Water-gas shift reaction over supported Au nanoparticles
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Shekhar, Mayank↗
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Improved Annotation of Untargeted Metabolomics Data through Buffer Modifications That Shift Adduct Mass and Intensity
Annotation of untargeted high-resolution full-scan LC-MS metabolomics data remains challenging due to individual metabolites generating multiple LC-MS peaks arising from isotopes, adducts and fragments. Adduct annotation is a particular challenge, as the same mass difference between peaks can arise from adduct formation, fragmentation, or different biological species. To address this, here we describe a Buffer Modification Workflow (BMW), in which the same sample is run by LC-MS in both liquid chromatography solvent with 14 NH 3 -acetate buffer, and in solvent with the buffer modified with 15 NH 3 -formate. Buffer switching results in characteristic mass and signal intensity changes for adduct peaks, facilitating their annotation. This relatively simple and convenient chromatography modification annotated yeast metabolomics data with similar effectiveness to growing the yeast in isotope-labeled media. Application to mouse liver data annotated both known metabolite and known adduct peaks with 95% accuracy. Altogether, it identified 26% of ~ 27,000 liver LC-MS features as putative metabolites, of which ~ 2600 showed HMDB or KEGG database formula match. This workflow is well-suited to biological samples that cannot be readily isotope labeled, including plants, mammalian tissues, and tumors.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Assessing the viability of K-Mo2C for reverse water-gas shift scale-up: molecular to laboratory to pilot scale
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99 GENERAL AND MISCELLANEOUS↗
Spectroscopy of water vapor in the 720-nm wavelength region - Line strengths, self-induced pressure broadenings and shifts, and temperature dependence of linewidths and shifts
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Grossmann, Benoist E.↗
Regional tropical rainfall shifts under global warming: an energetic perspective
Abstract Future climate simulations feature pronounced spatial shifts in the structure of tropical rainfall. We apply a novel atmospheric energy flux analysis to diagnose late 21st century tropical rainfall shifts in a large ensemble of simulations of 21st century climate. The method reconstructs 2D spatial changes in rainfall based on horizontal shifts in the lines of zero meridional and zonal divergent energy flux, called the energy flux equator (EFE) and energy flux prime meridian (EFPM), respectively. Two main sources of future atmospheric energy flux changes, and hence rainfall shifts, are identified by the analysis: the high-latitude North Atlantic due to a weakened Atlantic Meridional Overturning Circulation that shifts tropical rainfall southwards over the greater Tropical Atlantic sector and eastern Pacific; and the eastern tropical Pacific due to a permanent El-Niño-like response that produces zonal shifts over the Maritime Continent and South America. To first order, the shifts in the EFE and EFPM mirror gross distributional changes in tropical precipitation, with a southward shift in rainfall over the tropical Atlantic, West Africa, and eastern tropical Pacific and an eastward shift over the Maritime Continent and western Pacific. When used to reconstruct future rainfall shifts in the tropical Atlantic and Sahel, the method reasonably represents the simulated meridional structure of rainfall shifts but does not do so for the zonal structures.
54 ENVIRONMENTAL SCIENCES↗
Simulated Night- Shift Schedule Disrupts the Plasma Lipidome and Reveals Early Markers of Cardiovascular Disease Risk
Introduction: The circadian system coordinates daily rhythms in lipid metabolism, storage and utilization. Disruptions of internal circadian rhythms due to altered sleep/wake schedules, such as in night-shift work, have been implicated in increased risk of cardiovascular disease and metabolic disorders. To determine the impact of a night-shift schedule on the human blood plasma lipidome, an in-laboratory simulated shift work study was conducted. Methods: Fourteen healthy young adults were assigned to 3 days of either a simulated day or night-shift schedule, followed by a 24-h constant routine protocol with fixed environmental conditions, hourly isocaloric snacks, and constant wakefulness to investigate endogenous circadian rhythms. Blood plasma samples collected at 3-h intervals were subjected to untargeted lipidomics analysis. Results: More than 400 lipids were identified and quantified across 21 subclasses. Focusing on lipids with low between-subject variation per shift condition, alterations in the circulating plasma lipidome revealed generally increased mean triglyceride levels and decreased mean phospholipid levels after night-shift relative to day-shift. The circadian rhythms of triglycerides containing odd chain fatty acids peaked earlier during constant routine after night-shift. Regardless of shift condition, triglycerides tended to either peak or be depleted at 16:30 h, with chain-specific differences associated with the direction of change. Discussion: The simulated night-shift schedule was associated with altered temporal patterns in the lipidome. This may be premorbid to the elevated cardiovascular risk that has been found epidemiologically in night-shift workers.
