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At least 37 records · Page 2

The Role of Marangoni Convection for the FZ-Growth of Silicon

Growing crystals by the floating zone (FZ) technique under microgravity avoids the size restriction we have under earth conditions due to hydrostatic pressure. Further, buoyancy related convection is eliminated to a great degree. But in the case of silicon, the gravity independent thermocapillary (Marangoni) convection is time-dependent even for small zone geometries. This has been demonstrated in several Technische Experimente unter Schwerelosigkeit (TEXUS) technical experiments under reduced gravity flights. Thus, to really take advantage of microgravity with respect to improved crystal quality, tools are required to control Marangoni convection in space facilities. With the application of magnetic fields, convection can be influenced; fluid flow can either be damped (static magnetic fields) or overlaid by a regular flow regime (rotating magnetic fields). In floating zones of 8-10 mm diameter and height (i.e., Ma is much greater than 6X 10(exp 3), a static magnetic field of about 2OOmT is sufficient to suppress time-dependent Marangoni convection to a high degree, but in dependence on the kind and the concentration of the added dopant, a new type of strongly pronounced dopant inhomogeneities have been detected. They are originated by thermoelectromagnetic convection. This can be avoided as well as detrimental effects on the radial dopant distribution by using rotating magnetic fields instead of static ones. Applying 7.5mT/5OHz to the FZ, the intensity of the dopant fluctuations is reduced to a high degree. Considering the rather low power consumption of rotating magnetic fields, this will be a useful tool for control or elimination of time-dependent Marangoni convection under microgravity. The strong time-dependent character of thermocapillary flow and its influence on the temperature field has been measured in silicon half-zones for Marangoni numbers of Ma is much greater than l - 1.5 X 10(exp 4): temperature fluctuations up to 4C have been determined, their frequency range was 0.4 and 0.4Hz. Between certain thermocouple or sensor pairs, strong correlation has been detected.

Dold, P.↗

Phase-controlled direct laser acceleration enabled by longitudinal variation of the laser-driven quasi-static plasma magnetic field

Direct laser acceleration (DLA) enables energy transfer from an ultra-high-intensity laser to plasma electrons and underpins many laser-driven particle and radiation-source concepts. A laser-driven azimuthal plasma magnetic field is a key player in this process: it confines energetic electrons, induces betatron oscillations, and makes possible a resonant interaction between the betatron motion and the laser field. While this betatron resonance can enhance electron energy gain, the gain itself generally drives frequency detuning and promotes largely reversible energy exchange that limits net acceleration. Here we show, using a test-electron model with prescribed fields, that a slow longitudinal increase of the quasi-static plasma magnetic field qualitatively changes DLA by introducing hysteresis in the ratio of the betatron frequency to the laser frequency experienced by the electron, so that this ratio depends on the prior evolution of the electron even at the same energy. This hysteresis enables phase control of the electron-laser energy exchange and suppresses the usual reversibility of DLA, allowing electrons to retain the acquired energy and sustain energy gain without intermittent losses.

direct laser acceleration↗

Semiconductor Crystal Growth in Static and Rotating Magnetic fields

Magnetic fields have been applied during the growth of bulk semiconductor crystals to control the convective flow behavior of the melt. A static magnetic field established Lorentz forces which tend to reduce the convective intensity in the melt. At sufficiently high magnetic field strengths, a boundary layer is established ahead of the solid-liquid interface where mass transport is dominated by diffusion. This can have a significant effect on segregation behavior and can eliminate striations in grown crystals resulting from convective instabilities. Experiments on dilute (Ge:Ga) and solid solution (Ge-Si) semiconductor systems show a transition from a completely mixed convective state to a diffusion-controlled state between 0 and 5 Tesla. In HgCdTe, radial segregation approached the diffusion limited regime and the curvature of the solid-liquid interface was reduced by a factor of 3 during growth in magnetic fields in excess of 0.5 Tesla. Convection can also be controlled during growth at reduced gravitational levels. However, the direction of the residual steady-state acceleration vector can compromise this effect if it cannot be controlled. A magnetic field in reduced gravity can suppress disturbances caused by residual transverse accelerations and by random non-steady accelerations. Indeed, a joint program between NASA and the NHMFL resulted in the construction of a prototype spaceflight magnet for crystal growth applications. An alternative to the suppression of convection by static magnetic fields and reduced gravity is the imposition of controlled steady flow generated by rotating magnetic fields (RMF)'s. The potential benefits of an RMF include homogenization of the melt temperature and concentration distribution, and control of the solid-liquid interface shape. Adjusting the strength and frequency of the applied magnetic field allows tailoring of the resultant flow field. A limitation of RMF's is that they introduce deleterious instabilities above a critical magnetic field value. Growth conditions in which static magnetic fields rotational magnetic fields, and reduced gravitational levels can have a beneficial role will be described.

