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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Vibrational and rotational excitation of CO in comets. Part 1: Non-equilibrium calculations. Part 2: Results of the calculation for standard bright comet, comet Iras-Araki-Alcock and comet Halley

The vibrational and rotational excitation of the CO molecule in cometary comae were investigated using a model which includes IR vibrational pumping by the solar flux, vibrational and rotational radiative decay, and collisional coupling among rotational states. Steady state was not assumed in solving the rate equations. The evolution of a shell of CO gas was monitored as it expanded from the nucleus into the outer coma. Collisional effects were treated using a kinetic temperature profile derived from theoretical work on the coma energy balance. The kinetic temperature was assumed to be extremely cold in the inner coma; this has significant consequences for the CO excitation. If optical depth effects are ignored, only low J transitions will be significantly excited in comets observed at high spatial resolution. Ground-based observations of CO co-vibrational and rotational transitions will be extremely difficult due to lack of sensitivity and/or terrestrial absorption. However, CO should be detectable from a large comet with favorable observing geometry if the CO is a parent molecule present at the 10% level (or greater) relative to H2O. Observations using cooled, spaceborne instruments should be capable of detecting CO emission from even moderately bright comets.

Chin, G.↗
NASA NTRS1973

Kinetics of CO2 production on Venus.

Consideration of theoretical limits and experimental data for the kinetics of the reaction quartz plus calcite yields wollastonite plus CO2 supports the concept of a short-term quasi-equilibrium state for the atmosphere of Venus. These data indicate that the time scale of this reaction and of any competing CO2 producing reaction may be as short as several hundred years or less at the inferred Venus surface temperatures.

Mueller, R. F.↗
NASA NTRS1993

A local dynamic model for large eddy simulation

The dynamic model is a method for computing the coefficient C in Smagorinsky's model for the subgrid-scale stress tensor as a function of position from the information already contained in the resolved velocity field rather than treating it as an adjustable parameter. A variational formulation of the dynamic model is described that removes the inconsistency associated with taking C out of the filtering operation. This model, however, is still unstable due to the negative eddy-viscosity. Next, three models are presented that are mathematically consistent as well as numerically stable. The first two are applicable to homogeneous flows and flows with at least one homogeneous direction, respectively, and are, in fact, a rigorous derivation of the ad hoc expressions used by previous authors. The third model in this set can be applied to arbitrary flows, and it is stable because the C it predicts is always positive. Finally, a model involving the subgrid-scale kinetic energy is presented which attempts to model backscatter. This last model has some desirable theoretical features. However, even though it gives results in LES that are qualitatively correct, it is outperformed by the simpler constrained variational models. It is suggested that one of the constrained variational models should be used for actual LES while theoretical investigation of the kinetic energy approach should be continued in an effort to improve its predictive power and to understand more about backscatter.

Ghosal, Sandip↗
NASA NTRS2009

Analysis of Electromagnetic Wave Propagation in a Magnetized Re-Entry Plasma Sheath Via the Kinetic Equation

Based on a theoretical model of the propagation of electromagnetic waves through a hypersonically induced plasma, it has been demonstrated that the classical radiofrequency communications blackout that is experienced during atmospheric reentry can be mitigated through the appropriate control of an external magnetic field of nominal magnitude. The model is based on the kinetic equation treatment of Vlasov and involves an analytical solution for the electric and magnetic fields within the plasma allowing for a description of the attendant transmission, reflection and absorption coefficients. The ability to transmit through the magnetized plasma is due to the magnetic windows that are created within the plasma via the well-known whistler modes of propagation. The case of 2 GHz transmission through a re-entry plasma is considered. The coefficients are found to be highly sensitive to the prevailing electron density and will thus require a dynamic control mechanism to vary the magnetic field as the plasma evolves through the re-entry phase.

Manning, Robert M.↗
NASA NTRS1957

Relation of Turbojet and Ramjet Combustion Efficiency to Second-Order Reaction Kinetics and Fundamental Flame Speed

Theoretical studies of the turbojet and ramjet combustion process are summarized and the resulting equations are applied to experimental data obtained from various combustor tests. The theoretical treatment assumes that one step in the over-all chain of processes which constitute jet-engine combustion is sufficiently slow to be the rate-controlling step that determines combustion efficiency.

