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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Changes in the High-latitude Ocean as Possible Causes of Atmospheric CO2 Variations

Measurements on air enclosed in old polar ice have indicated that the atmospheric CO2 concentration was ca. 50 to 70 ppm lower in late glacial times than during the Holocene. Similar measurements performed on samples from a Greenland ice core, dating ca. 30,000 to 40,000 B.P., and have yielded evidence of several CO2 oscillations with an amplitude of ca. 50 ppm. Each change lasted on the order of a few centuries. A mechanism by which circulation changes in the high-latitude ocean could lead to rapid variations in atmospheric CO2 is proposed. In the Antarctic Ocean a slowing down of the vertical mixing would imply a smaller upward flux of sigma CO2 and nutrients. Assuming constant productivity, sigma CO2 and nutrients would be more completely used which would imply lower CO2 in these high-latitude surface waters. In areas with a warm surface, a slowing down of the circulation would not have a direct impact on CO2 because productivity would automatically decrease by the same factor as the upwelling rate of nutrients. Studies with a simple box model of the ocean-atmosphere system suggest that a suddent decrease by a factor of 2 of the water exchange between the surface and deep sea in high latitudes could lead to a CO2 decrease of ca. 40 to 50 ppm with a time constant of ca. 200 years. Deep-sea sediment studies indicate rapid changes in the high-latitude surface conditions of the North Atlantic and the Antarctic Oceans at the end of the last glaciation. Studies of carbon isotope ratios should help ascertain whether this proposed mechanism was indeed responsible for the CO2 variation.

Siegenthaler, U.↗
NASA NTRS1997

The effects of atmospheric [CO2] on carbon isotope fractionation and magnesium incorporation into biogenic marine calcite

The influences of atmospheric carbon dioxide on the fractionation of carbon isotopes and the magnesium incorporation into biogenic marine calcite were investigated using samples of the calcareous alga Amphiroa and benthic foraminifer Sorites grown in the Biosphere 2 Ocean system under variable atmospheric CO2 concentrations (approximately 500 to 1200 ppm). Carbon isotope fractionation was studied in both the organic matter and the skeletal carbonate. Magnesium analysis was to be performed on the carbonate removed during decalcification. These data have not been collected due to technical problems. Carbon isotope data from Amphiroa yields a linear relation between [CO2] and Delta(sup 13)C(sub Corg)values suggesting that the fractionation of carbon isotopes during photosynthesis is positively correlated with atmospheric [CO2]. [CO2] and Delta(sup 13)C(sub Corg) values for Sorites produce a relation that is best described by a hyperbolic function where Delta(sup 13)C(sub Corg) values increase between 300 and 700 ppm and decrease from 700 to 1200 ppm. Further investigation of this relation and Sorites physiology is needed.

Vieira, Veronica↗
NASA NTRS2012

A 2-Micron Pulsed Integrated Path Differential Absorption Lidar Development For Atmospheric CO2 Concentration Measurements

A 2-micron pulsed, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric CO2 concentration measurements via direct detection method is being developed at NASA Langley Research Center. This instrument will provide an alternate approach to measure atmospheric CO2 concentrations with significant advantages. A high energy pulsed approach provides high-precision measurement capability by having high signal-to-noise level and unambiguously eliminates the contamination from aerosols and clouds that can bias the IPDA measurement.

Yu, Jirong↗
NASA NTRS2014

2-Micron Pulsed Direct Detection IPDA Lidar for Atmospheric CO2 Measurement

A 2-micron high energy, pulsed Integrated Path Differential Absorption (IPDA) lidar has been developed for atmospheric CO2 measurements. Development of this lidar heavily leverages the 2-micron laser technologies developed in LaRC over the last decade. The high pulse energy, direct detection lidar operating at CO2 2-micron absorption band provides an alternate approach to measure CO2 concentrations. This new 2-micron pulsed IPDA lidar has been flown in spring of this year for total ten flights with 27 flight hours. It is able to make measurements of the total amount of atmospheric CO2 from the aircraft to the ground or cloud. It is expected to provide high-precision measurement capability by unambiguously eliminating contamination from aerosols and clouds that can bias the IPDA measurement.

