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NASA NTRS2022

GJ 3929: High-precision Photometric and Doppler Characterization of an Exo-Venus and Its Hot, Mini-Neptune-mass Companion

We detail the follow-up and characterization of a transiting exo-Venus identified by TESS, GJ 3929b (TOI-2013b), and its nontransiting companion planet, GJ 3929c (TOI-2013c). GJ 3929b is an Earth-sized exoplanet in its star’s Venus zone ( P b = 2.616272 ± 0.000005 days; S b = 17.3 +0.8 -0.7 S ⊕ ) orbiting a nearby M dwarf. GJ 3929c is most likely a nontransiting sub-Neptune. Using the new, ultraprecise NEID spectrometer on the WIYN 3.5 m Telescope at Kitt Peak National Observatory, we are able to modify the mass constraints of planet b reported in previous works and consequently improve the significance of the mass measurement to almost 4σ confidence ( M b = 1.75 ± 0.45 M ⊕ ). We further adjust the orbital period of planet c from its alias at 14.30 ± 0.03 days to the likely true period of 15.04 ± 0.03 days, and we adjust its minimum mass to m sin i = 5.71 ± 0.92 M ⊕ . Using the diffuser-assisted ARCTIC imager on the ARC 3.5 m telescope at Apache Point Observatory, in addition to publicly available TESS and LCOGT photometry, we are able to constrain the radius of planet b to R p = 1.09 ± 0.04 R ⊕ . GJ 3929b is a top candidate for transmission spectroscopy in its size regime (TSM = 14 ± 4), and future atmospheric studies of GJ 3929b stand to shed light on the nature of small planets orbiting M dwarfs.

Exoplanets↗

NASA NTRS1998

Surface Chemistry, Microstructure, and Tribological Properties of Cubic Boron Nitride Films

This report deals with the surface chemistry, microstructure, bonding state, morphology, and friction and wear properties of cubic boron nitride (c-BN) films that were synthesized by magnetically enhanced plasma ion plating. Several analytical techniques - x-ray photoelectron spectroscopy, transmission electron microscopy and electron diffraction, Fourier transform infrared spectroscopy, atomic force microscopy, and surface profilometry - were used to characterize the films. Sliding friction experiments using a ball-on-disk configuration were conducted for the c-BN films in sliding contact with 440C stainless-steel balls at room temperature in ultrahigh vacuum (pressure, 10(exp -6), in ambient air, and under water lubrication. Results indicate that the boron-to-nitrogen ratio on the surface of the as-deposited c-BN film is greater than 1 and that not all the boron is present as boron nitride but a small percentage is present as an oxide. Both in air and under water lubrication, the c-BN film in sliding contact with steel showed a low wear rate, whereas a high wear rate was observed in vacuum. In air and under water lubrication, c-BN exhibited wear resistance superior to that of amorphous boron nitride, titanium nitride, and titanium carbide.

Watanabe, Shuichi↗

NASA NTRS2010

NICMOS Spectroscopy of HD 189733b

Spectral features corresponding to methane and water opacity were reported based on transmission spectroscopy of HD 189733b with Hubble/NICMOS. Recently, these data, and a similar data set for XO-1b, have been reexamined in Gibson et al. 2010, who claim they cannot reliably reproduce prior results. We examine the methods used by the Gibson team and identify two specific issues that could act to increase the formal uncertainties and to create instability in the minimization process. This would also be consistent with the GPA10 finding that they could not identify a way to select among the several instrument models they constructed. In the case of XO-1b, the Gibson team significantly changed the way in which the instrument model is defined (both with respect to the three approaches they used for HD 189733b, and the approach used by previous authors); this change, which omits the effect of the spectrum position on the detector, makes direct intercomparison of results difficult. In the experience of our group, the position of the spectrum on the detector is an important element of the instrument model because of the significant residual structure in the NICMOS spectral flat field. The approach of changing instrument models significantly complicates understanding the data reduction process and interpreting the results. Our team favors establishing a consistent method of handling NICMOS instrument systematic errors and applying it uniformly to data sets.

infrared↗

NASA NTRS1999

Modeling and Real-Time Process Monitoring of Organometallic Chemical Vapor Deposition of III-V Phosphides and Nitrides at Low and High Pressure

