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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Laboratory measurements of the microwave opacity and vapor pressure of sulfuric acid vapor under simulated conditions for the middle atmosphere of Venus

Microwave absorption measurements at wavelengths of 13.4 and 3.6 cm were made in gaseous H2SO4 in a CO2 atmosphere under simulated conditions for the Venus middle atmosphere. The results suggest that abundances of gaseous H2SO4 on the order of 15-30 ppm could account for the absorption observed by radio occultation measurements at these wavelengths. They also imply that such abundances would correspond to saturation vapor pressure existing at or above the 46-48-km range, which correlates with the observed cloud base.

Steffes, P. G.↗
NASA NTRS1959

Propellant Vaporization as a Criterion for Rocket-Engine Design; Experimental Performance, Vaporization and Heat-Transfer Rates with Various Propellant Combinations

Experimental combustion efficiencies of eleven propellant combinations were determined as a function of chamber length. Efficiencies were measured in terms of characteristic exhaust velocities at three chamber lengths and in terms of gas velocities. The data were obtained in a nominal 200-pound-thrust rocket engine. Injector and engine configurations were kept essentially the same to allow comparison of the performance. The data, except for those on hydrazine and ammonia-fluorine, agreed with predicted results based on the assumption that vaporization of the propellants determines the rate of combustion. Decomposition in the liquid phase may be.responsible for the anomalous behavior of hydrazine. Over-all heat-transfer rates were also measured for each combination. These rates were close to the values predicted by standard heat-transfer calculations except for the combinations using ammonia.

Clark, Bruce J.↗
NASA NTRS1992

Diffusion mechanisms in chemical vapor-deposited iridium coated on chemical vapor-deposited rhenium

Radiation-cooled rocket thruster chambers have been developed which use CVD Re coated with CVD Ir on the interior surface that is exposed to hot combustion gases. The Ir serves as an oxidation barrier which protects the structural integrity-maintaining Re at elevated temperatures. The diffusion kinetics of CVD materials at elevated temperatures is presently studied with a view to the prediction and extension of these thrusters' performance limits. Line scans for Ir and Re were fit on the basis of a diffusion model, in order to extract relevant diffusion constants; the fastest diffusion process is grain-boundary diffusion, where Re diffuses down grain boundaries in the Ir overlayer.

Hamilton, J. C.↗
NASA NTRS2013

In-Situ Water Vapor Probe for a Robot Arm-Mounted, Compact Water Vapor Analyzer: Preliminary Results

This work describes the ongoing development of an instrument package for the in-situ detection and isotopic analysis of water (from ice, icy soils, and hydrated minerals) on future lunar, asteroid, or martian exploration missions. This instrument is intended to be mounted on a robotic arm and be brought to the sample, rather than necessitating expensive and complicated sample handling to bring the sample to the instrument.

Socki, Richard A.↗
NASA NTRS1997

A High Temperature Vapor Phase Lubrication Study Utilizing a Thioether Liquid Lubricant

Much of the experimental work on vapor phase lubrication has employed certain organo phosphorous compounds as the vapor phase lubricant. Graham and Klaus, for instance, used tricresyl phosphate (TCP) and tributyl phosphate to vapor phase lubricate a four-ball wear tester using M50 steel balls at 370 C. Makki and Graham were able to vapor phase lubricate a reciprocating pin on plate tribometer using 1018 steel at 280 C with TCP vapor. Although a few organo phosphorous compounds, such as TCP, have been successfully used as vapor phase lubricants in many laboratory experiments, many problems remain unsolved. Two areas of concern relate to the 'durability' of phosphate deposited films and to the ability of the lubricating system to "self-recover" when vapor phase lubricated with an organo phosphorous compound. Durability refers to the ability of the deposited film to provide effective lubrication, for a period of time, after the vapor flow to the lubricating surfaces has been interrupted. Vapor phase lubrication tests, conducted at Cleveland State University with their high temperature tribometer, revealed that when TCP vapor flow to the lubricating surfaces was interrupted the frictional coefficient of the system rapidly increased from a value less than 0.1 to a value of 0.3 which was selected as our failure point. Self-recovery means the ability of the vapor phase lubricant to reduce the frictional coefficient of the lubricating system back down to value less than 0.1 after startup of the interrupted vapor flow. Lubrication tests conducted at Cleveland State University revealed that the high temperature tribometer could not self-recover after startup of the interrupted TCP vapor flow.