Volz, Martin↗

Whistler modulational instability.

Derivation of the modulational instability characteristics of whistlers in cold and hot plasmas. The cold-plasma analysis considers both ion motion and relativistic effects; the unstable band, with a growth rate proportional to (B/B sub zero)squared, is contiguous to Omega sub e/4 and, depending on the plasma density, lies above or below that frequency (Omega sub e is the electron cyclotron frequency of the static magnetic field; B and B sub zero are the whistler and static magnetic fields). In hot plasmas, stability occurs between Omega sub e/4 and Omega prime (less than Omega sub e), with Omega prime depending mainly on the mean energy and anisotropy of the energetic electron population; the complementary unstable band has a growth rate proportional to (B/B sub zero) to the 1/2 power. The relevance of the instability to whistlers in the magnetosphere is discussed.

Brinca, A. L.↗

The Role of Marangoni Convection for the FZ-Growth of Silicon

Fluctuations of the electrical resistivity due to inhomogeneous dopant distribution are still a serious problem for the industrial processing yield of doped silicon crystals. In the case of silicon floating-zone growth, the main sources of these inhomogeneities are time- dependent flows in the liquid phase during the growth process. Excluding radio frequency (RF) induced convection, buoyancy and thermocapillary (Marangoni) convection are the two natural reasons for fluid flow. Both originate from temperature/concentration gradients in the melt, buoyancy convection through thermal/concentrational volume expansion, and thermocapillary convection through the temperature/concentration dependence of the surface tension. To improve the properties of grown crystals, knowledge of the strength, the characteristic, and the relation of these two flow mechanisms is essential. By the use of microgravity, the effect and the strength of buoyancy (gravity dependent) and thermocapillary (gravity independent) convection can be separated and clarified. Applying magnetic fields, both convective modes can be influenced: fluid flow can either be damped (static magnetic fields) or overlaid by a regular flow regime (rotating magnetic fields). Two complementary approaches have been pursued: Silicon full zones (experiments on the German sounding rockets TEXUS 7, 12, 22, 29, and 36) with the maximum temperature at half of the zone height and silicon half zones (experiments on the Japanese sounding rockets TR-IA4 and 6) with the maximum temperature at the top of the melt. With the full zone arrangement, the intensity and the frequency of the dopant striations could be determined and the critical Marangoni number could be identified. The half zone configuration is suited to classify the flow pattern and to measure the amplitude and the frequency of temperature fluctuations in the melt by inserting thermocouples or temperature sensors into the melt. All experiments have been carried out in monoellipsoid mirror furnaces. Typical zone geometries are approx. 8 to 14 mm in diameter and height. The crystals grown under microgravity are compared to crystals grown in static axial magnetic fields (B<5 tesla) and in transversal rotating magnetic fields (B<7.5 mT / f=50 Hz). Experimental results are completed by 3D numerical simulations: the obtained temperature and concentration distribution in the melt confirm the damping effect of rotating magnetic fields and explain the change in the radial segregation under static magnetic fields.

Dold, P.↗

Heating system with induction power supply and electromagnetic acoustic transducer with induction power supply

A system for heating a fluid and an electromagnetic acoustic transducer EMAT system is provided. Both systems have a drive circuit. The amount of heat and the amplitude (and acceleration) of the vibrations is respectively controllable by controlling an input to a terminal of a switch. The heating system comprises a porous graphite foam conductor which is exposed to an electromagnetic field generated by an oscillating circuit. When exposed, the foam conductor conducts induced electric current which heats the same and a fluid in contact with the conductor. The EMAT system comprises at least one magnet configured to generate a static magnetic field, an oscillating circuit and a working element. The working element, when exposed to the static magnetic field and the electromagnetic field produced by the oscillating circuit, vibrates against a load. The vibrations dry the load.