The purpose of this paper is to review modeling and real-time monitoring by robust methods of reflectance spectroscopy of organometallic chemical vapor deposition (OMCVD) processes in extreme regimes of pressure. The merits of p-polarized reflectance spectroscopy under the conditions of chemical beam epitaxy (CBE) and of internal transmission spectroscopy and principal angle spectroscopy at high pressure are assessed. In order to extend OMCVD to materials that exhibit large thermal decomposition pressure at their optimum growth temperature we have designed and built a differentially-pressure-controlled (DCP) OMCVD reactor for use at pressures greater than or equal to 6 atm. We also describe a compact hard-shell (CHS) reactor for extending the pressure range to 100 atm. At such very high pressure the decomposition of source vapors occurs in the vapor phase, and is coupled to flow dynamics and transport. Rate constants for homogeneous gas phase reactions can be predicted based on a combination of first principles and semi-empirical calculations. The pressure dependence of unimolecular rate constants is described by RRKM theory, but requires variational and anharmonicity corrections not included in presently available calculations with the exception of ammonia decomposition. Commercial codes that include chemical reactions and transport exist, but do not adequately cover at present the kinetics of heteroepitaxial crystal growth.

Bachmann, K. J.↗

NASA NTRS2020

The Hubble Space Telescope's Near-UV and Optical Transmission Spectrum of Earth as an Exoplanet

We observed the 2019 January total lunar eclipse with the Hubble Space Telescope’s STIS spectrograph to obtain the first near-UV (1700–3200 Å) observation of Earth as a transiting exoplanet. The observatories and instruments that will be able to perform transmission spectroscopy of exo-Earths are beginning to be planned, and characterizing the transmission spectrum of Earth is vital to ensuring that key spectral features (e.g., ozone, or O3) are appropriately captured in mission concept studies. O3 is photochemically produced from O2, a product of the dominant metabolism on Earth today, and it will be sought in future observations as critical evidence for life on exoplanets. Ground-based observations of lunar eclipses have provided the Earth’s transmission spectrum at optical and near-IR wavelengths, but the strongest O3 signatures are in the near-UV. We describe the observations and methods used to extract a transmission spectrum from Hubble lunar eclipse spectra, and identify spectral features of O3 and Rayleigh scattering in the 3000–5500 Å region in Earth’s transmission spectrum by comparing to Earth models that include refraction effects in the terrestrial atmosphere during a lunar eclipse. Our near-UV spectra are featureless, a consequence of missing the narrow time span during the eclipse when near-UV sunlight is not completely attenuated through Earth’s atmosphere due to extremely strong O3 absorption and when sunlight is transmitted to the lunar surface at altitudes where it passes through the O3 layer rather than above it.

Allison Youngblood↗

NASA NTRS1997

Electrodeposited CuInSe2 Thin Film Junctions

We have investigated thin films and junctions based on copper indium diselenide (CIS) which have been grown by electrochemical deposition. CIS is a leading candidate for use in polycrystalline thin film photovoltaic solar cells. Electrodeposition is a cost-effective method for producing thin-film CIS. We have produced both p and n type CIS thin films from the same aqueous solution by simply varying the deposition potential. A CIS pn junction was deposited using a step-function potential. Stoichiometry of the single layer films was determined by energy dispersive spectroscopy. Carrier densities of these films increased with deviation from stoichiometry, as determined by the capacitance versus voltage dependence of Schottky contacts. Optical bandgaps for the single layer films as determined by transmission spectroscopy were also found to increase with deviation from stoichiometry. Rectifying current versus voltage characteristics were demonstrated for the Schottky barriers and for the pn junction.

Raffaelle, R. P.↗

NASA NTRS1998

Electrodeposited CulnSe2 Thin Film Junctions

Raffaelle, R. P.↗

NASA NTRSDate not supplied

The LHS 1678 System: Two Small Planets and a Likely Brown Dwarf Orbiting a Nearby M Dwarf in Unconventional Circumstances

