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DOE OSTI2023

Reduced viscosity steadily weakens oceanic currents

The viscosity of both air and water is temperature dependent. A rising temperature leads to an increased viscosity for air but a decreased viscosity for water. As climate becomes warmer, this increased air viscosity can partly inhibit the reduction of wind stress over the ocean, and the reduced water viscosity causes less downward momentum and heat transport. As these opposing effects of warming on air and water viscosity are not included in the state-of-the-art climate models, the understanding of their potential impacts on the response of the climate system to the anthropogenic warming is lacking. Here, via analyzing the Simple Ocean Data Assimilation oceanic reanalysis dataset, we show that the ocean heat content increases at a rate of ~1.3 × 10 22 J/yr over 35 years, which leads to a continuous reduction of oceanic viscosity. As a result, the ocean vertical shear enhances with a shoaling of the mixed layer depth and a reduced vertical linkage in the ocean. Our calculations show a reduction of the oceanic kinetic energy at a rate of ~2.4 × 10 16 J/yr. Potentially, this could generate far-reaching impacts on the energy storage of the climate system and, hence, could pace the global warming. Thus, it is important to include the temperature-dependent viscosity in our climate models. Freshwater discharged from polar ice sheets and mountain glaciers also contributes to the reduction in oceanic viscosity but, at present, to a lesser extent than that in oceanic warming. Reduced oceanic viscosity, therefore, is an important, but hitherto overlooked, response to a warming climate and contributes to many recent weather extremes including heavier rainfall rates in hurricanes, slackening of the polar vortex, and oceanic heat waves.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

A Review of Offshore Methane Quantification Methodologies

Since pre-industrial times, anthropogenic methane emissions have increased and are partly responsible for a changing global climate. Natural gas and oil extraction activities are one significant source of anthropogenic methane. While methods have been developed and refined to quantify onshore methane emissions, the ability of methods to directly quantify emissions from offshore production facilities remains largely unknown. Here, we review recent studies that have directly measured emissions from offshore production facilities and critically evaluate the suitability of these measurement strategies for emission quantification in a marine environment. The average methane emissions from production platforms measured using downwind dispersion methods were 32 kg h−1 from 188 platforms; 118 kg h−1 from 104 platforms using mass balance methods; 284 kg h−1 from 151 platforms using aircraft remote sensing; and 19,088 kg h−1 from 10 platforms using satellite remote sensing. Upon review of the methods, we suggest the unusually large emissions, or zero emissions observed could be caused by the effects of a decoupling of the marine boundary layer (MBL). Decoupling can happen when the MBL becomes too deep or when there is cloud cover and results in a stratified MBL with air layers of different depths moving at different speeds. Decoupling could cause: some aircraft remote sensing observations to be biased high (lower wind speed at the height of the plume); the mass balance measurements to be biased high (narrow plume being extrapolated too far vertically) or low (transects miss the plume); and the downwind dispersion measurements much lower than the other methods or zero (plume lofting in a decoupled section of the boundary layer). To date, there has been little research on the marine boundary layer, and guidance on when decoupling happens is not currently available. We suggest an offshore controlled release program could provide a better understanding of these results by explaining how and when stratification happens in the MBL and how this affects quantification methodologies.

Riddick, Stuart N. (ORCID:0000000316841843)↗

DOE OSTI2021

Electrically Pumped Epitaxially Regrown GaSb-Based Type-I Quantum-Well Surface-Emitting Lasers with Buried High-Index-Contrast Photonic Crystal Layer

