Infrared spectroscopy experiment on the Mariner 9 mission: Preliminary results
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Hanel, R. A.↗
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The Nimbus 4 infrared spectroscopy experiment. 2: Comparison of observed and theoretical radiance from 425-1450 cm(minus 1)
The Nimbus 4 infrared interferometer spectrometer (IRIS) measured the thermal emission of the earth's atmosphere and surface from 400-1600/cm with an apodized spectral resolution of 2.8/cm. A comparison of theoretical radiances, computed from in-situ measurements and using a direct integration slant path atmospheric transmittance model, with the observed IRIS radiances has been made to verify the radiometeric and spectral performance of the instrument and to assess the accuracy of the atmospheric transmittances. The radiance comparison has indicated a relatively constant difference of less than 5% in the water vapor continuum in the 425-550/cm and 750-1200/cm atmospheric window regions while in the 667/cm CO2 band the difference was 5-10%. The absolute accuracy was found to be approximately 5-10% for each of the parameters; measured radiances, in-situ measurements, and the atmospheric transmittances, thus it is not possible to uniquely specify the degree of error arising from each parameter in the total resultant difference.
Kunde, V. G.↗
Infrared spectroscopy experiment: An overview
A retrospective look at the operation and results of the experiment is presented. The design and performance of the infrared interferometer spectrometer are discussed along with the results obtained concerning the atmospheric and surface properties.
Hanel, R.↗
Outer planets Grand Tour ultraviolet spectroscopy experiment
The principal objective is presented of the UV observations, with emphasis placed on hydrogen and helium. Calculations are given for airglow and occultation. Mission requirements and trajectories are also reported for future observations.
Donahue, T. M.↗
The Nimbus 4 infrared spectroscopy experiment. II - Comparison of observed and theoretical radiances from 425-1450 wavelengths/cm
The Nimbus 4 infrared interferometer spectrometer (IRIS) measured the thermal emission of the earth's atmosphere and surface from 400-1600 wavelengths/cm with an apodized spectral resolution of 2.8 wavelengths/cm. A comparison of theoretical radiances, computed from in situ measurements and using a direct integration slant path atmospheric transmittance model, with the observed IRIS radiances has been made to verify the radiometric and spectral performance of the instrument and to assess the accuracy of the atmospheric transmittances. The radiance comparison has indicated a relatively constant difference of less than 5% in the water vapor continuum in the 425 to 550 wavelengths/cm and 750 to 1200 wavelengths/cm atmospheric 'window' regions, whereas in the 667 wavelengths/cm CO2 band the difference was 5-10%.
Kunde, V. G.↗
The Nimbus 4 infrared spectroscopy experiment. III - Observations of the lower stratospheric thermal structure and total ozone
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Prabhakara, C.↗
The ATMOS (Atmospheric Trace MOlecule Spectroscopy) experiment - A tool for global monitoring of the middle atmosphere
A review is presented of the objectives, instrumentation, performance and results of the ATMOS program developed by NASA-JPL as part of the Spacelab 3 shuttle payload. ATMOS was developed to obtain high-resolution spectroscopic information of the middle atmosphere, from which the vertical distribution of the most possible trace and minor molecules could be retrieved. A complete occultation included not only data recorded when the optical path traversed the earth's atmosphere, but also many spectra with tangent heights big enough for no more telluric absorptions to be detected. The averaging of such 'high sun' observations has provided high quality solar spectra totally free of atmospheric absorption features.
Zander, R.↗
Construction of a Visible Diode Laser Source for Free Radical Photochemistry and Spectroscopy Experiments
Tunable diode lasers are reliable sources of narrow-band light and comparatively cheap. Optical feedback simplifies frequency tuning of the laser diodes. We are building an inexpensive diode laser system incorporating optical feedback from a diffraction grating. The external optical cavity can be used with lasers that emit between 2 and 100 mW, and will also work if they are pulsed, although this will significantly degrade the bandwidth. The diode laser output power and bandwidth are comparable to CW dye lasers used in kinetics and dynamics experiments. However, their cost and maintenance will be much less as will alignment time. We intend to use the diode lasers to investigate CN and C2 kinetics as well as to study dissociation dynamics of atmospherically important molecules.
Newman, Bronjelyn↗
Jupiter's atmospheric composition from the Cassini thermal infrared spectroscopy experiment
The Composite Infrared Spectrometer observed Jupiter in the thermal infrared during the swing-by of the Cassini spacecraft. Results include the detection of two new stratospheric species, the methyl radical and diacetylene, gaseous species present in the north and south auroral infrared hot spots; determination of the variations with latitude of acetylene and ethane, the latter a tracer of atmospheric motion; observations of unexpected spatial distributions of carbon dioxide and hydrogen cyanide, both considered to be products of comet Shoemaker-Levy 9 impacts; characterization of the morphology of the auroral infrared hot spot acetylene emission; and a new evaluation of the energetics of the northern auroral infrared hot spot.