Yu, Jirong↗
NASA NTRS2002

An Assessment of the Ability of Potential Satellite Instruments to Resolve Spatial and Temporal Variability of Atmospheric CO2

Sufficiently precise satellite observations with adequate spatial and temporal resolution would substantially increase our knowledge of the atmospheric CO2 distribution and would undoubtedly lead to reduced uncertainty in estimates of the global carbon budget. An overview of possible strategies for measuring CO2 from space will be presented, including IR and nearby measurements, active sensors and broad band and narrow band passive sensors. The ability of potential satellite instruments with a variety of orbits, horizontal resolution and vertical weighting functions to capture the variation in atmospheric CO2 mixing ratios will be illustrated using a combination of surface data, aircraft data and model results.

Andrews, A.↗
NASA NTRS2005

Modeling Atmospheric CO2 Processes to Constrain the Missing Sink

We report on a NASA supported modeling effort to reduce uncertainty in carbon cycle processes that create the so-called missing sink of atmospheric CO2. Our overall objective is to improve characterization of CO2 source/sink processes globally with improved formulations for atmospheric transport, terrestrial uptake and release, biomass and fossil fuel burning, and observational data analysis. The motivation for this study follows from the perspective that progress in determining CO2 sources and sinks beyond the current state of the art will rely on utilization of more extensive and intensive CO2 and related observations including those from satellite remote sensing. The major components of this effort are: 1) Continued development of the chemistry and transport model using analyzed meteorological fields from the Goddard Global Modeling and Assimilation Office, with comparison to real time data in both forward and inverse modes; 2) An advanced biosphere model, constrained by remote sensing data, coupled to the global transport model to produce distributions of CO2 fluxes and concentrations that are consistent with actual meteorological variability; 3) Improved remote sensing estimates for biomass burning emission fluxes to better characterize interannual variability in the atmospheric CO2 budget and to better constrain the land use change source; 4) Evaluating the impact of temporally resolved fossil fuel emission distributions on atmospheric CO2 gradients and variability. 5) Testing the impact of existing and planned remote sensing data sources (e.g., AIRS, MODIS, OCO) on inference of CO2 sources and sinks, and use the model to help establish measurement requirements for future remote sensing instruments. The results will help to prepare for the use of OCO and other satellite data in a multi-disciplinary carbon data assimilation system for analysis and prediction of carbon cycle changes and carbodclimate interactions.

Kawa, S. R.↗
NASA NTRS2006

A Test of Sensitivity to Convective Transport in a Global Atmospheric CO2 Simulation

Two approximations to convective transport have been implemented in an offline chemistry transport model (CTM) to explore the impact on calculated atmospheric CO2 distributions. GlobalCO2 in the year 2000 is simulated using theCTM driven by assimilated meteorological fields from the NASA s Goddard Earth Observation System Data Assimilation System, Version 4 (GEOS-4). The model simulates atmospheric CO2 by adopting the same CO2 emission inventory and dynamical modules as described in Kawa et al. (convective transport scheme denoted as Conv1). Conv1 approximates the convective transport by using the bulk convective mass fluxes to redistribute trace gases. The alternate approximation, Conv2, partitions fluxes into updraft and downdraft, as well as into entrainment and detrainment, and has potential to yield a more realistic simulation of vertical redistribution through deep convection. Replacing Conv1 by Conv2 results in an overestimate of CO2 over biospheric sink regions. The largest discrepancies result in a CO2 difference of about 7.8 ppm in the July NH boreal forest, which is about 30% of the CO2 seasonality for that area. These differences are compared to those produced by emission scenario variations constrained by the framework of Intergovernmental Panel on Climate Change (IPCC) to account for possible land use change and residual terrestrial CO2 sink. It is shown that the overestimated CO2 driven by Conv2 can be offset by introducing these supplemental emissions.

