Effects of impurities on the plastic flow of molybdenum crystals.
Impurities effect on plastic flow stress and activation volume as functions of strain, strain rate and temperature in molybdenum crystals
Brotzen, F. R.↗
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Plastic deformation of molybdenum-rhenium alloy crystals
Plastic deformation of Mo-Re single crystals produced by electron beam zone refining, investigating lattice frictional stress, activation volume temperature variation, etc
Brotzen, F. R.↗
Internal motion and its pressure dependence in FeSiF6+6/H2O/.
Both wideline and pulsed NMR techniques were used to examine the internal motion in FeSiF6+6(H2O). Corrections of second moments for bulk paramagnetic effects were essential. At room temperature and pressure, the fluorine-fluorine contribution to the 19F second moment is 0.38 (plus or minus 0.06) G2, and indicates rapid orientation of the SiF6(--) group. Analysis of the second moment within the transition region allows calculation of an activation volume which is 2.4 (plus or minus 0.4) % of the molar volume. The application of pressure slows the internal motion such that the rigid lattice values of the 19F second moment are obtained above 50 kbar.
Vaughan, R. W.↗
Lightning activity observed in upper and lower portions of storms and its relationship to storm structure from VHF mapping and Doppler radar
Space time mapping of very high frequencies (VHF) sources reveals lightning processes for cloud to ground (CG) and for large intracloud (IC) flashes are confined to an altitude below about 10 km and closely associated with the central high reflectivity region of a storm. Another class of IC flashes was identified that produces a splattering of small sources within the main electrically active volume of a storm and also within a large divergent wind canopy at the top of a storm. There is no apparent temporal association between the small high altitude IC flashes occurring almost continuously and the large IC and CG flashes sporadically occurring in the lower portions of storms.
Taylor, W. L.↗
Lightning activity and severe storm structure
Space-time mapping of VHF sources from four severe storms on June 19, 1980 reveals that lightning processes for cloud-to-ground (CG) and large intracloud (IC) flashes are confined to an altitude below about 10 km and closely associated with the central regions of high reflectivity. Another class of IC flashes produces a splattering of sources within the storms' main electrically active volumes and also within the large divergent wind canopy aloft. There is no apparent temporal association between the small high altitude IC flashes that occur almost continuously and the large IC and CG flashes that occur sporadically in the lower portions of storms.
Taylor, W. L.↗
A model for the kinetics of a solar-pumped long path laser experiment
A kinetic model for a solar-simulator pumped iodine laser system is developed and compared to an experiment in which the solar simulator output is dispersed over a large active volume (150 cu cm) with low simulator light intensity (approx. 200 solar constants). A trace foreign gas which quenches the upper level is introduced into the model. Furthermore, a constant representing optical absorption of the stimulated emission is introduced, in addition to a constant representing the scattering at each of the mirrors, via the optical cavity time constant. The non-uniform heating of the gas is treated as well as the pressure change as a function of time within the cavity. With these new phenomena introduced into the kinetic model, a best reasonable fit to the experimental data is found by adjusting the reaction rate coefficients within the range of known uncertainty by numerical methods giving a new bound within this range of uncertainty. The experimental parameters modeled are the lasing time, laser pulse energy, and time to laser threshold.
Stock, L. V.↗
Adiabaticity and viscosity in deep mantle convection
A study has been conducted of steady convection with adiabatic and viscous heating for variable viscosity in the Boussinesq limit using the mean-field theory. A strong nonlinear coupling is found between the thermodynamic constants governing adiabatic heating and the rheological parameters. The range of rheological values for which adiabaticity would occur throughout the mantle has been established. Too large an activation volume, greater than 6 cu cm/mol for the cases examined, would produce unreasonably high temperature at the bottom of the mantle (greater than 6000 K) and superadiabatic gradients, especially in the lower mantle. Radiogenic heating plays a profound role in controlling dynamically mantle temperatures. Present values for the averaged mantle heat production would yield objectionably high temperatures in the lower mantle.