Childs, J Howard↗
NASA NTRS1979

A fluid description of plasma double-layers

The space-charge double-layer that forms between two plasmas with different densities and thermal energies was investigated using three progressively realistic models which are treated by fluid theory, and take into account four species of particles: electrons and ions reflected by the double-layer, and electrons and ions transmitted through it. The two plasmas are assumed to be cold, and the self-consistent potential, electric field and space-charge distributions within the double-layer are determined. The effects of thermal velocities are taken into account for the reflected particles, and the modifications to the cold plasma solutions are established. Further modifications due to thermal velocities of the transmitted particles are examined. The applicability of a one dimensional fluid description, rather than plasma kinetic theory, is discussed. Theoretical predictions are compared with double layer potentials and lengths deduced from laboratory and space plasma experiments.

Levine, J. S.↗
NASA NTRS1994

Solar system formation and the distribution of volatile species

To understand how the solar system formed we must understand the compositional distribution of the current system. Volatile species are particularly important in that their stability as condensed phases is limited in temperature-pressure space, and hence variations in their distribution at present potentially contain an imprint of processes by which temperature and pressure varied in the solar nebula. In this talk we restrict ourselves to species more volatile than water ice, and address issues related to processes in the outer solar system and the formation of bodies there; others in this conference will cover volatile species relevant to inner solar system processes. Study of the outer solar system is relevant both to understanding the interface between the solar nebula and the progenitor giant molecular cloud (since the chemical links to present-day observables in molecular clouds are species like methane, carbon monoxide, etc.), as well as the origin of terrestrial planet atmospheres and oceans (the latter to be covered by Owen). The wealth of compositional information on outer solar system bodies which has become available from spacecraft and ground-based observations challenges traditional simplistic views of the composition and hence dynamics of the solar nebula. The basic assumption of thermochemical equilibrium, promulgated in the 1950's, in which methane and ammonia dominate nitrogen- and carbon-bearing species, is demonstrably incorrect on both observational and theoretical grounds. However, the kinetic inhibition model which replaced it, in which carbon monoxide and molecular nitrogen dominate a nebula which is fully mixed and hence cycles outer solar system gases through a hot, chemically active zone near the disk center, is not supported either by observations. Instead, a picture of the outer solar system emerges in which the gas and grains are a mixture of relatively unaltered, or modestly altered, molecular cloud material, along with a fraction which has been chemically altered in the solar nebula itself (and perhaps giant planet nebulae).

Lunine, Jonathan I.↗
NASA NTRS2005

Vapor Transport of ZnO in Closed Ampoules

Vapor transport of ZnO by PVT and CVT using carbon, carbon monoxide, and hydrogen as the transport agents was studied. Theoretical calculations of the mass flux were based on equilibrium thermodynamics and 1-D diffusional mass transport. Experimental results were found to be consistent with theoretical predictions. NO apparent kinetic limitations to sublimation were observed. Slow reaction of carbon with ZnO source was found.

Palosz, Witold↗
NASA NTRS1995

Mirror Instability in the Solar Wind: The Theory Revisited

"Magnetic holes", localized depressions in the interplanetary magnetic field, have been identified in Ulysses data over a range of several AU and as far as 23 degrees south in latitude by Winterhalter et al., who concluded that these structures are most likely the remnants of structures caused by occasional mirror-mode instability in the solar wind. However, these authors, like a number of previous investigators, used the mirror stability criterion derived from the kinetic theory under very special assumptions. On the other hand, theoretical investigations using the fully self-consistent kinetic theory (Vlasov-Maxwell equations) have shown that the mirror stability criterion is more complicated when electrons and ions have different anisotropies, as is normally the case in the solar wind. Winterhalter et al used an instability criterion of the form R is greater than 1, where R is a function of the thermal anisotropy; the correct criterion (for bi-Maxwellian distributions) is R R is greater than 1 - x(exp 2), where x is a real quantity that depends on both the proton anisotropy and electron anisotropy. So nonzero x would modify the Winterhalter et al results in the direction of reinforcing their conclusions. We have revisited the instability criterion in its most general form, allowing for (a) non-Maxwellian velocity distributions, (b) multiple ion species, and (c) interparticle streaming. These results should give sound theoretical grounding for future observational studies related to the mirror instability, by Ulysses and other spacecraft.

