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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Field Test and Thermal Performance Comparison of a Novel Underground Thermal Battery with a Single U-tube Borehole Heat Exchanger for Geothermal Heat Pump Application

Geothermal Heat Pumps (GHP) are a proven technology to electrify and decarbonize space heating and cooling by utilizing the thermally consistent underground as a heat sink or source. However, the high drilling costs of conventional borehole heat exchangers (BHEs) associated with GHP systems and subsurface heterogeneity have been two major challenges to their widespread adoption. In this paper, we present results from a field-scale pilot of an Underground Thermal Battery (UTB) as a potential alternative to a conventional BHE. To benchmark the UTB performance, a side-by-side field test was conducted to compare the UTB with a conventional BHE installed at the same site. The UTB was installed in a 7.01-meter-deep borehole having a diameter of 0.9 meter, whereas the conventional BHE (with single U-tube loop) is in a borehole with 36.6-meter depth and 0.15-meter diameter. Both are integrated into a GHP system to meet the thermal energy demands of office space at the Illinois Energy Farm on the University of Illinois Urbana-Champaign campus. The system’s performance is compared in terms of heat transfer rate, outlet temperatures, and contributions to the overall thermal power of the GHP system under varying thermal demands and in different heat pump operation modes: heating only, cooling only, and hybrid (alternative, diurnal heating and cooling). Results to date indicate that the UTB delivers a more consistent response under during a time period of varying thermal demands. Its operational performance is better during short-term with higher thermal demands, while the conventional BHE performs better under continuous, long-term thermal demands.

Pokhrel, Sajjan [ORNL] (ORCID:0000000228523749)↗

Experimental study on a novel three-phase absorption thermal battery with high energy density applied to buildings

Buildings contribute to 75% of total electricity consumption and 80% of peak electricity demand in the United States. A significant portion of building electricity consumption goes to space conditioning. Therefore, using thermal energy storage (TES) to decouple the building electricity consumption and the fluctuating space-conditioning load has significant potential to shift peak electricity demand and improve the stability of the grid. To provide effective TES within the spatial constraints in buildings, a three-phase absorption thermal battery (TATB) system with very high energy storage density was designed and studied. The TATB stores low-temperature heat in hydrate crystals of salts and supports space conditioning through absorption systems. In this study, a benchtop TATB using lithium chloride (LiCl) hydrate crystals as the storage material was tested under practical operating conditions for its energy storage density and discharge rate. We report the TATB successfully generated LiCl hydrate crystals during charging mode and then dissolved the crystals during discharging mode. A material-based energy storage density of 300 kWh/m 3 (specific energy of 903 kJ/kg) was achieved with a discharge rate of up to 1.3 kW thermal energy. The test results verified the high performance of the TATB and encouraged further development of this technology.

25 ENERGY STORAGE↗

Experimental Evaluation of Thermal Storage Performance of a Dual-Purpose Underground Thermal Battery

A geothermal heat pump (GHP) system is an energy-efficient building heating and cooling technology with great potential for reducing energy consumption and decarbonization. However, applications of GHP are still limited due to the high cost, of which 30% is related to the cost of installing the conventional vertical bore ground heat exchangers, which are usually installed in boreholes 60 meters deep. A dual-purpose underground thermal battery (DPUTB) has been developed to offer a low-cost ground heat exchanger with a built-in thermal storage capacity. The DPUTB innovatively integrates a shallow-bore ground heat exchanger (the outer tank), which can be installed in a borehole less than 6 m deep, with thermal energy storage (TES) (the inner tank). DPUTB has the potential to reduce the cost of a ground source heat pump system while allowing shifting the electric demand of the building served by the GHP system from peak to off-peak hours of the electric grid by charging and discharging the thermal storage. A lab-scale (1:125 in volume) DPUTB prototype was built. Phase change material (PCM) was added to increase the thermal storage capacity and maintain the supply water temperature from the TES within the desired range for direct cooling operation during the discharge period. As PCMs are critical to the TES performance of the DPUTB, this study compared the influence of different PCMs (including salt hydrate and organic PCMs) on the discharge performance of the DPUTB. The thermal State of Charge (SoC) of the DPUTB was used to compare the performance resulting from using different PCMs. Test results indicate that the organic PCM (Methyl Laurate) outperforms salt-hydrate PCMs due to a lower melting temperature and a narrower melting temperature range during the phase change process. The results of this study provide a guide for PCM selection and the optimal design of DPUTB.

