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Results for “VISIBLE SPECTRA”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

SMASS Near-Earth Object Survey: An Album of Results

The Small Main-Belt Asteroid Spectroscopic Survey (SMASS) undertaken at MIT has produced and published visible spectra for more than 1300 main-belt asteroids. The infrared extension of this program (SMASSIR) has produced near-infrared spectra for about 200 main-belt asteroids. In this poster we present visible and near-infrared spectral results for more than 300 near-Earth objects (NEOs) measured during the SMASS and SMASSIR programs and through ongoing observations at Kitt Peak, Palomar, IRTF, and Magellan observatories. The scientific goals for this sample are to deduce the compositional distribution of the near-Earth object population. Knowledge of this distribution will allow the origin and relative hazard of the NEO population to be better understood and will provide the basis for gaining further insights to asteroid-meteorite and asteroid-comet relationships. While a portion of our NEO sample has been published, spectral measurements are newly presented here for more than 250 NEOs. All published SMASS spectra are available at our website http://smass.mit.edu/. These new near-Earth object spectra will also be made available at the SMASS website at the time they are submitted for publication.

Binzel, R. P.↗
NASA NTRS1994

VV 114, a high infrared luminosity interacting galaxy system

VV 114 is a nearby example of a far-infrared (FIR) bright, high luminosity (L(sub FIR) greater than 10(exp 11) solar luminosity) interacting galaxy pair. At a redshift of z = 0.02 it provides an opportunity to study such interacting galaxies at a favorable spatial scale (390 pc/arcsec). This paper presents new high resolution near-infrared (1.25 to 3.7 micrometer) and visible images, and visible spectra of VV 114. A picture emerges of a system with widespread massive star formation throughout both interacting galaxies. The brighter visible galaxy (VV 114W) shows H II region-like emission in both visual spectra and near-infrared colors, with no more than two magnitudes of visual extinction. The brightest peak of infrared and radio emission (VV 114E) has extreme near-infrared colors and is located at a minimum of visible emission. This indicates a large concentration of dust in the nucleus of VV 114E that is nearly entirely obscuring a major luminosity source in this system.

Knop, R. A.↗
NASA NTRS1990

Photodissociation of Cl2O2 in the spring Antarctic lower stratosphere

The likely photodissociation pathways of chlorine peroxide are examined. Reasoning by analogy between hydrogen peroxide and chlorine peroxide, it is shown that photodissociation of chlorine peroxide at wavelengths longer than 250 nm is not likely to give chlorine atoms as a primary product. Reasoning by analogy with molecules whose visible spectra are known, it is concluded that chlorine peroxide is also likely to photodissociate in the visible to give ClO radicals as primary products.

Eberstein, Igor J.↗
NASA NTRS2016

The Spectrum of Jupiter's Great Red Spot: The Case for Ammonium Hydrosulfide (NH4SH)

Here we present new ultraviolet-visible spectra of irradiated ammonium hydrosulfide (NH4SH), a reported Jovian atmospheric cloud component, for a range of temperatures and radiation doses and make assignments to the spectral features. We show that the combination of radiolysis and thermal annealing of NH4SH causes the originally featureless ultraviolet-visible reflectance spectrum to evolve into one that absorbs in the ultraviolet-visible region. Furthermore, we find that our laboratory spectra resemble HST (Hubble Space Telescope) spectra below 500 nanometers, suggesting that the more stable reaction products of NH4SH radiolysis are likely an important component of the Great Red Spot.

Jupiter's Great Red Spot (GRS)↗
NASA NTRS2016

The Spectrum of Jupiters Great Red Spot: the Case for Ammonium Hydrosulfide (NH4SH)

Here we present new ultraviolet-visible spectra of irradiated ammonium hydrosulfide (NH4SH), a reported Jovian atmospheric cloud component, for a range of temperatures and radiation doses and make assignments to the spectral features. We show that the combination of radiolysis and thermal annealing of NH4SH causes the originally featureless ultraviolet-visible reflectance spectrum to evolve into one that absorbs in the ultraviolet-visible region. Furthermore, we find that our laboratory spectra resemble HST (Hubble Space Telescope) spectra below 500 nanometers, suggesting that the more stable reaction products of NH4SH radiolysis are likely an important component of the Great Red Spot.

