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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1980

The SERI solar energy storage program

In support of the DOE thermal and chemical energy storage program, the solar energy storage program (SERI) provides research on advanced technologies, systems analyses, and assessments of thermal energy storage for solar applications in support of the Thermal and Chemical Energy Storage Program of the DOE Division of Energy Storage Systems. Currently, research is in progress on direct contact latent heat storage and thermochemical energy storage and transport. Systems analyses are being performed of thermal energy storage for solar thermal applications, and surveys and assessments are being prepared of thermal energy storage in solar applications. A ranking methodology for comparing thermal storage systems (performance and cost) is presented. Research in latent heat storage and thermochemical storage and transport is reported.

Copeland, R. J.↗
DOE OSTI2023

Enhancement of conventional concrete mix designs for sensible thermal energy storage applications

The study examines twenty-nine different concrete mix designs with varying constituents to improve thermal performance for energy storage at elevated temperatures up to 420 °C. Effects of variables including the type and volumetric percentage of coarse and fine aggregates, the type and replacement content of supplemental cementitious materials, water-to-cement ratio, the type and quantity of steel fiber reinforcement, and the inclusion of iron oxide powder are experimentally investigated by measuring the mechanical and thermal properties of each mix, with the overall goal of enhancing thermal performance and mitigating mechanical degradation for thermal energy storage (TES) applications. It is found that the use of siliceous aggregate with a high volumetric percentage produces the highest improvement (23 %–37 % at elevated temperatures) of concrete thermal conductivity, while silica fume replacement of Type I cement provides the highest improvement (4 %–8 % at elevated temperatures) of concrete specific heat. To simulate the operation of a TES system, thermal cycling was conducted to examine the change in concrete properties as a function of repetitive heating (during and after 50 total cycles to 420 °C). Based on the results of testing, concrete mix designs with high aggregate percentages (up to 72 % by volume), siliceous coarse aggregate, silica fume replacement of Type I cement (15 % by weight), and steel fiber reinforcement (up to 2 % by volume) facilitate enhanced TES performance by providing consistent thermal conductivity of ~2.2 W/m·K and specific heat of ~3.2 MJ/m 3 ·K under cyclic high temperature exposure.

25 ENERGY STORAGE↗
DOE OSTI2024

Off-design operation and performance of pumped thermal energy storage

In this article, we describe off-design models and control strategies for a Pumped Thermal Energy Storage (PTES) system that uses liquid thermal energy storage: specifically molten salt for hot storage and methanol for cold storage. Off-design conditions arise when load-following, or due to variations in storage tank temperatures or ambient temperatures. We propose a control strategy that uses inventory control to manage the mass flow rate in the thermodynamic cycles, which facilitates load following. We also propose a control strategy for the storage fluid mass flow rates, which are varied to ensure the molten salt is maintained at its design temperature. This maximizes efficiency and minimizes problems with salt freezing or degradation. The cold storage fluid mass flow rate is varied so that the cold tanks have the same state-of-charge as the hot tanks. This leads to variations in cold fluid temperature, but these variations are shown to be acceptably small (e.g. 7.5% increase), and this control method is shown to be simpler and more efficient than an alternative strategy where tanks become unbalanced. The ambient temperature and storage tank temperatures are moved ±50 °C from the design values and the impact on power, duration, and tank temperatures is quantified. Results demonstrate that the proposed control strategy is stable and self-correcting - that is, storage temperatures converge on stable values after two-to-three charge-discharge cycles. When inputs return to design values, the system returns to its design point after two charge-discharge cycles. We also demonstrate that inventory control enables delivery of the target power output even when off-design conditions exist that would normally reduce the power output.

