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Thermodynamic and turbomachinery concepts for low power radioisotope and intermediate power reactor Brayton cycle systems - examination of intercooling and reheating effects
Thermodynamic and transport properties of oxygen- nitrogen equilibrium system
Thermodynamic and turbine characteristics of gas turbine-driven hydrogen fueled open cycle auxiliary space power systems
A unique zero-g thermodynamic vent system (TVS) is being developed by NASA's Marshall Space Flight Center (MSFC) and Rockwell International to meet cryogenic propellant management requirements for future space missions. The design is highly innovative in that it integrates the functions of a spray-bar tank mixer and a TVS. This concept not only satisfies the requirement for efficient tank mixing and zero-g venting but also accommodates thermal conditioning requirements for other components (e.g., engine feed lines, turbopumps, and liquid acquisition devices). In addition, operations can be extended to accomplish tank chill-down, no-vent fill, and emergency venting during zero-g propellant transfer. This paper describes the system performance characterization and future test activities that are part of MSFC's Multipurpose Hydrogen Test Bed (MHTB) program. The testing will demonstrate the feasibility and merit of the design, and serve as a proof-of-concept development activity.
A Solid-State Thermodynamic Vent System (STVS) is a novel Cryogenic Fluid Management (CFM) technology for spacecraft cryogenic propellant tanks that may reduce boiloff while providing greater control over the propellant condition. By exploiting the vacuum-induced cryocooling (VIC) potential of cryogen-saturated silica aerogel material, an internal STVS heat exchanger (HX) can expel some sacrificial cryogenic propellant to the vacuum of space to produce cooling within the storage tank. This cooling is transferred directly to the stored fluid, thereby reducing boiloff and increasing hold times. Testing proved the effectiveness of the concept by reducing the liquid nitrogen (LN 2 ) boiloff rate and tank pressure by roughly 70% and 77%, respectively, during a single pump-down cycle, which sacrificed around 1.8 kg of propellant.
Thermodynamic calculations based on the available data for flouride salt systems reveal that a number of congruently melting compositions and eutectics exist which have the potential to meet the lightweight, high energy storage requirements imposed for advanced solar dynamic systems operating between about 1000 and 1400 K. Compatibility studies to determine suitable containment alloys to be used with NaF-22CaF2-13MgF2, NaF-32CaF2, and NaF-23MgF2 have been conducted at the eutectic temperature + 25 K for each system. For these three NaF-based eutectics, none of the common, commercially available high temperature alloys appear to offer adequate corrosion resistance for a long lifetime; however mild steel, pure nickel and Nb-1Zr could prove useful. These latter materials suggest the possibility that a strong, corrosion resistant, nonrefractory, elevated temperature alloy based on the Ni-Ni3Nb system could be developed.
This report presents the results of several thermodynamic vent system (TVS) tests with liquid oxygen plus a test with liquid nitrogen. In all tests, the liquid was heated above its normal boiling point to 111 K for oxygen and 100 K for nitrogen. The elevated temperature was representative of tank conditions for a candidate lunar lander ascent stage. An initial test series was conducted with saturated oxygen liquid and vapor at 0.6 MPa. The initial series was followed by tests where the test tank was pressurized with gaseous helium to 1.4 to 1.6 MPa. For these tests, the helium mole fraction in the ullage was quite high, about 0.57 to 0.62. TVS behavior is different when helium is present than when helium is absent. The tank pressure becomes the sum of the vapor pressure and the partial pressure of helium. Therefore, tank pressure depends not only on temperature, as is the case for a pure liquid-vapor system, but also on helium density (i.e., the mass of helium divided by the ullage volume). Thus, properly controlling TVS operation is more challenging with helium pressurization than without helium pressurization. When helium was present, the liquid temperature would rise with each successive TVS cycle if tank pressure was kept within a constant control band. Alternatively, if the liquid temperature was maintained within a constant TVS control band, the tank pressure would drop with each TVS cycle. The final test series, which was conducted with liquid nitrogen pressurized with helium, demonstrated simultaneous pressure and temperature control during TVS operation. The simultaneous control was achieved by systematic injection of additional helium during each TVS cycle. Adding helium maintained the helium partial pressure as the liquid volume decreased because of TVS operation. The TVS demonstrations with liquid oxygen pressurized with helium were conducted with three different fluid-mixer configurations-a submerged axial jet mixer, a pair of spray hoops in the tank ullage, and combined use of the axial jet and spray hoops. A submerged liquid pump and compact heat exchanger located inside the test tank were used with all the mixer configurations. The initial series without helium and the final series with liquid nitrogen both used the axial jet mixer. The axial jet configuration successfully demonstrated the ability to control tank pressure; but in the normal-gravity environment, the temperature in the upper tank region (ullage and unwetted wall) was not controlled. The spray hoops and axial jet combination also successfully demonstrated pressure control as well as temperature control of the entire tank and contents. The spray-hoops-only configuration was not expected to be a reliable means of tank mixing because there was no direct means to produce liquid circulation. However, surprisingly good results also were obtained with the sprayhoops- only configuration (i.e., performance metrics such as cycle-averaged vent flowrate were similar to those obtained with the other configurations). A simple thermodynamic model was developed that correctly predicted the TVS behavior (temperature rise or pressure drop per TVS cycle) when helium was present in the ullage. The model predictions were correlated over a range of input parameters. The correlations show that temperature rise or pressure drop per cycle was proportional to both helium mole fraction and tank heat input. The response also depended on the tank fill fraction: the temperature rise or pressure drop (per TVS cycle) increased as the ullage volume decreased.
