Finite-mass helium atoms. ii - 2 super 3 p state.
Two triplet P states of helium isoelectronic series investigated via 50-term variational wave functions with isotopic shift determinations
HELIUM ATOM↗
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Leak rate measurements for satellite subsystems and residual gas analysis during space environment tests
The measuring and evaluation procedure for the determination of leak rates of satellite subsystems with a quadrupole mass spectrometer, and the results of the residual gas analysis are described. The method selected for leak rate determination was placing the system into a vacuum chamber and furnishing the chamber with a mass spectrometer and calibrated leaks. The residual gas of a thermal vacuum test facility, in which the thermal balance test radiation input was simulated by a heated canister, was analyzed with the mass spectrometer in the atomic mass unit range up to 300 amu. In addition to the measurements during the space environment tests, mass spectrometric studies were performed with samples of spacecraft materials. The studies were carried out during tests for the projects HELIOS, AEROS B and SYMPHONIE.
Nuss, H. E.↗
Mass spectra of neutral particles released during electrical breakdown of thin polymer films
A special type of time-of-flight mass spectrometer triggered from the breakdown event was developed to study the composition of the neutral particle flux released during the electrical breakdown of polymer films problem. Charge is fed onto a metal-backed polymer surface by a movable smooth platinum contact. A slowly increasing potential from a high-impedance source is applied to the contact until breakdown occurs. The breakdown characteristics is made similar to those produced by an electron beam charging system operating at similar potentials. The apparatus showed that intense instantaneous fluxes of neutral particles are released from the sites of breakdown events. For Teflon FEP films of 50 and 75 microns thickness the material released consists almost entirely of fluorocarbon fragments, some of them having masses greater than 350 atomic mass units amu, while the material released from a 50 micron Kapton film consists mainly of light hydrocarbons with masses at or below 44 amu, with additional carbon monoxide and carbon dioxide. The apparatus is modified to allow electron beam charging of the samples.
Kendall, B. R. F.↗
Cometary particulate analyzer design definition study
A concept for remotely determining the relative abundance of elements contained in cometary particulates collected by a spacecraft was conducted with very encouraging results. The technique utilizes a short high intensity burst of laser radiation to vaporize and ionize collected particulate material. Ions extracted from this laser-produced plasma are analyzed in a time of flight mass spectrometer to yield an atomic mass spectrum representative of the relative abundance of elements in the particulates. A prototype analyzer system was designed, constructed, and tested. Results show that: (1) energy-time focus performs as predicted in improving resolution; (2) power densities sufficient to produce usable ionization efficiencies can be obtained; (3) complex alloys such as stainless steel can be analyzed; and (4) a tiny, simple and reliable laser used in the demonstration easily meets spacecraft power and mass limitations. A mass resolution of 150 was experimentally demonstrated at mass 108, and an analytical extrapolation predicts a resolution sufficient to separate masses 250 and 251.
Utterback, N. G.↗
Evidence for ion transport and molecular ion dominance in the Venus ionotail
We present analyses from the five Pioneer Venus Orbiter plasma experiments and the plasma wave experiment when a patch of plasma with enhanced densities was encountered in the near-Venus ionotail during atmospheric entry at an altitude of approximately 1100 km in the nightside ionosphere. Our analyses of the thermal and superthermal ion measurements in this plasma feature provides the first evidence that at times molecular ions in the 28-32 amu mass range are dominant over atomic mass species thus yielding evidence for a transport mechanism that reaches into the lower ionosphere. Analysis of plasma analyzer (OPA) observations at this time indicates the presence of ions measured in the rest frame of the spacecraft at approximately 27 and 37 volt energy per unit charge steps. In the rest frame of the planet these superthermal ions are flowing from the dawn direction at speeds (assuming they are O2(+)) of approximately 8 km/s and with a flow component downward (perpendicular to the ecliptic plane) at speeds of approximately 2 km/s. OPA analyses also determine the ion number flux, energy, flow angles, and angular distributions. Plasma wave bursts appear to indicate that plasma density decreases within and on the equatorward edge of the patch of enhanced plasma densities are associated with ion acoustic waves and relative ion streaming.
