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PAHs in the Ices of Saturn's Satellites: Connections to the Solar Nebula and the Interstellar Medium

Aliphatic hydrocarbons and PAHs have been observed in the interstellar medium (e.g., Allamandola et al. 1985, Pendleton et al. 1994, Pendleton & Allamandola 2002, Tielens 2013, Kwok 2008, Chiar & Pendleton 2008) The inventory of organic material in the ISM was likely incorporated into the molecular cloud in which the solar nebula condensed, contributing to the feedstock for the formation of the Sun, major planets, and the smaller icy bodies in the region outside Neptune's orbit (transneptunian objects, or TNOs). Additional organic synthesis occurred in the solar nebula (Ciesla & Sandford 2012). Saturn's satellites Phoebe, Iapetus, and Hyperion open a window to the composition of one class of TNO as revealed by the near-infrared mapping spectrometer (VIMS) on the Cassini spacecraft at Saturn. Phoebe (mean diameter 213 km) is a former TNO now orbiting Saturn (Johnson & Lunine 2005). VIMS spectral maps of Phoebe's surface reveal a complex organic spectral signature consisting of prominent aromatic (CH) and aliphatic hydrocarbon (=CH2, -CH3) absorption bands (3.2-3.6 micrometers). Phoebe is the source of a huge debris ring encircling Saturn, and from which particles ((is) approximately 5-20 micrometers size) spiral inward toward Saturn (Verbiscer et al. 2009). They encounter Iapetus and Hyperion where they mix with and blanket the native H2O ice of those two bodies. Quantitative analysis of the hydrocarbon bands on Iapetus demonstrates that aromatic CH is approximately 10 times as abundant as aliphatic CH2+CH3, significantly exceeding the strength of the aromatic signature in interplanetary dust particles, comet particles, and in carbonaceous meteorites (Cruikshank et al. 2014). A similar excess of aromatics over aliphatics is seen in the qualitative analysis of Hyperion and Phoebe itself (Dalle Ore et al. 2012). The Iapetus aliphatic hydrocarbons show CH2/CH3 (is) approximately 4, which is larger than the value found in the diffuse ISM ((is) approximately 2-2.5). Insofar as Phoebe is a primitive body that formed in the outer regions of the solar nebula and has preserved some of the original nebula inventory, it can be key in understanding the content and degree of processing of that nebular material. A dynamical subset of TNOs define the Kuiper Belt, from which the short-period comets originate. Particles collected from comet 81P/Wild contain PAHs with an interstellar signature of deuterium. By inference, the PAHs contained in Phoebe and now dusted on the surfaces of two other Saturn satellites share that interstellar origin. There are other Phoebe-like TNOs that are presently beyond our ability to study in the organic spectral region, but JWST will open that possibility for a number of objects.

Solar nebula↗

Quaoar: New, Longitudinaly Resolved, Spectroscopic Characterization of Its Surface

(50000) Quaoar, one of the largest Trans-neptunian objects, is comparable in size to Pluto's moon Charon. However, while Charon's surface is rich almost exclusively in H2O ice, Quaoar's surface characterized by ices of CH4, N2, as well as C2H6, a product of irradiation of CH4 (Dalle Ore et al. 2009). Because of its distance from the Sun, Quaoar is expected to have preserved, to a degree, its original composition, however, its relatively small size did not make it a prime candidate for presence of volatile ices in the study by Schaller and Brown (2007). Furthermore, based on the Brown et al. (2011) study (Brown, Schaller, & Fraser, 2011. A Hypothesis for the Color Diversity of the Kuiper Belt. ApJL, 739, L60) its red coloration points to CH3OH as the ice which, when irradiated, might have produced the red material. We present new visible to near-infrared (0.3-2.48 micrometers) spectro-photometric data obtained with the XSHOOTER (Vernet et al. 2011, A&A, 536A, 105 ) instrument at the VLT-ESO facility at four different longitudes on the surface of Quaoar. The data are complemented by previously published photometric observations obtained in the near-infrared (3.6, 4.5 micrometers) with the Spitzer Space Telescope, which provide an extra set of constraints in the model calculation process in spite of the different observing times that preclude establishing the spatial consistency between the two sets. For each of the four spectra we perform spectral modeling of the entire wavelength range -from 0.3 to 4.5 micrometers- by means of a code based on the Shkuratov radiative transfer formulation of the slab model. We obtain spatially resolved compositional information for the surface of Quaoar supporting the presence of CH4 and C2H6, as previously reported, along with evidence for N2 and NH3OH. The albedo at the two Spitzer bands indicates the likely presence of CO and CO2. CH3OH, predicted on the basis of Quaoar's coloration (Brown et al. 2011), is not found at any of the four longitudes, implying that the presence of this ice is a sufficient, but not necessary condition for reddening of TNO surfaces. Other ices, in particular CH4 (Brunetto et al. 2006), have been shown to be plausible precursors for reddening of TNO surfaces.