Epitaxially regrown electrically pumped photonic crystal surface-emitting lasers (PCSELs) emitting near 2 and 2.6 μm are designed, fabricated, and characterized. A high-index-contrast photonic crystal layer is incorporated into the GaSb-based laser heterostructure by air-hole-retaining epitaxial regrowth. A square lattice of triangular holes is etched in the top waveguide core layer of the incomplete laser heterostructure. The nanopatterned surface is subsequently cleaned and regrown with AlGaAsSb p-cladding material. Transmission electron microscopy studies demonstrate uniform regrowth over the nanopatterned GaSb surface. The selected regrowth regimes yield a buried 2D array of elongated air-holes. The diode PCSELs based on moderately etched nanopatterns demonstrate band-edge lasing near 2 μm up to room temperatures. The cascade diode PCSELs operate near 2.6 μm with minimum threshold current densities of about 500 A cm -2 achieved at 180 K. The devices generate mW level output in narrow divergence beam emitted from the window in substrate contact. The angle-resolved electroluminescence measurements reveal a four-sub-band band structure with an apparent photonic bandgap corresponding to the buried high-index-contrast square photonic crystal layer. Finally, the PCSELs made of heterostructures supporting two modes in the vertical direction demonstrate two sets of sub-bands showing anti-crossing-like interaction.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

DOE OSTI2020

The Importance of Convective Stage on Out-of-Cloud Convectively Induced Turbulence from High-Resolution Simulations

Turbulence (clear-air, mountain wave, convectively induced) is an aviation hazard that is a challenge to forecast due to the coarse resolution ultilized in operational weather models. Turbulence indices are commonly used to aid pilots in avoiding turbulence, but these indices have been designed and calibrated for midlatitude clear-air turbulence prediction (e.g., the Ellrod index). A significant limitation with current convectively induced turbulence (CIT) prediction is the lack of storm stage dependency. In this study, six high-resolution simulations of tropical oceanic and midlatitude continental convection are performed to characterize the turbulent environment near various convective types during the developing and mature stages. Second-order structure functions, a diagnostic commonly used to identify turbulence in turbulence prediction systems, are used to characterize the probability of turbulence for various convective types. Turbulence likelihood was found to be independent of region (i.e., tropical vs midlatitude) but dependent on convective stage. The probability of turbulence increased near developing convection for the majority of cases. Additional analysis of static stability and vertical wind shear, indicators of turbulence potential, showed that the convective environment near developing convection was more favorable for turbulence production than mature convection. Near developing convection, static stability decreased and vertical wind shear increased. Vertical wind shear near mature and developing convection was found to be weakly correlated to turbulence intensity in both the tropics and the midlatitudes. Finally, this study emphasizes the need for turbulence avoidance guidelines for the aviation community that are dependent on convective stage.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Information Content of a Synergy of Ground-Based and Space-Based Infrared Sounders. Part I: Clear-Sky Environments

Abstract Profiles of atmospheric temperature and water vapor from remotely sensed platforms provide critical observations within the temporal and spatial gaps of the radiosonde network. The 2017 National Academies of Science Decadal Survey highlighted that observations of the planetary boundary layer (PBL) from the current space-based observing system are not of the necessary accuracy or resolution for monitoring and predicting high-impact weather phenomena. One possible solution to improving observations of the PBL is supplementing the existing space-based observing system with a network of ground-based profilers. A synthetic information content study is developed utilizing profiles from the Atmospheric Radiation Measurement (ARM) program sites at the Southern Great Plains (SGP), east North Atlantic (ENA), and North Slope of Alaska (NSA) to assess the benefits, in terms of degrees of freedom (DOF), vertical resolution, and uncertainties, of a synergy between the ground-based Atmospheric Emitted Radiance Interferometer (AERI) with space-based hyperspectral infrared (IR) sounders. A combination of AERI with any of the three polar-orbiting IR sounders: the Atmospheric Infrared Sounder (AIRS), the Cross-track Infrared Sounder (CrIS), or the Infrared Atmospheric Sounding Interferometer (IASI), results in a DOF increase of 30%–40% in the surface-to-700-hPa layer compared to the space-based instrument alone. Introducing AERI measurements to the observing system also results in significant improvements to vertical resolution and uncertainties in the bottom 1000 m of the atmosphere compared to CrIS measurements alone. A synergy of CrIS and AERI exceeds the 1-km-vertical-resolution goal set by the Decadal Survey in the lowest 1000 m.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Thermal-hydraulic Performance of Emerging Low GWP Refrigerant Mixture under Flow Boiling in Brazed Plate Heat Exchangers