Morales, Wilfredo↗
NASA NTRS1980

Method and apparatus for vapor detection

The method disclosed herein may be practiced by passing the vapors to be sampled along a path with halogen vapor, preferably chlorine vapor, heating the mixed vapors to halogenate those of the sampled vapors subject to halogenation, removing unreacted halogen vapor, and then sensing the vapors for organic halogenated compounds. The apparatus disclosed herein comprises means for flowing the vapors, both sample and halogen vapors, into a common path, means for heating the mixed vapors to effect the halogenation reaction, means for removing unreacted halogen vapor, and a sensing device for sensing halogenated compounds. By such a method and means, the vapors of low molecular weight hydrocarbons, ketones and alcohols, when present, such as methane, ethane, acetone, ethanol, and the like are converted, at least in part, to halogenated compounds, then the excess halogen removed or trapped, and the resultant vapors of the halogenated compounds sensed or detected. The system is highly sensitive. For example, acetone in a concentration of 30 parts per billion (volume) is readily detected.

Lerner, Melvin↗
NASA NTRS1998

Upper tropospheric water vapor: A field campaign of two Raman lidars, Airborne hygrometers, and Radiosondes

Water vapor in the atmosphere plays an important role in radiative transfer and the process of radiative balance so critical for understanding global change. It is the principal ingredient in cloud formation, one of the most difficult atmospheric processes to model, and the most variable component of the Earth-atmosphere albedo. And as a free molecule, it is the most active infrared absorber and emitter, thus, the most important greenhouse gas. The radiative impact of water vapor is important at all levels of the atmosphere. Even though moisture decreases by several orders-of-magnitude from the Earth's surface to the tropopause, recent research has shown that, from a radiative standpoint, a small percentage change in water vapor at any level is nearly equivalent. Therefore accurate and precise measurements of this important atmospheric constituent are needed at all levels to evaluate the full radiative impact. The need for improved measurements in the upper troposphere is particularly important because of the generally hostile (very dry and cold) conditions encountered. Because of the importance of water vapor to the understanding of radiative transfer, the Department of Energy's Atmospheric Radiation Measurements (ARM) program initiated a series of measurement campaigns at the Cloud And Radiation Testbed (CART) site in Oklahoma, especially focused on atmospheric water vapor. Three water vapor intensive observation period (water vapor IOP) campaigns were planned. Two of the water vapor IOP campaigns have been completed: the first IOP was held during the fall of 1996 with a focus on boundary layer water vapor measurements, and the second was conducted during the fall of 1997 with a focus on both boundary layer moisture e and moisture in the upper troposphere. This paper presents a review of the intercomparisons of water vapor measurements in the upper troposphere aquired during the second water vapor IOP. Data to be presented include water vapor measurements ements from: two Raman Lidars, the NASA Goddard Scanning Raman Lidar (SRL) and the CART Raman Lidar (CARL), a number of Vaisala radiosondes launched during the IOP campaign, and a dew point hygrometer flown on the University of North Dakota Cessna Citation Aircraft.

Melfi, S. Harvey↗
NASA NTRS1993

Possible near-IR channels for remote sensing precipitable water vapor from geostationary satellite platforms

Remote sensing of troposheric water vapor profiles from current geostationary weather satellites is made using a few broadband infrared (IR) channels in the 6-13 micron region. Uncertainties greater than 20% exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micron water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micron. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor. The ratio of the radiance from the absorption channel with the radiances from the two window channels removes the surface reflectance effects and yields approximately the mean atmospheric water vapor transmittance of the absorption channel. The integrated water vapor amount from ground to space can be obtained with a precision of better than 5% from the mean transmittance. Because surface reflectances vary slowly with time, temporal variation of precipitable water vapor can be determined reliably. High spatial resolution, precipitable water vapor images are derived from spectral data collected by the Airborne Visable-Infrared Imaging Spectrometer, which measures solar radiation reflected by the surface in the 0.4-2.5 micron region in 10-nm channels and has a ground instantaneous field of view of 20 m from its platform on an ER-2 aircraft at 20 km. The proposed near-IR reflectance technique would complement the IR emission techniques for remote sensing of water vapor profiles from geostationary satellite platforms, especially in the boundary layer where most of the water vapor is located.