Bian, H.↗
NASA NTRS2018

Measurement of Atmospheric CO2 Column Concentrations to Cloud Tops With a Pulsed Multi-Wavelength Airborne Lidar

We have measured the column-averaged atmospheric CO2 mixing ratio to a variety of cloud tops by using an airborne pulsed multi-wavelength integrated-path differential absorption (IPDA) lidar. Airborne measurements were made at altitudes up to 13 km during the 2011, 2013 and 2014 NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) science campaigns flown in the United States West and Midwest and were compared to those from an in situ sensor. Analysis of the lidar backscatter profiles shows the average cloud top reflectance was approx. 5% for the CO2 measurement at 1572.335 nm except to cirrus clouds, which had lower reflectance. The energies for 1 micro-s wide laser pulses reflected from cloud tops were sufficient to allow clear identification of CO2 absorption line shape and then to allow retrievals of atmospheric column CO2 from the aircraft to cloud tops more than 90% of the time. Retrievals from the CO2 measurements to cloud tops had minimal bias but larger standard deviations when compared to those made to the ground, depending on cloud top roughness and reflectance. The measurements show this new capability helps resolve CO2 horizontal and vertical gradients in the atmosphere. When used with nearby full-column measurements to ground, the CO2 measurements to cloud tops can be used to estimate the partial-column CO2 concentration below clouds, which should lead to better estimates of surface carbon sources and sinks. This additional capability of the range-resolved CO2 IPDA lidar technique provides a new benefit for studying the carbon cycle in future airborne and space-based CO2 missions.

atmospheric↗
NASA NTRS1987

Climate warming due to increasing atmospheric CO2 - Simulations with a multilayer coupled atmosphere-ocean seasonal energy balance model

The transient response of the climate to increasing CO2 is studied using a modified version of the multilayer energy balance model of Peng et al. (1982). The main characteristics of the model are described. Latitudinal and seasonal distributions of planetary albedo, latitude-time distributions of zonal mean temperatures, and latitudinal distributions of evaporation, water vapor transport, and snow cover generated from the model and derived from actual observations are analyzed and compared. It is observed that in response to an atmospheric doubling of CO2, the model reaches within 1/e of the equilibrium response of global mean surface temperature in 9-35 years for the probable range of vertical heat diffusivity in the ocean. For CO2 increases projected by the National Research Council (1983), the model's transient response in annually and globally averaged surface temperatures is 60-75 percent of the corresponding equilibrium response, and the disequilibrium increases with increasing heat diffusivity of the ocean.

Li, Peng↗
NASA NTRS1985

The relationship of global green leaf biomass to atmospheric CO2 concentrations

Advanced very high resolution radiometer data from NOAA's polar orbiting meteorological satellite have been obtained globally for a 21 month period, processed to produce a green leaf biomass spectral vegetative index for the entire terrestrial surface by month, zonally aggregated by latitude, and compared to atmospheric CO2 concentrations from observing stations. A strong inverse association was found between the monthly Pt. Barrow CO2 concentrations and the vegetation index measurements from 50 deg N to 80 deg N, between the monthly Mauna Loa CO2 concentrations and the vegetation index measurements from 10 deg N to 30 deg N, 10 deg N to 80 deg N, and the global total, and between the globally averaged CO2 concentrations and the globally averaged vegetation index. No relationships between atmospheric CO2 concentrations and the vegetative index measurements from any latitude zone or combinations of zones were found for the South Pole station.