25 ENERGY STORAGE↗
DOE OSTI2023

Optimizing Phase Change Composite Thermal Energy Storage Using the Thermal Ragone Framework

The thermal Ragone framework can be applied to the design of thermal energy storage heat exchangers to identifying relationships between their power requirements and energy capabilities. This presentation focuses on the design of planar thermal energy storage heat exchangers with phase change materials and thermal conductivity additives. Finite-difference models were used to optimize thermal storage heat exchanger designs focusing on key design parameters of conductivity additive volume fraction, spacing between tubes, and the phase transition temperatures. Design trends were developed for optimal designs based on varying thermal power requirements. To aid in future device design, models of reduced complexity were developed with the ability to predict optimal designs with computational speeds up to 5,000 times faster than finite-difference models.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION,↗
NASA NTRS1988

Structural assessment of a Space Station solar dynamic heat receiver thermal energy storage canister

This paper assesses the structural performance of a Space Station thermal energy storage (TES) canister subject to orbital solar flux variation and engine cold start-up operating conditions. The impact of working fluid temperature and salt-void distribution on the canister structure are assessed. Both analytical and experimental studies were conducted to determine the temperature distribution of the canister. Subsequent finite-element structural analyses of the canister were performed using both analytically and experimentally obtained temperatures. The Arrhenius creep law was incorporated into the procedure, using secondary creep data for the canister material, Haynes-188 alloy. The predicted cyclic creep strain accumulations at the hot spot were used to assess the structural performance of the canister. In addition, the structural performance of the canister based on the analytically-determined temperature was compared with that based on the experimentally-measured temperature data.

Tong, M. T.↗
DOE OSTI2024

Influence of Thermal Energy Storage Integration Strategy on System Performance and Refrigerant Charge for Small-Scale R290 Heat Pumps

As small-scale (2.5 – 5 kW) heat pumps across the US increase straining the grid during peak hours, integrated heat pump thermal energy storage (HP-TES) systems can assist by load shifting. However, challenges arise when assembling these systems, as direct refrigerant-phase change material (PCM) heat exchangers (HXs) increase refrigerant charge, and indirect secondary loops degrade HP-TES performance. In this work, direct and indirect HP-TES configurations were sized using commercially available HXs to compare the available load shift time and performance at similar refrigerant charges. For the same indirect 5 kW HP-TES refrigerant charge, directly HP-TES can operate up to 72 and 145 minutes in cooling and heating modes, respectively, using small diameter tubes. Using Modelica, COP increases for direct and indirect HP-TES were 22% and 9%, respectively, given the parasitic losses in the indirect HP-TES. Overall, small-scale direct HP-TES can have comparable refrigerant charges with indirect HP-TES maximizing COP improvements.

25 ENERGY STORAGE↗
DOE OSTI2021

A first principles framework to predict the transient performance of latent heat thermal energy storage

Thermal energy storage (TES) is increasingly recognized as an essential component of efficient Combined Heat and Power (CHP), Concentrated Solar Power (CSP), Heating Ventilation and Air Conditioning (HVAC), and refrigeration as it reduces peak demand while helping to manage intermittent availability of energy (e.g., from solar or wind). Latent Heat Thermal Energy Storage (LHTES) is a viable option because of its high energy storage density. Parametric analysis of LHTES in terms of dimensionless numbers is highly desired as a tool to model LHTES systems. One approach is to develop a model equation so as to minimize the error between the model and data obtained from experiments or simulations. While this approach can produce an accurate correlation applicable within the range of data used for its creation, it does not provide physical understanding of the rate-limiting process controlling the transient behavior of the device. In this paper we present an alternative approach whereby the potential rate-limiting processes are identified from first principles and then the key process is determined as a function of time as a LHTES device is charged. For example, in a simple geometry, the melt-fraction can be expected to vary linearly in time if the heat transfer rate is limited by natural convection of the phase changing material and we show it scales with the PCM Grashof number as $Gr^1_p$ and PCM Prandtl number as $Pr_p^{(1/3)}$. On the other hand, if surface area of solid PCM limits the heat transfer rate, the melt fraction increases asymptotically to reach full melting. The existence of these linear and asymptotic regions and the $Gr^1_pP r^{1/3}_p$ shape of the melt fraction curve is verified using our database of 64 simulations. Of practical importance in designing LHTES devices is the melt fraction at which the heat transfer rate ceases to be limited by convection, after which the heat storage rate deteriorates. For our geometry, this is found to be about 90%. This test case of our methodology shows the value of our approach, that predicting heat storage rate based on the rate-limiting physical phenomenon as a function of time is an effective approach to modeling LHTES devices.

