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Vibrational spectrum of blue-green system of aluminum oxide
Hydrogen molecule ion energy calculations at various internuclear separations
Molecular orbital calculation of potential function for excited state of hydrogen molecule
Forbidden absorption bands of carbon monoxide in vacuum UV region, noting rotational and vibrational constants and perturbations
He-He ground state and first excited state potentials obtained from differential scattering cross sections
Identification of faint emission Herzberg bands in oxygen-argon afterglow
Molecular N UV spectrum at various pressures, showing absorption band dependence on pressure induced dipole transitions
Molecular hydrogen Lyman bands radiative transition probabilities, using electronic dipole moment functions
Photoelectric intensity measurements on emission bands of oxygen Herzberg I system excited in argon-oxygen afterglow
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Results are presented for the rotationally resolved photoelectron spectra resulting from a (2 + 1) one-color resonant enhanced multiphoton ionization (REMPI) of NO via the rotationally clean S21(11.5) and mixed S11(15.5) + R21(15.5) branches of the 0-0 transition in the D-X band. The calculations were done in the fixed-nuclei frozen core approximation. The resulting photoionization spectra, convoluted with a Lorentzian detection function, agree qualitatively with experimental results of Viswanathan et al. (1986) and support their conclusion that the nonspherical nature of the molecular potential creates a substantial l-mixing in the continuum, which in turn leads to the intense Delta N = 0 peak. The rather strong photoelectron energy dependence of the rotational branching ratios of the D 2Sigma(+) S21(11.5) line was investigated and compared to the weak energy dependence of the A 2Sigma(+) R22(21.5) line.
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No abstract available
The description of a global version of the University of Wisconsin (UW) hybrid isentropic-sigma (theta-sigma) model and the results from an initial numerical weather prediction experiment are presented in this paper. The main objectives of this initial test are to (1) discuss theta-sigma model development and computer requirements, (2) demonstrate the ability of the UW theta-sigma model for global numerical weather prediction using realistic orography and parameterized physical processes, and (3) compare the transport of an inert trace constituent against a nominally 'identical' sigma coordinate model. Initial and verifying data for the 5-day simulations presented in this work were supplied by the Goddard Earth Observing System (GEOS-1) data assimilation system. The time period studied is 1-6 February 1985. This validation experiment demonstrates that the global UW theta-sigma model produces a realistic 5-day simulation of the mass and momentum distributions when compared to both the identical sigma model and GEOS-1 verification. Root-mean-square errors demonstrate that the theta-sigma model is slightly more accurate than the nominally identical sigma model with respect to standard synoptic variables. Of particular importance, the UW theta-sigma model displays a distinct advantage over the conventional sigma model with respect to the prognostic simulation of inert trace constituent transport in amplifying baroclinic waves of the extratropics. This is especially true in the upper troposphere and stratosphere where the spatial integrity and conservation of an inert trace constituent is severely compromised in the sigma model compared to the theta-sigma model.
Monthly Ku band sigma(sub 0) and significant wave height (SWH) histograms from the NASA altimeter on the TOPEX/POSEIDON satellite are preseneted for January through June 1993 for three latitude bands between +/- 60 degrees. The data are compared to distributions from the Geosat mission for the same months in 1987-1989. Generally, the distributions agree quite well, although there are some seasonal/hemispherical differences. The sigma(sub 0) comparison reveals an overall bias between the two altimeters with the TOPEX sigma(sub 0) higher by about 0.7 dB, which is consistent with algorithm improvements for TOPEX. The SWH distributions show strong hemispherical/seasonal changes. The seasonal/hemispherical differences between TOPEX and Geosat are consistent for SWH and sigma(sub 0). The joint distribution of sigma(sub 0) and SWH is extremely stable friom month to month. The typical SWH is independent of sigma(sub 0) for sigma(sub 0) greater than 11.3 dB. The minimum SWH grows exponentially with wind speed. This joint distribution may be useful for understanding electromagnetic bias in altimeter measurements. Finally, altimeter data are compared to buoy values from 21 overflights of the NASA verification site near Pt. Conception, California. Wave heights agree well with an root mean square (RMS) difference of only 0.2 m. Altimeter sigma(sub 0) values are compared to buoy wind speeds. The results are consistent with the -0.7 dB sigma(sub 0) offset from the histogram comparisons.