Gao, B.-C.↗
NASA NTRS1995

Imaging spectrometer measurement of water vapor in the 400 to 2500 nm spectral region

The Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) measures the total upwelling spectral radiance from 400 to 2500 nm sampled at 10 nm intervals. The instrument acquires spectral data at an altitude of 20 km above sea level, as images of 11 by up to 100 km at 17x17 meter spatial sampling. We have developed a nonlinear spectral fitting algorithm coupled with a radiative transfer code to derive the total path water vapor from the spectrum, measured for each spatial element in an AVIRIS image. The algorithm compensates for variation in the surface spectral reflectance and atmospheric aerosols. It uses water vapor absorption bands centered at 940 nm, 1040 nm, and 1380 nm. We analyze data sets with water vapor abundances ranging from 1 to 40 perceptible millimeters. In one data set, the total path water vapor varies from 7 to 21 mm over a distance of less than 10 km. We have analyzed a time series of five images acquired at 12 minute intervals; these show spatially heterogeneous changes of advocated water vapor of 25 percent over 1 hour. The algorithm determines water vapor for images with a range of ground covers, including bare rock and soil, sparse to dense vegetation, snow and ice, open water, and clouds. The precision of the water vapor determination approaches one percent. However, the precision is sensitive to the absolute abundance and the absorption strength of the atmospheric water vapor band analyzed. We have evaluated the accuracy of the algorithm by comparing several surface-based determinations of water vapor at the time of the AVIRIS data acquisition. The agreement between the AVIRIS measured water vapor and the in situ surface radiometer and surface interferometer measured water vapor is 5 to 10 percent.

Green, Robert O.↗
NASA NTRS1998

A Satellite-Derived Upper-Tropospheric Water Vapor Transport Index for Climate Studies

A new approach is presented to quantify upper-level moisture transport from geostationary satellite data. Daily time sequences of GOES-7 water vapor imagery were used to produce estimates of winds and water vapor mixing ratio in the upper-troposphere sensed by the 6.7-microns water vapor channel. The winds and mixing ratio values were gridded and then combined to produce a parameter called the Water Vapor Transport Index (WVTI) which represents the magnitude of the two dimensional transport of water vapor in the upper troposphere. Daily grids of WVTI, meridional moisture transport, mixing ratio, pressure and other associated parameters were averaged to produce monthly fields for June, July and August of 1987 and 1988 over the Americas and surrounding oceanic regions. The WVTI was used to compare upper-tropospheric moisture transport between the summers of 1987 and 1988, contrasting the latter part of the 1986/87 El Nino event and the La Nina period of 1988. A similar product derived from the NCEP reanalysis was used to help validate the index and understand interannual variability of moisture transport from the modeling perspective. Both datasets showed large upper-level water vapor transport associated with synoptic features over the Americas and with outflow from tropical convective systems. Minimal transport occurred over tropical and subtropical high pressure regions where winds were light. Index values from NCEP were 2-3 times larger than that determined from the GOES satellite This difference resulted from an over estimate of the zonal winds and upper-tropospheric moisture in the reanalysis model. A comparison of the satellite-derived monthly values between the summers of 1987 and 1988 provided some insight into the impact of the ENSO event on upper-level moisture and its transport during the period. During July 1987, a large portion of the tropics in the eastern Pacific Ocean and Caribbean Sea was dominated by strong vapor transport in excess of 5 g/kg/ms with relatively small amounts in the other months. In contrast, JJA 1988 showed an opposite trend with July 1988 being less dominated by tropical water vapor transport. The meridional transport of upper-level water vapor indicated significant poleward transport from the tropics to the higher latitudes. This transport favored the Southern Hemisphere with large transport occurring south of the ITCZ which extended across the eastern Pacific and northern South America. Zonally-averaged monthly transport values were shown to provide a simple way to quantify the monthly and interannual changes in water vapor transport. Zonally-averaged WVTI values peaked in the Southern Hemisphere subtropics during both Austral winters. In the tropics a single more pronounced peak located over the equator and south latitudes occurred in 1988 as opposed to a dual peak in 1987. The second peak around 20 deg.N latitude is consistent with findings of others where upper-tropospheric winds were noted to be stronger in this region during warm ENSO events. Zonally-averaged meridional transport was southward for all summer months and stronger in 1988. The asymmetric nature of the zonally-averaged meridional transport (more southerly water vapor transport) was enhanced during JJA 1998 thus indicating a stronger upper-level branch of the Hadley circulation during this notable strong La Nina period.

Jedlovec, Gary J.↗
NASA NTRS1998

A Satellite-Derived Upper-Tropospheric Water Vapor Transport Index for Climate Studies