The hydrofluorocarbon (HFC) refrigerants used in the current refrigeration systems are facing a phase-down due to their higher greenhouse effect resulting in global warming, and thus HVAC&R industry has undergone a transition to low Global Warming Potential (GWP) refrigerants. Refrigerant mixtures are attractive alternatives since their composition can be tailored to comply with environmental regulations while preserving favorable thermophysical properties. However, the new low-GWP zeotropic mixture refrigerants have two or more components with different saturation temperatures at the same pressure level, known as temperature glide, which can cause the degradation of the overall heat transfer performance. The brazed plate heat exchangers (BPHX) provide excellent heat transfer performance due to a compact design and are used in several air-conditioning and refrigeration applications. In this study, flow boiling heat transfer and the associated pressure drop of the refrigerant mixture in a vertical BPHX were experimentally investigated. The single-phase water-to-water experiments were conducted in the tested heat exchanger with a counter-flow configuration. The flow boiling experiments charged with R-134a and R-454C were then performed in a pumped refrigerant loop to evaluate its thermal-hydraulic performance. Furthermore, parametric studies of various heat fluxes, mass fluxes, vapor qualities, and saturation temperatures were also conducted.

Yang, Cheng-Min↗

DOE OSTI2021

Supercooled Liquid Water Detection Capabilities from Ka-Band Doppler Profiling Radars: Moment-Based Algorithm Formulation and Assessment

The occurrence of supercooled liquid water in mixed-phase cloud (MPC) affects their cloud microphysical and radiative properties. The prevalence of MPCs in the mid- and high latitudes translates these effects to significant contributions to Earth’s radiative balance and hydrological cycle. The current study develops and assesses a radar-only, moment-based phase partition technique for the demarcation of supercooled liquid water volumes in arctic, MPC conditions. The study utilizes observations from the Ka band profiling radar, the collocated high spectral resolution lidar, and ambient temperature profiles from radio sounding deployments following a statistical analysis of 5.5 years of data (January 2014–May 2019) from the Atmospheric Radiation Measurement observatory at the North Slope of Alaska. The ice/liquid phase partition occurs via a per-pixel, neighborhood-dependent algorithm based on the premise that the partitioning can be deduced by examining the mean values of locally sampled probability distributions of radar-based observables and then compare those against the means of climatologically derived, per-phase probability distributions. Analyzed radar observables include linear depolarization ratio (LDR), spectral width, and vertical gradients of reflectivity factor and radial velocity corrected for vertical air motion. Results highlight that the optimal supercooled liquid water detection skill levels are realized for the radar variable combination of spectral width and reflectivity vertical gradient, suggesting that radar-based polarimetry, in the absence of full LDR spectra, is not as critical as Doppler capabilities. The cloud phase masking technique is proven particularly reliable when applied to cloud tops with an Equitable Threat Score (ETS) of 65%; the detection of embedded supercooled layers remains much more uncertain (ETS = 27%).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Machine Learning Enabled Position Detection for 6.78 MHz UAV Wireless Power Transfer System

