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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Tailoring Carbide Dispersed Steels: A Path to Increased Strength and Hydrogen Tolerance

The use of transition metal carbides is reported for use as a hydrogen trapping mechanism for ferritic and austenitic steel materials. The program combined computational modeling and simulations to guide experiments towards candidate metal carbide traps, both for interfacial and interior trapping. It was found that interfacial trapping is less effective than interior trapping, with the group IVB transition metal carbides being the most effect internal traps with a loss of carbon. The sub-stoichiometric rocksalt structure accommodate the hydrogen atoms in its octahedral interstices. Using percolation theory, carbon loss of approximately 25% or more was sufficient to ensure an interconnected network of vacancies for such trapping from the surface to the internal sites within the carbide. Using this as a guide, the program developed a means to provide a uniform dispersion of ZrC nanoparticles with either Fe or 304L micron-scale powders which was then consolidated by direct current sintering. Electrolytic hydrogen diffusivity studies confirmed the reduction of hydrogen diffusion in the matrix with increasing ZrC content, which was a linear response over the sample range studied (0.01 to 1.0 wt.%). The consolidated material was micro-tensile tested in either a non-hydrogen or hydrogen charge condition and compared to a control with no carbides. Additions up to 0.05 wt.% ZrC increased the yield strength with no loss in ductility in either the non-hydrogen or hydrogen tested condition. ZrC concentrations above this amount further increased the yield strength at the expense of ductility. While these samples had a lower absolute ductility value prior to failure, the relative change in ductility between the non-hydrogen and hydrogen charge states was less for the carbides than that of the control. Metal-rich ZrC nanoparticles were fabricated through a conformal coating process yielding ZrC0.66 particles that were then incorporated into a metal matrix. Notch fatigue testing in a hydrogen environment was conducted where the number of cycles to failure was found to be less in the control than that of the carbide addition. However, the spread in experimental data and the number of samples tested limits a conclusive outcome based on defects noticed in the gauge section of all the powder processed samples. The collective outcomes of this report provide further insight into the mechanisms by which carbides act as hydrogen traps; a means to process such carbides through powder metallurgy; and their associated mechanical performance in either a non-hydrogen or hydrogen-charged condition.

08 HYDROGEN↗

Avalanche-diode oscillator circuit with tuning at multiple frequencies

Detailed theoretical analysis of three different modes or types of high efficiency oscillation in a PIN diode are presented. For the TRAPATT mode in a PIN diode, it is shown that a traveling avalanche zone is not necessary to generate a dense trapped plasma. An economical computer program for TRAPATT oscillations in a PIN diode is described. Typical results of diode power, dc-to-RF conversion efficiency, and required circuit impedances are presented for several different current waveforms. A semianalytical solution for a second type of high efficiency mode in a PIN diode is derived assuming a rectangular current waveform. A quasi-static approximation is employed to derive a semianalytical solution for the voltage across a PIN diode in a third mode, where avalanching occurs during a major portion of a half cycle. Calculations for this mode indicate that the power increases proportionally to the magnitude of the drive current with a small decrease in efficiency relative to the ordinary TRAPATT mode. An analytical solution is also given for a PIN diode, where it is assumed that the ionization coefficient is a step function. It is shown that the step-ionization approximation permits one to draw possible patterns of avalanche region in the depletion layer as a function of time. A rule governing admissible patterns is derived and an example solution given for one admissible pattern. Preliminary experimental results on the high-efficiency oscillations are presented and discussed. Two different experimental circuits, which used channel-dropping filters to provide independent harmonic tuning, are described. Simpler circuits used to produce high-efficiency oscillations are discussed. Results of experiments using inexpensive Fairchild FD300 diodes are given.