A two-phase cryogenic heat exchanger for a thermodynamic vent system was designed and analyzed, and the predicted performance was compared with test results. A method for determining the required size of the Joule-Thomson device was also developed. Numerous sensitivity studies were performed to show that the design was robust and possessed a comfortable capacity margin. The comparison with the test results showed very similar heat extraction performance for similar inlet conditions. It was also shown that estimates for Joule- Thomson device flow rates and exit quality can vary significantly and these need to be accommodated for with a robust system design.
A Solid-State Thermodynamic Vent System (STVS) is a novel Cryogenic Fluid Management (CFM) technology for spacecraft cryogenic propellant tanks that may reduce boiloff while providing greater control over the propellent condition. By exploiting the vacuum-induced cryocooling potential of cryogen-saturated silica aerogel material, an internal STVS heat exchanger expels some sacrificial cryogenic propellant to the vacuum of space to produce cooling within the storage tank. This cooling is transferred directly to the stored fluid, thereby reducing boiloff and increasing hold times. The primary STVS project objective was to design and build a bespoke STVS heat exchanger that employed aerogel blanket material and perform a ground demonstration of the technology using liquid nitrogen (LN2) as the cryogenic propellant. This demonstration aimed to prove that an STVS can have a positive influence on the tank boiloff, shown through a reduction in mass flow rate out of the system during operation, and exercise control over the tank pressure. Testing proved the effectiveness of the concept by reducing the LN2 boiloff rate and tank pressure by roughly 70% and 77% respectively during a single pump-down cycle, which sacrificed around 1.8 kg of propellant.
Thermodynamic data are required input for the finite kinetics and equilibrium computer programs needed for modeling the combustion of hydrocarbons in the fields of energy and pollution research. Least squares determined coefficients of the curve-fitted thermodynamic data for 193 species in the C-H-O-N system are presented in card image form and are of suitable format for use by common computer programs.
Viewgraphs are presented showing drawings of Centaur configurations, the Thermodynamic Vent System (TVS), the mixer pump, and the hydrogen vent motor pump inverter. A cryogenic performance summary is given in chart form. The TVS liquid flow operation and vapor flow operation are diagrammed.
This report documents the Zero-g Thermodynamic Venting System (TVS) performance prediction computer program. The zero-g TVS is a device that destratifies and rejects environmentally induced zero-g thermal gradients in the LH2 storage transfer system. A recirculation pump and spray injection manifold recirculates liquid throughout the length of the tank thereby destratifying both the ullage gas and liquid bulk. Heat rejection is accomplished by the opening of the TVS control valve which allows a small flow rate to expand to a low pressure thereby producing a low temperature heat sink which is used to absorb heat from the recirculating liquid flow. The program was written in FORTRAN 77 language on the HP-9000 and IBM PC computers. It can be run on various platforms with a FORTRAN compiler.
To support development of a microgravity pressure control capability for liquid oxygen, thermodynamic vent system (TVS) testing was conducted at Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a LOX simulant. The spray bar TVS hardware used was originally designed by the Boeing Company for testing in liquid hydrogen (LH2). With this concept, a small portion of the tank fluid is passed through a Joule-Thomson (J-T) device, and then through a longitudinal spray bar mixed-heat exchanger in order to cool the bulk fluid. To accommodate the larger mass flow rates associated with LN2, the TVS hardware was modified by replacing the recirculation pump with an LN2 compatible pump and replacing the J-T valve. The primary advantage of the spray-bar configuration is that tank pressure control can be achieved independent of liquid and vapor location, enhancing the applicability of ground test data to microgravity conditions. Performance testing revealed that the spray-bar TVS was effective in controlling tank pressure within a 6.89 kPa band for fill levels of 90%, 50%, and 25%. Tests were also conducted with gaseous helium (GHe) in the ullage. The TVS operated nominally with GHe in the ullage, with performance similar to the tests with gaseous nitrogen (GN2). Testing demonstrated that the spray-bar TVS design was flexible enough for use in two different propellants with minimal hardware modifications.
