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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Large space system: Charged particle environment interaction technology

Large, high voltage space power systems are proposed for future space missions. These systems must operate in the charged-particle environment of space and interactions between this environment and the high voltage surfaces are possible. Ground simulation testing indicated that dielectric surfaces that usually surround biased conductors can influence these interactions. For positive voltages greater than 100 volts, it has been found that the dielectrics contribute to the current collection area. For negative voltages greater than-500 volts, the data indicates that the dielectrics contribute to discharges. A large, high-voltage power system operating in geosynchronous orbit was analyzed. Results of this analysis indicate that very strong electric fields exist in these power systems.

Stevens, N. J.↗

Rare earth separation in voltage-gated 2D MXene membranes

The separation of rare earth elements (REEs) has historically been a complicated and expensive process, producing significant amounts of pollution. To this end, MXene membranes (MXMs) have attracted researchers' interest. It has been demonstrated that MXMs are capable of separating ions and that it is possible to precisely control the separation rate by applying a voltage to the membrane. Indeed, due to their chemical nature, MXenes show outstanding electrical conductivity. However, the effect of applied voltage on the permeation rate and separation effects of iconic species remains an intriguing area of research. In this work, we demonstrate how applying different voltages (gate voltage) to a MXM affects the permeation rate of various REE ions. Our hypothesis to explain MXMs behavior towards REE is that under negative voltage, the interlayer spacing decreases due to attraction between charged MXene surfaces and intercalated cations, increasing the separation factor between REEs. Under positive voltage, the interlayer spacing increases due to repulsion between the MXene surfaces and intercalated cations. However, we demonstrate relatively poor separation capability for REEs at 1mM starting concentration and 1.0 V applied DC voltage (separation factor ~1-3). This study demonstrates the need for future experiments to observe varied experimental conditions and chemical functionalization to determine whether MXene membranes can be an efficient platform for REE separation.

36 MATERIALS SCIENCE↗

Space environmental interactions with biased spacecraft surfaces

Large, high-voltage space power systems are being proposed for future space missions. These systems must operate in the charged-particle environment of space, and interactions between this environment and the high-voltage surfaces are possible. Ground simulation testing has indicated that dielectric surfaces that usually surround biased conductors can influence these interactions. For positive voltages greater than 100 V, it has been found that the dielectrics contribute to discharges. Using these experimental results a large, high-voltage power system operating in geosynchronous orbit was analyzed with the NASCAP code. Results of this analysis indicated that very strong electric fields exist in these power systems. A technology investigation is required to understand the interactions and develop techniques to alleviate any impact on power system performance.

Stevens, N. J.↗

Toward the Development of a High-Voltage Mg Cathode Using a Chromium Sulfide Host

Development of Mg-ion batteries as advanced electrochemical energy storage systems relies on the design and discovery of high-voltage positive electrode (cathode) materials. To date, a variety of sulfide cathodes have been reported (e.g., Mg x Mo 6 S 8 , Mg x Ti 2 S4, etc.), but the voltages of these materials are too low to prepare a high energy density Mg cell. Theoretical computations predicted that Mg x Cr 2 S 4 operating with the high-voltage Cr 3+/4+ redox couple would serve as a suitable cathode candidate, but experimental attempts to extract Mg 2+ from the lattice have been largely unsuccessful. Here, we show that reversible electrochemical activity within a thiospinel framework (AB 2 S 4 ) relies on a redox-active transition metal present in the B site; otherwise, anionic redox activity triggers decomposition of the spinel structure. Since Cr and S states are highly coupled in MgCr 2 S 4 , the Cr 3+/4+ redox couple is inaccessible so that reversible (de)intercalation of Mg 2+ cannot occur and charging leads to dissolution of the active material. These findings point to an insufficiency in the screening criteria previously used to identify MgCr 2 S 4 as a promising Mg cathode. Thus, a computable descriptor based on the electronic structure of the discharged material is proposed to predict the prevalence of cation vs anion redox and improve future surveys of potential candidates. It is unlikely that the high-voltage Cr redox couple will be accessible to oxidation in the presence of sulfur within the restrictions of a spinel framework; however, it is possible that a suitable layered Mg x CrS 2 structure could serve as a reversible high-voltage Mg cathode.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Flowing Plasma Interaction with an Electric Sail Tether Element

Harnessing the power of the solar wind, an Electric Sail, or E-sail, is a relatively new concept that promises to deliver high speed propellant-less propulsion. The electric sail is an invention made in 2006 at the Kumpula Space Centre in Finland by Pekka Janhunen [Janhunen and Sandroos, 2007]. At its core, an electric sail utilizes multiple positively biased tethers which exchange momentum with solar wind protons via the repelling electric field established around each tether, in other words, by reflecting the solar wind protons. Recognizing the solar wind is a plasma, the effective repelling area of each tether is increased significantly by the formation a plasma sheath around each tether. Fig. 1 shows schematically a spacecraft employing an electric sail. The positive voltage bias (greater than10kV) applied to each tether naturally results in electron collection. Therefore, the electric sail concept necessarily includes an electron source (electron gun) to return collected electrons to space and maintain the positive bias of the tether system.