Parker, D.↗

Qualifying the Instrument Thimble 11 Test Position in the Advanced Test Reactor Critical

The Advanced Test Reactor (ATR) is a versatile nuclear research reactor located at the Idaho National Laboratory (INL) in Eastern Idaho, United States of America. It is one of the most powerful and flexible research reactors in the world and is primarily used for materials testing, isotope production and basic nuclear science research. The ATR is a light-water-cooled, beryllium-moderated reactor with a nominal thermal power capacity of 250 MW utilizing specially designed fuel, arranged in a serpentine pattern to create 9 flux traps. The special design of ATR allows for the neutron flux within each of the flux traps providing flexibility for experiments, programs and allowing experiments with different dose requirements to be irradiated simultaneously. The Advance Test Reactor Critical (ATRC) is a full-scale replica of the ATR core but is housed in a pool instead of a pressure vessel. ATRC is usually operated at less than 600 watts [1]. There are 12 dry instrument thimbles located around the outside of the core tank where a variety of measurement equipment is housed to facilitate reactor operations. Currently Instrument Thimble 11 (IT-11) is not utilized in ATR or ATRC. A range of measurements is ongoing to qualify IT-11 as a test platform for nuclear instrumentation research, development and further experimentation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Initial Findings in Qualifying the Instrument Thimble 11 Position in the Advanced Test Reactor Critical

The Advanced Test Reactor (ATR) is a versatile nuclear research reactor located at the Idaho National Laboratory (INL) in Eastern Idaho, United States of America. It is one of the most powerful and flexible research reactors in the world and is primarily used for materials testing, isotope production and basic nuclear science research. The ATR is a light-water-cooled, beryllium-moderated reactor with a nominal thermal power capacity of 250 MW utilizing specially designed fuel, arranged in a serpentine pattern to create 9 flux traps. The special design of ATR allows for the neutron flux within each of the flux traps providing flexibility for experiments, programs and allowing experiments with different dose requirements to be irradiated simultaneously. The Advance Test Reactor Critical (ATRC) is a full-scale replica of the ATR core but is housed in a pool instead of a pressure vessel. ATRC is usually operated at less than 600 watts [1]. There are 12 dry instrument thimbles located around the outside of the core tank where a variety of measurement equipment is housed to facilitate reactor operations. Currently Instrument Thimble 11 (IT-11) is not utilized in ATR or ATRC. A range of measurements is ongoing to qualify IT-11 as a test platform for nuclear instrumentation research, development and further experimentation.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Generation of low–latitude seamount–trapped waves: a case study of the Seychelles Plateau

Baroclinic seamount-trapped waves are thought to influence their surrounding ecosystem; however, trapped waves are not well-studied in near-equatorial settings, where stratification is strong and Burger numbers are large. Motivated by observations, we use daily output (2005-2009) from the global 0.1-degree Parallel Ocean Program Model (POP) to examine topographically trapped baroclinic waves around the Seychelles Plateau (S > 400) in the tropical Indian Ocean. These trapped waves are associated with velocity and temperature oscillations at periods of 15–16 days, similar to the dominant period of some equatorial Yanai waves. Energy flux maps using POP output suggest that quasi-biweekly equatorial Yanai waves excite trapped waves on the western and south-western flanks of the Seychelles Plateau, near the surface. Here, the anticyclonic energy flux associated with the trapped wave extends vertically throughout the water column and around most of the plateau circumference, diminishing on the eastern flank of the plateau. This work highlights the role that equatorial planetary waves and trapped waves play in facilitating energy redistribution, dissipation, and mixing in the tropical ocean.

58 GEOSCIENCES↗

Implementing a Laser Stabilization System for Trapping Ca+ Ions: an Internship Reflection

At Lawrence Livermore National Laboratory, I contributed to a project developing 3D printed micro ion traps for quantum computing. I designed, implemented, and assessed a laser stabilization system that locked lasers to the frequencies required for calibrating our High Finesse WS8-10 wavelength meter and for laser cooling and trapping of Ca+ ions. I also programmed a Python interface for hardware communication, data collection, and statistical analysis. Additionally, I optimized and aligned laser beam paths, and I implemented a closed digital feedback loop using Proportional, Integral, and Derivative (PID) control parameters. I analyzed both the long-term and short-term behavior of our locked lasers and adjusted PID parameters to enhance performance. Furthermore, I used COMSOL to simulate the capacitance of a linear Paul trap design and predict our trap’s performance. The procedures I developed for the interface, analysis, and simulations will continue to support the ion trapping experiment after my appointment. I strengthened my skills in data analysis, Python coding, and optical alignment for laser systems. My confidence as a researcher grew, particularly in communicating my research. This experience taught me the importance of careful planning and consideration in research and solidified my desire to continue exploring novel quantum technology as an undergraduate

42 ENGINEERING↗

Using Space Weather Variability in Evaluating the Environment Design Specifications for NASA'S Constellation Program

Spectral models of solar particle events and trapped radiation belts are necessary for the design requirements of total ionizing radiation dose, single event effects, and spacecraft charging. Space radiation and plasma environment specifications for hardware design are necessarily conservative to assure system robustness for a wide range of space environments.