NASA's Marshall Space Flight Center conducted liquid methane testing in November 2006 using the multipurpose hydrogen test bed outfitted with a spray bar thermodynamic vent system (TVS). The basic objective was to identify any unusual or unique thermodynamic characteristics associated with densified methane that should be considered in the design of space-based TVSs. Thirteen days of testing were performed with total tank heat loads ranging from 720 to 420 W at a fill level of approximately 90%. It was noted that as the fluid passed through the Joule-Thompson expansion, thermodynamic conditions consistent with the pervasive presence of metastability were indicated. This Technical Publication describes conditions that correspond with metastability and its detrimental effects on TVS performance. The observed conditions were primarily functions of methane densification and helium pressurization; therefore, assurance must be provided that metastable conditions have been circumvented in future applications of thermodynamic venting to in-space methane storage.
A report discusses a cryogenic reaction control system (RCS) that integrates a Joule-Thompson (JT) device (expansion valve) and thermodynamic vent system (TVS) with a cryogenic distribution system to allow fine control of the propellant quality (subcooled liquid) during operation of the device. It enables zero-venting when coupled with an RCS engine. The proper attachment locations and sizing of the orifice are required with the propellant distribution line to facilitate line conditioning. During operations, system instrumentation was strategically installed along the distribution/TVS line assembly, and temperature control bands were identified. A sub-scale run tank, full-scale distribution line, open-loop TVS, and a combination of procured and custom-fabricated cryogenic components were used in the cryogenic RCS build-up. Simulated on-orbit activation and thruster firing profiles were performed to quantify system heat gain and evaluate the TVS s capability to maintain the required propellant conditions at the inlet to the engine valves. Test data determined that a small control valve, such as a piezoelectric, is optimal to provide continuously the required thermal control. The data obtained from testing has also assisted with the development of fluid and thermal models of an RCS to refine integrated cryogenic propulsion system designs. This system allows a liquid oxygenbased main propulsion and reaction control system for a spacecraft, which improves performance, safety, and cost over conventional hypergolic systems due to higher performance, use of nontoxic propellants, potential for integration with life support and power subsystems, and compatibility with in-situ produced propellants.
Thermodynamic calculations provide the means to quantify the chemical disequilibrium inherent in the mixing of reduced hydrothermal fluids with seawater. The chemical energy available for metabolic processes in these environments can be evaluated by taking into account the pressure and temperature dependence of the apparent standard Gibbs free energies of reactions in the S-H2-H2O system together with geochemical constraints on pH, activities of aqueous sulfur species and fugacities of H2 and/or O2. Using present-day mixing of hydrothermal fluids and seawater as a starting point, it is shown that each mole of H2S entering seawater from hydrothermal fluids represents about 200,000 calories of chemical energy for metabolic systems able to catalyze H2S oxidation. Extrapolating to the early Earth, which was likely to have had an atmosphere more reduced than at present, shows that this chemical energy may have been a factor of two or so less. Nevertheless, mixing of hydrothermal fluids with seawater would have been an abundant source of chemical energy, and an inevitable consequence of the presence of an ocean on an initially hot Earth. The amount of energy available was more than enough for organic synthesis from CO2 or CO, and/or polymer formation, indicating that the vicinity of hydrothermal systems at the sea floor was an ideal location for the emergence of the first chemolithoautotrophic metabolic systems.
NASA s Marshall Space Flight Center (MSFC) conducted liquid methane (LCH4) testing in November 2006 using the multipurpose hydrogen test bed (MHTB) outfitted with a spray-bar thermodynamic vent system (TVS). The basic objective was to identify any unusual or unique thermodynamic characteristics associated with subcooled LCH4 that should be considered in the design of space-based TVSs. Thirteen days of testing were performed with total tank heat loads ranging from 720 W to 420 W at a fill level of approximately 90%. During an updated evaluation of the data, it was noted that as the fluid passed through the Joule Thompson expansion, thermodynamic conditions consistent with the pervasive presence of metastability were indicated. This paper describes the observed thermodynamic conditions that correspond with metastability and effects on TVS performance.
Cryogens are viable candidate propellants for NASA's Lunar and Mars exploration programs. To provide adequate mass flow to the system's engines and/or to prevent feed system cavitation, gaseous helium (GHe) is frequently considered as a pressurant. During low gravity operations, a Thermodynamic Venting System (TVS) is designed to maintain tank pressure during low gravity operations without propellant resettling. Therefore, a series of tests were conducted in the Multi-purpose Hydrogen Test Bed (MHTB) of Marshall Space Flight Center (MSFC) in order to evaluate the effects of GHe pressurant on pressure control performance of a TVS with liquid hydrogen (LH2) and nitrogen (LN2) as the test liquids. The TVS used in these test series consists of a recirculation pump, Joule-Thomson (J-T) expansion valve, and a parallel flow concentric tube heat exchanger combined with a longitudinal spray bar. Using a small amount of liquid extracted from the tank recirculation line, passing it through the J-T valve, and then through the heat exchanger, thermal energy is extracted from the bulk liquid and ullage thereby enabling pressure control. The LH2/GHe tests were performed at fill levels of 90%, 50%, and 25% and LN2/GHe tests were conducted at fill levels of 50% and 25%. Moreover, each test was conducted with a specified tank ullage pressure control band. A one-dimensional TVS performance program was used to analyze and correlate the test data. Predictions and comparisons with test data of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented.