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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Redistribution - Why half a collision is better than a whole one

The study of spectral line shapes has traditionally been mainly concerned with the measurement and interpretation of absorption or emission profiles. Often only the line widths are studied. The present investigation has the objective to evaluate the additional information which can be obtained by scattering light (usually from a laser) from an atomic system which is being perturbed by collisions. A scattering experiment is discussed. The scattered light consists of two components, a (coherent) Rayleigh component and a redistributed (fluorescent) component. In order to obtain the absorption spectrum, questions regarding the probability of photon absorption are considered. By observing the fluorescence subsequent to absorption during a collision it is found possible to obtain information on the evolution of the system from the point of absorption to the completion of the collision. The information on the intracollisional evolution is the justification for the title of the study, namely 'Why half a collision is better than a whole one'.

Cooper, J.↗
NASA NTRS1983

Stimulated Rayleigh-Brillouin gain spectroscopy in pure gases

Stimulated Rayleigh-Brillouin gain spectra of pure gases are reported. Stimulated Rayleigh scattering is now clearly distinguishable from stimulated Brillouin scattering without the aid of induced absorption. As examples, spectral line shapes of Ar and SF6 at various pressures and the associated gain asymmetry are discussed. Potential applications of coherent Rayleigh-Brillouin spectroscopy are suggested.

She, C. Y.↗
NASA NTRS1984

Theory of collision-induced translation-rotation spectra: H2-He

An adiabatic quantal theory of spectral line shapes in collision-induced absorption and emission is presented which incorporates the induced translation-rotation and translation-vibration spectra. The generalization to account for the anisotropy of the scattering potential is given. Calculations are carried out of the collision-induced absorption spectra of He in collisions with H2 with ab initio electric dipole functions and realistic potentials. The anisotropy of the interaction potential is small and is not included in the calculations. The predicted spectra are in satisfactory agreement with experimental data though some deviations occur which may be significant. The rotational line shapes have exponential wings and are not Lorentzian. The connection between the quantal and classical theories is written out explicitly for the isotropic overlap induction.

Birnbaum, G.↗
NASA NTRS1984

Collisional narrowing effects in the Raman Q-branch spectral profiles of N2, CO, and NO

A description is presented of coherent Raman spectroscopic studies of N2, CO, and NO molecules. It is pointed out that the Q-branch Raman spectra of these simple diatomics are characterized by lines which overlap with increasing pressure as a result of collisional line broadening. Attention is given to Q-branch vibrational spectra and their determination, the spectral line shape of isolated lines, the line overlap regime, fitting laws, and the isotropic Raman spectrum of NO. It is found that the room temperature spectra of the considered molecules at low pressure (approximately 0.2 atm) may be treated as a sum of isolated lines. It is possible to extract J-dependent pressure-broadening coefficients. With increasing pressure, collisional narrowing occurs and the description of the spectrum must include the effects of interference among neighboring lines.

Hurst, W. S.↗
NASA NTRS1984

Hydrogen dimer structures in the far-infrared spectra of Jupiter and Saturn

On the basis of a spectral line shape computation and radiative transfer calculations, it is shown that the unexplained, diminutive structures seen in the Voyager IRIS Jovian spectra near the hydrogen S0(0) and S0(1) rotational frequencies are due to bound-free transitions involving hydrogen dimers. The absorption intensities of these transitions, as well as of the collision-induced background, are given. These dimer structures may possibly prove to be useful for determining the helium/hydrogen ratio and the para-hydrogen fraction in the atmospheres of the outer planets.

Frommhold, L.↗
NASA NTRS1986

Velocity-resolved observations of water in Comet Halley

High resolution (lambda/delta lambda approx. = 3 x 10 to the 5th power) near-infrared observations of H2O emission from Comet Halley were acquired at the time of maximum post-perihelion geocentric Doppler shift. The observed widths and absolute positions of the H2O line profiles reveal characteristics of the molecular velocity field in the coma. These results support H2O outflow from a Sun-lit hemisphere or the entire nucleus, but not from a single, narrow jet emanating from the nucleus. The measured pre- and post-perihelion outflow velocities were 0.9 + or - 0.2 and 1.4 + or - 0.2 km/s, respectively. Temporal variations in the kinematic properties of the outflow were inferred from changes in the spectral line shapes. These results are consistent with the release of H2O into the coma from multiple jets.

Larson, Harold P.↗
NASA NTRS1986

Velocity-resolved observations of water in comet Halley

High-resolution observations of H2O in comet Halley are presented. The positions and widths of the H2O emission line profiles are indicative of the coma's velocity field characteristics. Spectral line shape changes are used to infer temporal variations in the kinematic properties of the outflow. The results suggest that H2O is released into the coma by way of multiple jets.