Kisner, Roger A.↗

The Influence of Static and Rotating Magnetic Fields on Heat and Mass Transfer in Silicon Floating Zones

Hear and mass transfer in float-zone processing are strongly influenced by convective flows in the zone. They are caused by buoyancy convection, thermocapillary (Marangoni) convection, or artificial sources such as rotation and radio frequency heating. Flows in conducting melts can be controlled by the use of magnetic fields, either by damping fluid motion with static fields or by generating a def@ned flow with rotating fields. The possibilities of using static and rotating magnetic fields in silicon floating-zone growth have been investigated by experiments in axial static fields up to ST and in transverse rotating magnetic fields up to 7.S mT. Static fields of a few 100 MT already suppress most striations but are detrimental to the radial segregation by introducing a coring effect. A complete suppression of dopant striations caused by time-dependent thermocapillary convection and a reduction of the coring to insignificant values, combined with a shift of the axial segregation profile towards a more diffusion-limited case, is possible with static fields ? 1T. However, under certain conditions the use of high axial magnetic fields can lead to the appearance of a new type of pronounced dopant striations, caused by thermoelec:romagnetic convection. The use of a transverse rotating magnetic field influences the microscopic segregation at quite low inductions, of the order of a few mT. The field shifts time-dependent flows and the resulting striation patterns from a broad range of low frequencies at high amplitudes to a few high frequencies at low amplitudes

Croell, Arne↗

The Influence of Static and Rotating Magnetic Fields on Heat and Mass Transfer in Silicon Floating Zones

Heat and mass transfer in float-zone processing are strongly influenced by convective flows in the zone. They are caused by buoyancy convection, thermocapillary (Marangoni) convection, or artificial sources such as rotation and radio-frequency heating. Flows in conducting melts can be controlled by the use of magnetic fields, either by damping fluid motion with static fields or by generating a defined flow with rotating fields. The possibilities of using static and rotating magnetic fields in silicon floating-zone growth have been investigated by experiments in axial static fields up to 5 T and in transverse rotating magnetic fields up to 7.5 mT. Static fields of a few 100 mT already suppress most striations but are detrimental to the radial segregation by introducing a coring effect. A complete suppression of dopant striations caused by time-dependent thermocapillary convection and a reduction of the coring to insignificant values, combined with a shift of the axial segregation profile toward a more diffusion-limited case, is possible with static fields greater than or equal to 1 T. However, under certain conditions the use of high axial magnetic fields can lead to the appearance of a new type of pronounced dopant striations, caused by thermoelectromagnetic convection. The use of a transverse rotating magnetic field influences the microscopic segregation at quite low inductions, of the order of a few millitesla. The field shifts time- dependent flows and the resulting striation patterns from a broad range of low frequencies at high amplitudes to a few high frequencies at low amplitudes.

Croll, A.↗

Exact-Two-Component Complete Active Space Method with Variational Treatment of Magnetic Field and Spin–Orbit Coupling: Application to X-ray Magnetic Circular Dichroism Spectroscopy

We introduce an exact-two-component complete active space self-consistent-field (X2C-CASSCF) method formulated under the restricted-magnetic-balance condition. This framework allows for the nonperturbative treatment of static magnetic fields using gauge-including atomic orbitals (GIAOs). The GIAO-X2C-CASSCF methodology effectively captures all microstates within the same 2J + 1-degenerate manifold and their splitting in a static magnetic field, which are not accessible through single-reference-based methods. We also present mathematical recursive expressions for evaluating one-electron relativistic integrals by using GIAOs in the presence of a finite magnetic field. Benchmark studies include oxygen and nitrogen K-edge X-ray magnetic circular dichroism spectroscopy (XMCD) for closed-shell organic compounds, as well as L-edge XMCD spectroscopy for the high-spin open-shell transition metal ion Mn 2+ and the tetrahedral Mn(II)O 4 6– complex.

Chemical calculations↗

Electron cyclotron wave acceleration outside a flaring loop

A model for the secondary acceleration of electrons outside a flaring loop is proposed. The results suggest that the narrow bandwidth radiation emitted by the unstable electron distribution inside a flaring loop can become the driver for secondary electron acceleration outside the loop. It is shown that a system of electrons gyrating about and streaming along an adiabatically spatially varying, static magnetic field can be efficiently accelerated to high energies by an electromagnetic wave propagating along and polarized transverse to the static magnetic field. The predictions from our model appear to be in general agreement with existing observations.