Quareni, F.↗
Synthesis of phthalocyanine doped sol-gel materials
The synthesis of sol-gel silica materials doped with three different types of metallophthalocyanines has been studied. Homogeneous materials of good optical quality were prepared and the first optical limiting measurements of dyes in sol-gel hosts were carried out. The properties of these solid state limiters are similar to limiters based on phthalocyanine (Pc) in solution. Sol-gel silica materials containing copper, tin and germanium phthalocyanines were investigated. The initial step in all cases was to prepare silica sols by the sonogel method using tetramethoxy silane (TMOS), HCl and distilled water. Thereafter, the synthesis depended upon the specific Pc and its solubility characteristics. Copper phthalocyanine tetrasulfonic acid tetra sodium salt (CuPc4S) is soluble in water and various doping levels (1 x 10 (exp -4) M to 1 x 10 (exp -5) M) were added to the sol. The group IV Pc's, SnPc(OSi(n-hexyl)3)2 and GePc(OSi(n-hexyl)3)2, are insoluble in water and the process was changed accordingly. In these cases, the compounds were dissolved in THF and then added to the sol. The Pc concentration in the sol was 2 x 10(exp -5)M. The samples were then aged and dried in the standard method of making xerogel monoliths. Comparative nanosecond optical limiting experiments were performed on silica xerogels that were doped with the different metallophthalocyanines. The ratio of the net excited state absorption cross section (sigma(sub e)) to the ground state cross section (sigma(sub g)) is an important figure of merit that is used to characterize these materials. By this standard the SnPc sample exhibits the best limiting for the Pc doped sol-gel materials. Its cross section ratio of 19 compares favorably with the value of 22 that was measured in toluene. The GePc materials appear to not be as useful as those containing SnPc. The GePc doped solids exhibit a higher onset energy (2.5 mj and lower cross section ratio, 7. The CuPc4S sol-gel material has a still lower cross section ratio, 4, however, the tetrasulfonate groups make the dye soluble in water which greatly facilitates its incorporation into the sol-gel matrix. The nonlinear transmission of CuPc4S in a pH 2 buffer solution and in a silica xerogel were compared. It is evident that the CuPc4S preserves its optical limiting behavior in the sol-gel matrix, indicating that the fundamental excited state absorption process is essentially the same for a molecule in solution or in the solid state. Although the spectroscopic details of energy level lifetimes are unknown, the significance is that passive optical limiting has been achieved in the solid state via incorporation of a dye into an inorganic host. The only compromise occurs at the extremely high energy regime where photobleaching is observed. This is a result of the limited mobility of the dye molecules in the solid silica host relative to a liquid host. The effects of photodegradation in the xerogel are additive, whereas the solution provides a supply of fresh molecules that are free to enter the active volume between pulses.
Dunn, Bruce↗
Microliter-sized ionization device and method
A microliter-sized metastable ionization device with a cavity, a sample gas inlet, a corona gas inlet and a gas outlet. A first electrode has a hollow and disposed in the cavity and is in fluid communication with the sample gas inlet. A second electrode is in fluid communication with the corona gas inlet and is disposed around the first electrode adjacent the hollow end thereof. A gap forming means forms a corona gap between the first and second electrodes. A first power supply is connected to the first electrode and the second power supply is connected to the second electrode for generating a corona discharge across the corona gap. A collector has a hollow end portion disposed in the cavity which is in fluid communications with the gas outlet for the outgassing and detection of ionized gases. The first electrode can be a tubular member aligned concentrically with a cylindrical second electrode. The gap forming means can be in annular disc projecting radially inwardly from the cylindrical second electrode. The collector can have a tubular opening aligned coaxially with the first electrode and has an end face spaced a short distance from an end face of the first electrode forming a small active volume therebetween for the generation and detection of small quantities of trace analytes.
Cohen, Martin J.↗
Carbon Nanotubes as Resonators for RF Spectrum Analyzers
Electromechanical resonators of a proposed type would comprise single carbon nanotubes suspended between electrodes (see Figure 1). Depending on the nanotube length, diameter, and tension, these devices will resonate at frequencies in a range from megahertz through gigahertz. Like the carbon-nanotube resonators described in the preceding article, these devices will exhibit high quality factors (Q values), will be compatible with integration with electronic circuits, and, unlike similar devices made from silicone and silicone carbide, will have tunable resonant frequencies as high as several GHz. An efficient electromechanical transduction method for the carbon nanotube resonators is provided by the previously observed variation of carbon nanotube length with charge injection. It was found that injection of electrons or holes, respectively, lengthens or shortens carbon nanotubes, by amounts of the order of a percent at bias levels of a few volts. The charge-dependent length change also enables a simple and direct means of tuning the resonant frequency by varying the DC bias and hence the tension along the tube, much like tuning a guitar string. In its basic form, the invention is a tunable high-Q resonator based on a suspended carbon nanotube bridge with attached electrodes (see Figure 1). An applied DC bias controls the tension and thus the frequency of resonance. If one were to superimpose a radio-frequency (RF) bias on the DC bias, then the resulting rapid variation in tension or length would set the tube into vibration. If, on the other hand, the carbon nanotube were to be set into vibration by interaction between an incident RF electric field and electric charges in the nanotube, then the vibration would give rise to an RF signal output that is proportional to the RF amplitude at the resonance frequency. Because the transduction mechanism is extremely sensitive and the active volume is only a few nanometers in diameter, this device is not well suited for use as a microwave power device. Instead, this carbon nanotube mechanical resonator would be useful primarily as part of a highly precise, sensitive, frequency-selective detector. An array of such devices featuring nanotubes of different lengths (and thus different frequencies) could be made to operate as a highspeed spectrum analyzer (see Figure 2)
Hunt, Brian↗
Space User Visibility Benefits of the Multi-GNSS Space Service Volume: An Internationally-Coordinated, Global and Mission-Specific Analysis
The number and scope of Global Navigation Satellite System (GNSS)-based space applications has grown significantly since the first GNSS space receiver was flown in the early 1980's. The vast majority of GNSS space users operate in Low-Earth Orbit (LEO), where the use of GNSS receivers has become routine. However, the use of GNSS has expanded to other orbit regimes like Geostationary Orbits (GEO) and High Eccentric Orbits (HEO) but has been very limited due to the challenges involved. The major challenges for such types of orbits including much weaker signals, reduced geometric diversity, and limited signal availability. In any case, considering the recent development of multiple GNSS constellations and ongoing upgrades to existing constellations, GNSS signal availability will improve significantly. As a result, this expanded multi-GNSS signal capability will enable improved on-orbit navigation performance and will also allow the development of new mission concepts. High altitude space users will especially benefit from this evolution, which will provide GNSS signals to challenging regimes well beyond Low Earth Orbit. These benefits will only be realised, however, if additional signals are designed to be interoperable, are clearly documented and supported. In order to enhance the overall GNSS performance for spacecraft's in regimes from LEO, GEO to HEO and beyond, all Satellite Navigation constellation providers and regional augmentation system providers are working together through the United Nations International Committee on GNSS (ICG) forum to establish an interoperable GNSS Space Service Volume (SSV) for the benefit of all GNSS space users. This paper provides an overview of the technical work and in particular the simulations, performance analysis and discussions of the outcomes and results obtained by the UN ICG Working Group-B in the context of the GNSS Space Service Volume activities, which were supported by all GNSS service providers.