This paper presents a novel supervised machine learning (SML) approach for accurate position detection of the receiver coil in wireless power transfer (WPT) systems using only secondary-side electrical measurements, with applications in autonomous unmanned aerial vehicle (UAV) charging. The proposed method trains a supervised learning model to map measured secondary-side voltage and current features to the receiver’s spatial position with high precision. This enables an autonomous UAV to determine its location relative to the primary coil center, the optimal position for maximizing wireless charging efficiency. The sensing method is fully integrated into a standard WPT system, utilizing the same primary and secondary coils for both power transfer and position detection, thereby eliminating additional sensing hardware. The use of a 6.78 MHz operating frequency enhances positional sensitivity, as high-frequency near-field electromagnetic fields respond strongly to small spatial variations. Experimental validation is performed on a 30 W scaled prototype featuring a 210 mm × 140 mm primary coil, a 50 mm × 80 mm receiver coil, and a 15 mm air gap. Results demonstrate reliable position estimation and a strong correlation between predicted position and optimal coil alignment. This integrated framework unifying position detection and wireless charging offers a promising foundation for future autonomous electric vertical takeoff and landing (eVTOL) systems, enabling compact, hardware-efficient, and high-accuracy charging solutions.

Colak, Kerim [New York University]↗

DOE OSTI2020

Mesoscale Modeling to Characterize Eagle Soaring Habitat

Uncovering drivers of risk is crucial to understanding interactions between wildlife and wind turbines, and identifying options for impact minimization. These drivers tie to co-variates linked to behavior and movement patterns that allow us to estimate locations and periods of risk. For volant species, atmospheric flow can have significant influence on flight patterns. For obligate soaring birds, like golden eagles, updraft velocities can inform where eagles are likely to travel, at what altitude, and where conditions are not likely sufficient to sustain soaring flight. This has been an active area of study in recent years, using relatively coarse atmospheric data generally at the 20km x 20km scale or larger. Leveraging a 20-year dataset from the Weather Research and Forecasting Model (WRF) (https://www.mmm.ucar.edu/weather-research-and-forecasting-model), we are quantifying vertical velocities across the continental United States at a 2km x 2km resolution. Wind resource data sets originally were static maps showing the mean annual wind speed over an area. However, for these data sets to be optimally used for various applications they must be high-resolution time series, seamlessly span large geographic contexts, and account for uncertainty in wind speed. The National Renewable Energy Laboratory is producing public available datasets that meet these criteria and will be bias corrected to yield the most accurate wind resource data. This effort is an augment to the current WIND Toolkit which houses a high resolution data set. In the new iteration of the WIND Toolkit, a 20-year dataset will be used to improve the accuracy and estimate uncertainty using ensemble and machine-learning techniques. The resulting product will be the most accurate dataset of its size and at a 2km x 2km spatial and 5-minute temporal resolution. Through this work, a mesoscale vertical velocity layer will be produced by calculating the likelihood of orographic updraft and thermal updraft conditions across the continental United States. Specifically, we will use WRF model output combined with digital elevation maps to predict updrafts and then determine if vertical velocities are sufficient to support Golden Eagle soaring and gliding. Ultimately this data layer will be made available as a GIS layer in the Wind Prospector (maps.nrel.gov/wind-prospector/) tool or a similar framework. Data that will be incorporated include wind speed, direction temperature, relative humidity, barometric pressure, air density, precipitation rate, solar radiation, atmospheric stability, skin temperature, and upward heat flux. These products will advance research on interactions between volant species and wind energy by providing open access to highly resolved data with uncertainty quantification not previously available at this scale.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2020

Drizzle, Turbulence, and Density Currents Below Post Cold Frontal Open Cellular Marine Stratocumulus Clouds

Nine cases of postcold frontal marine stratocumulus clouds exhibiting open cellular mesoscale organization are analyzed to characterize the drizzle, turbulence, and density currents below them. Data collected by the vertically pointing Doppler cloud radar and multiple lidars part of the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic (ENA) site are used in these analyses. A total of 251 drizzle shafts passed over the site with 76 shafts sampled for more than 15 min by the vertically pointing instruments. On average the drizzle shafts were ~18 km wide with below-cloud drizzle water path of ~40 g m −2 , cloud base rain rate of 7.78 mm day −1 , and cloud base drizzle modal diameter of 393 μm. The widths of the drizzle shafts did not exhibit any relationship with the cloud base rain rate, below-cloud drizzle water path, and the total water removed from the cloud. The downdrafts in the lowest 500 m within the drizzle cells strengthened with increasing cloud base rain rates, while the updrafts within drizzle cells did not exhibit this behavior. On average, the surface air density, pressure, water vapor mixing ratio, and wind speed along the background wind during the drizzle shaft were higher by 1.88 g m −3 , 8.60 Pa, 0.24 g kg −1 , and 1.22 m s −1 , respectively, from their background values. On the other hand, the surface air temperature was lower by 0.43 K during the drizzle shaft than its background value. The coincident measurements highlight the drizzle-turbulence-surface coupling in these cloud systems.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2024