Sprangle, P.↗

Ring current electron trajectories associated with VLF emissions

The reported investigation had the objective to explain features of the ring current electron enhancements which are associated with the simultaneously observed VLF emissions during geomagnetic storms and substorms. Two examples of the electron intensity enhancements observed by Explorer 45 are presented, and the calculations of the electron trajectories injected from the geomagnetic tail into the nightside of the plasmasphere are discussed. These calculations are performed by modifying the computer program developed by Ejiri (1978) to explain the so-called nose events of the ring current protons. The presented calculation demonstrates the soundness of the models of the convective electric field and the static magnetic field.

Maeda, K.↗

Magnetic Field Effect on the Stability of Flow Induced by a Rotating Magnetic Field

A linear stability analysis has been performed for the flow induced by a rotating magnetic field in a cylindrical column filled with electrically conducting fluid. The first transition is time-independent and results in the generation of Taylor vortices. The critical value of the magnetic Taylor number has been examined as a function of the strength of the transverse rotating magnetic field, the strength of an axial static magnetic field, and thermal buoyancy. Increasing the transverse field increases the critical magnetic Taylor number and decreases the aspect ratio of the Taylor vortices at the onset of instability. An increase in the axial magnetic field also increases the critical magnetic Taylor number but increases the aspect ratio of the Taylor vortices. Thermal buoyancy is found to have only a negligible effect on the onset of instability.

Mazuruk, K.↗

Magnetic Field Effect on the Stability of Flow Induced by a Rotating Magnetic Field

A linear stability analysis has been performed for the flow induced by a rotating magnetic field in a cylindrical column filled with electrically conducting fluid. The first transition is time- independent and results in the generation of Taylor vortices. The critical value of the magnetic Taylor number has been examined as a function of the strength of the transverse rotating magnetic field, the strength of an axial static magnetic field, and thermal buoyancy. Increasing the transverse field increases the critical magnetic Taylor number and decreases the aspect ratio of the Taylor vortices at the onset of instability. An increase in the axial magnetic field also increases the critical magnetic Taylor number but increases the aspect ratio of the Taylor vortices. Thermal buoyancy is found to have only a negligible effect on the onset of instability.

Mazuruk, K.↗

Quantitative measurements of reactive oxygen species partitioning in electron transfer flavoenzyme magnetic field sensing

Biological magnetic field sensing that gives rise to physiological responses is of considerable importance in quantum biology. The radical pair mechanism (RPM) is a fundamental quantum process that can explain some of the observed biological magnetic effects. In magnetically sensitive radical pair (RP) reactions, coherent spin dynamics between singlet and triplet pairs are modulated by weak magnetic fields. The resulting singlet and triplet reaction products lead to distinct biological signaling channels and cellular outcomes. A prevalent RP in biology is between flavin semiquinone and superoxide (O 2 •–) in the biological activation of molecular oxygen. This RP can result in a partitioning of reactive oxygen species (ROS) products to form either O 2 •– or hydrogen peroxide (H 2 O 2 ). Here, we examine magnetic sensing of recombinant human electron transfer flavoenzyme (ETF) reoxidation by selectively measuring O 2 •– and H 2 O 2 product distributions. ROS partitioning was observed between two static magnetic fields at 20 nT and 50 μT, with a 13% decrease in H 2 O 2 singlet products and a 10% increase in O 2 •– triplet products relative to 50 µT. RPM product yields were calculated for a realistic flavin/superoxide RP across the range of static magnetic fields, in agreement with experimental results. For a triplet born RP, the RPM also predicts about three times more O 2 •– than H 2 O 2 , with experimental results exhibiting about four time more O 2 •– produced by ETF. The method presented here illustrates the potential of a novel magnetic flavoprotein biological sensor that is directly linked to mitochondria bioenergetics and can be used as a target to study cell physiology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Momentum space AC Josephson effect and intervalley coherence in multilayer graphene