59 BASIC BIOLOGICAL SCIENCES↗
Satellite Data Reveals a Recent Increase in Shifting Cultivation and Associated Carbon Emissions in Laos
Although shifting cultivation is the major land use type in Laos, the spatial-temporal patterns and the associated carbon emissions of shifting cultivation in Laos are largely unknown. This study provides a nationwide analysis of the spatial-temporal patterns of shifting cultivation and estimations of the associated carbon emissions in Laos over the last three decades. This study found that shifting cultivation has been expanding and intensifying in Laos, especially in the last five years. The newly cultivated land from 2016-2020 accounted for 4.5% (±1.2%) of the total land area of Laos. Furthermore, the length of fallow periods has been continuously declining, indicating that shifting cultivation is becoming increasingly intensive. Combining biomass derived from GEDI (Global Ecosystem Dynamics Investigation) and shifting cultivation maps and area estimates, we found that the net carbon emissions from shifting cultivation declined in 2001-2015 but increased in 2016-2020. The largest carbon source is conversion from intact forests to shifting cultivation, which contributed to 89% of the total emissions from 2001 to 2020. In addition, there were increased emissions from intensified use of fallow land. This research provides useful information for policymakers in Laos to understand the changes in shifting cultivation and improve land use management. This study not only supports REDD+ (Reducing Emissions from Deforestation and forest Degradation) reporting for Laos but also provides a methodology for tracking carbon emissions and removals of shifting cultivation.
Shifting cultivation↗
Decoding the dynamics of poleward shifting climate zones using aqua-planet model simulations
Growing evidence indicates that the atmospheric and oceanic circulation experiences a systematic poleward shift in a warming climate. However, the complexity of the climate system, including the coupling between the ocean and the atmosphere, natural climate variability and land-sea distribution, tends to obfuscate the causal mechanism underlying the circulation shift. Here, using an idealised coupled aqua-planet model, we explore the mechanism of the shifting circulation, by isolating the contributing factors from the direct CO 2 forcing, the indirect ocean surface warming, and the wind-stress feedback from the ocean dynamics. We find that, in contrast to the direct CO 2 forcing, ocean surface warming, in particular an enhanced subtropical ocean warming, plays an important role in driving the circulation shift. This enhanced subtropical ocean warming emerges from the background Ekman convergence of surface anomalous heat in the absence of the ocean dynamical change. Additionally, it expands the tropical warm water zone, causes a poleward shift of the mid-latitude temperature gradient, hence forces a corresponding shift in the atmospheric circulation and the associated wind pattern. The shift in wind, in turn drives a shift in the ocean circulation. Our simulations, despite being idealised, capture the main features of the observed climate changes, for example, the enhanced subtropical ocean warming, poleward shift of the patterns of near-surface wind, sea level pressure, storm tracks, precipitation and large-scale ocean circulation, implying that increase in greenhouse gas concentrations not only raises the temperature, but can also systematically shift the climate zones poleward.
54 ENVIRONMENTAL SCIENCES↗
Seasonally and Regionally Dependent Shifts of the Atmospheric Westerly Jets under Global Warming
A distinct feature of the atmospheric circulation response to increasing greenhouse gas forcing is the poleward shift of the zonal-mean westerly jet. The dynamical mechanisms of the zonal-mean poleward jet shift have been extensively studied in literature. At seasonal/regional scales, however, the westerly jets can shift equatorward, such as in the early-summer Asia–Pacific region, the late-winter America–Atlantic region, and the winter/spring east Pacific. These equatorward jet shifts imply climate impacts distinct from those of the poleward shifts, yet their causes are not well understood. In this work, based on a hierarchy of coupled, prescribed-SST, and aquaplanet simulations, we attribute the seasonal/regional equatorward jet shifts to the enhanced tropical upper-level warming (ETUW), which arises from both the tropical moist adiabat and the enhanced equatorial surface warming. By steepening the meridional temperature gradient in the subtropical upper-to-middle level and assisted by positive eddy feedback, the ETUW increases the zonal wind equatorward of the climatological jet. When the regional/seasonal meridional temperature gradients (or equivalently the westerly jets) are weak and peak close to the tropics, the ETUW effect overcomes the poleward jet-shift mechanisms and leads to the equatorward jet shifts. This climatological-state dependency is consistently seen in the decomposed jet responses to uniform warming and surface warming pattern, and further demonstrated through idealized aquaplanet experiments with designed climatological states. For uniform warming, the ETUW arising from moist adiabat makes the general poleward jet shifts insignificant in the aforementioned favorable regions/seasons. For warming pattern, the ETUW from enhanced equatorial warming drives substantial equatorward jet shifts in these favorable seasons/regions.