Jupiter Atmosphere↗
NASA NTRS1982

The Cloud Field Simulation Project

Progress toward the research goals of CFOS (the Cloud Field Optical Simulator) were noted in the following areas: (1) improvement in the shape of the desired (visible) spectra response of the measurement, (2) selection of two usable materials for cloud simulation, (3) a means of assigning a visible optical depth to the simulated clouds, and (4) confirmation that the apparatus is capable of detecting basic finite cloud characteristics.

Source record↗
NASA NTRS1994

Ultraviolet spectra of quenched carbonaceous composite derivatives: Comparison to the '217 nanometer' interstellar absorption feature

QCCs (quenched carbonaceous composite) are amorphus carbonaceous material formed from a hydrocarbon plasma. We present the UV-visible spectra of 'filmy QCC; (obtained outside of the beam ejected from the hydrocarbon plasma) and 'dark QCC' (obtained very near to the beam) for comparison to the stellar extinction curve. When filmy QCC is heated to 500-700 C (thermally altered), the wavelength of the absorption maximum increases form 204 nm to 220-222 nm. The dark QCC has an absorption maximum at 217-222 nm. In addition, the thermally altered filmy QCC has a slope change at about 500 nm which resmbles that in the interstellar extinction curve. The resemblance of the extinction curve of the QCCs to that of the interstellar medium suggests that QCC derivatives may be representative of the type of interstellar material that produces the 217 nm interstellar medium feature. The peak extinction of the dark QCC is higher than the average interstellar extinction curve while that of the thermally altered filmy QCC is lower, so that a mixture of dark and thermally altered filmy QCC can match the peak extinction observed in the interstellar medium. It is shown from electron micrographs that most of the thermally altered flimy QCC is in the form of small grainy structure less than 4 nm in diameter. This shows that the structure unit causing the 217-222 nm feature in QCC is very small.

Sakata, Akira↗
NASA NTRS1993

Exploratory investigations of hypervelocity intact capture spectroscopy

The ability to capture hypervelocity projectiles intact opens a new technique available for hypervelocity research. A determination of the reactions taking place between the projectile and the capture medium during the process of intact capture is extremely important to an understanding of the intact capture phenomenon, to improving the capture technique, and to developing a theory describing the phenomenon. The intact capture of hypervelocity projectiles by underdense media generates spectra, characteristic of the material species of projectile and capture medium involved. Initial exploratory results into real-time characterization of hypervelocity intact capture techniques by spectroscopy include ultra-violet and visible spectra obtained by use of reflecting gratings, transmitting gratings, and prisms, and recorded by photographic and electronic means. Spectrometry proved to be a valuable real-time diagnostic tool for hypervelocity intact capture events, offering understanding of the interactions of the projectile and the capture medium during the initial period and providing information not obtainable by other characterizations. Preliminary results and analyses of spectra produced by the intact capture of hypervelocity aluminum spheres in polyethylene (PE), polystyrene (PS), and polyurethane (PU) foams are presented. Included are tentative emission species identifications, as well as gray body temperatures produced in the intact capture process.