25 ENERGY STORAGE↗
DOE OSTI2026

Design and performance assessment of a dual-mode latent thermal storage integrated heat pump across multiple climate zones

The electrification of space cooling and heating systems risks overloading the existing electrical grid during peak hours. Heat pumps integrated with thermal energy storage (HP-TES) offer a promising solution by shifting peak loads to off-peak hours, reducing grid strains. This work presents the design and assessment of a dual-mode HP-TES that uses a single 22°C phase-change material (PCM) as a heat source or sink in heating and cooling modes, respectively. Performance assessment was conducted using Modelica-based transient models, and full-year simulations were conducted across eight US climate zones using typical weather data. Two HP-TES performance metrics: peak energy reduction and recharge energy increases, were defined by comparing HP-TES energy consumption with base HP peak consumptions. Annual heating demand reductions (40–65%) exceeded cooling demand reductions (15–20%) due to the elimination of peak-hour backup heating. Cooling mode recharge energy requirements (0–10%) were reduced in locations with lower summer nighttime temperatures, while heating recharge requirements were lower than the high base-peak energy demand from backup heating. Simplified rapid methods that were 10 7 times faster than annual simulations were developed to predict seasonal cooling and heating energy reductions, and recharge energy requirements, with maximum deviations of ±2.5% and ±3.5% points. These methods enabled rapid parametric studies that identified optimal location-specific PCM temperatures between 22°C and 27°C, highlighting the need to consider both discharge and recharge energy requirements to achieve sustainable, energy-efficient peak load shifting across various climate zones.

25 ENERGY STORAGE↗
DOE OSTI2021

Performance evaluation of a dynamic wall integrated with active insulation and thermal energy storage systems

Thermal energy storage systems in buildings can store cooling/heating energy during non-peak load hours or when renewable energy sources are available for later use when demanded. Using the building envelope as a thermal battery can help to shave the peak load, reduce the burden in electric grids, and enhance the occupant's thermal comfort. Sensible energy storage on wall systems such as thermally activated building systems can provide an active thermal storage strategy. However, most of the stored energy is used through passive means directed by the thermal lag, which can impede the on-demand release of the stored energy. Integrating active insulation systems with building thermal storage systems can increase the flexibility of charging and discharging time and duration. In this study, a wall system equipped with an active insulation system and thermally activated storage system was designed, and its performance on active cooling energy contribution was studied. The performances of energy storage (charging), release (discharging) of the thermal energy storage energy, and the active insulation system were studied separately and together as an integrated system. Results showed that the thermal properties of the thermal energy storage core material and the pipe spacing of both embedded pipes in the thermal energy storage and hydronic pipes used in the active insulation system affected the wall performance the most out of all the tested wall system parameters. During discharging, the heat flux into the wall was as high as 81.92 W/m 2 . This active insulation system's dynamic R-value varied between less than 1ft 2 •°F•h/BTU (0.18 m 2 •K/W) to 98% of the equally thick foam insulation's R-value.

25 ENERGY STORAGE↗
DOE OSTI2026

EXERGETIC: De-Risking Next-Generation Resilient Geothermal Hybrids via At-Scale Evaluation Using Virtual Emulation Digital Twin Environment for Efficient Operation