54 ENVIRONMENTAL SCIENCES↗
Low-Light-Shift Cesium Fountain without Mechanical Shutters
A new technique for reducing errors in a laser-cooled cesium fountain frequency standard provides for strong suppression of the light shift without need for mechanical shutters. Because mechanical shutters are typically susceptible to failure after operating times of the order of months, the elimination of mechanical shutters could contribute significantly to the reliability of frequency standards that are required to function continuously for longer time intervals. With respect to the operation of an atomic-fountain frequency standard, the term "light shift" denotes an undesired relative shift in the two energy levels of the atoms (in this case, cesium atoms) in the atomic fountain during interrogation by microwaves. The shift in energy levels translates to a frequency shift that reduces the precision and possibly accuracy of the frequency standard. For reasons too complex to describe within the space available for this article, the light shift is caused by any laser light that reaches the atoms during the microwave- interrogation period, but is strongest for near-resonance light. In the absence of any mitigating design feature, the light shift, expressed as a fraction of the standard fs frequency, could be as large as approx. 2 x 10(exp -11), the largest error in the standard. In a typical prior design, to suppress light shift, the intensity of laser light is reduced during the interrogation period by using a single-pass acoustooptic modulator to deflect the majority of light away from the main optical path. Mechanical shutters are used to block the remaining undeflected light to ensure complete attenuation. Without shutters, this remaining undeflected light could cause a light shift of as much as .10.15, which is unacceptably large in some applications. The new technique implemented here involves additionally shifting the laser wavelength off resonance by a relatively large amount (typically of the order of nanometers) during microwave interrogation. In this design, when microwave interrogation is not underway, the atoms are illuminated by a slave laser locked to the lasing frequency of a lower power master laser.
Enzer, Daphna↗
Mitigating Headward Fluid Shifts with Venoconstrictive Thigh Cuffs during Spaceflight
Venoconstrictive thigh cuffs (VTC) are a mechanical countermeasure capable of attenuating the spaceflight induced headward fluid shift, and thus may be a viable spaceflight associated neuro-ocular syndrome (SANS) countermeasure. Crewmembers can use VTC to mitigate the headward fluid shift to aid in adapting to spaceflight. However, data are needed to determine if VTC affect ocular structures. PURPOSE The purpose of this study is to determine the efficacy of long duration use of VTC application to mitigate the spaceflight-induced headward fluid shift. We hypothesize that a VTC countermeasure will temporarily reverse the headward fluid shift and attenuate spaceflight-induced changes of internal jugular vein (IJV) cross-sectional area, IJV pressure, stroke volume, cardiac output, intraocular pressure (IOP), and optic nerve head and retinal morphology. METHODS This study will evaluate the effectiveness of VTC countermeasure application on the headward fluid shift, as well as cardiovascular and ocular variables. VTC during spaceflight will be worn for an extended duration (up to 6 hours) with data collected at three time points (30 minutes, 3 hours, and 6 hours) to characterize the temporal profile of key fluid shift outcome measures of the vascular fluid shift, IOP, and ocular structure changes. Ten astronauts will be recruited to participate and will be studied before and during approximately 180-day International Space Station (ISS) spaceflight missions. Baseline data collection will occur approximately 90-days before launch (Figure). Preflight, each leg of the crewmember will be measured to determine the VTC cuff size and a cuff fit check session will occur prior to the preflight baseline ground imaging to verify the appropriate fit measured via a surface contact pressure. Prior to donning the VTC, baseline measures without VTC will be collected seated, supine, and supine followed by data collection with the VTC. The baseline data collection will include ultrasound (IJV area and pressure, stroke volume and cardiac output), brachial blood pressure and heart rate, optical coherence tomography (OCT) imaging (total retinal thickness and choroid thickness), and IOP. An inflight cuff fit check session, same as the preflight fit check, will occur prior to VTC use on ISS. The inflight VTC experiment will be conducted early (FD45) and late (R-45) to determine if mission duration affects VTC fit and the efficacy of fluid redistribution. A system usability scale comfort questionnaire will be included in each VTC session to capture feedback from crewmembers regarding the comfort and usability of the VTC. SCIENTIFIC & MISSION IMPACT Results will narrow knowledge gaps described in the Human Research Roadmap to mitigate the headward fluid shift during spaceflight and help NASA to 1) determine the efficacy of extended use VTC application to mitigate the spaceflight-induced headward fluid shift and 2) further the understanding of the use of VTC on vascular fluid shifts, IOP, and ocular structure during spaceflight. Supported by NASA Human Research Program Directed Research. Figure. Detailed Testing Schedule. Baseline data collection at L-90 will be performed in a randomized order of position.