A new approach is presented to quantify upper-level moisture transport from geostationary satellite data. Daily time sequences of Geostationary Operational Environmental Satellite GOES-7 water vapor imagery were used to produce estimates of winds and water vapor mixing ratio in the cloud-free region of the upper troposphere sensed by the 6.7- microns water vapor channel. The winds and mixing ratio values were gridded and then combined to produce a parameter called the water vapor transport index (WVTI), which represents the magnitude of the two-dimensional transport of water vapor in the upper troposphere. Daily grids of WVTI, meridional moisture transport, mixing ratio, pressure, and other associated parameters were averaged to produce monthly fields for June, July, and August (JJA) of 1987 and 1988 over the Americas and surrounding oceanic regions, The WVTI was used to compare upper-tropospheric moisture transport between the summers of 1987 and 1988, contrasting the latter part of the 1986/87 El Nino event and the La Nina period of 1988. A similar product derived from the National Centers for Environmental Prediction (NCEP)-National Center for Atmospheric Research (NCAR) 40-Year Reanalysis Project was used to help to validate the index. Although the goal of this research was to describe the formulation and utility of the WVTI, considerable insight was obtained into the interannual variability of upper-level water vapor transport. Both datasets showed large upper-level water vapor transport associated with synoptic features over the Americas and with outflow from tropical convective systems. Minimal transport occurred over tropical and subtropical high pressure regions where winds were light. Index values from NCEP-NCAR were 2-3 times larger than that determined from GOES. This difference resulted from large zonal wind differences and an apparent overestimate of upper-tropospheric moisture in the reanalysis model. A comparison of the satellite-derived monthly values between the summers of 1987 and 1988 provided some insight into the impact of the ENSO event on upper-level moisture and its transport during the period. During July 1987, a large portion of the Tropics in the eastern Pacific Ocean and Caribbean Sea was dominated by strong vapor transport in excess of 4.0 g/kg m/s, with relatively small amounts in the other months. JJA 1988 transport values reached similar magnitude and showed similar patterns for all three months. The meridional transport of upper-level water vapor indicated large poleward transport from the Tropics to the higher latitudes. This transport favored the Southern Hemisphere, with large transport occurring south of the ITCZ, which extended across the eastern Pacific and northern South America. Zonally averaged monthly transport values were shown to provide a simple way to quantify the monthly and interannual changes in water vapor transport. Zonally averaged WVTI values peaked in the Southern Hemisphere subtropics during both austral winters. In the Tropics, a single, more- pronounced peak located over the equator and south latitudes occurred in 1988 as opposed to a dual peak in 1987. The second peak around 20'N latitude is consistent with findings of others in which upper-tropospheric winds were noted to be stronger in this region during warm ENSO events. Zonally averaged meridional transport was southward for all summer months and was stronger in 1988. The asymmetric nature of the zonally averaged meridional transport (more southerly water vapor transport) was enhanced during JJA 1988, thus indicating a stronger upper- level branch of the Hadley circulation during this notably strong La Nina period.

Jedlovec, Gray J.↗
NASA NTRS2007

Electrification in Hurricanes over the Tropical Americas: Implication for Stratospheric Water Vapor

This study explores the relation between lightning activity and water vapor in the Tropical Tropopause Layer (TTL) over hurricane systems in the Tropical Americas. The hypothesis herein is that hurricanes that exhibit enhanced lightning activity are associated with stronger updrafts that can transport more moisture directly into the TTL (and subsequently into the tropical stratosphere) or even directly into the tropical stratosphere over this region. The TTL over the Tropical Americas, which includes the Caribbean and Gulf of Mexico, is of particular interest, because summertime cold point tropopause is the lowest in height and thus the warmest in temperature over the tropics. The latter condition implies higher saturation values and thus potential for more water vapor to enter the stratosphere. Climate forecast is very sensitive to stratospheric water vapor abundance, because of the key role that water vapor plays in regulating the chemical and radiative properties of the stratosphere. Given the potential for increases in hurricane intensity and frequency under predicted warmer conditions, it becomes essential to understand the effect of hurricanes on stratospheric water vapor. In this study, we use a combination of ground and space-borne observations as well as trajectory calculations. The observations include: cloud-to-ground (CG) lightning data from the U.S. National Lightning Detection Network (NLDN), geostationary infrared observations from the National Climatic Data Center Hurricane Satellite (HURSAT) data set, cloud properties from Aqua-MODIS, and water vapor from Aura-MLS. We analyze hurricanes from the 2005 season when Aura-MLS data are available, namely: Dennis, Emily, Katrina, Rita, and Wilma. Our analysis consists of examining CG lightning, cloud-top properties, and TTL water vapor (i.e., 100 and 147 mb) over the hurricane while it remains over water in the Tropical Americas region. We investigate daily as well as diurnal statistical properties. The hurricanes analyzed in this study showed that lightning activity is negatively correlated with minimum infrared brightness temperature and positively correlated with 100-mb water vapor. An examination of the maxima in water vapor observed over the hurricane not only shows larger magnitudes, but also larger differences between water vapor averages and water vapor maxima over the hurricane as lightning activity increases. Trajectory calculations are performed using the Flextra model in order to investigate the fate of the moister air masses found in the TTL.

Pittman, Jasna V.↗