An analysis of parameters affecting ampacity in aircraft bipolar MVDC power cables via coupled electrical, thermal, and computational fluid dynamic modelling

Abstract The next generation of aircraft, including more electric aircraft and all‐electric aircraft (AEA), requires electric power systems with high power density and low system mass specifications. Increasing the voltage of the system to the range of a few kV, medium voltage (MV), is a reasonable approach to achieving high‐power‐density and low‐system‐mass EPSs for aircraft applications. Higher voltages, however, pose many challenges for aviation MV power cables such as arcs and arc tracking, partial discharges (PDs), and thermal management. In this regard, thermal management is more challenging since heat transfer by convection is greatly reduced at wide‐body aircraft's cruising altitudes due to the reduced air pressure. In this paper, a finite element method (FEM) model is developed in COMSOL Multiphysics for an aircraft bipolar MVDC (±5 kV) power cable. Using the model, the maximum permissible cable current at a low pressure of 18.8 kPa (at an altitude of 12.2 km from sea level, the usual cruising altitude for wide‐body aircraft) is calculated. Also, an analytical model is developed based on analytical and proven empirical correlations governing conductive, radiative, and convective heat transfers at the steady state to estimate the ampacity of the bipolar cable system at reduced pressure. It was shown that the proposed analytical model can be used for atmospheric pressure and systems with a larger number of poles, expanding its range of applications. The results of the FEM and analytical models correlate at wide ranges of parameters such as ambient temperature, duct size, distance between the positive and negative pole cables, and the overall diameter of the cables. The influence of horizontal and vertical arrangement of poles is included in the analytical model. The results of this study can be used to design bipolar MVDC power cable systems for the envisaged wide‐body AEA.

Azizi, Arian↗

DOE OSTI2025

Collaborative Proposal: Improving understanding of the internal structure and dynamics of deep convection using ARM observations and large eddy simulations

Recent observational and large eddy simulation (LES) modeling studies have nearly unanimously supported the view of deep cumulus convection being composed of a series of quasi-spherical bubbles of buoyant air, known as moist thermals. Despite the prevalence of moist thermals in deep convection, a comprehensive theory for the dynamics of these structures is lacking. Most current conceptual models for cumulus convection are based on canonical scaling theories for dry thermals or plumes; however, there is considerable evidence that the behavior of moist thermals differs markedly from these theories. Furthermore, the theoretical basis for most cumulus parameterizations originates from the plume conceptual model, and therefore these parameterizations are inconsistent with the real structure of moist convection. Motivated by the aforementioned knowledge gaps, this “end-to-end” research effort use theory, observations, numerical simulations, and direct improvements to the Zhang-McFarlane (ZM) convection scheme in the global climate Community Atmosphere Model (CAM) to address the following research questions: What key environmental parameters determine whether or not shallow convection will transition into deep convection, in the context of thermal-like updrafts? What factors regulate the size of thermals within cumulus updrafts? How does vertical wind shear influence thermal behavior, and as a consequence, vertical velocity and mass flux profiles and the shallow-to-deep convective transition? What are the critical processes that determine updraft vertical velocities and their connection to the vertical mass flux profile for thermal-like updrafts? Idealized LES modeling will be used in conjunction with theoretical models for the core properties of thermal-like updrafts to better understand key processes that regulate thermal ascent rates and entrainment properties. Thermal-tracking procedures will be used to characterize the behavior of thermals within the LES, and recently developed direct measures of entrainment and detrainment will be used to quantify entrainment/detrainment rates. Building from these results, we will analyze the structure of moist thermals from hemispheric range-height indicator scans taken during the Atmospheric Radiation Measurement Cloud, Aerosol, and Complex Terrain Interactions (CACTI) field campaign, and from “real case” LES of CACTI events. This combined modeling and observational analysis will provide essential validation for the existing body of research on moist thermal dynamics, which is based primarily on modeling studies. With the insight gained from the aforementioned activities, we will modify the Zhang-McFarlane convection scheme to improve its representation of updraft vertical velocity and entrainment rate profiles. These process-level changes will be tested in the Community Atmosphere Model to assess the impact on global climate simulations.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Arctic Mixed-Phase Cloud Base Ice Precipitation Properties During the M-PACE Field Campaign