Larson, Harold P.↗
NASA NTRS1988

Photoreflectance Study of Boron Ion-Implanted (100) Cadmium Telluride

Ion implanted (100) cadmium telluride was studied using the contactless technique of photoreflectance. The implantations were performed using 50- to 400-keV boron ions to a maximum dosage of 1.5 x 10(16)/sq cm, and the annealing was accomplished at 500 C under vacuum. The spectral measurements were made at 77 K near the E(0) and E(1) critical points; all the spectra were computer-fitted to Aspnes' theory. The spectral line shapes from the ion damaged, partially recovered and undamaged, or fully recovered regions could be identified, and the respective volume fraction of each phase was estimated.

Amirtharaj, P. M.↗
NASA NTRS1989

Optical Stark effect in the four-wave mixing and stimulated Raman spectra of N2

The influence of the optical Stark effect on spectral line shapes in four-wave-mixing Raman spectroscopy (FWMRS) and stimulated Raman spectroscopy (SRS) is investigated experimentally and theoretically. Using an experimental setup capable of rapid alternation between the simultaneous measurement of coherent Stokes Raman spectroscopy and inverse Raman spectroscopy at low and high intensities, together with a sophisticated frequency reference scheme, it was possible to perform a rather direct comparison between Stark-broadened and non-Stark-broadened spectra of both classes of Raman spectroscopies. The results demonstrate that SRS spectra show more Stark shift and broadening than their FWMRS counterparts. A discrepancy with theoretical results is pointed out, and an attempt is made to explain it.

Moosmuller, H.↗
NASA NTRS1992

Vacuum ultraviolet absorption in a hydrogen arcjet

Atomic absorption spectroscopy was utilized to measure the ground state atomic hydrogen number density in the plasma produced in a low power hydrogen arcjet. A microwave driven hydrogen plasma was used as the source of radiation resonant with the vacuum ultraviolet Lyman alpha transition. The suitability of this radiation source is discussed. The optical depth of this transition prevented measurements at locations where the ground state atomic hydrogen number density was larger than 3 x 10 exp 19/cu m. These results indicate that other single-photon optical diagnostic techniques are equally ineffective in locations of higher hydrogen number density unless the spectral line shape of the atomic hydrogen absorbers is known.

Manzella, David H.↗
NASA NTRS1992

Observations of the solar corona with a high resolution EUV imaging spectrograph

An extreme ultraviolet imaging spectrograph was used to obtain coronal observations with high spectral and spatial resolution. The imaging properties of the instrument enable measurements of spectral line shapes and positions in discrete spatial elements of a region, so that the dynamic characteristics of the coronal plasma, as well as the distribution of emission measure with temperature and well known density diagnostics, can be studied for specific features. The instrumentation is described and several results of a sounding rocket flight on 5 May 1989, when the corona over NOAA Region 5464 including emission over the umbra of the region's largest sunspot and the pre-impulsive phase emission of a small flare was recorded, are summarized.

Neupert, Werner M.↗
NASA NTRS1994

Column amounts of trace gases from ground based FTIR measurements in the late north polar winters 1990 and 1991

Two FTIR spectrometers were employed in the late winters 1990 and 1991 in Esrange, North Sweden, and in Ny Aalesund, Spitsbergen to detect zenith column amounts of several trace gases. Time series of column amounts of the trace gases O3, N2O, CH4, HNO3, NO2, CHl, and HF have been derived from the measured spectra. Additionally, some information on the vertical distribution of HCl could be obtained by analyzing the spectral line shapes. The results are interpreted in terms of dynamical and chemical processes.

Adrian, Gabriele↗
NASA NTRS1996

Demonstration and Analysis of Filtered Rayleigh Scattering Flow Field Diagnostic System

Filtered Rayleigh Scattering (FRS) is a diagnostic technique which measures velocity, temperature, and pressure by determining Doppler shift, total intensity, and spectral line shape of laser induced Rayleigh-Brillouin scattering. In the work reported here, this is accomplished by using a narrow line width, injection seeded Nd-YAG laser sheet to induce Rayleigh-Brillouin scattering from a gas flow. This light is passed through an optical notch filter, and transmitted light is imaged onto an intensified charge coupled display (CCD) camera. By monitoring the grayscale value at a particular pixel while the laser frequency is tuned, the convolution between the Rayleigh-Brillouin scattering profile and the filter transmission profile is attained. Since the filter profile can be independently measured, it can be deconvolved from the measuring signal, yielding the Rayleigh-Brillouin scattering profile. From this profile, flow velocity, temperature, and pressure are determined. In this paper the construction and characterization of the optical notch filter and a newly developed frequency apparatus are discussed.