Intriligator, D. S.↗
The Effect of Temperature on the Preservation of Volatile-Rich Lunar Samples
Introduction. The Moon’s south pole is a high-priority target for human exploration and scientific study. This interest is, in part, due to the presence of Permanently Shadowed Regions (PSRs), which could contain high concentrations of unique volatiles at cryogenic temperatures [1]. Returned samples from PSRs may include a unique combination of rocks, regolith, and volatile species, providing unprecedented insights into the history of the Solar System and the potential for resource utilization on the Moon. However, because PSR samples are cryogenic up-on collection, lunar polar sample return will eventually require cold stowage for the journey from the Moon to Earth. Without cold stowage, PSR sample return will likely result in phase changes and chemical reactions within the volatile component of the sample, which would negatively impact the resulting scientific studies of those samples. This abstract summarizes the initial results from an ongoing characterization of analog PSR samples at a range of temperatures, with the goal of defining the temperatures needed for a flight cold stowage freezer. Background. Based on remote sensing observations of the Moon [2], south polar PSRs range in temperature from ~120K for small and/or shallow PSRs to ~20K at the most extreme locations in large, deep PSRs. A range of volatiles have been hypothesized to exist at the surface or subsurface of the lunar poles [3-5 and others]. This hypothesis was verified when the LCROSS mission impacted the <50-K PSR in the crater Cabeus, detecting a range of volatiles from water to low condensation temperature species such as H2S and methane [6]. Species such as H2S and ammonia (also detected by LCROSS) are also highly reactive, and increase the likelihood of chemical reactions at elevated (non-cryogenic) temperatures. At the Johnson Space Center’s Planetary Exploration and Astromaterials Research Laboratory (JSC-PEARL), we have developed a volatile-bearing lunar simulant that incorporates several of the species detected by LCROSS [Table 1] mixed cryogenically with the USGS Lunar Highlands Type (LHT) regolith simulant. The new volatile-regolith simulant will be used to assess the degree of sample alteration at room temperature, -20°C, -80°C, and -196°C (liquid nitro-gen), over a two-week period. Room temperature samples represent those likely to be returned during initial missions without cold stowage, -20°C provides an analog to Apollo cold curated samples, -80°C is the temperature of multiple flight payload freezers (e.g., MELFI), and -196°C is analogous to lunar PSRs. Two weeks is an approximation of the time between sample collection and Earth return for initial Artemis missions. Over this period of time, sample head-space gases will be analyzed using a Universal Gas Analyzer (UGA, a type of mass spectrometer) coupled with a Baratron pressure sensor. After testing, the regolith component of the simulant will be purged of volatiles and preserved for future electron beam and/or FTIR analysis. Experimental Procedure. Volatile-regolith simulants will be produced as an initial homogenous batch; this batch will then be distributed into aliquots (gas chromatography/GC vials or cryo vials), ensuring that each sample has the same starting composition and conditions [Fig. 1]. In addition to the “full” simulant shown in Table 1, less complex simulant compositions will be used as baseline and control samples [Table 2]. Aliquots will be produced in triplicate for each simulant composition, storage temperature, and date of sampling. Headspace gases in all Day 0 samples will be analyzed by the UGA immediately. Cold storage samples for future analytical days will be placed in freezers appropriate to their target temperatures (-20°C, -80°C, -196°C). For ambient-temperature samples, regolith and regolith-water samples will be stored in a fume hood, while the full simulant will be stored in a sealed Parr vessel for safety; no other simulants (RWCM/ RWCM+) will be stored at ambient temperature for this test. Samples will be analyzed by UGA in this manner on each Analysis Day outlined in Table 2. Analytical Data. The UGA measures the partial pressures in a single sample aliquot over a set mass range of 0-105 atomic mass units (AMU) [Figure 2]; this set range was selected to slightly exceed the mass of the highest-mass expected reaction product (H2SO4). The Baratron complements the UGA by measuring the total pressure in the headspace of a sample vial. Coupled together, the quantitative abundances of gases will be monitored throughout