Cloud-climate feedbacks are still the greatest source of uncertainty in current climate projections. Arctic clouds, which are predominantly stratiform and supercooled, often long-lived, and nearly-continuously precipitate ice particles, contribute roughly 10% of the uncertainty attributed to the global cloud feedback. This Arctic cloud uncertainty is driven by incomplete observational and theoretical knowledge required to estimate and explain the state and active processes occurring in those clouds. A focus on ice precipitation properties at Arctic cloud base rather than the surface deconfounds the product of cloud condensate sink processes from the influence of the atmospheric thermodynamic state below cloud base, rendering cloud-base properties a more appealing target for inference and evaluation of model simulations. This dataset provides a set of 25 samples from the M-PACE field campaign, all of which were retrieved using the synthesis of ARM radar and lidar measurements. The retrieved ice precipitation variables in this dataset include, among others, the ice number concentration, water content, PSD parameters, precipitation rate, mass-weighted fall velocity, vertical air motion, and effective radius, all of which are highly valuable for model evaluation and a general understanding of polar cloud sink processes. Each variable sample includes its mean value and associated uncertainty. Additional variables based on ARM measurements (liquid layer statistics, etc.) are included in this dataset as well. The retrieval algorithm and analysis of this dataset are described in Silber (JGR, 2023, https://doi.org/10.1029/2022JD038202).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Sensitivity of Arctic Surface Temperature to Including a Comprehensive Ocean Interior Reflectance to the Ocean Surface Albedo Within the Fully Coupled CESM2

Abstract Almost all current climate models simplify the ocean surface albedo (OSA) by assuming the reflected solar energy without the ocean interior contribution. In this study, an improved ocean surface albedo scheme is incorporated into the Community Earth System Model version 2 (CESM2) to assess the sensitivity of Arctic surface temperature to including ocean interior reflectance to the OSA. Fully coupled CESM2 simulations with and without ocean interior reflectance are subsequently performed, we focus on the analysis of Arctic surface temperature responses. Incorporating ocean interior reflectance increases absorbed solar radiation and warms the ocean, enhancing seasonal heat storage and release across the Arctic Ocean, and increasing sea ice reduction and positive climate feedbacks that elevates Arctic surface temperature. Seasonal variations in air‐surface temperature differences induce changes in turbulent heat flux patterns, concurrently modifying dynamic advection and moisture processes that affect boundary layer humidity and low clouds, especially in winter. Based on partitioning physical processes in the thermodynamic energy equation, surface air warming is induced primarily through positive heating anomalies of vertical advection, latent heat release, and longwave radiative forcing. Through an examination of the surface energy budget, skin temperature warming is driven predominantly by increased downward longwave radiation, positive surface albedo feedback in summer, and increased conductive heat transport from the ocean particularly in winter. Significant effects of ocean interior reflectance on the Arctic Ocean, including sea surface warming and sea ice reduction, justify the importance of ocean interior reflectance in climate models for better understanding of ongoing Arctic climate changes.