Hydrocarbons↗
Lunar and Planetary Science XXXV: Meteorites: Experiments and Spectroscopy
The session "Meteorites: Experiments and Spectroscopy" included the following reports:The Suitability of Laser Induced Breakdown Spectroscopy for Determining the Compositions of Extraterrestrial Material; Deconvolving Terrestrial Alteration Mineral Spectral Signatures from Meteorite Reflectance Measurements; Impacts of Ions and Micrometeorites on Mineral Surfaces: Reflectance and Chemical Changes Found in Ordinary Chondrites; FT-IR Micro-spectroscopy of Fine-grained Planetary Materials: Further Results; Effusion Cell Measurements of the Vapor Pressure of Cobalt at Temperatures up to 2000K: Comparisons with Iron and Nickel; Kinetics of Fe2+-Mg Order-Disorder in P21/c Pigeonite: Implications for Cooling Rates Calculations; Compressional and Shear Wave Velocities in Meteorites; Chemical and Mineralogical Size Segregation in the Impact Disruption of Anhydrous Stone Meteorites; and Shock Pressures of Impacts vs. Crystallization Pressures of Shock-induced Melt Veins of the chondrites.
Source record↗
High resolution infrared spectroscopy from space: A preliminary report on the results of the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment on Spacelab 3
The ATMOS (Atmospheric Trace Molecule Spectroscopy) experiment has the broad purpose of investigating the physical structure, chemistry, and dynamics of the upper atmosphere through the study of the distributions of the neutral minor and trace constituents and their seasonal and long-term variations. The technique used is high-resolution infrared absorption spectroscopy using the Sun as the radiation source, observing the changes in the transmission of the atmosphere as the line-of-sight from the Sun to the spacecraft penetrates the atmosphere close to the Earth's limb at sunrise and sunset. During these periods, interferograms are generated at the rate of one each second which yield, when transformed, high resolution spectra covering the 2.2 to 16 micron region of the infrared. Twenty such occultations were recorded during the Spacelab 3 flight, which have produced concentration profiles for a large number of minor and trace upper atmospheric species in both the Northern and Southern Hemispheres. Several of these species have not previously been observed in spectroscopic data. The data reduction and analysis procedures used following the flight are discussed; a number of examples of the spectra obtained are shown, and a bar graph of the species detected thus far in the analysis is given which shows the altitude ranges for which concentration profiles were retrieved.
Farmer, Crofton B.↗
(abstract) Validation of Stratospheric Ozone Observed by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment During 1992
Stratospheric ozone measurements made by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment from onboard the Space Shuttle during the period 8-16 April 1992 are compared with other space-based remote sensing measurements.
ozone↗
Validation of stratospheric ozone observed by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment during 1992
Measurements of stratospheric ozone were made by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment from onboard the Space Shuttle during the period 8-16 April 1992. The precision and accuracy of the measurements are discussed in the context of establishing the accuracy and compatibility of the measurements relative to other space-based measurements of ozone. Coincident measurements were obtained from the Stratospheric Aerosol and Gas Experiment (SAGE) 2 instrument onboard the Earth Radiation Budget Satellite (ERBS) and three instruments, the Microwave Limb Sounder (MLS), the Cryogenic Limb Array Etalon Spectrometer (CLAES), the Halogen Occultation Experiment (HALOE) onboard the Upper Atmospheric Research Satellite (UARS). Three of the instruments, ATMOS, SAGE-2 and MLS are demonstrated to be consistent to within +10% over the altitude range between 100 hPa and 0.5 hPa (approximately 20 to 60 km), with ATMOS and MLS displaying a zero mean bias and a root mean square deviation (rms) of 3% and SAGE-2 displaying an essentially systematic bias of -5% over the majority of the altitude range, except for below 30 hPa where SAGE-2 displays a large positive systematic bias due to the effect of the aerosol attenuation resulting from the Mt. Pinatubo volcanic eruption in 1991. The comparison with HALOE indicates that ozone levels observed by ATMOS are systematically higher than HALOE by 5 to 25% with a clear gradient in the differences; in contrast the comparison with CLAES displays differences of as much as + 30% with no obvious systematic scaling possible. Comparisons are evaluated in two separate schemes, by geographical coincidence and through zonal averages which illustrate the limitations of both schemes. Latitudinal and longitudinal variation are used to assess the sensitivity of the ATMOS measurements and to confirm the precision and accuracy, which should be less than 4% and 10% respectively.