NASA Center JPL↗
NASA NTRS1972

The ultraviolet flux envelopes of main-sequence B stars

Flux envelopes on an absolute energy scale from 1100 to 6000 A prepared from OAO-2 scans and from published ground-based material are presented for gamma Leporis, B0.5 5 eta Ursae Majoris, B3 5, gamma Ursae Majoris, A0 5, and alpha Lyrae, A0 5, and for alpha Canis Majoris Al 5 from rocket scans. These, with already published flux envelopes for Zeta Draconis, B6 3, and alpha Leonis, B7 5 (Underhill 1972) are intercompared and compared with reference flux envelopes predicted by LTE theory from lightly line-blanketed model atmospheres. A considerable line blocking occurs at wavelengths shortward of 3000 A with respect to the theoretical continuous spectra. The line blocking may be as much as 50 per cent at 1500 A and between 1500 A and 2500 A it is comparable to that which exists in the sun between 3000 A and 4000 A. Although gamma Urase Majoris, alpha Lyrae and alpha Canis Majoris have very similar visible spectra when viewed at low resolution, their ultraviolet spectra are significantly different, in particular alpha Lyrae shows an ultraviolet excess.

Underhill, A. B.↗
NASA NTRS1985

Optically transparent/colorless polyimides

Several series of linear aromatic polyimide films have been synthesized and characterized with the objective of obtaining maximum optical transparency. Two approaches have been used as part of this structure-property relationship study. The first approach is to vary the molecular structure so as to separate chromophoric centers and reduce electronic interactions between polymer chains to lower the intensity of color in the resulting polymer films. A second and concurrent approach is to perform polymerizations with highly purified monomers. Glass transition temperatures of thermally cured polyimide films are obtained by thermomechanical analysis and thermal decomposition temperatures are determined by thermogravimetric analysis. Transmittance UV-visible spectra of the polyimide films are compared to that of a commercial polyimide film. Fully imidized films are tested for solubility in common organic solvents. The more transparent films prepared in this study are evaluated for use on second-surface mirror thermal control coating systems. Lightly colored to colorless films are characterized by UV-visible spectroscopy before and after exposure to 300 equivalent solar hours UV irradiation and varying doses of 1 MeV electron irradiation. The effects of monomer purity, casting solvent and cure atmosphere on polyimide film transparency are also investigated.

Stclair, A. K.↗
NASA NTRS1981

Raman scattering as a probe of planetary atmospheres

The observable effects of Raman scattering on the spectra of the giant planets may provide new information on the composition and structure of these atmospheres. Satellite observations have already shown the influence of Raman scattering on the UV continuum albedo. A cross correlation technique is presented for detecting rotational and vibrational transitions of the Raman active gases in the atmosphere. This technique has been applied to ground-based visible spectra of Venus, Jupiter, Saturn and Uranus. Extension of this method into the UV would improve the detectability of the Raman lines because the ratio of Raman to Rayleigh cross section increases with decreasing wavelength. The technology currently exists to efficiently obtain high-signal-to-noise ratio UV spectra through the use of silicon diode array detectors. Application of the cross-correlation technique to UV spectra obtained from space vehicles would give a new important probe of the structure and composition of planetary atmospheres by enabling the use of the UV spectra of a planet to observe what would normally be an infrared molecular transition.

Cochran, W. D.↗
NASA NTRS2011

Initiating Molecular Growth in the Interstellar Medium via Dimeric Complexes of Observed Ions and Molecules

A feasible initiation step for particle growth in the interstellar medium (ISM) is simulated by means of ab quantum chemistry methods. The systems studied are dimer ions formed by pairing nitrogen containing small molecules known to exist in the ISM with ions of unsaturated hydrocarbons or vice versa. Complexation energies, structures of ensuing complexes and electronic excitation spectra of the encounter complexes are estimated using various quantum chemistry methods. Moller-Plesset perturbation theory (MP2, Z-averaged perturbation theory (ZAP2), coupled cluster singles and doubles with perturbative triples corrections (CCSD(T)), and density functional theory (DFT) methods (B3LYP) were employed along with the correlation consistent cc-pVTZ and aug-cc-pVTZ basis sets. Two types of complexes are predicted. One type of complex has electrostatic binding with moderate (7-20 kcal per mol) binding energies, that are nonetheless significantly stronger than typical van der Waals interactions between molecules of this size. The other type of complex develops strong covalent bonds between the fragments. Cyclic isomers of the nitrogen containing complexes are produced very easily by ion-molecule reactions. Some of these complexes show intense ultraviolet visible spectra for electronic transitions with large oscillator strengths at the B3LYP, omegaB97, and equations of motion coupled cluster (EOM-CCSD) levels. The open shell nitrogen containing carbonaceous complexes especially exhibit a large oscillator strength electronic transition in the visible region of the electromagnetic spectrum.