the test. UGA analyses of the triplicate samples for each storage temperature, day, and simulant composition will be averaged, and standard deviations for each will be calculated. The compositions of starting species (shown in Table 1) will be characterized as a function of time, and the presence of any new compounds (reaction products) will be monitored as well. Total pressures will be recorded for each sample analysis, and any samples that show signs of leakage (e.g., a significant reduction in pressure or simulant volatiles) will be discarded. Anticipated Results. Testing is planned to begin in January 2022. The resulting data will allow compositional and phase changes in the volatile component of the simulants to be determined. Both the reduction in initial compounds and the addition of reaction products are expected to be observed. In addition, the relative efficacy of the different temperatures at pre-serving the initial composition of the simulants will be quantified. Finally, the regolith component of each sample will be argon-purged and stored in a controlled environment for future laboratory analysis. Compositional and morphological changes in the regolith are expected for samples above 0°C. This test will be repeated three times over the course of 2022. Understanding the effect of temperature on both the volatile and regolith components of analog lunar materials will allow requirements for a cold stowage freezer to be developed. The implementation of cold stowage for lunar polar missions will maximize the preservation of returned samples, enabling ground-breaking lunar and Solar System volatiles science for decades to come.
J L Mitchell↗
Composition measurements of the topside ionosphere using a magnetic mass spectrometer, ion mass spectrometer on ISIS-2 spacecraft
The ion mass spectrometer (IMS) on the ISIS-II satellite is described; it measures the composition and distribution of positive ions in the earth's ionosphere in the mass range of 1 to 64 atomic mass units. Significant data were received which show a wide variation in ion composition at night near the equator and in the daytime poleward of the plasmapause. It was found that these data enable further study of the polar wind and that the experiment produced timely data during the August, 1972 magnetic storm to show the development of a unique ionosphere above the plasmapause during the period of the storm. The scientific objectives and results of the experiment, the technical description of the instrument, a bibliography with sample papers attached, and a summary of recommendations for further study are presented.
Hoffman, J. H.↗
Toward a Micro Gas Chromatograph/Mass Spectrometer (GC/MS) System
Miniature mass filters (e.g., quadrupoles, ion traps) have been the subject of several miniaturization efforts. A project is currently in progress at JPL to develop a miniaturized Gas Chromatograph/Mass Spectrometer (GC/MS) system, incorporating and/or developing miniature system components including turbomolecular pumps, scroll type roughing pump, quadrupole mass filter, gas chromatograph, precision power supply and other electronic components. The preponderance of the system elements will be fabricated using microelectromechanical systems (MEMS) techniques. The quadrupole mass filter will be fabricated using an X-ray lithography technique producing high precision, 5x5 arrays of quadrupoles with pole lengths of about 3 mm and a total volume of 27 cubic mm. The miniature scroll pump will also be fabricated using X-ray lithography producing arrays of scroll stages about 3 mm in diameter. The target detection range for the mass spectrometer is 1 to 300 atomic mass units (AMU) with are solution of 0.5 AMU. This resolution will allow isotopic characterization for geochronology, atmospheric studies and other science efforts dependant on the understanding of isotope ratios of chemical species. This paper will discuss the design approach, the current state-of-the art regarding the system components and the progress toward development of key elements. The full system is anticipated to be small enough in mass, volume and power consumption to allow in situ chemical analysis on highly miniaturized science craft for geochronology, atmospheric characterization and detection of life experiments applicable to outer planet roadmap missions.
Wiberg, D. V.↗
Portable mass spectrometer
Eighteen-pound unit gives real-time onsite sample analysis. Mass range is twelve to two hundred atomic mass units with resolution of two hundred. Device has biomedical application possibilities, such as determination of alcohol and gas content of blood and breath.