J V Jasien↗
Considerations when Implementing Shift Work in Nuclear Operations
Many domestic and international nuclear facilities have processes that require personnel to work on some type of shift. Shift work has many different schedules such as night, morning, swing, and rotating shift. Some common shifts are DuPont, Pitman, and Panama. There are many psychological and physiological impacts to a person working shifts. These impacts can affect work performance, safety, and security within an organization. A well-established nuclear organization relies on a strong security culture that implements a trustworthiness or reliability program. The IAEA defines this type of program as individuals meeting the highest standards of reliability, trustworthiness, and physical and mental suitability. Psychological and physiological impacts that apply to a Trustworthiness Program are reliability (an individual’s ability to adhere to security and safety rules and regulations) and physical and mental suitability. If shift work isn’t properly implemented in Facility Operations, then several issues or human factors can arise. An employee that suffers from a poorly designed shift, gets overworked, or doesn’t have the proper rest period implemented, may suffer from shift work disorder, acute fatigue, or cumulative fatigue. Introducing fatigue into Facility Operations can have severe consequences to security, safety, production, and cost. Another challenge of shiftwork within a facility is laziness and complacency. Creating an atmosphere where the employee is willing to admit fatigue to his or her supervisor is a challenge. It is up to the organization to do the needed research on shift work and to implement the best shift for their facility and personnel.
Stockwell, Brandon↗
Night shift schedule causes circadian dysregulation of DNA repair genes and elevated DNA damage in humans
Circadian disruption has been identified as a risk factor for health disorders such as obesity, cardiovascular disease, and cancer. Although epidemiological studies suggest an increased risk of various cancers associated with circadian misalignment due to night shift work, the underlying mechanisms have yet to be elucidated. Here, we sought to investigate the potential mechanistic role that circadian disruption of cancer hallmark pathway genes may play in the increased cancer risk in shift workers. In a controlled laboratory study, we investigated the circadian transcriptome of cancer hallmark pathway genes and associated biological pathways in circulating leukocytes obtained from healthy young adults during a 24‐hour constant routine protocol following 3 days of simulated day shift or night shift. The simulated night shift schedule significantly altered the normal circadian rhythmicity of genes involved in cancer hallmark pathways. A DNA repair pathway showed significant enrichment of rhythmic genes following the simulated day shift schedule, but not following the simulated night shift schedule. In functional assessments, we demonstrated that there was an increased sensitivity to both endogenous and exogenous sources of DNA damage after exposure to simulated night shift. Our results suggest that circadian dysregulation of DNA repair may increase DNA damage and potentiate elevated cancer risk in night shift workers.