Wang, Lingshi↗

Design and experimental testing of a 150 kWh thermal battery using thermosiphons embedded in a concrete matrix for power plant flexible operation

One of the options for achieving the global temperature limitation of 1.5 °C target, for the mitigation of global warming, is based on the better penetration of renewables into the electrical grid. This has imposed a burden to fossil fuel fired power plants since they are required to operate away from their baseload mode to compensate for the inherent intermittence of the renewable power. Integrating energy storage with fossil plants is an option to achieve their needed flexibility. A cost competitive energy storage option for the solution is based on storing sensible heat in concrete. Here, this paper reports research results and development of a thermal battery cell (TBC) capable of operating at temperatures up to 425 °C. A novel concept consisting of a concrete matrix for sensible heat storage, engineered to provide enhanced thermal and mechanical properties, and twenty-two thermosiphon elements, engineered for dual action were designed and fabricated into a single thermal energy storage (TES) module. Research for the development of the components for the TBC was performed in the laboratory. Efficient heat transfer, to/from the storage media, was demonstrated under several charging and discharging conditions with a thermal storage capacity of 150 kWh th and a rapid discharge, making the TBC suitable for fast ramping when integrated with a fossil fuel fired power plant. Efficient radial heat transfer to the concrete was observed due to the well designed spacing and location of thermosiphons in the radial direction. A minimal temperature difference of 2 °C, between the thermosiphons bottom and top was obtained, demonstrating the isothermicity of those elements. An overall end-to-end TBC energy-to-energy round trip efficiency of 70% was achieved.

25 ENERGY STORAGE↗

Sidewall Breach During Lithium-Ion Battery Thermal Runaway Triggered by Cell-to-Cell Propagation Visualized Using High-Speed X-Ray Imaging

With the rapid deployment of Li-ion batteries (LiBs) in a range of applications, it is crucial to ensure their safe operation. Therefore, it is necessary to investigate the rapid thermal runaway failure that LiBs can undergo if improperly operated or subjected to abuse scenarios so that hazardous events can be avoided or mitigated. Sidewall breaches or ruptures of LiBs during thermal runaway are considered the most hazardous failure scenario, resulting in hot abrasive flare from the casing of the cell that can impinge on neighbouring cells and lead to the propagation of thermal runaway throughout a battery pack. Yet, the process leading up to the sidewall breach is not well understood due to the extreme difficulty in visualizing such a failure in commercially relevant cells. With the application of a newly developed chamber for remote-controlled abuse testing of batteries coupled with simultaneous X-ray imaging, we demonstrate here for the first time an in-situ visualization of a sidewall breach. By further applying spatiotemporal mapping techniques, the internal thermal runaway events leading up to the sidewall breach can be analyzed in detail. Subsequently, the speed of the electrode layer delamination could be calculated to a speed of 0.6 m/s. These new insights bring more clarity regarding this phenomenon, that in turn can help battery designers improve battery safety.

battery safety↗

Dual Purpose – Heating & Cooling – Thermal Battery for Flexible and Energy-Efficient Heat Pump Systems

The integration of heat pumps with thermal energy storage (HP-TES) systems is gaining attention as a viable solution for managing peak building demand driven by immense cooling and heating loads. With growing reliance on renewable energy sources, thermal energy storage offers an excellent opportunity to mitigate mismatches in thermal load between energy supply and demand. The use of phase-change material (PCM) TES is especially promising, as PCMs offer significant latent energy storage capacity with smaller temperature glides in smaller volumes compared to other TES technologies. However, challenges arise because current HP-TES architectures can load-shift only cooling or heating, not both, requiring two systems and thus doubling cost, weight, and footprint. Furthermore, current research efforts lack specific tools and techniques to advance integrated systems from concept design to end-user application, focusing on only discharge performance. To address these challenges, this research proposes a dual-mode (heating and cooling) integrated HP-TES system that uses room-temperature PCM-TES as a high-temperature heat source in heating mode and a low-temperature heat sink in cooling mode, thereby reducing temperature lifts and compressor power. Design criteria for PCM-TES heat exchangers were developed, balancing thermal-hydraulic performance with practical constraints such as available building space and weight requirements along with PCM selection considerations such as shipping conditions, moisture exposure, and number of available cycles. A detailed transient model for HP-TES systems was developed to enable rapid annual performance assessments in any US climate zone.

