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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

A new analysis of the vibration-rotation spectrum of CH from solar spectra

In the solar spectrum, CH vibration-rotation lines are excited to higher vibrational and much higher rotational quantum numbers than in any laboratory source. Observations were made, for the first time, of a very large number of new lines (1-0 and 2-1 up to J = 34.5, 3-2 up to J = 31.5, and even 4-3, never seen before, up to J = 24.5) on solar spectra obtained from space, with the ATMOS-SL3 instrument. A total of 558 lines have been used to derive new accurate molecular constants for the X 2Pi ground state of CH.

Melen, F.↗

An Analysis of the Torsion-Rotation-Vibration Rotational Spectrum of the Lowest In-Plane Bend and First Excited Torsional State of the C(3V) Internal Rotor C2H5CN

C2H5CN (Propionitrile or ethyl cyanide) is a well known interstellar species abundantly observed in hot cores during the onset of star formation. The onset of star formation generally results in elevated temperature, which thermally populates may low lying vibrational states such as the 206/cm in-plane bend and the 212/cm first excited torsional state in C2H5CN. Unfortunately, these two states are strongly coupled through a complex series of torsion-vibration-rotation interactions, which dominate the spectrum. In order to understand the details of these interactions and develop models capable of predicting unmeasured transitions for astronomical observations in C2H5CN and similar molecules, several thousand rotational transitions in the lowest excited in-plane bend and first excited torsional state have been recorded, assigned and analyzed. The analysis reveals very strong a- and b-type Coriolis interactions and a number of other smaller interactions and has a number of important implications for other C3V torsion-rotation-vibration systems. The relative importance and the physical origins of the coupling among the rotational, vibrational and torsional motions will be presented along with a full spectroscopic analysis and supporting astronomical observations.

Pearson, J. C.↗

Measurement of the fundamental vibration-rotation spectrum of ClO

The ClO fundamental absorption band near 850/cm is observed, with a tunable PbSnTe diode laser used as a source of monochromatic radiation. The chlorine monoxide concentration in the absorption tube was measured indirectly via a UV transmission technique. Frequencies and assignments for the ClO lines, and band centers and rotational constants for the ClO fundamental vibration, are tabulated. Diatomic vibration-rotation transitions within and between electronic substates are discussed. The tunable diode laser is valuable for studying the hyperfine structure. The IR spectroscopic technique is developed in order to monitor chlorine monoxide concentration in the stratosphere, since the short-lived ClO is a crucial intermediate participant in reactions involving destruction of stratospheric ozone.

Menzies, R. T.↗

The vibrational overtone spectrum of liquid methane in the visible and near infrared - Applications to planetary studies

The strengths of 10 bands in the absorption spectrum of liquid methane between 19,400 and 6190 A have been measured. After a small correction for the polarizability of the liquid is applied for the purpose of comparison with similar gas-phase measurements, it is found that there is no temperature dependence of the band strengths between 95 and 295 K. Changes of band shape with temperature cause the 95 K laboratory spectra to resemble Saturn more than room-temperature observations do. Gas-phase absorption clearly dominates the liquid in planetary spectra, so liquid methane cannot be detected in the outer solar system by earth-based observations.

Ramaprasad, K. R.↗

Investigation of the 1-0 pressure-induced vibrational absorption spectrum of hydrogen at temperatures below ambient

A theoretical fit has been made to laboratory measurements of the 1-0 collisionally induced H2 absorption band over a temperature range of 100-273 K and for densities up to 22 amagats. Both the Birnbaum-Cohen and the MacTaggert-Hunt line shape profiles were used. In addition, an intermolecular potential of either a Lennard-Jones 6-12 or a Morse-spline-van der Waals has been used for each line shape. The best fit resulted in a chi-square of 5%. Line widths have also been derived as a function of temperature. The lifetimes of the states were calculated.

Goorvitch, D.↗

Investigation of the 2-0 pressure-induced vibrational absorption spectrum of hydrogen at temperatures below ambient

A theoretical fit has been made to our laboratory measurements of the 2-0 collisionally induced H2 absorption band for temperatures of 122 and 273.3 K and at a density of 20 amagats. A Lennard-Jones 6-12 intermolecular potential and a Birnbaum-Cohen line profile have been used. The fit resulted in a chi-square of 0.2%. Line widths have also been derived as a function of temperature. The lifetimes of the states have been calculated.

Silvaggio, P. M.↗

Matching Vibration Testing to "Real-World" Conditions

Vibration spectrum of test machine adjusted to that observed in operation. Test specimen placed in test fixture and attached to shaker. Shaker initially operated at one-quarter full level of input spectrum to prevent overloading. Short vibration test run, and specimen response compared to control spectrum. Imput spectrum then adjusted until response resembles control spectrum.