Meteorology & Atmospheric Sciences↗

DOE OSTI2021

Exploring the elevated water vapor signal associated with the free tropospheric biomass burning plume over the southeast Atlantic Ocean

In southern Africa, widespread agricultural fires produce substantial biomass burning (BB) emissions over the region. The seasonal smoke plumes associated with these emissions are then advected westward over the persistent stratocumulus cloud deck in the southeast Atlantic (SEA) Ocean, resulting in aerosol effects which vary with time and location. Much work has focused on the effects of these aerosol plumes, but previous studies have also described an elevated free tropospheric water vapor signal over the SEA. Water vapor influences climate in its own right, and it is especially important to consider atmospheric water vapor when quantifying aerosol-cloud interactions and aerosol radiative effects. Here we present airborne observations made during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign over the SEA Ocean. In observations collected from multiple independent instruments on the NASA P-3 aircraft (from near-surface to 6-7 km), we observe a strongly linear correlation between pollution indicators (carbon monoxide (CO) and aerosol loading) and atmospheric water vapor content, seen at all altitudes above the boundary layer. The focus of the current study is on the especially strong correlation observed during the ORACLES-2016 deployment (out of Walvis Bay, Namibia), but a similar relationship is also observed in the August 2017 and October 2018 ORACLES deployments. Using reanalyses from the European Centre for Medium-Range Weather Forecasts (ECMWF) and Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), and specialized WRF-Chem simulations, we trace the plume-vapor relationship to an initial humid, smoky continental source region, where it mixes with clean, dry upper tropospheric air and then is subjected to conditions of strong westward advection, namely the southern African easterly jet (AEJ-S). Our analysis indicates that air masses likely left the continent with the same relationship between water vapor and carbon monoxide as was observed by aircraft. This linear relationship developed over the continent due to daytime convection within a deep continental boundary layer (up to ~5-6 km) and mixing with higher-altitude air, which resulted in fairly consistent vertical gradients in CO and water vapor, decreasing with altitude and varying in time, but this water vapor does not originate as a product of the BB combustion itself. Due to a combination of conditions and mixing between the smoky, moist continental boundary layer and the dry and fairly clean upper-troposphere air above (~6 km), the smoky, humid air is transported by strong zonal winds and then advected over the SEA (to the ORACLES flight region) following largely isentropic trajectories. Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT) back trajectories support this interpretation. This work thus gives insights into the conditions and processes which cause water vapor to covary with plume strength. Better understanding of this relationship, including how it varies spatially and temporally, is important to accurately quantify direct, semi-direct, and indirect aerosol effects over this region.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Arctic tropospheric ozone: assessment of current knowledge and model performance

As the third most important greenhouse gas (GHG) after carbon dioxide (CO 2 ) and methane (CH 4 ), tropospheric ozone (O 3 ) is also an air pollutant causing damage to human health and ecosystems. This study brings together recent research on observations and modeling of tropospheric O 3 in the Arctic, a rapidly warming and sensitive environment. At different locations in the Arctic, the observed surface O 3 seasonal cycles are quite different. Coastal Arctic locations, for example, have a minimum in the springtime due to O 3 depletion events resulting from surface bromine chemistry. In contrast, other Arctic locations have a maximum in the spring. The 12 state-of-the-art models used in this study lack the surface halogen chemistry needed to simulate coastal Arctic surface O 3 depletion in the springtime; however, the multi-model median (MMM) has accurate seasonal cycles at non-coastal Arctic locations. There is a large amount of variability among models, which has been previously reported, and we show that there continues to be no convergence among models or improved accuracy in simulating tropospheric O 3 and its precursor species. The MMM underestimates Arctic surface O 3 by 5% to 15% depending on the location. The vertical distribution of tropospheric O 3 is studied from recent ozonesonde measurements and the models. The models are highly variable, simulating free-tropospheric O 3 within a range of ±50% depending on the model and the altitude. The MMM performs best, within ±8% for most locations and seasons. However, nearly all models overestimate O 3 near the tropopause (~300 hPa or ~8 km), likely due to ongoing issues with underestimating the altitude of the tropopause and excessive downward transport of stratospheric O 3 at high latitudes. For example, the MMM is biased high by about 20% at Eureka. Observed and simulated O 3 precursors (CO, NO x , and reservoir PAN) are evaluated throughout the troposphere. Models underestimate wintertime CO everywhere, likely due to a combination of underestimating CO emissions and possibly overestimating OH. Throughout the vertical profile (compared to aircraft measurements), the MMM underestimates both CO and NO x but overestimates PAN. Perhaps as a result of competing deficiencies, the MMM O 3 matches the observed O 3 reasonably well. Our findings suggest that despite model updates over the last decade, model results are as highly variable as ever and have not increased in accuracy for representing Arctic tropospheric O 3 .