Schneider, Todd↗

Improving the Operational Lifetime of the CEBAF Photo-Gun by Anode Biasing

The operating lifetime of GaAs-based photocathodes in DC high voltage electron photo-guns is dominated by the ionization rate of residual beamline gas molecules. In this work, experiments were performed to quantify the improvement in photocathode charge lifetime by biasing the photo-gun anode with a positive voltage, which repels ions generated downstream of the anode. The photo-cathode charge lifetime improved by almost a factor of two when the anode was biased compared to the usual grounded configuration. Simulations were performed using the particle tracking code General Particle Tracer (GPT) with a new custom element. The simulation results showed that both the number and energy of ions play a role in the pattern of QE degradation. The experiment results and conclusions supported by GPT simulations will be presented.

Yoskowitz, J. T.↗

Conceptual Design of an Electric Sail Technology Demonstration Mission Spacecraft

There is great interest in examining the outer planets of our solar system and Heliopause region (edge of Solar System) and beyond regions of interstellar space by both the Planetary and Heliophysics communities. These needs are well docu-mented in the recent National Academy of Sciences Decadal Surveys. There is significant interest in developing revolutionary propulsion techniques that will enable such Heliopause scientific missions to be completed within 10 to15 years of the launch date. One such enabling propulsion technique commonly known as Electric Sail (E-Sail) propulsion employs positively charged bare wire tethers that extend radially outward from a rotating spacecraft spinning at a rate of one revolution per hour. Around the positively charged bare-wire tethers, a Debye Sheath is created once positive voltage is applied. This sheath stands off of the bare wire tether at a sheath diameter that is proportional to the voltage in the wire coupled with the flux density of solar wind ions within the solar system (or the location of spacecraft in the solar system. The protons that are expended from the sun (solar wind) at 400 to 800 km/sec are electrostatically repelled away from these positively charged Debye sheaths and propulsive thrust is produced via the resulting momentum transfer. The amount of thrust produced is directly proportional to the total wire length. The Marshall Space Flight Center (MSFC) Electric Sail team is currently funded via a two year Phase II NASA Innovative Advanced Concepts (NIAC) awarded in July 2015. The team's current activities are: 1) Developing a Particle in Cell (PIC) numeric engineering model from the experimental data collected at MSFC's Solar Wind Facility on the interaction between simulated solar wind interaction with a charged bare wire that can be applied to a variety of missions, 2) The development of the necessary tether deployers and tethers to enable successful de-ployment of multiple, multi km length bare tethers, 3) Controllability of the space-craft via a voltage bias to steer itself through the solar system to destinations of discovery. These activities once demonstrated analytically, will require a technology demonstration mission (TDM) around the year2020 to demonstrate that all systems work together seamlessly before a Heliophysics Electrostatic Rapid Transit System (HERTS) mission could be initiated. A notional TDM spacecraft that meets the requirements of such a mission will be showcased in this paper.

Wiegmann, Bruce M.↗

Voltage gradients in solar array cavities as possible breakdown sites in spacecraft-charging-induced discharges

A possible explanation for environmentally-induced discharges on geosynchronous satellites exists in the electric fields formed in the cavities between solar cells - the small gaps formed by the cover slides, solar cells, metallic interconnects and insulating substrate. When exposed to a substorm environment, the cover slides become less negatively charged than the spacecraft ground. Hence, it is possible for metallic surfaces (usually silver mesh) to be at a negative potential in a cavity that has a 'positive' surface above it. If the resultant electric field becomes large enough, then the interconnect could emit electrons (probably by field emission) which could be accelerated to space by the positive voltage on the covers. An experimental study was connected using a small solar array segment in which the interconnect potential was controlled by a power supply while the cover slides were irridated by monoenergetic electrons. It was found that discharges could be triggered when the interconnect potential became at least 500 volts negative with respect to the cover slides. Analytical modeling of satellites exposed to substorm environments indicates that such gradients are possible. Therefore, it appears that this trigger mechanism for discharges is possible. Details of the experiment and modeling study are presented.