Ices↗

OSSOS. IV. Discovery of a Dwarf Planet Candidate in the 9:2 Resonance with Neptune

We report the discovery and orbit of a new dwarf planet candidate, 2015 RR245, by the Outer Solar System Origins Survey (OSSOS). The orbit of 2015 RR245 is eccentric (e 0.586), with a semimajor axis near 82 au, yielding a perihelion distance of 34 au. 2015 RR245 has g - r 0.59 +/- 0.11 and absolute magnitude Hr 3.6 +/- 0.1; for an assumed albedo of pV 12, the object has a diameter of approximately 670 km. Based on astrometric measurements from OSSOS and Pan-STARRS1, we find that 2015 RR245 is securely trapped on ten-megayear timescales in the 9:2 mean-motion resonance with Neptune. It is the first trans-Neptunian object (TNO) identied in this resonance. On hundred-megayear timescales, particles in 2015 RR245-like orbits depart and sometimes return to the resonance, indicating that 2015 RR245 likely forms part of the long-lived metastable population of distant TNOs that drift between resonance sticking and actively scattering via gravitational encounters with Neptune. The discovery of a 9:2 TNO stresses the role of resonances in the long-term evolution of objects in the scattering disk and reinforces the view that distant resonances are heavily populated in the current solar system. This object further motivates detailed modeling of the transient sticking population.

Bannister, Michele T.↗

Relevance of Tidal Heating on Large TNOs

We examine the relevance of tidal heating for large Trans-Neptunian Objects, with a focus on its potential to melt and maintain layers of subsurface liquid water. Depending on their past orbital evolution, tidal heating may be an important part of the heat budget for a number of discovered and hypothetical TNO systems and may enable formation of, and increased access to, subsurface liquid water. Tidal heating induced by the process of despinning is found to be particularly able to compete with heating due to radionuclide decay in a number of different scenarios. In cases where radiogenic heating alone may establish subsurface conditions for liquid water, we focus on the extent by which tidal activity lifts the depth of such conditions closer to the surface. While it is common for strong tidal heating and long lived tides to be mutually exclusive, we find this is not always the case, and highlight when these two traits occur together. We find cases where TNO systems experience tidal heating that is a significant proportion of, or greater than radiogenic heating for periods ranging from100 s of millions to a billion years. For subsurface oceans that contain a small antifreeze component, tidal heating due to very high initial spin states may enable liquid water to be preserved right up to the present day. Of particular interest is the Eris-Dysnomia system, which in those cases may exhibit extant cryovolcanism.