42 ENGINEERING↗

Early Detection of Li-Ion Battery Thermal Runaway Using Commercial Diagnostic Technologies

The rate of electric vehicle (EV) adoption, powered by the Li-ion battery, has grown exponentially; largely driven by technological advancements, consumer demand, and global initiatives to reduce carbon emissions. As a result, it is imperative to understand the state of stability (SoS) of the cells inside an EV battery pack. That understanding will enable the warning of or prevention against catastrophic failures that can lead to serious injury or even, loss of life. The present work explores rapid electrochemical impedance spectroscopy (EIS) coupled with gas sensing technology as diagnostics to monitor cells and packs for failure markers. These failure markers can then be used for onboard assessment of SoS. Experimental results explore key changes in single cells and packs undergoing thermal or electrical abuse. Rapid EIS showed longer warning times, followed by VOC sensors, and then H 2 sensors. While rapid EIS gives the longest warning time, with the failure marker often appearing before the cell vents, the reliability of identifying impedance changes in single cells within a pack decreases as the pack complexity increases. This provides empirical evidence to support the significant role that cell packaging and battery engineering intricacies play in monitoring the SoS.

25 ENERGY STORAGE↗

Prevention of lithium-ion battery thermal runaway using polymer-substrate current collectors

Isolating electronically conducting material from internal short circuits is a promising way to prevent the onset of thermal runaway within lithium-ion cells. Here, a metal-coated polymer current collector, which is designed to disconnect internal short circuits by withdrawing from the heating region, is tested in 18650 cells. In addition to having lower mass and manufacturing costs, cells with metal-coated polymer current collectors demonstrate a reduced risk of thermal runaway during nail penetration. High-speed synchrotron X-ray radiography of 18650 cells during nail-penetration testing, in tandem with pre- and post-mortem X-ray computed tomography, provides insights into the function of the current collectors. The results are compared with those of 18650 cells with standard commercial aluminum and copper current collectors. Cells with aluminum-coated polymer current collectors demonstrated 100% success in thermal runaway prevention during nail penetration, retaining a cell voltage >4.00 V, while standard cells consistently experienced thermal runaway.

25 ENERGY STORAGE↗

Dynamic Earth Energy Storage: Terawatt-year, Grid-scale Energy Storage Using Planet Earth as a Thermal Battery (GeoTES): Phase I Project (Final Report)

Grid-scale energy storage has been identified by the U.S. Department of Energy’s (DOE) Energy Storage Grand Challenge as a necessary technology to support the continued build-out of intermittent renewable energy resources required to attain a carbon-free energy future. To meet this goal, the 2018 Department of Energy Research and Innovation Act mandated the creation of a comprehensive program to accelerate the development and commercialization of next-generation energy storage technologies. One of numerous energy storage technology options is the storage of excess energy as heated geothermal brine in suitable geologic formations. This concept, known as reservoir thermal energy storage (RTES), geologic thermal energy storage (GeoTES), aquifer thermal energy storage (ATES), etc., relies on the storage of thermal energy in geologic formations for recovery and use in large-scale direct use geothermal (e.g., district heating, industrial processes, etc.) and electrical power generation applications. This thermal energy is derived from excess or waste heat from any high-temperature heat source, such as concentrated solar or from conventional thermal/nuclear generation. As such, RTES can potentially play a significant role in meeting the energy storage shortfall in the coming decades. RTES can provide energy arbitrage through both the storage and production of thermal energy stored in geologic formations for direct use applications and can serve as a source of hot fluids that can be used to generate electricity to support peak demand ramping, thus easing stress on transmission and distribution. This energy storage option has geographic benefits in that energy can be stored locally or regionally depending on the various needs/loads. RTES can also be located across an enormous geographic area, without the need for a traditional hydrothermal resource but where thermal gradients and hydrogeology allow economic exploitation of subsurface heat. The work conducted for this project includes (1) a review of lessons learned from past high-temperature RTES international projects; (2) geochemical experimental investigation and numerical simulations of potential domestic sedimentary reservoirs and (3) development of a thermo-hydrological-mechanical (THM) numerical simulation tool for optimizing formation properties and design parameters to maximize thermal energy storage performance.

15 GEOTHERMAL ENERGY↗