Stevens, N. J.↗

Voltage gradients in solar array cavities as possible breakdown sites in spacecraft-charging-induced discharges

A possible explanation for environmentally-induced discharges on geosynchronous satellites exists in the electric fields formed in the cavities between solar cells - the small gaps formed by the cover slides, solar cells, metallic interconnects and insulating substrate. When exposed to a substorm environment, the cover slides become less negatively charged than the spacecraft ground. If the resultant electric field becomes large enough, then the interconnect could emit electrons (probably by field emission) which could be accelerated to space by the positive voltage on the covers. An experimental study was conducted using a small solar array segment in which the interconnect potential was controlled by a power supply while the cover slides were irradiated by monoenergetic electrons. It was found that discharges could be triggered when the interconnect potential became at least 500 volts negative with respect to the cover slides. Analytical modeling of satellites exposed to substorm environments indicates that such gradients are possible. Therefore, it appears that this trigger mechanism for discharges is possible.

Stevens, N. J.↗

Plasma interaction experiment 2 (PIX 2): Laboratory and flight results

The Plasma Interaction Experiments 1 and 2 (PIX 1 and 2) were designed as first steps toward understanding interactions between high-voltage solar arrays and the surrounding plasma. The PIX 2 consisted of an approximately 2000-sq cm array divided into four equal segments. Each of the segments could be biased independently and the current measured separately. In addition to the solar array segments, PIX 2 had a hot-wire-filament electron emitter and a spherical Langmuir probe. The emitter was operated when the array segments were biased positively bove 125 V. Thermal electrons from the emitter aided in balancing the electron currents collected by the array. Laboratory and flight results of PIX 2 are presented. At high positive voltages on the solar array segments, the flight currents were approximately an order of magnitude larger than the ground test currents. This is attributed to the tank walls in the laboratory interfering with the electron currents to the array segments. From previous tests it is known that the tank walls limit the electron currents at high voltages. This was the first verification of the extent of the laboratory tank effect on the plasma coupling current.

Grier, N. T.↗

Susceptibility to polarization type potential induced degradation in commercial bifacial p-PERC PV modules

Potential induced degradation (PID) is a reliability issue affecting photovoltaic (PV) modules, mainly when PV strings operate under high voltages in hot/humid conditions. Polarization-type PID (PID-p) has been known to decrease module performance quickly. PID-p can be reduced or recovered under the light in some cases, but this effect, as expected, would be less pronounced on the rear side of bifacial PV modules receiving lower irradiance. As bifacial PV modules are projected to dominate the PV market within the next 10 years, it is crucial to understand the PID-p issue in bifacial modules better. In this study, we performed indoor PID testing to induce PID-p on 14 commercial bifacial p-PERC modules with three different module constructions from three manufacturers. Here, four rounds (+ve and –ve polarities for front and rear sides) of PID testing are done at 25°C, 54% relative humidity (RH) for 168 h using the aluminum foil method. Each module side (front cell side and back cell side) is tested individually under both negative and positive voltage bias. The results show that the highest degradation of 32% in maximum power (Pmax) at standard test conditions (1000 W/m 2 ) and 51% at low irradiance (200 W/m 2 ) has been observed in some cases. Recovery under sunlight is also done, and outcomes show a near-complete recovery in Pmax. This study presents an extensive experimental methodology and a detailed analysis to systematically and simultaneously/sequentially evaluate multiple construction types of bifacial modules to the PID-p susceptibility and recovery.

14 SOLAR ENERGY↗

Fatigue failure load indicator

An indicator for recording the load at which a fatigue specimen breaks during the last cycle of a fatigue test is described. A load cell is attached to the specimen which is alternately subjected to tension and compression loads. The output of the load cell which is proportional to the load on the specimen is applied to the input of a peak detector. Each time the specimen is subjected to a compression load, means are provided for applying a positive voltage to the rest of the peak detector to reset it. During the last cycle of the tension load the peak detector measures the maximum load on the specimen. Means are provided for disconnecting the load cell from the peak detector when there is a failure in the specimen.

Imig, L. A.↗

Photoelectrochemical fabrication of spectroscopic diffraction gratings

Photoelectrochemical etching was demonstrated as a means of fabricating a variety of periodic structures in semiconductors. The semiconductor is used as an electrode in an electrochemical cell, and is in contact with a liquid electrolyte. When the crystal is held at a positive voltage and illuminated, etching occurs in only the illuminated regions to a depth proportional to the illumination intensity and exposure time. In Phase 1, it was determined that diffraction gratings could be produced in gallium arsenide crystals by this method, using either a scanned focused laser beam or by uniform illumination of a ruling mask defined in metal or photoresist on the crystal surface. The latter approach was determined to produce V-grooves if the mask is oriented along certain crystallographic directions. These V-grooves were produced with an exceedingly smooth crystal morphology due to the highly controllable nature of the process and the mild electrolytes involved. The results form the basis for photoelectrochemical fabrication of deep, low pitch Eschelle gratings for use in high orders in NASA spectrographic instrumentation such as the Space Telescope Imaging Spectrograph.