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Arctic Mixed-Phase Cloud Base Ice Precipitation Properties Over the NSA Site

Cloud-climate feedbacks are still the greatest source of uncertainty in current climate projections. Arctic clouds, which are predominantly stratiform and supercooled, often long-lived, and nearly continuously precipitate ice particles, contribute roughly 10% of the uncertainty attributed to the global cloud feedback. This arctic cloud uncertainty is driven by incomplete observational and theoretical knowledge required to estimate and explain the state and active processes occurring in those clouds. A focus on ice precipitation properties at arctic cloud base rather than the surface deconfounds the product of cloud condensate sink processes from the influence of the atmospheric thermodynamic state below cloud base, rendering cloud-base properties a more appealing target for inference and evaluation of model simulations. This data set provides more than 1800 samples of cloud-base ice precipitation properties over Utqiagvik, North Slope of Alaska, all of which were retrieved using the synthesis of ARM radar and lidar measurements. The retrieved ice precipitation variables in this data set include, among others, the ice number concentration, water content, PSD parameters, precipitation rate, mass-weighted fall velocity, vertical air motion, and effective radius, all of which are highly valuable for model evaluation and a general understanding of polar cloud sink processes. Each variable sample includes its mean value and associated uncertainty. Additional variables based on ARM measurements (liquid layer statistics, etc.) are included in this data set. The retrieval algorithm and analysis of this data set are described in Silber (JGR, 2023, https://doi.org/10.1029/2022JD038202).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Full-Scale Implementation of Propane Biosparge System for In-Situ Remediation of 1,4-Dioxane - 20174

1,4-Dioxane is a common co-contaminant with chlorinated solvents but is not readily remediated via similar treatment approaches (e.g., sorption, reductive dechlorination). However, 1,4-dioxane can be cometabolically biodegraded in the presence of alkane gases and oxygen. At Vandenberg Air Force Base in California, USA, historical use of chlorinated solvents resulted in 1,4-dioxane in groundwater across three vertical groundwater zones. Between April 2013 and December 2016, laboratory testing and various field demonstrations were conducted by us, and others. The results from these tests showed in-situ propane biosparging as a promising technology for reduction of both chlorinated solvent and 1,4-dioxane concentrations, with up to 99 percent reduction in groundwater concentrations. Stable isotope probing (SIP) was also used in 2015 to verify that biodegradation was a (destructive) mechanism occurring in the subsurface.). The success of the propane biosparge demonstrations, and confirmation of the biodegradation mechanism via SIP, has led to the full-scale implementation of a propane biosparge treatment system at Site 24 at Vandenberg Air Force Base. The treatment area is a relatively small footprint (e.g., less than 61 meters (200 feet) long), with 83 new wells installed simultaneously across the three groundwater zones. Ultimately 93 wells will be connected to an above-ground treatment system the includes an air compressor, a propane tank, controls to ensure safe operating conditions, and nutrient amendment elements. This full-scale system is currently known to be among the first of its kind. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