Abrams, M. C.↗
A data reduction package for multiple object spectroscopy
Experience with fiber-optic spectrometers has demonstrated improvements in observing efficiency for clusters of 30 or more objects that must in turn be matched by data reduction capability increases. The Medusa Automatic Reduction System reduces data generated by multiobject spectrometers in the form of two-dimensional images containing 44 to 66 individual spectra, using both software and hardware improvements to efficiently extract the one-dimensional spectra. Attention is given to the ridge-finding algorithm for automatic location of the spectra in the CCD frame. A simultaneous extraction of calibration frames allows an automatic wavelength calibration routine to determine dispersion curves, and both line measurements and cross-correlation techniques are used to determine galaxy redshifts.
Hill, J. M.↗
The Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment: Experiences From Three Space Shuttle Missions
The Atmospheric Trace Molecule Spectroscopy (ATMOS) project was initiated more than ten years ago, as an investigation of the detailed chemical composition of the middle atmosphere.
spectrometer amospheric constituents↗
Laser Spectroscopy of Exotic Atoms and Molecules Containing Octupole-Deformed Nuclei
This project investigated the nuclear, atomic, and molecular structure of exotic atoms and molecules containing actinide isotopes. These short-lived radioactive systems are challenging to produce and study in the laboratory, yet they offer unique opportunities for fundamental science. These nuclei are predicted to exhibit pear-shaped (octupole) deformation, a rare collective nuclear behavior that dramatically enhances their sensitivity to fundamental physics phenomena such as time-reversal- and parity-violating effects. Such enhancements make them ideal probes for exploring open questions in our understanding of the universe such as the origin of the matter–antimatter asymmetry of the universe. To realize these measurements, the project led the development of a new laser spectroscopy experiment at MIT, and later commissioned at the Facility for Rare Isotope Beams (FRIB) at Michigan State University: the Resonance Ionization Spectroscopy Experiment (RISE). RISE combines the spectroscopic precision of collinear laser spectroscopy with the sensitivity of particle-detection techniques, enabling measurements of rare isotopes produced at rates as low as a few ions per second. The beamline was designed, built, and installed, and was successfully commissioned at FRIB during the grant period. RISE is now a permanent capability of the FRIB facility, and has produced several results on the study of rare atoms and molecules for nuclear structure and fundamental symmetries. In parallel with the FRIB program, the project contributed to the first precision laser-spectroscopy measurements of short-lived radioactive molecules. Working with international collaborators at CERN's ISOLDE facility, the team conducted pioneering experiments on radium monofluoride (RaF) and actinium monofluoride (AcF). The results from this work have been published in major journals of science, including Nature, Science, Nature Physics, Nature Communications, and Physical Review Letters. These findings have guided future experiments on the laser cooling of radioactive molecules, opening a new platform for precision tests of fundamental symmetries.
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
time-resolved spectroscopy fit (trspecfit) v0.01
Analyze 2D time- and energy-resolved data, such as from a pump-probe spectroscopy experiment. User can select and input different peak shapes/ functions and background types to first fit a ground state/ unperturbed spectrum. This would be similar to how standard spectroscopy data is fit. Subsequently, to describe the time domain, users can choose functions that describe the temporal dynamics of one or more spectral features, such as a peak amplitude, peak position, etc. These time dynamics functions can be added or convoluted (e.g. describing an instrument response function) with each other. Functionality to integrate implicit variables leading to distributions of certain parameters/ functions is in development. Alternatively, 2D data can be analyzed one time step at a time to get an idea of the time dynamics of the system before deploying the global 2D fit described above. Typically people write custom software for this purpose. During my PhD I've seen five internal LBL and external researchers write one-off code in different languages to analyze time- and energy-resolved spectra. While this was specifically was for a laser pump - X-ray probe spectroscopy experiment, I'm trying to write a general package for the time-resolved spectroscopy community.
Mahl, Johannes [Lawrence Berkeley National Laborat↗
High-speed assembly language (80386/80387) programming for laser spectra scan control and data acquisition providing improved resolution water vapor spectroscopy
An assembly language program using the Intel 80386 CPU and 80387 math co-processor chips was written to increase the speed of data gathering and processing, and provide control of a scanning CW ring dye laser system. This laser system is used in high resolution (better than 0.001 cm-1) water vapor spectroscopy experiments. Laser beam power is sensed at the input and output of white cells and the output of a Fabry-Perot. The assembly language subroutine is called from Basic, acquires the data and performs various calculations at rates greater than 150 faster than could be performed by the higher level language. The width of output control pulses generated in assembly language are 3 to 4 microsecs as compared to 2 to 3.7 millisecs for those generated in Basic (about 500 to 1000 times faster). Included are a block diagram and brief description of the spectroscopy experiment, a flow diagram of the Basic and assembly language programs, listing of the programs, scope photographs of the computer generated 5-volt pulses used for control and timing analysis, and representative water spectrum curves obtained using these programs.
Allen, Robert J.↗