Rauh, R. David↗

Using a Commercial Ethernet PHY Device in a Radiation Environment

This work involved placing a commercial Ethernet PHY on its own power boundary, with limited current supply, and providing detection methods to determine when the device is not operating and when it needs either a reset or power-cycle. The device must be radiation-tested and free of destructive latchup errors. The commercial Ethernet PHY's own power boundary must be supplied by a current-limited power regulator that must have an enable (for power cycling), and its maximum power output must not exceed the PHY's input requirements, thus preventing damage to the device. A regulator with configurable output limits and short-circuit protection (such as the RHFL4913, rad hard positive voltage regulator family) is ideal. This will prevent a catastrophic failure due to radiation (such as a short between the commercial device's power and ground) from taking down the board's main power. Logic provided on the board will detect errors in the PHY. An FPGA (field-programmable gate array) with embedded Ethernet MAC (Media Access Control) will work well. The error detection includes monitoring the PHY's interrupt line, and the status of the Ethernet's switched power. When the PHY is determined to be non-functional, the logic device resets the PHY, which will often clear radiation induced errors. If this doesn't work, the logic device power-cycles the FPGA by toggling the regulator's enable input. This should clear almost all radiation induced errors provided the device is not latched up.

Parks, Jeremy↗

Electric Sail Propulsion for Exploring Nearby Interstellar Space

An Electric Sail is a revolutionary propellant-less propulsion system that is ideal for deep space missions to the outer planets, the Heliopause, and beyond. It is revolutionary in that it uses momentum exchange with the hypersonic solar wind to propel a spacecraft within the heliosphere. The momentum exchange is affected by the deflection of charged solar wind particles by an array of electrically biased wires that extend outward up to 30 km from a slowly rotating spacecraft. A high-voltage, positive bias on the wires, which are oriented normal to the solar wind flow, deflects the streaming protons, resulting in a reaction force on the wires that is also directed radially away from the sun. Over a period of months, this small force can accelerate the spacecraft to enormous speeds-on the order of 100-150 km/s (approximately 20 to 30 AU/yr). Unlike solar sails, Electric Sails do not rely on a fixed area to produce thrust. In fact, as they move away from the Sun and solar wind pressure decreases, the area for solar proton momentum transfer becomes larger, increasing system efficiency. As a result, thrust decreases at ≈1/r**(7/6) instead of the ≈1/r**2 rate typical for solar sails. The net effect is that an increased radial range of operation, together with increased thrust, both contribute to higher velocities and shorter total trip times to distant destinations. The MSFC Advanced Concepts Office (ACO) was awarded a Phase II NASA Innovative Advanced Concepts (NIAC) study to mature the technology for possible future demonstration and implementation. Preliminary results indicate that the physics of the system is viable and that a spacecraft propelled by an Electric Sail could reach the Heliopause in less than 15 years - and could be developed within a decade.

Johnson, Les↗

A Feasibility Study to Control Airfoil Shape Using THUNDER

The objective of this study was to assess the capabilities of a new out-of-plane displacement piezoelectric actuator called thin-layer composite-unimorph ferroelectric driver and sensor (THUNDER) to alter the upper surface geometry of a subscale airfoil to enhance performance under aerodynamic loading. Sixty test conditions, consisting of combinations of five angles of attack, four dc applied voltages, and three tunnel velocities, were studied in a tabletop wind tunnel. Results indicated that larger magnitudes of applied voltage produced larger wafer displacements. Wind-off displacements were also consistently larger than wind-on. Higher velocities produced larger displacements than lower velocities because of increased upper surface suction. Increased suction also resulted in larger displacements at higher angles of attack. Creep and hysteresis of the wafer, which were identified at each test condition, contributed to larger negative displacements for all negative applied voltages and larger positive displacements for the smaller positive applied voltage (+102 V). An elastic membrane used to hold the wafer to the upper surface hindered displacements at the larger positive applied voltage (+170 V). Both creep and hysteresis appeared bounded based on the analysis of several displacement cycles. These results show that THUNDER can be used to alter the camber of a small airfoil under aerodynamic loads.

Pinkerton, Jennifer L.↗