Electron transport driven by the phase coherence and interference of quantum many-body wavefunctions is a fascinating phenomenon with potential technological significance. Superconductivity, for example, enables dissipationless transport through macroscopic phase twisting, while charge-density waves show broadband noise and AC-DC interference once their phase is depinned. We identify an analogous phase-coherent dynamics in the intervalley-coherent (IVC) state frequently observed in rhombohedral multilayer graphene. We show that a static magnetic field drives an oscillating intervalley current, which produces an oscillating orbital magnetization and thereby a detectable AC Hall response. This mechanism is similar to the Josephson effect observed in superconductors but now happening in momentum space. In this analogy, the static magnetic field acts as the DC voltage, while the oscillating intervalley current is the AC Josephson current. We provide microscopic calculations of all the phase-number free-energy parameters in rhombohedral trilayer graphene, establishing this effect as an experimental signature of IVC order.

electronic properties and materials↗

Nonexistence of integrable nonlinear magnetic fields with invariants quadratic in momenta

Nonlinear, completely integrable Hamiltonian systems that serve as blueprints for novel particle accelerators at the intensity frontier are promising avenues for research, as Fermilab’s Integrable Optics Test Accelerator (IOTA) example clearly illustrates. Here, we show that only very limited generalizations are possible when no approximations in the underlying Hamiltonian or Maxwell equations are allowed, as was the case for IOTA. Specifically, no such systems exist with invariants quadratic in the momenta, precluding straightforward generalization of the Courant-Snyder theory of linear integrable systems in beam physics. We also conjecture that no such systems exist with invariants of higher degree in the momenta. This leaves solenoidal magnetic fields, including their nonlinear fringe fields, as the only completely integrable static magnetic fields, albeit with invariants that are linear in the momenta. The difficulties come from enforcing Maxwell equations; without constraints, we show that there are many solutions. In particular, we discover a previously unknown large family of integrable Hamiltonians.

97 MATHEMATICS AND COMPUTING↗

Voltage-Controlled Differential Faraday Rotation from FMNWs and Magnetoelastic Silicone-Nickel Composites

Differential Faraday rotation has been observed from strain-Differential Faraday rotation has been observed from strain-modulated magnetoelastic membranes using millimeter-wave polarimetry at 61.25 GHz. The membranes, consisting of aligned chains of nickel micro-particles embedded in silicone rubber, were manufactured using a roll-to-roll electromagnetic processing line, mounted onto piezoelectric ceramic annuli, and immersed in externally-generated static magnetic fields. Experiments were conducted in which the membranes were periodically stretched by operating the piezoelectric crystals close to their radial resonant frequencies—thereby modulating nickel particle density as well as magnetic material properties. A customized quasi-optical apparatus was used to determine the Faraday-rotation difference between the strained and unstrained states of the magnetoelastic membranes. Possible applications that could emerge from this polymer-based technology include nonreciprocal millimeter-wave components with voltage-controlled frequency response and bio-inspired geomagnetic sensors for GPS-denied navigation. Investigations were conducted to estimate the maximum attainable differential Faraday rotation and the minimum detectable static magnetic field.

nickel↗

High-Sensitivity rf Detection Using an Optically Pumped Comagnetometer Based on Natural-Abundance Rubidium with Active Ambient-Field Cancellation

To detect a specific radio-frequency (rf) magnetic field, rf optically pumped magnetometers (OPMs) require a static magnetic field to set the Larmor frequency of the atoms equal to the frequency of interest. However, unshielded and variable magnetic field environments (e.g., an rf OPM on a moving platform) pose a problem for rf OPM operation. Here, we demonstrate the use of a natural-abundance rubidium vapor to make a comagnetometer to address this challenge. Our implementation builds upon the simultaneous application of several OPM techniques within the same vapor cell. First, we use a modified implementation of an OPM variometer based on 87 Rb to detect and actively cancel unwanted external fields at frequencies ≲60 Hz using active feedback to a set of field control coils. In this experiment, we exploit this stabilized field environment to implement a high-sensitivity rf magnetometer using 85 Rb. Using this approach, we demonstrate the ability to measure rf fields with a sensitivity of approximately 9 fT Hz -1/2 inside a magnetic shield in the presence of an applied field of approximately 20 μT along three mutually orthogonal directions. This demonstration opens up a path toward completely unshielded operation of a high-sensitivity rf OPM.

47 OTHER INSTRUMENTATION↗