The DOE-GTO-funded project, award number 5.1.2.12, entitled "EXERGETIC - De-risking Next Generation Resilient Geothermal Hybrids via at-Scale Evaluation Using a Virtual Emulation Digital Twin Environment for Efficient Operation," advances the solution to these challenges by developing and validating a geothermal co-emulation environment implemented at the National Laboratory of the Rockies (NLR)'s Advanced Research on Integrated Energy Systems (ARIES) platform. This framework enables the de-risking of next-generation geothermal and geothermal hybrid systems through high-fidelity modeling, real-time digital emulation, advanced control strategies, and techno-economic assessment. The project focused on geothermal hybrid configurations that integrate geothermal power plants with concentrated solar power and underground thermal energy storage, enabling enhanced efficiency, flexibility, and grid support capabilities. The main goal of this project was the development of a geothermal digital co-emulation environment to demonstrate the technical and economic value of geothermal hybrid systems and their contribution to grid stability and flexibility. The EXERGETIC framework combined physics-based models, controls, and real assets at ARIES, including digital real-time simulators (DRTS), a 20-MW-scale controllable grid interface (CGI), and a 2-MW conventional generator. Detailed transient models were developed for the key subsystems of a hybrid geothermal plant, including parabolic trough solar collectors, reservoir thermal energy storage (RTES), and a binary Organic Rankine Cycle (ORC) power plant. The ORC model explicitly captured thermal inertia and off-design operation and integrated control strategies to dynamically respond to electric load profiles. The models were validated against published experimental and numerical studies, demonstrating strong agreement and confirming the accuracy and robustness of the modeling approach. The resulting digital twin represents geothermal-solar-storage systems at multiple scales (1 MW to 100 MW) and enables realistic emulation of grid-connected operation. The control architecture allows the geothermal resource to provide stable baseload generation, while solar and stored thermal energy supply flexible, dispatchable support during periods of high demand or variable grid conditions. A key contribution of the EXERGETIC project is the demonstration that geothermal hybrid systems can be designed to be active grid assets rather than passive baseload generators. Using the ARIES platform, the digital twin was evaluated under multiple grid scenarios, including load following, voltage support at the distribution level, and frequency response at the transmission level. Results show that hybrid geothermal systems can respond effectively to dynamic grid conditions, providing inertia-like behavior, primary frequency support, and voltage regulation through coordinated control. In addition to the performance and grid services capability analysis of geothermal and hybrid geothermal systems, the EXERGETIC project also focused on scalability and techno-economic analysis of geothermal hybrid plants. In particular, for the scalability analysis, machine-learning (ML)-based surrogate models were trained using data generated from the geothermal digital twin under different grid-connected scenarios and plant capacities. These ML models demonstrated strong interpolation and extrapolation capabilities across plant sizes, accurately reproducing both steady-state and transient responses with very low errors. Regarding the techno-economic analysis, plant performance results were integrated with cost models for hybrid geothermal systems, and the levelized cost of electricity (LCOE) was used as the main economic metric to evaluate system performance across a range of system capacities, solar shares, solar multiples, and storage durations. Results indicate that economies of scale significantly reduce geothermal LCOE as plant capacity increases, with large-scale systems (25-100 MW) achieving substantially lower costs than small plants. Hybridization with solar thermal energy and storage further improves economic performance by increasing capacity utilization and enabling flexible dispatch. In addition, thermal storage plays a critical role in reducing LCOE by maximizing geothermal, solar, and stored energy resources. In summary, the results from this project demonstrate that geothermal hybrid systems represent a promising alternative for increasing the energy conversion efficiency of geothermal technologies, contributing to the preservation of geothermal resources, and supporting the transition of geothermal plants from traditional baseload resources into flexible, resilient, and cost-competitive energy conversion technologies.

15 GEOTHERMAL ENERGY↗
DOE OSTI2021

Design and performance evaluation of a dual-circuit thermal energy storage module for air conditioners

We present experimental results and a validated numerical model of a dual-circuit phase-change thermal energy storage module for air conditioners. The module incorporates a phase-change material encapsulated in compressed expanded natural graphite foam. We used n-tetradecane as the PCM with a transition temperature (~4.5 °C) suitable for air-conditioning applications. Heat exchange to and from the module is accomplished through two fluid loops operating as a heat source and sink embedded inside multiple slabs of the composite material. This dual-circuit design enables easier integration with air-conditioning equipment and provides enhanced flexibility in system operation as compared to the state-of-the-art thermal storage systems. When integrated with an air-conditioner, this design will enable peak-load shaving and enhances operational efficiency. The thermal storage device was designed for a nominal storage capacity of ~ 3.5 kWh. We evaluated the heat transfer and energy storage performance of this device using standalone heat transfer experiments to estimate key thermal resistances and identify design improvements before integration with an air conditioner. The numerical model of the heat exchanger uses a combination of discretized and lumped parameter approaches to maintain a balance between accuracy and computational expense. Our analyses show that the geometric features and integration of fluid tubes are key contributors to the thermal contact resistance between the fluid and the thermal storage material, and consequently, to the overall performance of the thermal storage module. Our standalone experiments also identified important operating scenarios in which this thermal storage module can be used for air-conditioning in buildings.