circadian misalignment↗
Phase-Shifting Liquid Crystal Point-Diffraction Interferometry
Microgravity fluid physics experiments frequently measure concentration and temperature. Interferometers such as the Twyman Green illustrated have performed full-field measurement of these quantities. As with most such devices, this interferometer uses a reference path that is not common with the path through the test section. Recombination of the test and reference wavefronts produces interference fringes. Unfortunately, in order to obtain stable fringes, the alignment of both the test and reference paths must be maintained to within a fraction of the wavelength of the light being used for the measurement. Otherwise, the fringes will shift and may disappear. Because these interferometers are extremely sensitive to bumping, jarring and transmitted vibration, they are typically mounted on optical isolation tables. Schlieren deflectometers or the more recent Shack-Hartmann wavefront sensors also measure concentration and temperature in laboratory fluid flows. Ray optics describe the operation of both devices. In a schlieren system, an expanded, collimated beam passes through a test section where refractive index gradients deflect rays. A lens focuses the beam to a filter placed in the rear focal plane of the decollimating lens. In a quantitative color schlieren system, gradients in the index of refraction appear as colors in the field of view due to the action of the color filter. Since sensitivity is a function of the focal length of the decollimating lens, these systems are rather long and filter fabrication and calibration is rather difficult. A Shack-Hartmann wavefront sensor is an array of small lenslets. Typical diameters are on the order of a few hundred microns. Since these lenslets divide the test section into resolution elements, the spatial resolution can be no smaller than an individual lenslet. Such a device was recently used to perform high-speed tomography of heated air exiting a 1.27 cm diameter nozzle. While these wavefront sensors are very compact, the limited spatial resolution and the methods required for data reduction suggest that a more useful instrument needs to be developed. The category of interferometers known as common path interferometers can eliminate much of the vibration sensitivity associated with traditional interferometry as described above. In these devices, division of the amplitude of the wavefront following the test section produces the reference beam. Examples of these instruments include shearing and point diffraction interferometers. In the latter case, shown schematically, a lens focuses light passing through the test section onto a small diffracting object. Such objects are typically either a circle of material on a high quality glass plate or a small sphere in a glass cell. The size of the focused spot is several times larger than the object so that the light not intercepted by the diffracting object forms the test beam while the diffracted light generates a spherical reference beam. While this configuration is mechanically stable, phase shifting one beam with respect to the other is difficult due to the common path. Phase shifting enables extremely accurate measurements of the phase of the interferogram using only gray scale intensity measurements and is the de facto standard of industry. Mercer and Creath 2 demonstrated phase shifting in a point diffraction interferometer using a spherical spacer in a liquid crystal cell as the diffracting object. By changing the voltage across the cell, they were able to shift the phase of the undiffracted beam relative to the reference beam generated by diffraction from the sphere. While they applied this technology to fluid measurements, the device shifted phase so slowly that it was not useful for studying transient phenomena. We have identified several technical problems that precluded operation of the device at video frame rates and intend to solve them to produce a phase-shifting liquid crystal point-diffraction interferometer operating at video frame rates. The first task is to produce high contrast fringes. Since the diffracted beam is much weaker than the transmitted beam, interferograms have poor contrast unless a dye is added to the liquid crystal to reduce the intensity of the undiffracted light. Dyes previously used were not rigorously characterized and suffered from hysteresis in both the initial alignment state of the device and the electro-optic switching characteristics. Hence, our initial effort will identify and characterize dyes that do not suffer from these difficulties and are readily soluble in the liquid crystal host. Since the ultimate goal of this research is to produce interferometers capable of phase shifting at video frame rates, we will quantify the difference in switching times between ferroelectric and nematic liquid crystals. While we have more experience with nematic crystals, they typically switch more slowly than ferroelectric cells. As part of that effort, we will investigate the difference in the modulation of the interferograms as a function of the type of liquid crystal in the cell. Because the temporal switching response of a liquid crystal cell is directly related its thickness, we intend to explore techniques required to produce cells that are as thin as possible. However, the cells must still produce a total phase shift of two pi radians.
Griffin, DeVon W.↗
Changes in Extratropical Storm Track Cloudiness 1983-2008: Observational Support for a Poleward Shift
Climate model simulations suggest that the extratropical storm tracks will shift poleward as a consequence of global warming. In this study the northern and southern hemisphere storm tracks over the Pacific and Atlantic ocean basins are studied using observational data, primarily from the International Satellite Cloud Climatology Project, ISCCP. Potential shifts in the storm tracks are examined using the observed cloud structures as proxies for cyclone activity. Different data analysis methods are employed, with the objective to address difficulties and uncertainties in using ISCCP data for regional trend analysis. In particular, three data filtering techniques are explored; excluding specific problematic regions from the analysis, regressing out a spurious viewing geometry effect, and excluding specific cloud types from the analysis. These adjustments all, to varying degree, moderate the cloud trends in the original data but leave the qualitative aspects of those trends largely unaffected. Therefore, our analysis suggests that ISCCP data can be used to interpret regional trends in cloudiness, provided that data and instrumental artefacts are recognized and accounted for. The variation in magnitude between trends emerging from application of different data correction methods, allows us to estimate possible ranges for the observational changes. It is found that the storm tracks, here represented by the extent of the midlatitude-centered band of maximum cloud cover over the studied ocean basins, experience a poleward shift as well as a narrowing over the 25 year period covered by ISCCP. The observed magnitudes of these effects are larger than in current generation climate models (CMIP3). The magnitude of the shift is particularly large in the northern hemisphere Atlantic. This is also the one of the four regions in which imperfect data primarily prevents us from drawing firm conclusions. The shifted path and reduced extent of the storm track cloudiness is accompanied by a regional reduction in total cloud cover. This decrease in cloudiness can primarily be ascribed to low level clouds, whereas the upper level cloud fraction actually increases, according to ISCCP. Independent satellite observations of radiative fluxes at the top of the atmosphere are consistent with the changes in total cloud cover. The shift in cloudiness is also supported by a shift in central position of the mid-troposphere meridional temperature gradient. We do not find support for aerosols playing a significant role in the satellite observed changes in cloudiness. The observed changes in storm track cloudiness can be related to local cloud-induced changes in radiative forcing, using ERBE and CERES radiative fluxes. The shortwave and the longwave components are found to act together, leading to a positive (warming) net radiative effect in response to the cloud changes in the storm track regions, indicative of positive cloud feedback. Among the CMIP3 models that simulate poleward shifts in all four storm track areas, all but one show decreasing cloud amount on a global mean scale in response to increased CO2 forcing, further consistent with positive cloud feedback. Models with low equilibrium climate sensitivity to a lesser extent than higher-sensitivity models simulate a poleward shift of the storm tracks.
