little ozone change (less than 2%) between 1984 and 1990, except in layer 3 where SAGE II measures a large ozone decrease. But over 11 years, SBUV measured a 7% per decade ozone decrease between 40 and 50 km, decreasing in magnitude at lower altitudes, in good agreement with 11-year trends derived from the average of 5 Umkehr stations.

Mcpeters, R. D.↗
NASA NTRS1972

Vacuum measurements on the lunar surface.

Results of measurements of neutral gas pressure on the lunar surface made with a cold cathode ionization gauge carried to the moon by Apollo 14. The vacuum quality at the landing site is much influenced by the adsorption of rocket gases and their later release. During surface operations by the astronauts, the pressure was near 10 to the minus 8th torr. No data were obtained between the time of the surface operations and lunar sunset about 12 days later, at which time the temperature fell rapidly to the vicinity of 100 K. The pressure was about 10 to the minus 12th torr shortly after sunset, but intermittent releases of gas, perhaps from within the moon itself, occasionally raised the pressure by less than an order of magnitude for as long as a day or two at a time and on one occasion to about 10 to the minus 10th torr for about an hour. At lunar sunrise, as the surface was warmed rapidly to about 300 K, the pressure rose rapidly to about 10 to the minus 10th torr, most likely due to the release of absorbed gases in the immediate landing area or on the landing module itself. For comparison with interplanetary vacuum conditions, the directed pressure of the solar wind is usually less than 10 to the minus 11th torr and the pressure of random gas motion within the solar wind, less than 10 to the minus 13th torr.

Johnson, F. S.↗
NASA NTRS1972

Suprathermal ions near the moon.

This paper reports some preliminary results from the suprathermal ion detectors deployed on the lunar surface by the Apollo 12 and 14 astronauts. Salient features of these results include: the possible observation of sporadic venting of gas from the lunar surface; evidence for a prompt ionization and acceleration mechanism operating in the lunar exosphere; and a preliminary measurement yielding approximately 1 month for the e-folding decay time for the heavier components of the exhaust gases from the Apollo lunar landing systems. Prominent phenomena from which these results have been derived are: (1) ion bursts of low to moderate energy seen in conjunction with lunar sunrise and sunset; (2) solar wind energy ions detected on the night side of the moon; (3) ions of several keV energy seen during the lunar sunset to midnight quadrant of the moon's orbit; (4) magnetosheath ion flux enhancements; (5) ion bursts generated by the lunar impact of the Apollo 13 Saturn upper stage; and (6) geomagnetic storm associated ion flux variations in the earth's magnetotail.

Freeman, J. W., Jr.↗