Saxena, Prabal↗

Interstellar Organics, the Solar Nebula, and Saturn's Satellite Phoebe

The diffuse interstellar medium inventory of organic material (Pendleton et al. 1994, Pendleton Allamandola 2002) was likely incorporated into the molecular cloud in which the solar nebula condensed. This provided the feedstock for the formation of the Sun, major planets, and the smaller icy bodies in the region outside Neptune's orbit (transneptunian objects, or TNOs). Saturn's satellites Phoebe, Iapetus, and Hyperion open a window to the composition of one class of TNO as revealed by the near-infrared mapping spectrometer (VIMS - Visible and Infrared Mapping Spectrometer) on the Cassini spacecraft at Saturn. Phoebe (mean diameter 213 kilometers) is a former TNO now orbiting Saturn. VIMS spectral maps of Phoebe's surface reveal a complex organic spectral signature consisting of prominent aromatic (CH) and aliphatic hydrocarbon (CH2, CH3) absorption bands (3.2-3.6 meters). Phoebe is the source of a huge debris ring encircling Saturn, and from which particles (5-20 meter size) spiral inward toward Saturn. They encounter Iapetus and Hyperion where they mix with and blanket the native H2O ice of those two bodies. Quantitative analysis of the hydrocarbon bands on Iapetus demonstrates that aromatic CH is 10 times as abundant as aliphatic CH2 plus CH3, significantly exceeding the strength of the aromatic signature in interplanetary dust particles, comet particles, and in carbonaceous meteorites (Cruikshank et al. 2013). A similar excess of aromatics over aliphatics is seen in the qualitative analysis of Hyperion and Phoebe itself (Dalle Ore et al. 2012). The Iapetus aliphatic hydrocarbons show CH2/CH3 4, which is larger than the value found in the diffuse ISM (InterStellar Matter - (2-2.5). Insofar as Phoebe is a primitive body that formed in the outer regions of the solar nebula and has preserved some of the original nebula inventory, it can be key to understanding the content and degree of processing of that nebular material. There are other Phoebe-like TNOs that are presently beyond our ability to study in the organic spectral region, but JWST (James Webb Space Telescope) will open that possibility for a number of objects. We now need to explore and understand the connection of this organic-bearing Solar System material to the solar nebula and the inventory of ISM (Interstellar Medium) materials incorporated therein.

Phoebe↗

Ionic Liquid–Directed Nanoporous TiNb 2 O 7 Anodes with Superior Performance for Fast–Rechargeable Lithium–Ion Batteries

Nanoporous TiNb 2 O 7 (NPTNO) material is synthesized by a sol–gel method with an ionic liquid (IL) as the nanoporous structure directing template. NPTNO exhibits a high reversible capacity of 210 mAh g –1 even at the charging rate of 50 C and an excellent cyclability of half-cell capacity retention of 74% for 1000 cycles at 5 C and LiNi 0.5 Mn 1.5 O 4 -coupled full-cell capacity retentions of 81% and 87% for 1000 cycles at 1 C and 2 C, respectively. The studies of the 1000 cycled NPTNO electrode illustrate that the IL-directed mesoporous structure can enhance the cyclability of NPTNO cells due to the alleviation of repetitive mechanical stress and volume fluctuation induced by the repetitive Li + insertion-extraction processes. The measured Li + diffusion coefficients from the galvanostatic intermittent titration technique suggest that the IL-templating strategy indeed ensures the fast rechargeability of NPTNO cells based on the fast Li + diffusion kinetics. Benefitting from the nanoporous structure, NPTNO with unhindered Li + diffusion pathways achieves a superior rate capability in the titanium-based oxide materials and the best full-cell cyclability in the TNO materials. Furthermore, the templating potential of IL is demonstrated, and the superb electrochemical performance establishes the IL-directed NPTNO as a promising anode candidate for fast-rechargeable LIBs.

25 ENERGY STORAGE↗

A Multi-Sensor Approach for Measuring Bird and Bat Collisions with Offshore Wind Turbines (Final Technical Report)