We present the LHS 1678 (TOI-696) exoplanet system: two nearly Earth-sized transiting planets detected by TESS and a likely brown dwarf orbiting a bright M2 dwarf at 19.9 pc. The ultra-short-period LHS 1678 b (0.70 Earth radii, 0.9-day orbit) is a captivating target for emission spectroscopy observations with the JWST. LHS 1678 c (0.98 Earth radii, 3.7- day orbit) is in the Venus-zone and may be Venus density: a promising target for greenhouse effect studies. Both planets are favorable targets for EPRV mass measurements and for JWST transmission spectroscopy observations to study their atmospheres. The substellar companion, detected via CTIO/SMARTS 0.9m astrometry, is on a decades-long orbit and may someday eclipse the host star, revealing a rare system architecture in which more and less massive objects orbit in the same plane. There is also a candidate third planet detected in TESS multi-cycle data in near 4:3 resonance with LHS 1678 c. The host star is associated with an observed gap in the HR diagram tied to a change in M dwarf energy transport mechanisms. The effect of the associated stellar astrophysics on exoplanet evolution is currently unknown. In aggregate, LHS 1678 an exciting playground for comparative exoplanet science and understanding the formation and evolution of small, short-period exoplanets orbiting low-mass stars.

Michele L Silverstein↗

NASA NTRS2020

HD 191939: Three Sub-Neptunes Transiting a Sun-like Star Only 54 pc Away

We present the discovery of three sub-Neptune-sized planets transiting the nearby and bright Sun-like star HD 191939 (TIC 269701147, TOI 1339), a Ks = 7.18 mag G8 V dwarf at a distance of only 54 pc. We validate the planetary nature of the transit signals by combining 5 months of data from the Transiting Exoplanet Survey Satellite with follow-up ground-based photometry, archival optical images, radial velocities, and high angular resolution observations. The three sub-Neptunes have similar radii (R(b)=3.42(+0.11,-0.11), R(c)=3.23(+0.11,-0.11), and R(d)=3.16(+0.11,-0.11 Rꚛ), and their orbits are consistent with a stable, circular, and coplanar architecture near mean-motion resonances of 1:3 and 3:4 (P(b) = 8.88, P(c) = 28.58, and P(d) = 38.35 days). The HD 191939 system is an excellent candidate for precise mass determinations of the planets with high-resolution spectroscopy due to the host star's brightness and low chromospheric activity. Moreover, the system's compact and near-resonant nature can provide an independent way to measure planetary masses via transit timing variations while also enabling dynamical and evolutionary studies. Finally, as a promising target for multiwavelength transmission spectroscopy of all three planets' atmospheres, HD 191939 can offer valuable insight into multiple sub-Neptunes born from a protoplanetary disk that may have resembled that of the early Sun.

Mariona Badenas-Agusti↗

NASA NTRS2011

Using FT-IR Spectroscopy to Elucidate the Structures of Ablative Polymers

The composition and structure of an ablative polymer has a multifaceted influence on its thermal, mechanical and ablative properties. Understanding the molecular level information is critical to the optimization of material performance because it helps to establish correlations with the macroscopic properties of the material, the so-called structure-property relationship. Moreover, accurate information of molecular structures is also essential to predict the thermal decomposition pathways as well as to identify decomposition species that are fundamentally important to modeling work. In this presentation, I will describe the use of infrared transmission spectroscopy (FT-IR) as a convenient tool to aid the discovery and development of thermal protection system materials.

Fan, Wendy↗

NASA NTRS2023

STXM-C-XANES, IR Microspectroscopy, and Raman Microspectroscopy Analysis of Organic Matter in the Chwichiya 002 C3.00-Ungrouped Chondrite