Bender, Frida A-M.↗
Inverse size-dependent Stokes shift in strongly quantum confined CsPbBr 3 perovskite nanoplates
Colloidal semiconductor nanocrystals (NCs) are used as bright chromatic fluorophores for energy-efficient displays. Here we focus here on the size-dependent Stokes shift for CsPbBr 3 nanocrystals. The Stokes shift, i.e., the difference between the wavelengths of absorption and emission maxima, is crucial for display application, as it controls the degree to which light is reabsorbed by the emitting material reducing the energetic efficiency. One major impediment to the industrial adoption of NCs is that slight deviations in manufacturing conditions may result in a wide dispersion of the product's properties. A data-driven analysis of over 2000 reactions comparing two data sets, one produced via standard colloidal synthesis and the other via high-throughput automated synthesis is discussed. We show that differences in the reaction conditions of colloidal CsPbBr 3 nanocrystals yield nanocrystals with opposite Stokes shift size-dependent trends. These match the morphologies of two-dimensional nanoplatelets (NPLs) and nanocrystal cubes. The Stokes shift size dependence trend of NPLs and nanocubes is non-monotonic indicating different physics is at play for the two nanocrystal morphologies. For nanocrystals with cubic shape, with the increase of edge length, there is a significant decrease in Stokes shift values. However, for NPLs with the increase of thickness (1–4 ML), Stokes shift values will increase. The study emphasizes the transition from a spectroscopic point of view and relates the two Stokes shift trends to 2D and 0D exciton dimensionalities for the two morphologies. Our findings highlight the importance of CsPbBr 3 nanocrystal morphology for Stokes shift prediction.
36 MATERIALS SCIENCE↗
Energy shift of Fe-K fluorescence lines due to low ionization demonstrated with XRISM in Centaurus X-3
The Fe K$\alpha$ fluorescence line at 6.4 keV is a powerful probe of cold matter surrounding X-ray sources and has been widely used in various astrophysical contexts. The X-ray microcalorimeter spectrometer onboard XRISM can measure line shifts with unprecedented precision of ${\sim }$0.2 eV, equivalent to a line-of-sight velocity of ${\sim }$10 km s$^{-1}$. At this level of accuracy, however, several factors that influence the line energy must be carefully considered prior to astrophysical interpretation. One such important factor is the ionization degree, Fe$^{q+}$. The K$\alpha$ line shifts redward by ${\sim }$4 eV as q increases from 0 (neutral) to 8 (Ar-like). Additionally, the accompanying Fe K$\beta$ line at 7.06 keV shifts blueward by ${\sim }$30 eV from $q=0$ to 8. We demonstrate that this effect is actually observable in the XRISM data of the high-mass X-ray binary Centaurus X-3 (Cen X-3). We advocate that the differential energy shift between the K$\alpha$ and K$\beta$ line provides a robust estimate of q by decoupling from other effects that shift the two lines in the same direction. We derived $q \sim 5$ (Sc-like) for the fluorescing matter by comparing the observation with atomic structure calculations of our own and in the literature. By accounting for the derived charge state and the corresponding shift in the rest-frame line energy, we made corrections for this effect and reached a consistent residual shift among the K$\alpha$, K$\beta$, and the optical measurement attributable to the systemic velocity of the system. Consequently, we obtained a new constraint on the location of the cold matter. This ionization effect needs to be assessed in all use cases of the Fe K$\alpha$ line shift beyond Cen X-3, and the proposed metric is generally applicable to all of them.
Astronomy and AstroPhysics↗