Forkey, Joseph N.↗
NASA NTRS2004

Microscopic Theory and Simulation of Quantum-Well Intersubband Absorption

We study the linear intersubband absorption spectra of a 15 nm InAs quantum well using the intersubband semiconductor Bloch equations with a three-subband model and a constant dephasing rate. We demonstrate the evolution of intersubband absorption spectral line shape as a function of temperature and electron density. Through a detailed examination of various contributions, such as the phase space filling effects, the Coulomb many-body effects and the non-parabolicity effect, we illuminate the underlying physics that shapes the spectra. Keywords: Intersubband transition, linear absorption, semiconductor heterostructure, InAs quantum well

Li, Jianzhong↗
NASA NTRS2010

Cryogenic Absorption Cells Operating Inside a Bruker IFS-125HR: First Results for 13CH4 at 7 Micrometers

New absorption cells designed specifically to achieve stable temperatures down to 66 K inside the sample compartment of an evacuated Bruker IFS-125HR Fourier transform spectrometer (FTS) were developed at Connecticut College and tested at the Jet Propulsion Laboratory (JPL). The temperature stabilized cryogenic cells with path lengths of 24.29 and 20.38 cm were constructed of oxygen free high conductivity (OFHC) copper and fitted with wedged ZnSe windows using vacuum tight indium seals. In operation, the temperature-controlled cooling by a closed-cycle helium refrigerator achieved stability of 0.01 K. The unwanted absorption features arising from cryodeposits on the cell windows at low temperatures were eliminated by building an internal vacuum shroud box around the cell which significantly minimized the growth of cryodeposits. The effects of vibrations from the closed-cycle helium refrigerator on the FTS spectra were characterized. Using this set up, several high-resolution spectra of methane isotopologues broadened with nitrogen were recorded in the 1200-1800 per centimeter spectral region at various sample temperatures between 79.5 and 296 K. Such data are needed to characterize the temperature dependence of spectral line shapes at low temperatures for remote sensing of outer planets and their moons. Initial analysis of a limited number of spectra in the region of the R(2) manifold of the v4 fundamental band of 13CH4 indicated that an empirical power law used for the temperature dependence of the N2-broadened line widths would fail to fit the observed data in the entire temperature range from 80 to 296 K; instead, it follows a temperature-dependence similar to that reported by Mondelain et al. [17,18]. The initial test was very successful proving that a high precision Fourier transform spectrometer with a completely evacuated optical path can be configured for spectroscopic studies at low temperatures relevant to the planetary atmospheres.

Sung, K.↗
NASA NTRS2012

Error Reduction Methods for Integrated-path Differential-absorption Lidar Measurements

We report new modeling and error reduction methods for differential-absorption optical-depth (DAOD) measurements of atmospheric constituents using direct-detection integrated-path differential-absorption lidars. Errors from laser frequency noise are quantified in terms of the line center fluctuation and spectral line shape of the laser pulses, revealing relationships verified experimentally. A significant DAOD bias is removed by introducing a correction factor. Errors from surface height and reflectance variations can be reduced to tolerable levels by incorporating altimetry knowledge and "log after averaging", or by pointing the laser and receiver to a fixed surface spot during each wavelength cycle to shorten the time of "averaging before log".

averging before log↗
NASA NTRS2014

Alma Measurements of the HNC and HC3N Distributions in Titan's Atmosphere

We present spectrally and spatially resolved maps of HNC and HC3N emission from Titan's atmosphere, obtained using the Atacama Large Millimeter/submillimeter Array on 2013 November 17. These maps show anisotropic spatial distributions for both molecules, with resolved emission peaks in Titan's northern and southern hemispheres. TheHC3N maps indicate enhanced concentrations of this molecule over the poles, consistent with previous studies of Titan's photochemistry and atmospheric circulation. Differences between the spectrally integrated flux distributions of HNC and HC3N show that these species are not co-spatial. The observed spectral line shapes are consistent with HNC being concentrated predominantly in the mesosphere and above (at altitudes z approx.. greater than 400 km), whereas HC3N is abundant at a broader range of altitudes (z approx. equal to 70-600 km). From spatial variations in the HC3N line profile, the locations of the HC3N emission peaks are shown to be variable as a function of altitude. The peaks in the integrated emission from HNC and the line core (upper atmosphere) component of HC3N (at z approx. greater than 300 km) are found to be asymmetric with respect to Titan's polar axis, indicating that the mesosphere may be more longitudinally variable than previously thought. The spatially integrated HNC and HC3N spectra are modeled using the NEMESIS planetary atmosphere code and the resulting best-fitting disk-averaged vertical mixing ratio profiles are found to be in reasonable agreement with previous measurements for these species. Vertical column densities of the best-fitting gradient models for HNC and HC3N are 1.9 × 10(exp 13) per sq.cm and 2.3 × 10(exp 14) per sq.cm, respectively.

ALMA Telescope↗
NASA NTRS1977

The expansion velocities of laser-produced plasmas determined from extreme ultraviolet spectral line profiles

The expansion of laser-produced plasma is determined from the shapes of spectral lines of highly ionized iron emitted in the extreme ultraviolet. The plasmas were produced by focusing the pulse from a Nd:glass laser onto solid planar targets, and spectra were recorded with a high-resolution grazing-incidence spectrograph. From the Doppler broadening of lines of Fe XX and Fe XXI, expansion velocities of about 830 km/s were determined. The relative time-averaged ion abundances of Fe XVIII, Fe XIX, Fe XX, and Fe XXI are estimated for three different spectra. The abundances do not differ by more than a factor of 4 for any of the spectra.

Feldman, U.↗