Unveiling the dimensionality effect of conductive fillers in thick battery electrodes for high-energy storage systems
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Low temperature mechanical properties of aluminum alloy sheet and plate of various thicknesses
An experimental study was made on five 2024-T3 aluminum-alloy multiweb wing structures (MW-2-(4), MW-4-(3), mw-16, MW-17, and MW-18), at a Mach number of 2 and an angle of attack of 2 deg under simulated supersonic flight conditions. These models, of 20-inch chord and semi-span and 5-percent-thick circular-arc airfoil section, were identical except for the type and amount of chordwise stiffening. One model with no chordwise ribs between root and tip bulkhead fluttered and failed dynamically partway through its test. Another model with no chordwise ribs (and a thinner tip bulkhead) experienced a static bending type of failure while undergoing flutter. The three remaining models with one, two, or three chordwise ribs survived their tests. The test results indicate that the chordwise shear rigidity imparted to the models by the addition of even one chordwise rib precludes flutter and subsequent failure under the imposed test conditions. This paper presents temperature and strain data obtained from the tests and discusses the behavior of the models.
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Ni-rich NMC (LiNixMnyCo1-x-yO2, x = 0.6) has the attributes of high specific capacity (greater than 180 mAh g-1), high operating voltage (ca. 3.8 V) and low cost, which is therefore deemed as one of the most promising cathode candidates for next-generation high-energy Li-ion batteries (LIBs). However, challenges exist before the large-scale commercialization of Ni-rich cathode such as gas generation, capacity degradation especially at high rate or elevated temperatures. From thin film to densely pack high loading cathode, this work investigates the rate-limiting steps in Ni-rich cathodes e.g., phase structure, electronic and ionic conductivity to understand the reaction kinetics at different scales. This work provides new insights in understanding the electrochemical properties of Ni-rich cathode at different levels to inspire revolutionary ideas to address the fundamental issues of Ni-rich cathode from materials to relevant electrode levels.
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