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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1991

Negative thermal ion mass spectrometry of osmium, rhenium, and iridium

This paper describes a technique for obtaining, in a conventional surface ionization mass spectrometer, intense ion beams of negatively charged oxides of Os, Re, and Ir by thermal ionization. It is shown that the principal ion species of these ions are OsO3(-), ReO4(-), and IrO2(-), respectively. For Re-187/Os-187 studies, this technique offers the advantage of isotopic analyses without prior chemical separation of Re from Os.

Creaser, R. A.↗
NASA NTRSDate not supplied

Robust and Mass Efficient Thermal Protection Systems for Future Venus Missions

Several international Venus missions, both orbiter, and in-situ probe are in the works after a prolonged absence. Future missions are expected to be long-duration lander missions and balloon missions to investigate the cloud layer. The entry mass for these in-situ missions will be significantly higher, and the aeroshell will be larger, than previous missions. Two cardinal requirements govern the selection and use of thermal protection systems (TPS), namely, robustness to assure mission safety during entry and mass efficiency so that the useful mass for science is maximized. One cannot trade mission safety for mass when it comes to TPS. The robustness of the TPS is a paramount requirement as it is a single point of system failure. At the same time, TPS mass is carried for the entire mission duration prior to entry, and any excess TPS mass is at the cost of science payload. Future missions will benefit enormously from TPS options with mass and performance benefits far beyond advanced carbon-carbon (ACC) that is currently proposed for the DAVINCI mission. NASA STMD, and SMD jointly invested in the development of 3-D woven thermal protection systems in the last decade, and as a result, the Heat-shield for Extreme Entry Environment Technology (HEEET) TPS has been matured to TRL 6. It is ready for future mission use including Venus. The HEEET project focused on developing a broad technology base, applicable for missions not only to Venus, but also to Saturn, the Ice Giants, and higher speed sample return missions such as Mars Sample Return requiring extreme robustness due to bio-hazards. The dual-layer HEEET (DL-HEEET) is proven to be extremely robust. DL-HEEET performed well in arc jet and laser testing conditions where heritage carbon-phenolic failed. HEEET also proved to be more mass efficient compared to Carbon-Phenolic. Recently, the principal author was invited to present his perspectives to the 2023-2032 Planetary Sciences Decadal Venus subcommittee on the current state of TPS for future Venus missions [1]. In addition to pointing out successful TPS and other developments in the last decade in support of entry systems, the principal author made two findings: 1) importance of and need to sustain TPS capabilities that took nearly a decade to develop and 2) the opportunity to further optimize TPS mass without sacrificing robustness to further enable future in-situ missions. This talk will focus on the above two recommendations and provide the rationale for them. The intent of the talk is to seek advocacy from the VEXAG community for the criticality of TPS sustainment and the benefits of 3D woven TPS optimization. TPS Capability Sustainment: HEEET development was necessitated by the atrophy of heritage carbon-phenolic. Atrophy has impacted other TPS materials as well. Avcoat, the TPS that successfully allowed astronauts to explore the Moon in the 1960s and 70s, took nearly a decade and $10’sM to recover in support of Orion/Artemis. One of the most used TPS materials, SLA 561V, had to be recovered prior to its use on Mars Pathfinder. Phenolic Impregnated Carbon Ablator (PICA), the TPS that replaced SLA 561V on MSL, has undergone multiple replacements and recovery due to constituent rayon changes. Recently, NASA invested in a domestic rayon replacement program and also invested in FMI to consolidate PICA capability for NASA missions, as a result of FMI’s decision to discontinue commercial FiberForm, which is needed for PICA. TPS used for planetary missions are unique and have no other commercial or defense use. In addition, low mission cadence is also a driver for TPS atrophy. Hence, NASA, as the steward, must take steps to ensure and sustain TPS capabilities. In this talk, we outline steps NASA can take to keep abreast of emerging risks and target risk mitigation steps to ensure TPS capability sustainment for Venus and other extreme environment missions. Next Generation of Mass efficient and Robust TPS: NASA invested in an alternate TPS to PICA based on felt-technology called Conformal-PICA which has the potential to save 30% - 50% mass over PICA. The development was discontinued at a Technology Readiness Level (TRL) of ~ 5. 3D Mid-Density Carbon Phenolic (3MDCP) is a single layer variant of HEEET, based on the insulating layer only (SL-HEEET) and currently baselined for the Mars Sample Return Mission Earth Entry System due to its mass efficiency (30% more mass efficient than DL- HEEET). Currently, SL-HEEET is limited to aeroshell diameters of < 1.3m. The SL-HEEET was compared to DL-HEEET in the recent ADVENT flag-ship class mission study in support of the Planetary Science Decadal. SL HEEET was the recommended TPS based on 30% mass savings for both the balloon and lander missions. Given C-PICA and SL-HEEET have superior reliability and mass efficiency, advocacy from VEXAG is sought for completing their further development to TRL 5/6 in this decade so as to enable TPS readiness for future missions.

Thermal Protection Systems↗
NASA NTRS2013

The Thermal Hogan - A Means of Surviving the Lunar Night

document describes the Thermal Hogan, a new shelter concept that would be used on the Moon to moderate the extreme nighttime temperatures, allowing survival of equipment with minimal heater power. It is lightweight, has few mechanical parts, and would be relatively easy to deploy on the Moon. The Lunar Hogan has two parts: an insulated shelter and a thermal mass. The shelter is constructed of multilayer insulation (MLI) draped over a structural framework. Entry and egress are accomplished either by raising the structure or via a door constructed of the same MLI material as the shelter. The thermal mass can be manufactured from locally available materials, either by piling substantially sized rocks to a depth of 0.25 meter, or by filling a 0.25-meter-deep conductive honeycomb-like structure with lunar dust. For ease of transport, the structural framework and honeycomb can be collapsible. The door can be opened by pushing on it in either direction. Gravity would cause it to close and it could be sealed via magnetic strips on the doorframe.

Fruitwala, Neelay↗
NASA NTRS1973

Thermally driven mass flows in the convection zone of the sun

A formulation of the fluid dynamics of convective regions is developed which leads to an analytical description of the solar rotation, the Evershed flow, and the supergranulation. The starting point of the present formulation is the mixing length picture of convective equilibrium, but the earlier point mass model for convective molecules is replaced here by a model with both inertia and intrinsic moment of inertia. This extension introduces three rotational degrees of freedom into the dynamics of individual convective molecules, which enter into the dynamical equations for a mixing length fluid in the form of a separate vector field which we term the spin field. It is shown that for convective molecules having a spherically symmetric mass distribution, the spin field is proportional to the local vorticity.

Dijkhuis, G. C.↗
NASA NTRS1978

Some aspects of the interaction of radiation with the thermal and mass budgets of cloud droplets

It is shown that the effects of radiative heating or cooling can have a substantial influence on the mass budget of a cloud droplet and thus on the microphysical properties of a cloud as a whole. The radiative transfer equation, including all orders of multiple scattering, is solved for spectral windows of earth's atmosphere by adopting the Eddington approximation and assuming that the cloud is isothermal and illuminated by fluxes from both the ground and the sky. The results obtained for the 8-12-micron window indicate that radiative cooling can increase a droplet's growth rate and may also make the droplet cooler than the surrounding gas while water vapor is diffusing in, which would cause diffusiophoreisis and thermophoreisis to combine and increase the efficiency with which droplets would scavenge aerosols.

Barkstrom, B. R.↗
NASA NTRS1987

Fluid mass and thermal loading effects on the modal characteristics of space shuttle main engine liquid oxygen inlet splitter vanes

An analysis and evaluation of experimental modal survey test data on the variations of modal characteristics induced by pressure and thermal loading events are presented. Extensive modal survey tests were carried out on a Space Shuttle Main Engine (SSME) test article using liquid nitrogen under cryogenic temperatures and high pressures. The results suggest that an increase of pressure under constant cryogenic temperature or a decrease of temperature under high pressure induces an upward shift of frequencies of various modes of the structures.

Panossian, H. V.↗
NASA NTRS2018

Predictive Thermal Control (PTC) Technology to Enable Thermally Stable Telescopes

Validate models that predict thermal optical performance of real mirrors and structure based on their structural designs and constituent material properties, i.e. CTE distribution, thermal conductivity, thermal mass, etc.. Derive thermal system stability specifications from science-driven wavefront-stability requirement. Demonstrate utility of PTC system for achieving thermal stability.

Space Mirror Technology↗
NASA NTRS2013

An Update on the Non-Mass-Dependent Isotope Fractionation under Thermal Gradient

Mass flow and compositional gradient (elemental and isotope separation) occurs when flu-id(s) or gas(es) in an enclosure is subjected to a thermal gradient, and the phenomenon is named thermal diffusion. Gas phase thermal diffusion has been theoretically and experimentally studied for more than a century, although there has not been a satisfactory theory to date. Nevertheless, for isotopic system, the Chapman-Enskog theory predicts that the mass difference is the only term in the thermal diffusion separation factors that differs one isotope pair to another,with the assumptions that the molecules are spherical and systematic (monoatomic-like structure) and the particle collision is elastic. Our previous report indicates factors may be playing a role because the Non-Mass Dependent (NMD) effect is found for both symmetric and asymmetric, linear and spherical polyatomic molecules over a wide range of temperature (-196C to +237C). The observed NMD phenomenon in the simple thermal-diffusion experiments demands quantitative validation and theoretical explanation. Besides the pressure and temperature dependency illustrated in our previous reports, efforts are made in this study to address issues such as the role of convection or molecular structure and whether it is a transient, non-equilibrium effect only.

Sun, Tao↗
NASA NTRS2007

Imaging Thermal He(+)in Geospace from the Lunar Surface

By mass, thermal plasma dominates near-earth space and strongly influences the transport of energy and mass into the earth's atmosphere. It is proposed to play an important role in modifying the strength of space weather storms by its presence in regions of magnetic reconnection in the dayside magnetopause and in the near to mid-magnetotail. Ionospheric-origin thermal plasma also represents the most significant potential loss of atmospheric mass from our planet over geological time. Knowledge of the loss of convected thermal plasma into the solar wind versus its recirculation across high latitudes and through the magnetospheric flanks into the magnetospheric tail will enable determination of the mass balance for this mass-dominant component of the Geospace system and of its influence on global magnetospheric processes that are critical to space weather prediction and hence to the impact of space processes on human technology in space and on Earth. Our proposed concept addresses this basic issue of Geospace dynamics by imaging thermal He(+) ions in extreme ultraviolet light with an instrument on the lunar surface. The concept is derived from the highly successful Extreme Ultraviolet imager (EUV) flown on the Imager for Magnetopause-to-Aurora Global Exploration (IMAGE) spacecraft. From the lunar surface an advanced EUV imager is anticipated to have much higher sensitivity, lower background noise, and higher communication bandwidth back to Earth. From the near-magnetic equatorial location on the lunar surface, such an imager would be ideally located to follow thermal He(+) ions to high latitudes, into the magnetospheric flanks, and into the magnetotail.

Gallagher, D. L.↗
NASA NTRS1989

Cryogenic Limb Array Etalon Spectrometer (CLAES) S/N001 cryostat test results

The results of a test program designed to verify the operational and thermal performance of the Cryogenic Limb Array Etalon Spectrometer (CLAES) S/N001 Ne/CO2 cryostat, as monitored and serviced by the Data Acquisition System and Ground Support Equipment, are presented. The S/N001 model test assembly consists of the S/N001 configuration coupled with an instrument thermal mass simulator (ITMS) for simulating the thermal behavior of the instrument package. The test data for the cryostat include the rate of temperature decrease of the various parts of the cryostat/ITMS and the final equilibrium temperatures of the shields, thermal links, and tank. The test results showed that system heat rates, operating temperatures, and expected end-of-life temperature predictions all agree with predictions within estimated margins.

Horsley, W. J.↗
NASA NTRS2010

Time-Separating Heating and Sensor Functions of Thermistors in Precision Thermal Control Applications

A method allows combining the functions of a heater and a thermometer in a single device, a thermistor, with minimal temperature read errors. Because thermistors typically have a much smaller thermal mass than the objects they monitor, the thermal time to equilibrate the thermometer to the temperature of the object is typically much shorter than the thermal time of the object to change its temperature in response to an external perturbation.

Cho, Hyung J.↗
NASA NTRS1986

Technique for Measuring Gas Conversion Factors

Technique for measuring calibration conversion factors for hydrocarbon mass flowmeters applied to widely used type of commercial thermal mass flowmeter for hydrocarbon gases. Values of conversion factors for two common hydrocarbons measured using this technique in good agreement with empirical values cited by manufacturer. Similar agreement expected for all other hydrocarbons. Technique based on Nernst theorem for matching partial pressure of oxygen in combustion product gases with that in normal air. Simple, quick, and relatively safe, particularly for toxic/poisonous hydrocarbons.

Singh, J. J.↗
NASA NTRS2014

Transient Thermoelectric Solution Employing Green's Functions

The study works to formulate convenient solutions to the problem of a thermoelectric couple operating under a time varying condition. Transient operation of a thermoelectric will become increasingly common as thermoelectric technology permits applications in an increasing number of uses. A number of terrestrial applications, in contrast to steady-state space applications, can subject devices to time varying conditions. For instance thermoelectrics can be exposed to transient conditions in the automotive industry depending on engine system dynamics along with factors like driving style. In an effort to generalize the thermoelectric solution a Greens function method is used, so that arbitrary time varying boundary and initial conditions may be applied to the system without reformulation. The solution demonstrates that in thermoelectric applications of a transient nature additional factors must be taken into account and optimized. For instance, the materials specific heat and density become critical parameters in addition to the thermal mass of a heat sink or the details of the thermal profile, such as oscillating frequency. The calculations can yield the optimum operating conditions to maximize power output andor efficiency for a given type of device.

thermoelectric power generation↗
NASA NTRS1998

LSPRAY: Lagrangian Spray Solver for Applications With Parallel Computing and Unstructured Gas-Phase Flow Solvers

Sprays occur in a wide variety of industrial and power applications and in the processing of materials. A liquid spray is a phase flow with a gas as the continuous phase and a liquid as the dispersed phase (in the form of droplets or ligaments). Interactions between the two phases, which are coupled through exchanges of mass, momentum, and energy, can occur in different ways at different times and locations involving various thermal, mass, and fluid dynamic factors. An understanding of the flow, combustion, and thermal properties of a rapidly vaporizing spray requires careful modeling of the rate-controlling processes associated with the spray's turbulent transport, mixing, chemical kinetics, evaporation, and spreading rates, as well as other phenomena. In an attempt to advance the state-of-the-art in multidimensional numerical methods, we at the NASA Lewis Research Center extended our previous work on sprays to unstructured grids and parallel computing. LSPRAY, which was developed by M.S. Raju of Nyma, Inc., is designed to be massively parallel and could easily be coupled with any existing gas-phase flow and/or Monte Carlo probability density function (PDF) solver. The LSPRAY solver accommodates the use of an unstructured mesh with mixed triangular, quadrilateral, and/or tetrahedral elements in the gas-phase solvers. It is used specifically for fuel sprays within gas turbine combustors, but it has many other uses. The spray model used in LSPRAY provided favorable results when applied to stratified-charge rotary combustion (Wankel) engines and several other confined and unconfined spray flames. The source code will be available with the National Combustion Code (NCC) as a complete package.

Raju, Manthena S.↗
NASA NTRS2002

Spray and High-Pressure Flow Computations in the National Combustion Code (NCC) Improved

Sprays occur in a wide variety of industrial and power applications and in materials processing. A liquid spray is a two-phase flow with a gas as the continuous phase and a liquid as the dispersed phase in the form of droplets or ligaments. The interactions between the two phases--which are coupled through exchanges of mass, momentum, and energy--can occur in different ways at disparate time and length scales involving various thermal, mass, and fluid dynamic factors. An understanding of the flow, combustion, and thermal properties of a rapidly vaporizing spray requires careful modeling of the ratecontrolling processes associated with turbulent transport, mixing, chemical kinetics, evaporation, and spreading rates of the spray, among many other factors. With the aim of developing an efficient solution procedure for use in multidimensional combustor modeling, researchers at the NASA Glenn Research Center have advanced the state-of-the-art in spray computations in several important ways.

Raju, Manthena S.↗
NASA NTRS1983

A new technique for measuring gas conversion factors for hydrocarbon mass flowmeters

A technique for measuring calibration conversion factors for hydrocarbon mass flowmeters was developed. It was applied to a widely used type of commercial thermal mass flowmeter for hydrocarbon gases. The values of conversion factors for two common hydrocarbons measured using this technique are in good agreement with the empirical values cited by the manufacturer. Similar agreements can be expected for all other hydrocarbons. The technique is based on Nernst theorem for matching the partial pressure of oxygen in the combustion product gases with that in normal air. It is simple, quick and relatively safe--particularly for toxic/poisonous hydrocarbons.

Singh, J. J.↗