Tucker, C. J.↗
NASA NTRS2008

Development and Evaluation of a High Sensitivity DIAL System for Profiling Atmospheric CO2

A ground-based 2-micron Differential Absorption Lidar (DIAL) CO2 profiling system for atmospheric boundary layer studies and validation of space-based CO2 sensors is being developed and tested at NASA Langley Research Center as part of the NASA Instrument Incubator Program. To capture the variability of CO2 in the lower troposphere a precision of 1-2 ppm of CO2 (less than 0.5%) with 0.5 to 1 km vertical resolution from near surface to free troposphere (4-5 km) is one of the goals of this program. In addition, a 1% (3 ppm) absolute accuracy with a 1 km resolution over 0.5 km to free troposphere (4-5 km) is also a goal of the program. This DIAL system leverages 2-micron laser technology developed under NASA's Laser Risk Reduction Program (LRRP) and other NASA programs to develop new solid-state laser technology that provides high pulse energy, tunable, wavelength-stabilized, and double-pulsed lasers that are operable over pre-selected temperature insensitive strong CO2 absorption lines suitable for profiling of lower tropospheric CO2. It also incorporates new high quantum efficiency, high gain, and relatively low noise phototransistors, and a new receiver/signal processor system to achieve high precision DIAL measurements. This presentation describes the capabilities of this system for atmospheric CO2 and aerosol profiling. Examples of atmospheric measurements in the lidar and DIAL mode will be presented.

Ismail, Syed↗
NASA NTRS2010

Carbon and Oxygen Stable Isotope Measurements of Martian Atmospheric CO2 by the Phoenix Lander

Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars [1]. The isotopic composition of the martian atmosphere has been measured using a number of different methods (Table 1), however a precise value (<1%) has yet to be achieved. Given the elevated Delta(sup 13)C values measured in carbonates in martian meteorites [2-4] it has been proposed that the martian atmosphere was enriched in 13C [8]. This was supported by measurements of trapped CO2 gas in EETA 79001[2] which showed elevated Delta(sup 13)C values (Table 1). More recently, Earth-based spectroscopic measurements of the martian atmosphere have measured the martian CO2 to be depleted in C-13 relative to CO2 in the terrestrial atmosphere[ 7, 9-11]. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Mars Phoenix Lander [12] included a magnetic-sector mass spectrometer (EGA) [13] which had the goal of measuring the isotopic composition of martian atmospheric CO2 to within 0.5%. The mass spectrometer is a miniature instrument intended to measure both the martian atmosphere as well as gases evolved from heating martian soils.

Niles, Paul B.↗
DOE OSTI2019

Antarctic Sea Ice Expansion, Driven by Internal Variability, in the Presence of Increasing Atmospheric CO2

A number of physically-based hypotheses have been proposed to explain the surprising expansion of Antarctic sea ice area (SIA) over the satellite era (1979 to 2015). Here, we use a fully-coupled state-of-the-art global climate model to show that internal variability alone can produce such multidecadal periods of Antarctic SIA expansion even as atmospheric CO2 increases at observed rates and the planet warms. When our model is started from a relatively warm Southern Ocean state, Antarctic SIA sometimes (in one of three ensemble members) expands over multidecadal time scales at a rate comparable to that over the satellite era. SIA expansion occurs concurrently with rising atmospheric CO2 and warming global surface temperatures, and SIA trends by region and sector resemble those over the satellite era. Our results suggest that internal variability, particularly on long time scales over the Southern Ocean, may suffice to explain Antarctic SIA expansion over the satellite era.

Singh, Hansi AK↗
NASA NTRS2012

Mars Atmospheric CO2 Condensation Above the North and South Poles as Revealed by Radio Occultation, Climate Sounder, and Laser Ranging Observations