Chwichiya 002 is a C3.00-ungrouped carbonaceous chondrite discovered in Western Sahara in 2018. The presence of hydrated phases in Chwichiya 002 was not confirmed by XRD analysis, and only a faint water and Si-O band attributed to phyllosilicate were observed by infrared transmission spectroscopy, indicating a very low degree of aqueous alteration (Meteoritical Bulletin, 2020). The structural order of polycyclic aromatic hydrocarbons evaluated by Raman spectroscopy indicates that the effect of thermal metamorphism is less severe than in the Semarkona meteorite, an LL3.00 ordinary chondrite (Meteoritical Bulletin, 2020). Chiwichiya 002 is a very primitive carbonaceous chondrite and an important information source for the early stage of the evolution of organic matter in the solar system. In this study, we investigated the molecular structure and distribution of organic matter in Chiwichiya 002 by Carbon X-ray Absorption Near Edge Structure (C-XANES) analysis using a Scanning Transmission X-ray Microscope (STXM). The STXM-C-XANES analysis has a spatial resolution of 20~100 nm and can observe the spatial distribution of organic materials in microstructures. In addition, to investigate the degree of thermal metamorphism of the organic matter, micro-IR, and micro-Raman spectroscopic analyses were performed. In addition, the Murchison CM2 chondrite was also analyzed for comparison. To evaluate contamination during analytical procedures, antigorite, which was heated in air at 500°C for 5 hours to eliminate organic matter was also analyzed in the same manner. The samples were milled into 100 nm-thick, thin sections using a Focused Ion Beam (FIB), and C-XANES spectra were obtained using the STXM at the High Energy Accelerator Research Organization, Photon Factory (PF), BL-19B. The obtained C-XANES spectra were smoothed and then fitted with Gaussian functions using the method of Le Guillou et al. (2018). The C-XANES showed that the ratio of oxygenated functional group (ketone, phenolic) carbons in Chwichiya 002 was lower than in Murchison, whereas the ratio of aliphatic carbons was almost the same. This may reflect the low degree of aqueous alteration of Chwichiya 002. In addition, contamination peaks were detected at 287.3-287.7 eV and 288.3-288.7 eV in the C-XANES spectra of some of the antigorite samples. The source of these peaks is under investigation. Raman spectroscopic analysis showed that the intensity ratio of the D band to the G band of Chwichiya 002 was slightly higher than that of Murchison. IR absorption spectra showed aromatic absorption at 1630 cm -1 , but there was little absorption due to aliphatic C-H around 2900 cm -1 . These results suggest that the organic matter in Chwichiya 002 may be more heated than in Murchison.

Chwichiya 002↗

NASA NTRS2019

Stellar Activity Effects on Moist Habitable Terrestrial Atmospheres Around M Dwarfs

Transit spectroscopy of terrestrial planets around nearby M dwarfs will be a primary goal of space missions in coming decades. Three-dimensional climate modeling has shown that slow-synchronous rotating terrestrial planets may develop thick clouds at the substellar point, increasing the albedo. For M dwarfs with T(eff)>3000 K, such planets at the inner habitable zone (IHZ) have been shown to retain moist greenhouse conditions, with enhanced stratospheric water vapor ( fH2O>10(exp −3)) and low Earth-like surface temperatures. However, M dwarfs also possess strong UV activity, which may effectively photolyze stratospheric H2O. Prior modeling efforts have not included the impact of high stellar UV activity on the H2O. Here, we employ a 1D photochemical model with varied stellar UV, to assess whether H2O destruction driven by high stellar UV would affect its detectability in transmission spectroscopy. Temperature and water vapor profiles are taken from published 3D climate model simulations for an IHZ Earth-sized planet around a 3300 K M dwarf with an N2–H2O atmosphere; they serve as self-consistent input profiles for the 1D model. We explore additional chemical complexity within the 1D model by introducing other species into the atmosphere. We find that as long as the atmosphere is well-mixed up to 1 mbar, UV activity appears to not impact detectability of H2O in the transmission spectrum. The strongest H2O features occur in the James Webb Space Telescope MIRI instrument wavelength range and are comparable to the estimated systematic noise floor of ∼50 ppm.

Badhan, Mahmuda Afrin↗

NASA NTRS2019

Stellar Activity Effects on Moist Habitable Terrestrial Atmospheres Around M Dwarfs

Transit spectroscopy of terrestrial planets around nearby M dwarfs is a primary goal of space missions in coming decades. 3-D climate modeling has shown that slow-synchronous rotating terrestrial planets may develop thick clouds at the substellar point, increasing the albedo. For M dwarfs with T(eff) > 3000 K, such planets at the inner habitable zone (IHZ) have been shown to retain moist greenhouse conditions, with enhanced stratospheric water vapor (fH2O > 10(exp -3)) and low Earth-like surface temperatures. However, M dwarfs also possess strong UV activity, which may effectively photolyze stratospheric H2O. Prior modeling efforts have not included the impact of high stellar UV activity on the H2O. Here, we employ a 1-D photochemical model with varied stellar UV, to assess whether H2O destruction driven by high stellar UV would affect its detectability in transmission spectroscopy. Temperature and water vapor profiles are taken from published 3-D climate model simulations for an IHZ Earth-sized planet around a 3300 K M dwarf with an N2-H2O atmosphere; they serve as self-consistent input profiles for the 1-D model. We explore additional chemical complexity within the 1-D model by introducing other species into the atmosphere. We find that as long as the atmosphere is well-mixed up to 1 mbar, UV activity appears to not impact detectability of H2O in the transmission spectrum. The strongest H2O features occur in the JWST MIRI instrument wavelength range and are comparable to the estimated systematic noise floor of ~50 ppm.