25 ENERGY STORAGE↗
DOE OSTI2025

The role of moisture in MgCl 2 salt: A multiscale approach to TES performance

This study presents a comprehensive multiscale analysis to evaluate the influence of moisture on the thermal performance of thermal energy storage systems using magnesium chloride (MgCl 2 ) as the phase-changing material. The system uses graphite foam with 90% relative density to enhance thermal conductivity. The analysis includes thermal conductivity calculations and specific heat capacity for different hydrate phases of MgCl 2 : Anhydrous, Mono, Di, Tetra, and Hexa. These properties were evaluated for the first time using the phonon density of states from Density Functional Theory simulations. Results showed that thermal conductivity decreased, while specific heat capacity increased by a factor of two as the phase changed from anhydrous to hexahydrate. Meso-scale models were created to account for the anisotropy of graphite foam and property variations of the MgCl 2 hydrate phases. Asymptotic Expansion homogenization simulations determined the anisotropic thermal conductivity for all phases. This unique methodology improved simulation accuracy, which matched experimental data for anhydrous MgCl 2 . A parametric study examined various operating conditions and their effect on TES performance. It revealed that higher charging temperatures did not enhance exergy efficiency, but increased discharge mass flow rates improved it due to better heat transfer. Thermal performance evaluated by the exergy efficiency remained consistent across hydrate systems under the tested conditions. Furthermore, the study suggests that this uniformity is linked to missing key data, particularly latent heat and melting point for different hydrates. Overall, it highlights the importance of multiscale effects and accurate material properties in designing and optimizing TES systems.

Molten salt degradation↗
NASA NTRS1991

Analysis, design, and experimental results for lightweight space heat receiver canisters, phase 1

Critical technology experiments have been performed on thermal energy storage modules in support of the Brayton Advanced Heat Receiver program. The modules are wedge-shaped canisters designed to minimize the mechanical stresses that occur during the phase change of the lithium fluoride phase change material. Nickel foam inserts were used in some of the canisters to provide thermal conductivity enhancement and to distribute the void volume. Two canisters, one with a nickel foam insert, and one without, were thermally cycled in various orientations in a fluidized bed furnace. The only measurable impact of the nickel foam was seen when the back and short sides of the canister were insulated to simulate operation in the advanced receiver design. In tests with insulation, the furnace to back side delta T was larger in the canister with the nickel foam insert, probably due to the radiant absorptivity of the nickel. However, the differences in the temperature profiles of the two canisters were small, and in many cases the profiles matched fairly well. Computed Tomography (CT) was successfully used to nondestructively demarcate void locations in the canisters. Finally, canister dimensional stability, which was measured throughout the thermal cycling test program with an inspection fixture was satisfactory with a maximum change of 0.635 mm (0.025 in.).

Schneider, Michael G.↗
NASA NTRS1991

Critical technology experiment results for lightweight space heat receiver

Critical technology experiments have been performed on thermal energy storage modules in support of the NASA Advanced Solar Dynamic Brayton Heat Receiver Program. The modules, wedge-shaped canisters containing lithium fluoride (LiF), were designed to minimize the mechanical stresses that occur during the phase change of the LiF. Nickel foam inserts were placed in two of the test canisters to provide thermal conductivity enhancement and to distribute the void volume throughout the canister. A procedure was developed for reducing the nickel oxides on the nickel foam to enhance the wicking ability of the foam. The canisters were filled with LiF and closure-welded at the NASA Lewis Research Center. Two canisters, one with a nickel foam insert, the other without an insert, were thermally cycled in various orientations in a fluidized bed furnace. Computer-aided tomography was successfully used to nondestructively determine void locations in the canisters. Finally, canister dimensional stability was measured after thermal cycling with an inspection fixture.

Schneider, Michael G.↗