Olsen, Albert D., Jr.↗

Non-linear resonance of fluids in a crystal growth cavity

In the microgravity environment, the effect of gravity on fluid motion is much reduced. Hence, secondary effects such as vibrations, jitters, surface tension, capillary effects, and electromagnetic forces become the dominant mechanism of fluid convection. Numerous studies have been conducted to investigate fluid behavior in microgravity with the ultimate goal of developing processes with minimal influence from convection. Industrial applications such as crystal growth from solidification of melt and protein growth for pharmatheutical application are just a few examples of the vast potential benefit that can be reaped from material processing in space. However, a space laboratory is not immune from all undesirable disturbances and it is imperative that such disturbances be well understood, quantifiable, and controlled. Non-uniform and transient accelerations such as vibrations, jitters, and impulsive accelerations exist as a result of crew activities, space vehicle maneuvering, and the operations of on-board equipment. Measurements conducted on-board a U.S. Spacelab showed the existence of vibrations in the frequency range of 1 to 100 Hz with a dominant mode of 17 Hz and harmonics of 54 Hz. The observed vibration is not limited to any coordinate plane but exists in all directions. Similar situation exists on-board the Russian MIR space station. Due to the large structure of its design, the future International Space Station will have its own characteristic vibration spectrum. It is well known that vibration can exert substantial influence on heat and mass transfer processes, thus hindering any attempts to achieve a diffusion-limited process. Experiments on vibration convection for a liquid-filled enclosure under one-g environment showed the existence of different flow regimes as vibration frequency and intensity changes. Results showed the existence of a resonant frequency, near which the enhancement is the strongest, and the existence of a high frequency asymptote. Numerical simulations of vibration convection have been conducted by Yurkov, Fu and Shieh, and by Wang. These analyses considered a two-dimensional air-filled cell under weightlessness condition and showed results similar to those of the experiments. It is not yet known whether resonance convection can be triggered by jitter alone or whether it requires the interaction of jitter with other convective forces in low gravity. An order of magnitude analysis, however, can be used to show the dependence of the resonance frequency on the fluid Prandtl number. Even though the onset of resonance convection may depend on other factors, results indicates that fluids with low Prandtl numbers are more susceptible to resonance than those with high Prandtl numbers. The current study is aimed at gaining additional insights to this problem using germanium as working fluid. Germanium was chosen for this analysis because of its common usage in solidification process and its relatively low Prandtl number (Pr = 0.02).

Wang, Francis C.↗

NTS-2 retroreflector array

The NTS-II Laser Retroreflector consists of a honeycomb tray onto which are mounted 44 fused silica cube corners with a 50-millimeter hexagonal entrance pupil and single infrared cube. A thermal shield with a highly reflective outer surface and a black inner surface was incorporated to shroud the assembly protecting it from extreme high temperature exposure thus reducing cube corner thermal distortions to a minimum. A dummy retroreflector, utilizing simulated aluminum cube corners was fabricated and vibration tested to qualification levels to substantiate the integrity of the tray and cube mounting clips. This dummy was further used in the spacecraft spin balance test. The flight Laser Retroreflector was tested to the flight level vibration spectrum to verify that the unit will survive its expected vibration environment. During this test several GFE cube corners exhibited slight crazing at the clip support mounting holes. These cubes were reworked and retested and proved to be satisfactory.

Source record↗

The surface glow of the Atmosphere Explorer C and E satellites

Detailed line intensities of the rotational-vibrational spectrum of OH are calculated for various rates of population of sixteen bound vibrational levels in which the rotational level populations are in thermal equilibrium. The line intensities are convolved with the instrument function of the Visible Airglow Experiment on the AE C and E satellites to obtain spectra for comparison with the atmospheric data. Within the uncertainties, a model can be constructed that reproduces the observed spectrum. Synthetic spectra are computed for the OH Meinel system between 2000 A and 5.5 microns. The maximum intensity occurs between 1 micron and 2 microns.

Langhoff, S. R.↗

A use of regression analysis in acoustical diagnostics of gear drives

A study is presented of components of the vibration spectrum as the filtered first and second harmonics of the tooth frequency which permits information to be obtained on the physical characteristics of the vibration excitation process, and an approach to be made to comparison of models of the gearing. Regression analysis of two random processes has shown a strong dependence of the second harmonic on the first, and independence of the first from the second. The nature of change in the regression line, with change in loading moment, gives rise to the idea of a variable phase shift between the first and second harmonics.

Balitskiy, F. Y.↗

Ab Initio Studies of Chlorine Oxide and Nitrogen Oxide Species of Interest in Stratospheric Chemistry

The ability of modern state-of-the art ab initio quantum chemical techniques to characterize reliably the gas-phase molecular structure, vibrational spectrum, electronic spectrum, and thermal stability of chlorine oxide and nitrogen oxide species will be demonstrated by presentation of some example studies. In particular the geometrical structures, vibrational spectra, and heats of formation Of ClNO2, CisClONO, and trans-ClONO are shown to be in excellent agreement with the available experimental data, and where the experimental data are either not known or are inconclusive, the ab initio results are shown to fill in the gaps and to resolve the experimental controversy. In addition, ab initio studies in which the electronic spectra and the characterization of excited electronic states of ClONO2, HONO2, ClOOC17 ClOOH, and HOOH will also be presented. Again where available, the ab initio results are compared to experimental observations, and are used to aid in the interpretation of the experimental studies.

Lee, Timothy J.↗