Bera, Partha P.↗
NASA NTRS1974

Rocket-ultraviolet spectra of kappa, lambda, tau, and upsilon Scorpii

The present work describes high- and low-resolution rocket-ultraviolet spectra of kappa, lambda, tau, and upsilon Scorpii obtained in the range from 1160 to 1880 A. The Si IV resonance lines in tau Sco show asymmetries indicating outward mass motions of up to about 400 km/sec. The suitability of some of the lines observed for indication of luminosity or temperature is discussed. It is pointed out that the intrinsic strength and large changes of the lines of Si III and C IV may permit a more accurate spectral classification of stars between B0 and B3 than has been demonstrated in this same spectral type region using visible spectra.

Jenkins, E. B.↗
NASA NTRS1972

Interstellar lines in the ultraviolet spectrum of zeta Oph

Interstellar lines arising in carbon, oxygen, silicon, and sulfur observed in the ultraviolet spectrum of zeta Oph by rocket spectrographic techniques were analyzed. Within a factor of 10, the abundances of c(+), neutral 0, and Si(+) outside the H II region surrounding zeta Oph, relative to the hydrogen abundance, are equal to solar values. The lines in neutral C and S(+) imply that the interstellar matter is distributed among several clouds as indicated by high resolution visible spectra. It is suggested that the excited C(+) ions are inside the Stromgren sphere where proton densities equal to or greater than 0.0022 cm can collisionally excite the ions at sufficient rates. Stellar absorption lines of C IV (1548.2, 1550.8A) and N V (1238.8, 1242.8A) were observed shifted to lower wavelengths, indicating stellar mass loss.

Smith, A. M.↗
NASA NTRS1973

A study of marine luminescence signatures, part 1

Fluorescent excitation and emission spectral data on chlorophyll and Gelbstoff in natural sea waters from the Atlantic, Gulf, and Pacific coasts show that algae particulates are totally absorbing over much of the near ultraviolet and visible spectra and act approximately as quantum counters; plant pigments absorb energy and transfer a large portion to chlorophyll where some fraction is emitted as chlorophyll fluorescence. Gelbstoff data do not exhibit quantum counter action because of their low concentration. It is concluded that luminescence data of natural sea waters are useful in monitoring algal and Gelbstoff as well as pollutant concentrations.

Hornig, A. W.↗
NASA NTRS1977

Tunable acoustical optical filter

Solid state filter with active crystal element increases sensitivity and resolution of passive and active spectrometers. Filter is capable of ranging through infrared and visible spectra, can be built as portable device for field use, and is suitable for ecological surveying, for pollution detection, and for pollutant classification.

Lane, A. L.↗
NASA NTRS1977

Large, high resolution integrating TV sensor for astronomical appliations

A magnetically focused SEC tube developed for photometric applications is described. Efforts to design a 70 mm version of the tube which meets the ST f/24 camera requirements of the space telescope are discussed. The photometric accuracy of the 70 mm tube is executed to equal that of the previously developed 35 mm tube. The tube meets the criterion of 50 percent response at 20 cycles/mm in the central region of the format, and, with the removal of the remaining magnetic parts, this spatial frequency is expected over almost all of the format. Since the ST f/24 camera requires sensitivity in the red as well as the ultraviolet and visible spectra, attempts were made to develop tubes with this ability. It was found that it may be necessary to choose between red and u.v. sensitivity and tradeoff red sensitivity for low background. Results of environmental tests indicate no substantive problems in utilizing it in a flight camera system that will meet the space shuttle launch requirements.

Spitzer, L. J.↗