Collision of birds and bats with wind turbines is a conservation concern for both land-based and offshore wind projects. The fatality rates of birds and bats at land-based turbines are well documented. The measurement strategies on land focus on finding carcasses following collision, estimating the number of carcasses missed through searcher efficiency, carcass persistence trials and carcass fall distributions, and modeling statistically robust fatality rates. Few technologies have been developed to monitor offshore bird and bat collisions, and many that have been developed focused on detecting collisions with large birds. The few studies that have attempted to document collisions at offshore turbines do not account for smaller bodied animals or for collisions that might be missed, which prevents the calculation of statistically robust fatality rates. The overall goal of this report, A Multi-Sensor Approach for Measuring Bird and Bat Collisions with Offshore Wind Turbines (Project), was to develop an effective multi-sensor system for quantifying bird and bat collision rates, specifically for offshore wind facilities. The Project goal and resulting automated collision detection system was achieved through two major technological advancements: 1) refining The Netherlands Organisation for Applied Scientific Research’s (TNO’s) existing WT-Bird® vibration sensing system, that had successfully detected large bird collisions during daytime, to allow for improved detection of smaller birds and bats during both daytime and nighttime hours and 2) improving image processing systems and developing and integrating machine learning algorithms to automatically detect and classify small and large bird and bat collisions with offshore turbines. This final technical report (FTR) summarizes Methods , Results , Conclusions , and Lessons Learned during each of the five Tasks identified for this research and development effort. This FTR includes summaries of the following: Task 1. Initial Engineering Tests to Improve WT-Bird® Task 2. Installation of WT‐Bird® on a Utility-scale Turbine at the National Wind Technology Center – National Renewable Energy Laboratory Task 3. Field Tests and Refinement of the Object Detection System Task 4. Validation of WT-Bird® on a Land-based Turbine Task 5. Preparation for the Implementation of WT-Bird® on an Offshore Turbine. This research and development effort documented successful improvement of the WT Bird® collision detection system to detect small birds and bats, and WT-Bird® is the first collision detection system to validate results compared to land-based post-construction monitoring. The collision trials provide estimates of missed targets that can be used to estimate fatality rates, a significant improvement relative to other offshore collision monitoring systems. Advances were made in developing an edge-processing solution to reduce data storage requirements, which is important if the system is deployed for long periods of time at offshore turbines. The improved WT-Bird® system also provides an important option for wind operators on land or offshore who need to document specific details about when collisions occur, particularly efforts to further research on bat impact minimization, or when standard fatality searches are impractical (e.g. offshore) or inadequate (e.g. challenging locations on land).

17 WIND ENERGY↗

No Evidence for Orbital Clustering in the Extreme Trans-Neptunian Objects

The apparent clustering in longitude of perihelion piv and ascending node Ω of extreme trans-Neptunian objects (ETNOs) has been attributed to the gravitational effects of an unseen 5–10 Earth-mass planet in the outer solar system. To investigate how selection bias may contribute to this clustering, we consider 14 ETNOs discovered by the Dark Energy Survey, the Outer Solar System Origins Survey, and the survey of Sheppard and Trujillo. Using each survey's published pointing history, depth, and TNO tracking selections, we calculate the joint probability that these objects are consistent with an underlying parent population with uniform distributions in $\bar{w}$ and Ω. We find that the mean scaled longitude of perihelion and orbital poles of the detected ETNOs are consistent with a uniform population at a level between 17% and 94% and thus conclude that this sample provides no evidence for angular clustering.

79 ASTRONOMY AND ASTROPHYSICS↗

Application of modified VICAR/IBIS GIS to analysis of July 1991 Flevoland AIRSAR data

Three overflights of the Flevoland calibration/agricultural site were made by the JPL Airborne Synthetic Aperture Radar (AIRSAR) on 3, 12, and 28 July 1991 as part of MAC-Europe '92. A polygon map was generated at TNO-FEL which overlayed the slant range projected July 3 data set. Each polygon was identified by a sequence of points and a crop label. The polygon map was composed of 452 uniquely identified polygons and 15 different crop types. Analysis of the data was done using our modified Video Image Communication and Retrieval/Image Based Information System Geographic Information System (VICAR/IBIS GIS). This GIS is an extension of the VICAR/IBIS GIS first developed by Bryant in the 1970's which is itself an extension of the VICAR image processing system also developed at JPL.

Norikane, L.↗

POINTER: Portable Intelligent Trainer for External Robotics

Intelligent tutoring systems (ITS's) play an increasing role in training and education of people with different levels of skill and knowledge. As compared to conventional computer based training (CBT) an ITS provides more tailored instruction by trying to mimic the teaching behavior of a human instructor as much as possible and is therefore much more flexible. This paper starts with an introduction to ITS's, followed by the description of an ITS for training of an (astronaut) operator in monitoring and controlling robotic arm procedures. The robotic arm will be used for exchange of equipment between a space station and a space plane involving critical and accurate movements of the robotic arm. The ITS for this application, called Pointer, is developed by TNO Physics and Electronics Laboratory and is based upon an existing ITS that includes procedural training. Pointer has been developed on a workstation whereas the target platform was a portable computer. Therefore, a lot of attention had to be paid to scaling effects and keeping up with user friendliness of the much smaller user interface. Although the learning domain was the control of a robotic arm, it is clear that use of intelligent training technologies on a portable computer has many other applications (payload operations, operation control rooms, etc.). Training can occur at any time and place in an attractive and cost effective way.