Barnes, A.↗
NASA NTRS1973

Condensation in CO2 free jet expansions. I - Dimer formation.

A theoretical and experimental investigation of the kinetics of CO2 dimer formation in the adiabatically expanding core of a free jet expansion has been carried out. The theoretical analysis is based on dimer formation by an efficient termolecular process and dimer destruction by bimolecular collisions. Account is taken of the expected variation of the specific heat ratio during the expansion and of the effective increase in the termolecular collision rate at low temperatures due to the presence of loosely bound orbiting pairs. Experimental dimer concentrations were measured mass spectrometrically by forming a molecular beam from the expanded gas mixture after the onset of molecular flow. Observed dimer concentrations, for a range of pre-expansion conditions of 400 to 900 torr pressure and room temperature, are in good agreement with the theoretical analysis, provided that account is taken of the effect of loosely bound orbiting pairs at low temperatures.

Dorfeld, W. G.↗
NASA NTRS1978

Nitric oxide formation in gas turbine engines: A theoretical and experimental study

A modified Zeldovich kinetic scheme was used to predict nitric oxide formation in the burned gases. Nonuniformities in fuel-air ratio in the primary zone were accounted for by a distribution of fuel-air ratios. This was followed by one or more dilution zones in which a Monte Carlo calculation was employed to follow the mixing and dilution processes. Predictions of NOX emissions were compared with various available experimental data, and satisfactory agreement was achieved. In particular, the model is applied to the NASA swirl-can modular combustor. The operating characteristics of this combustor which can be inferred from the modeling predictions are described. Parametric studies are presented which examine the influence of the modeling parameters on the NOX emission level. A series of flow visualization experiments demonstrates the fuel droplet breakup and turbulent recirculation processes. A tracer experiment quantitatively follows the jets from the swirler as they move downstream and entrain surrounding gases. Techniques were developed for calculating both fuel-air ratio and degree of nonuniformity from measurements of CO2, CO, O2, and hydrocarbons. A burning experiment made use of these techniques to map out the flow field in terms of local equivalence ratio and mixture nonuniformity.

Mikus, T.↗
NASA NTRS1974

A theoretical model of the wave particle interaction of plasma in space

A theoretical model, based on the kinetic theory for the perturbation of plasma in the magnetosphere, is proposed to study the observed disturbances which are caused by both natural and artificial sources that generate wave-like perturbations propagating around the globe. The proposed model covers the wave propagation through a media of transitional (from collisional to collisionless) fully ionized magnetoactive plasma. A systematic formulation of the problem is presented and the method of solution for the transitional model of magnetosphere is discussed. The possible emission of hydromagnetic waves in the magnetosphere during the quiet and disturbed time are also discussed.

Wu, S. T.↗
NASA NTRS1972

Nonequilibrium shock wave structure, 1. Kinetics of nitric oxide formation and decomposition, 2

Theoretical and numerical aspects of molecular flow simulation focussed on the development of collision models for diatomic and triatomic gases undergoing rotational excitation and energy exchange. A laser absorption technique is proposed and analyzed as sufficiently sensitive for measuring rotational populations in a nonequilibrium shock wave. Also reported is a survey of available literature on NO chemical rate data in preparation for experiments on NO decompensation kinetics in atmospheric pollution.