We study the condensation of CO2 in Mars atmosphere using temperature profilesretrieved from radio occultation measurements from Mars Global Surveyor (MGS) as wellas the climate sounding instrument onboard the Mars Reconnaissance Orbiter (MRO),and detection of reflective clouds by the MGS Mars Orbiter Laser Altimeter (MOLA). Wefind 11 events in 1999 where MGS temperature profiles indicate CO2 condensation andMOLA simultaneously detects reflective clouds. We thus provide causal evidence thatMOLA non-ground returns are associated with CO2 condensation, which strongly indicatestheir nature being CO2 clouds. The MGS and MRO temperature profiles together revealthe seasonal expansion and shrinking of the area and the vertical extent of atmosphericsaturation. The occurrence rate of atmospheric saturation is maximized at high latitudes inthe middle of winter. The atmospheric saturation in the northern polar region exhibits moreintense seasonal variation than in the southern polar region. In particular, a shrinking ofsaturation area and thickness from LS 270 to 300 in 2007 is found; this is probablyrelated to a planet-encircling dust storm. Furthermore, we integrate the condensation areaand the condensation occurrence rate to estimate cumulative masses of CO2 condensatesdeposited onto the northern and southern seasonal polar caps. The precipitation flux isapproximated by the particle settling flux which is estimated using the impulse responses ofMOLA filter channels. With our approach, the total atmospheric condensation mass canbe estimated from these observational data sets with average particle size as the onlyfree parameter. By comparison with the seasonal polar cap masses inferred from thetime-varying gravity of Mars, our estimates indicate that the average condensate particleradius is 822 mm in the northern hemisphere and 413 mm in the southern hemisphere.Our multi-instrument data analysis provides new constraints on modeling the global climateof Mars.

MOLA↗
NASA NTRS1983

Three-Dimensional Tracer Model Study of Atmospheric CO2 - Response to Seasonal Exchanges with the Terrestrial Biosphere

A three-dimensional tracer transport model is used to investigate the annual cycle of atmospheric CO2 concentration produced by seasonal exchanges with the terrestrial biosphere. The tracer model uses winds generated by a global general circulation model to advect and convect CO2; no explicit diffusion coefficients are employed. A biospheric exchange function constructed from a map of net primary productivity, and Azevedo's (1982) seasonality of CO2 uptake and release closely simulates the annual cycles at coastal stations. The results show that zonal homogeneity in surface CO2 concentrations can never be achieved at mid-latitudes where the time scale for zonal mixing is longer than the time scale for biospheric exchange. Analysis of the zonal mean balance in the lower troposphere reveals that atmospheric transport processes may alter the CO2 response to local biospheric exchanges by 50% or more. Hence year-to-year variation of the annual CO2 cycle may result from the natural variability of the atmospheric circulation as well as from changes in the sources and sinks.

Fung, I.↗
NASA NTRS1999

Effect of Elevated Atmospheric CO2 and Temperature on Leaf Optical Properties and Chlorophyll Content in Acer saccharum (Marsh.)

Elevated atmospheric CO2 pressure and numerous causes of plant stress often result in decreased leaf chlorophyll contents and thus would be expected to alter leaf optical properties. Hypotheses that elevated carbon dioxide pressure and air temperature would alter leaf optical properties were tested for sugar maple (Acer saccharum Marsh.) in the middle of its fourth growing season under treatment. The saplings had been growing since 1994 in open-top chambers at Oak Ridge, Tennessee under the following treatments: 1) Ambient CO2 pressure and air temperature (control); 2) CO2 pressure approximately 30 Pa above ambient; 3) Air temperatures 3 C above ambient; 4) Elevated CO2 and air temperature. Spectral reflectance, transmittance, and absorptance in the visible spectrum (400-720 nm) did not change significantly (rho = 0.05) in response to any treatment compared with control values. Although reflectance, transmittance, and absorptance at 700 nm correlated strongly with leaf chlorophyll content, chlorophyll content was not altered significantly by the treatments. The lack of treatment effects on pigmentation explained the non-significant change in optical properties in the visible spectrum. Optical properties in the near-infrared (721-850 nm) were similarly unresponsive to treatment with the exception of an increased absorptance in leaves that developed under elevated air temperature alone. This response could not be explained by the data, but might have resulted from effects of air temperature on leaf internal structure. Results indicated no significant potential for detecting leaf optical responses to elevated CO2 or temperature by the remote sensing of reflected radiation in the 400-850 nm spectrum.

Carter, Gregory A.↗