Kuiper, Hilbert↗

Observations of Planet Crossing Asteroids

The goals of this research were the physical and dynamical characterization of planet crossing asteroids (Earth crossers, Mars crossers, Centaurs, and Pluto crossers, meaning trans-Neptunian objects), including colorimetry, rotational studies, and astrometry. Highlights are listed as follows: 1) Produced one doctoral dissertation (R. J. Whiteley, A Compositional and Dynamical Survey of the Near-Earth Asteroids). A key result is the fraction of Q-type asteroids among the near-Earth population was found to be about one-third; 2) Had prediscovery image showing the binary nature of trans-Neptunian object 1998 WW31, which is the first TNO to have a satellite found in orbit around it; 3) Discovery of shortest known rotation period for any asteroid (2000 D08, rotation period 78 seconds); it is just one of several fast-rotating small asteroids observed during the course of this project; 4) Discovery of a Centaur asteroid (1998 QM107) with, at the time, the smallest known orbital eccentricity among the Centaurs (0.13) and nearly in a 1:1 resonance with Uranus (semimajor axis of 19.9 AU); 5) Discovery of Apollo-type asteroid 1999 OW3, with a surprisingly bright absolute magnitude of 14.6 (estimated diameter of 4.6 km), brightest Apollo found in that calendar year; 6) Discovery of Aten-type asteroid 2000 SG344, which has the highest cumulative Earth impact probability among the near-Earth asteroids and a very Earth-similar orbit; 7) Instrumental in repairing the orbit of a numbered near-Earth asteroid for which prediscovery observations had been mis-attributed to it (2000 VN2); 8) Second-opposition recovery of 30-meter diameter Apollo-type asteroid 1998 KY26 in early 2002 when it was at a favorable magnitude of 24.8; 9) Primary contributor of astrometric observations of the CONTOUR fragments to the CONTOUR project following the failure of the spacecraft s kick motor; and 10) Development of orbit and ephemeris computation code that handles short observational arcs, observations at small solar elongations where indeterminacy is a known problem, and a small number of observations (including just two). Starting in 2000 November, the Spaceguard Central Node began prioritizing near-Earth asteroids in need of astrometric observation. Our own follow-up efforts relied on these listings, with emphasis given to the faintest objects where the combination of a 2.2-m telescope and a site with subarcsecond seeing produces a limiting magnitude close to 25, which represents a unique and valuable capability. The attached table, last updated in August, demonstrates the arc-lengthening capabilities of a faint limiting magnitude. Tabulated are the arc lengths before and after our observation(s), whether our observation is the last one available for the object in question, and the approximate magnitude of the object at the time of the observation.

Tholen, David J.↗

International Low-Earth-Orbit Spacecraft Materials Test Program Initiated for Better Prediction of Durability and Performance

Spacecraft in low Earth orbit (LEO) are subjected to many components of the environment, which can cause them to degrade much more rapidly than intended and greatly shorten their functional life. The atomic oxygen, ultraviolet radiation, and cross contamination present in LEO can affect sensitive surfaces such as thermal control paints, multilayer insulation, solar array surfaces, and optical surfaces. The LEO Spacecraft Materials Test (LEO-SMT) program is being conducted to assess the effects of simulated LEO exposure on current spacecraft materials to increase understanding of LEO degradation processes as well as to enable the prediction of in-space performance and durability. Using ground-based simulation facilities to test the durability of materials currently flying in LEO will allow researchers to compare the degradation evidenced in the ground-based facilities with that evidenced on orbit. This will allow refinement of ground laboratory test systems and the development of algorithms to predict the durability and performance of new materials in LEO from ground test results. Accurate predictions based on ground tests could reduce development costs and increase reliability. The wide variety of national and international materials being tested represent materials being functionally used on spacecraft in LEO. The more varied the types of materials tested, the greater the probability that researchers will develop and validate predictive models for spacecraft long-term performance and durability. Organizations that are currently participating in the program are ITT Research Institute (USA), Lockheed Martin (USA), MAP (France), SOREQ Nuclear Research Center (Israel), TNO Institute of Applied Physics (The Netherlands), and UBE Industries, Ltd. (Japan). These represent some of the major suppliers of thermal control and sensor materials currently flying in LEO. The participants provide materials that are exposed to selected levels of atomic oxygen, vacuum ultraviolet radiation, contamination, or synergistic combined environments at the NASA Lewis Research Center. Changes in characteristics that could affect mission performance or lifetime are then measured. These characteristics include changes in mass, solar absorptance, and thermal emittance. The durability of spacecraft materials from U.S. suppliers is then compared with those of materials from other participating countries. Lewis will develop and validate performance and durability prediction models using this ground data and available space data. NASA welcomes the opportunity to consider additional international participants in this program, which should greatly aid future spacecraft designers as they select materials for LEO missions.