Kruger, C. H.↗
NASA NTRS1971

Shock wave structure using nonlinear model Boltzmann equations

The structure of a strong plane shock wave in a monatomic rarefied perfect gas is one of the simplest problems able to be posed in kinetic theory, and one of the hardest to solve. Its simplicity lies in the absence of solid boundaries, geometrical complications, or internal molecular energy. Its difficulty arises from the great departure of the gas from equilibrium within the shock, which invalidates many of the techniques used successfully elsewhere in kinetic theory. In addition to this theoretical challenge, the modern development of ballistics and hypersonic flight has helped to stimulate extensive theoretical and experimental interest in the shock problem. The experimenters in turn have encountered great difficulties on account of the very small physical dimensions of shocks. In fact, until very recently indeed, any close comparisons of theoretical and experimental shock structure results have been rather unprofitable due to the inadequacies of both theory and experiment. During the last few years this situation has been appreciably improved by development of the Monte Carlo method. This allows idealized 'experiments' to be performed on large computers instead of in wind tunnels, using a known intermolecular force law. The most developed of these methods has been shown to be equivalent theoretically to the Boltzmann equation and to give results which agree extremely closely with measurements of high accuracy. Thus Monte Carlo results not only form the soundest basis for our present theoretical knowledge of shock wave structure, but, for purposes of developing other theories, can also be considered a very valuable experimental resource. However, such results remain very expensive to obtain. In this thesis we develop more economical kinetic theory methods for the approximate prediction of shock structure, and compare our results with those of the Monte Carlo method.

Segal, Ben Maurice↗
NASA NTRS1992

Dehydration kinetics and thermochemistry of selected hydrous phases, and simulated gas release pattern in carbonaceous chondrites

As part of our continued program of study on the volatile bearing phases and volatile resource potential of carbonaceous chondrite, results of our experimental studies on the dehydration kinetics of talc as a function of temperature and grain size (50 to 0.5 microns), equilibrium dehydration boundary of talc to 40 kbars, calorimetric study of enthalpy of formation of both natural and synthetic talc as a function of grain size, and preliminary results on the dehydration kinetics of epsomite are reported. In addition, theoretical calculations on the gas release pattern of Murchison meteorite, which is a C2(CM) carbonaceous chondrite, were performed. The kinetic study of talc leads to a dehydration rate constant for 40-50 microns size fraction of k = (3.23 x 10(exp 4))exp(-Q/RT)/min with the activation energy Q = 376 (plus or minus 20) kJ/mole. The dehydration rate was found to increase somewhat with decreasing grain size. The enthalpy of formation of talc from elements was measured to be -5896(10) kJ/mol. There was no measurable effect of grain size on the enthalpy beyond the limits of precision of the calorimetric studies. Also the calorimetric enthalpy of both synthetic and natural talc was found to be essentially the same, within the precision of measurements, although the natural talc had a slightly larger field of stability in our phase equilibrium studies. The high pressure experimental data the dehydration equilibrium of talc (talc = enstatite + coesite + H2O) is in strong disagreement with that calculated from the available thermochemical data, which were constrained to fit the low pressure experimental results. The calculated gas release pattern of Murchison meteorite were in reasonable agreement with that determined by stepwise heating in a gas chromatograph.

Bose, Kunal↗
NASA NTRS1973

Turbulent heating of colliding streams in the solar wind.

Turbulent heating of colliding plasma streams has previously been observed in the solar wind. The original data were interpreted in terms of a fluid model. It is contended that a plasma-kinetic description is the more appropriate theoretical approach and is necessary in order to better understand the microscopic physical phenomena that underlie all fluid models. Microscopic solar-wind parameters characteristic of conditions during the observations were used, together with the quasi-linear plasma-kinetic theory, to compute the expected magnetic field and temperature enhancements in the interaction region between two counterstreaming plasma beams. The physical mechanism of excitation is the electromagnetic two-stream instability in which Alfven waves are unstable. A total field in the interaction region of about 8 gamma and a change in temperature of about 100,000 K are obtained.

Goldstein, M. L.↗
NASA NTRS1973

Theoretical models for electron energy relaxation in the lower ionosphere

Elastic collisions and rotation inelastic collisions involving quadrupole molecular transitions are important in energy relaxation of electrons in molecular gases. It has been customary in studying the cooling of electrons in a plasma heated by high-frequency waves to characterize this relaxation by the ionospheric G factor. The G factor is first defined in a fundamental way by use of kinetic theory. Then present models for theoretical cross sections for electron collision with O2 and N2 are used to derive expressions for the G factor in the lower ionosphere. Two models are considered: one uses Gerjuoy-Stein models for both N2 and O2; the other uses a Gerjuoy-Stein model for N2 and a Geltman-Takayanaki model for O2. Neither O2 model has been definitely established experimentally. It is found that temperature dependence of G is critically dependent on the O2 model.

Hagenbuch, K. M.↗