Mahmuda Afrin Badhan↗

NASA NTRS1965

Lattice vibration spectra of GaAsxP1-x single crystals

Photon-phonon interaction in gallium arsenide alloy single crystal studied by infrared reflection and transmission spectroscopy

SINGLE CRYSTAL↗

NASA NTRS1989

Halogen occultation experiment (HALOE) optical witness-plate program

An optical witness plate program was implemented to monitor buildup of molecular contamination in the clean room during the assembly and testing of the Halogen Occulation Experiment (HALOE) instrument. Travel plates to monitor molecular contamination when the instrument is not in the clean room are also measured. The instrument technique is high-resolution transmission spectroscopy in the 3 micron spectral region using a Fourier transform spectrometer. Witness specimens of low index of refraction, infrared transmitting material are used for contaminant monitoring and for spectral signature analysis. Spectral signatures of possible molecular contamination are presented. No condensible volatile material contamination of HALOE optical witness specimens have yet been found.

Harvey, Gale A.↗

NASA NTRS2002

Foam Optics and Mechanics

The Foam Optics and Mechanics (FOAM) project will exploit the microgravity environment to more accurately measure the rheological and optical characteristics of wet aqueous foams. Using both rheology and laser light scattering diagnostics, the goal is to quantify the unusual elastic character of foams in terms of their underlying microscopic structure and dynamics. Of particular interest is determining how the elastic character vanishes, i.e., how the foam 'melts' into a simple viscous liquid, as a function of both increasing liquid content and increasing shear strain rate. The unusual elastic character of foams will be quantified macroscopically by measurement of the shear stress as a function of shear strain rate and of time following a step strain. Such data will be analyzed in terms of a yield stress, shear moduli, and dynamical time scales. Microscopic information about bubble packing and rearrangement dynamics, from which the macroscopic non-Newtonian properties ultimately arise, will be obtained non-invasively by multiple-light scattering: diffuse transmission spectroscopy (DTS) and diffusing wave spectroscopy (DWS). Quantitative trends with materials parameters, most importantly average bubble size and liquid content, will be sought in order to elucidate the fundamental connection between the microscopic structure and dynamics and the macroscopic rheology.

Durian, Douglas J.↗

NASA NTRS2004

Scanning Tunneling Optical Resonance Microscopy Developed

The ability to determine the in situ optoelectronic properties of semiconductor materials has become especially important as the size of device architectures has decreased and the development of complex microsystems has increased. Scanning Tunneling Optical Resonance Microscopy, or STORM, can interrogate the optical bandgap as a function of its position within a semiconductor micro-structure. This technique uses a tunable solidstate titanium-sapphire laser whose output is "chopped" using a spatial light modulator and is coupled by a fiber-optic connector to a scanning tunneling microscope in order to illuminate the tip-sample junction. The photoenhanced portion of the tunneling current is spectroscopically measured using a lock-in technique. The capabilities of this technique were verified using semiconductor microstructure calibration standards that were grown by organometallic vapor-phase epitaxy. Bandgaps characterized by STORM measurements were found to be in good agreement with the bulk values determined by transmission spectroscopy and photoluminescence and with the theoretical values that were based on x-ray diffraction results.

Bailey, Sheila G.↗

NASA NTRS2005

Chemically Deposited Thin-Film Solar Cell Materials

We have been working on the development of thin film photovoltaic solar cell materials that can be produced entirely by wet chemical methods on low-cost flexible substrates. P-type copper indium diselenide (CIS) absorber layers have been deposited via electrochemical deposition. Similar techniques have also allowed us to incorporate both Ga and S into the CIS structure, in order to increase its optical bandgap. The ability to deposit similar absorber layers with a variety of bandgaps is essential to our efforts to develop a multi-junction thin-film solar cell. Chemical bath deposition methods were used to deposit a cadmium sulfide (CdS) buffer layers on our CIS-based absorber layers. Window contacts were made to these CdS/CIS junctions by the electrodeposition of zinc oxide (ZnO). Structural and elemental determinations of the individual ZnO, CdS and CIS-based films via transmission spectroscopy, x-ray diffraction, x-ray photoelectron spectroscopy and energy dispersive spectroscopy will be presented. The electrical characterization of the resulting devices will be discussed.

Raffaelle, R.↗