Rutledge, Sharon K.↗

Co1lisional Grooming Models of the Kuiper Belt Dust Cloud

Debris disks around other stars, like the disks around Fomalhaut, Vega, and Epsilon Eridani, are often described as more massive versions of the Kuiper Belt. But for a long time, it's been hard to test this notion, because grain-grain collisions limit the grain lifetimes and we lacked the tools to model the effects of these collisions on the appearance of the disks. I'll describe a new breakthrough that has allowed us to make 3-D models of grain-grain collisions in debris disks for the first time, and I'll show the latest supercomputer simulations of these systems, illustrating how planets and collisions together sculpt the TNO dust.

Kuchner, Marc↗

Binaries in Transneptunian Resonances: Evidence for Slow Migration of Neptune?

A distinguishing feature of trans neptunian objects (TNO) is the high fraction that arc binary. This is particularly true for the Cold Classicals (CC), objects in lowe and low i orbits concentrated between the 3:2 and 2: 1 mean-motion resonances. CCs have other physical markers: red colors, high albedos, and equal-mass binaries. The CCs appear to be a coherent and physically distinct population of planetesimals that has survived to the present with their physical properties relatively unaltered. Their spatial concentration between 39.4 and 47.7 AU has made identification of the CCs as a physical group possible. However, objects that started out as CCs arc almost certainly 1101 limited to this one dynamical niche. We can, therefore, use the measurable physical properties of CCs as tracers of Neptune-driven dynamical mixing in the Kuiper Belt. As Neptune migrated, its mean-motion resonances preceded it into the planetesimal disk. The efficiency of capture into mean motion resonances depends on the smoothness of Neptune's migration and the local population available to be captured. The two strongest resonances, the 3:2 at 39.4 AU and 2: 1 at 47.7 AU, straddle the core repository of the physically distinct CCs, providing a unique opportunity to test the details of Neptune's migration. Smooth migration should result in a measurable difference between the 3:2 and 2:1 with low inclination 2:1s having a red, binary population mirroring that of the CC itself while the 3:2 will be less contaminated. Alternative models with rapid migration would generate a more homogeneous result.

Noll, Keith↗

Rotational Properties of the Haumea Family Members and Candidates: Short-Term Variability

Haumea is one of the most interesting and intriguing trans-Neptunian objects (TNOs). It is a large, bright, fast rotator, and its spectrum indicates nearly pure water ice on the surface. It has at least two satellites and a dynamically related family of more than 10 TNOs with very similar proper orbital parameters and similar surface properties. The Haumean family is the only one currently known in the trans-Neptunian belt. Various models have been proposed, but the formation of the family remains poorly understood. In this work, we have investigated the rotational properties of the family members and unconfirmed family candidates with short-term variability studies, and report the most complete review to date. We present results based on five years of observations and report the short-term variability of five family members, and seven candidates. The mean rotational periods, from Maxwellian fits to the frequency distributions, are 6.27 +/- 1.19 hr for the confirmed family members, 6.44 +/- 1.16 hr for the candidates, and 7.65 +/- 0.54 hr for other TNOs (without relation to the family). According to our study, there is a possibility that Haumea family members rotate faster than other TNOs, however, the sample of family member is still too limited for a secure conclusion. We also highlight the fast rotation of 2002 GH(sub 32). This object has a 0.36 +/- 0.02 mag amplitude lightcurve and a rotational period of about 3.98 hr. Assuming 2002 GH(sub 32) is a triaxial object in hydrostatic equilibrium, we derive a lower limit to the density of 2.56 g cm(exp -3). This density is similar to Haumea's and much more dense than other small TNO densities.