Coffey, Victoria N.↗

It's a Trap! A Review of MOMA and Other Ion Traps in Space or Under Development

Since the Viking Program, quadrupole mass spectrometer (QMS) instruments have been used to explore a wide survey of planetary targets in our solar system, including (from the inner to outer reaches): Venus (Pioneer); our moon (LADEE); Mars (Viking, Phoenix, and Mars Science Laboratory); and, Saturns largest moon Titan (Cassini-Huygens). More recently, however, ion trap mass spectrometer (ITMS) instruments have found a niche as smaller, versatile alternatives to traditional quadrupole mass analyzers, capable of in situ characterization of planetary environments and the search for organic matter. For example, whereas typical QMS systems are limited to a mass range up to 500 Da and normally require multiple RF frequencies and pressures of less than 10(exp -6) mbar for optimal operation, ITMS instruments commonly reach upwards of 1000 Da or more on a single RF frequency, and function in higher pressure environments up to 10(exp -3) mbar.

ion trap↗

Design of An Improved Miniature Ion Neutral Mass Spectrometer for NASA Applications

The ion optics of NASA's Ion Neutral Mass Spectrometer (INMS) sensor was simulated with three dimensional models of the open source, the quadrupole deflector, the exit lens system and the quadrupole mass analyzer to design more compact models with lower weight. Comparison of calculated transmission with experimental results shows good agreement. Transmission analyses with varying geometrical parameters and voltages throw light on possible ways of reducing the size of the sensor. Trajectories of ions of mass 1-99 amu were simulated to analyze and optimize transmission. Analysis of open source transmission with varying angle of attack shows that the angular acceptance can be considerably increased by programming the voltages on the ion trap/ collimator. Analysis of transmission sensitivity to voltages and misalignments of the quadrupole deflector rods indicate that increased transmission is possible with a geometrically asymmetrical deflector and a deflector can be designed with much lower sensitivities of transmission. Bringing the disks closer together can decrease the size of the quadrupole deflector and also increase transmission. The exit lens system can be redesigned to be smaller by eliminating at least one electrode entirely without loss of transmission. Ceramic materials were investigated to find suitable candidates for use in the construction of lighter weight mass spectrometer. A high-sensitivity, high-resolution portable gas chromatograph mass spectrometer with a mass range of 2-700 amu has been built and will be commercialized in Phase 3.

Swaminathan, Viji K.↗

Laboratory Study of the Diagnostic Utility of the 3C/3D Line Ratio in Fe XVII

Fe XVII X-ray emission is present in a multitude of sources, such as the corona of the Sun, Capella, and Procyon. Two of the strongest lines observed in these spectra are the resonance and intercombination lines located at 15.01 and 15.26 A, respectively. As part of the laboratory astrophysics program at the electron beam ion traps EBIT-I & EBIT-II located at the Lawrence Livermore National Laboratory we have measured this line ratio for the case where the relative abundance of Fe XVI to Fe XVII is approx. 1. Our results show that an Fe XVI innershell satellite line coincides with the intercombination line and can significantly reduce the relative intensity, R, of the resonance to intercombination line. The fact that the apparent relative intensity of the resonance and intercombination line in Fe XVII is sensitive to the strength of an Fe XVI innershell satellite, and therefore, tho relative abundance of Fe XVI to Fe XVII, makes the line ratio a diagnostic of temperature, and explains the anomalously low ratios observed in the solar and stellar coronae.