systems↗
Catalogue of Solar Activity During 1960-1963, Volume V
Catalog on solar activity from 1960 to 1963
GEOMAGNETIC STORM↗
Extravehicular activities limitations study. Volume 2: Establishment of physiological and performance criteria for EVA gloves
One of the major probelms faced in Extravehicular Activity (EVA) glove development has been the absence of concise and reliable methods to measure the effects of EVA gloves on human hand capabilities. This report describes the development of a standardized set of tests designed to assess EVA-gloved hand capabilities in six measurement domains: Range of Motion, Strength, Tactile Perception, Dexterity, Fatigue, and Comfort. Based on an assessment of general human hand functioning and EVA task requirements several tests within each measurement domain were developed to provide a comprehensive evaluation. All tests were designed to be conducted in a glove box with the bare hand as a baseline and the EVA glove at operating pressure. A test program was conducted to evaluate the tests using a representative EVA glove. Eleven test subjects participated in a repeated-measures design. The report presents the results of the tests in each capability domain.
Ohara, John M.↗
Active flutter control for flexible vehicles, volume 1
An active flutter control methodology based on linear quadratic gaussian theory and its application to the control of a super critical wing is presented. Results of control surface and sensor position optimization are discussed. Both frequency response matching and residualization used to obtain practical flutter controllers are examined. The development of algorithms and computer programs for flutter modeling and active control design procedures is reported.
Mahesh, J. K.↗
United States data collection activities and requirements, volume 1
The potential market for a data collection system was investigated to determine whether the user needs would be sufficient to support a satellite relay data collection system design. The activities of 107,407 data collections stations were studied to determine user needs in agriculture, climatology, environmental monitoring, forestry, geology, hydrology, meteorology, and oceanography. Descriptions of 50 distinct data collections networks are described and used to form the user data base. The computer program used to analyze the station data base is discussed, and results of the analysis are presented in maps and graphs. Information format and coding is described in the appendix.
Hrin, S.↗
Microwave remote sensing: Active and passive. Volume 1 - Microwave remote sensing fundamentals and radiometry
The three components of microwave remote sensing (sensor-scene interaction, sensor design, and measurement techniques), and the applications to geoscience are examined. The history of active and passive microwave sensing is reviewed, along with fundamental principles of electromagnetic wave propagation, antennas, and microwave interaction with atmospheric constituents. Radiometric concepts are reviewed, particularly for measurement problems for atmospheric and terrestrial sources of natural radiation. Particular attention is given to the emission by atmospheric gases, clouds, and rain as described by the radiative transfer function. Finally, the operation and performance characteristics of radiometer receivers are discussed, particularly for measurement precision, calibration techniques, and imaging considerations.
Ulaby, F. T.↗
Evaluation of a semi-active gravity gradient system. Volume I - Technical summary
Semi-active gravity gradient system for attitude control of earth oriented spacecraft
GRAVITY GRADIENT SATELLITE↗
Microwave remote sensing: Active and passive. Volume 3 - From theory to applications
Aspects of volume scattering and emission theory are discussed, taking into account a weakly scattering medium, the Born approximation, first-order renormalization, the radiative transfer method, and the matrix-doubling method. Other topics explored are related to scatterometers and probing systems, the passive microwave sensing of the atmosphere, the passive microwave sensing of the ocean, the passive microwave sensing of land, the active microwave sensing of land, and radar remote sensing applications. Attention is given to inversion techniques, atmospheric attenuation and emission, a temperature profile retrieval from ground-based observations, mapping rainfall rates, the apparent temperature of the sea, the emission behavior of bare soil surfaces, the emission behavior of vegetation canopies, the emission behavior of snow, wind-vector radar scatterometry, radar measurements of sea ice, and the back-scattering behavior of cultural vegetation canopies.
Ulaby, F. T.↗