Thirouin, Audrey↗

Hydrovolcanic Astromaterials in the Lab

Zag and Monahans (1998) are H chondrite regolith breccias that contain 4.5 GY old halite crystals which in turn contain abundant inclusions of aqueous fluids, solids and organics. We have previously proposed that these halites originated on a hydrovolcanically-active C class asteroid, probably Ceres, or a trans-neptunian object (TNO - or P- or D-class asteroid) injected into the inner solar system during giant planet migration. We have begun a detailed analysis of organics and other solids trapped within the halite, which we hypothesize sample the mantle of the halite parent object, and are examining a halite-bearing C1 chondrite clast also found in Zag, which is similar to the solids in the halite. These investigations will reveal the water-rock interactions on the hydrovolcanically-active parent world.

Zolensky, M. E.↗

Overview of NASA's Ocean Color Instrument Solar Calibration Architecture, Pre-Launch Tests and Preliminary On-Orbit Results

Launched in February 2024, the PACE mission represents NASA’s next investment in ocean biology, clouds, and aerosol data records. A key feature of PACE is the inclusion of an advanced satellite radiometer known as the Ocean Color Instrument (OCI), a global mapping radiometer that combines multispectral and hyperspectral remote sensing. Like its predecessors, OCI will provide two day global coverage of TOA radiances. Unlike its predecessors, OCI will cover a spectral range from 340nm to 2260nm. Below 900nm, OCI will include two spectrometers that continuously span the ultraviolet to 600nm and 600nm to near-infrared spectral regions to provide hyperspectral radiances sampled every 2.5 nm, with a bandwidth of 5 nm for each channel. Wavelengths above 900nm are measured in seven discrete multispectral bands of varying bandwidths, six of which are at similar wavelengths to those on heritage missions to support both atmospheric and ocean color applications. Nominal spatial resolution is similar to the SeaWiFS instrument with 1050 m at nadir. As for SeaWiFS, the pixel size increases due to a ~20 degree tilt and as a function of scan angle. Variations in the radiometric sensitivity of each OCI channel over time will be monitored by solar diffuser measurements for short term instrument gain adjustments and independent lunar measurements for trend adjustments of long time periods, similar to the approach employed for the VIIRS instrument [4]. The OCI flight-unit was built at NASA’s Goddard Space Flight Center. At the time of this writing, OCI has completed on-orbit commissioning activities and normal science operations have begun. A key aspect of the OCI architecture is the capability to trend absolute and relative calibration changes over the course of mission life with solar calibration. Every 24 hours, the PACE spacecraft performs an inertial hold as the ground track nears the North Pole which orients a Quasi-Volume Diffuser (QVD) mounted on OCI towards the sun. By knowing the irradiance of the sun and the reflectivity of the target, the absolute radiance at the input to the OCI aperture can be computed as OCI scans the target. The allowable absolute uncertainty budget for each solar calibration measurement is 1.6% 1-sigma below 900nm at beginning of life (BOL) and the allowable relative uncertainty budget is ~0.26% 1-sigma. The Solar Calibration Assembly (SCA) consists of three targets selectable via a single mechanism which also opens a door. The targets consist of a Daily Bright Target (DBT), Monthly Bright Target (MBT), and Daily Dim Target (DDT). The bright targets are quartz QVDs with the monthly target being used to track the degradation of the daily target. The dim target is used to track CCD linearity using Progressive Time-Delay Integration (PTDI). A composite baffle is attached to the SCA housing aperture to block Earth shine and stray light from the spacecraft. The SCA assembly is mounted to a view port ~90° from OCI nadir. This paper provides an overview of driving solar calibration requirements, error-budgets and early trade studies which drove the solar calibration assembly (SCA) architecture and on-orbit maneuver. Measurements of the diffuser Bidirectional Reflectance Distribution Function (BRDF) at TNO, Netherlands and GSFC are briefly described. Optical modelling and test results at the sub-system and instrument level are included. Finally, preliminary measurements on-orbit are compared to pre-launch predictions.

Joseph J Knuble↗