Brown, G. V.↗

The importance of cost considerations in the systems engineering process

This paper examines the question of cost, from the birth of a program to its conclusion, particularly from the point of view of large multi-center programs, and suggests how to avoid some of the traps and pitfalls. Emphasis is given to cost in the systems engineering process, but there is an inevitable overlap with program management. (These terms, systems engineering and program management, have never been clearly defined.) In these days of vast Federal budget deficits and increasing overseas competition, it is imperative that we get more for each research and development dollar. This is the only way we will retain our leadership in high technology and, in the long run, our way of life.

Hodge, John D.↗

Improving cost efficiency in large programs

This paper examines the question of cost, from the birth of a program to its conclusion, particularly from the point of view of large multi-center programs, and suggests how to avoid some of the traps and pitfalls. Emphasis is given to cost in the systems engineering process, but there is an inevitable overlap with program management. (The terms systems engineering and program management have never been clearly defined.) In these days of vast Federal budget deficits and increasing overseas competition, it is imperative that we get more for each research and development dollar. This is the only way we will retain our leadership in high technology and, in the long run, our way of life.

Hodge, John D.↗

Electron Impact Excitation Cross Section Measurement for n=3 to n=2 Line Emission in Fe(17+) to Fe(23+)

We have measured the electron impact excitation cross sections for the strong iron L-shell 3 --> 2 lines of Fe XVIII to Fe XXIV at the EBIT-I electron beam ion trap using a crystal spectrometer and NASA-Goddard Space Flight Centers 6 x 6 pixel array microcalorimeter. The cross sections were determined by direct normalization to the well established cross section of radiative electron capture through a sophisticated model analysis which results in the excitation cross section for the strong Fe L-shell lines at multiple electron energies. This measurement is part of a laboratory X-ray astrophysics program utilizing the Livermore electron beam ion traps EBIT-I and EBIT-II.

Chen, H.↗

Programmable Quantum Simulations of Bosonic Systems with Trapped Ions

Trapped atomic ion crystals are a leading platform for quantum simulations of spin systems, with programmable and long-range spin-spin interactions mediated by excitations of phonons in the crystal. In this study, we describe a complementary approach for quantum simulations of bosonic systems using phonons in trapped-ion crystals, here mediated by excitations of the trapped-ion spins. The scheme enables a high degree of programability across a dense graph of bosonic couplings, utilizing long-lived collective phonon modes in a trapped-ion chain. As such, it is well suited for tackling hard problems such as boson sampling and simulations of long-range bosonic and spin-boson Hamiltonians.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The JPL trapped mercury ion frequency standard

In order to provide frequency standards for the Deep Space Network (DSN) which are more stable than present-day hydrogen masers, a research task was established under the Advanced Systems Program of the TDA to develop a Hg-199(+) trapped ion frequency standard. The first closed-loop operation of this kind is described. Mercury-199 ions are confined in an RF trap and are state-selected through the use of optical pumping with 194 nm UV light from a Hg-202 discharge lamp. Absorption of microwave radiation at the hyperfine frequency (40.5 GHz) is signaled by atomic fluorescence of the UV light. The frequency of a 40.5 GHz oscillator is locked to a 1.6 Hz wide atomic absorption line of the trapped ions. The measured Allan variance of this locked oscillator is currently gamma sub y (pi) = 4.4 x 10 to the minus 12th/square root of pi for 20 is less than pi is less than 320 seconds, which is better stability than the best commercial cesium standards by almost a factor of 2. This initial result was achieved without magnetic shielding and without regulation of ion number.

Prestage, J. D.↗

Simulated Aging of Metal Tritides by Ball Milling Induced Gas Incorporation

The study of tritium aging effects on materials requires a significant time commitment as a consequence of its 12.3-year half-life, making developmental studies prohibitively difficult and expensive. However, detailed knowledge of long-term aging effects is critical to the development of structural and storage materials for future fusion reactor technologies. As a result, multiple approaches to simulated aging effects have been investigated. Here, we report a method of simulated tritium aging achieved though the incorporation of trapped gases via high-energy ball milling of LaNi 4.25 Al 0.75 alloy storage material. Experimental results verify the presence of trapped gases by a combination of temperature programmed desorption and LECO chemical analysis. Following gas incorporation, we find that many of the degraded hydrogen sorption properties found in aged storage materials are reproduced by the ball milled powders.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