Giffin, C. E.↗
First polymer in space identified in Comet Halley
The heavy-ion mass spectrum obtained in the inner coma of Comet Halley with the PICCA instrument on the Giotto spacecraft has been examined. Short polymer chains of polyoxymethylene and their decay products are identified as the source for the spectrum with six mass peaks between about 45 and 120 atomic mass units. The properties of polyoxymethylene are consistent with many of the unexpected observations in the coma.
Huebner, W. F.↗
The abundance of interstellar sulphur and zinc in high density sight-lines
On the basis of early absorption line studies of individual lines of sight with the Copernicus satellite, chlorine, sulphur and zinc were classed together as elements which showed little or no depletion, relative to hydrogen, in the interstellar medium. The abundances of other less volatile elements, such as Fe and Mg were found to vary widely from one sight-line to another with gas-phase abundances in some cases being orders of magnitude below their solar counterparts. Detailed studies are reported of the depletion/density behavior of two other volatile elements which were previously considered to be virtually undepleted, S and Zn, using equivalent width data from both Copernicus and IUE observations. The results provide further evidence that the established dependence of depletion on n bar (H) extends to volatile elements and show that their use as tracers of metallicity, or for estimating hydrogen column densities, may lead to large errors in sight-lines through dense regions. It now appears that such elements may take part in the surface chemistry of grains and be important constituents of grain mantle material, although they probably do not contribute significantly to the bulk mass of grains. Due to the very similar atomic masses and ionization potentials of sulphur and phosphorous, the thermal velocity distributions of the singly ionized species of these elements in interstellar clouds should be very similar. However, a comparison of Doppler widths (b-values) derived for SIT and PIT in the same sight-lines from the Bohlin et al Copernicus equivalent width measurements has revealed an unexpected systematic discrepancy of a factor of approx. 1.7. This Discrepancy indicates that the normally adopted oscillators strengths of the PII lambda lambda 1153 and 1302 A lines may require revision.
Harris, A. W.↗
Neutral stellar winds that drive bipolar outflows in low-mass protostars
The Arecibo radio telescope at the 21-cm line of atomic hydrogen has been used to detect a neutral atomic wind in the bipolar flow source HH 7-11. An atomic mass of about 0.015 solar associated with the rapidly flowing gas is deduced. The stellar mass-loss rate is roughly 3 x 10 to the -6th solar mass/yr if the crossing time of the decelerating wind is 5000 yr. The excess emission in the H I line core gives a total duration of the outflow of about 70,000 yr. A detailed analysis of the H I line shape yields a reasonable deceleration rate for the atomic wind if the stellar wind continuously entrains ambient molecular gas as it propagates from the protostar. A stellar wind with the described characteristics and a terminal velocity of 170 km/s would be more than sufficient to drive the known extended CO bipolar outflow in HH 7-11.
Lizano, Susana↗
Miniature Time-of-Flight Mass Spectrometer
Major advances must occur to protect astronauts from prolonged periods in near-zero gravity and high radiation associated with extended space travel. The dangers of living in space must be thoroughly understood and methods developed to reverse those effects that cannot be avoided. Six of the seven research teams established by the National Space Biomedical Research Institute (NSBRI) are studying biomedical factors for prolonged space travel to deliver effective countermeasures. To develop effective countermeasures, each of these teams require identification of and quantitation of complex pharmacological, hormonal, and growth factor compounds (biomarkers) in humans and in experimental animals to develop an in-depth knowledge of the physiological changes associated with space travel. At present, identification of each biomarker requires a separate protocol. Many of these procedures are complicated and the identification of each biomarker requires a separate protocol and associated laboratory equipment. To carry all of this equipment and chemicals on a spacecraft would require a complex clinical laboratory; and it would occupy much of the astronauts time. What is needed is a small, efficient, broadband medical diagnostic instrument to rapidly identify important biomarkers for human space exploration. The Miniature Time-Of- Flight Mass Spectrometer Project in the Technology Development Team is developing a small, high resolution, time-of-flight mass spectrometer (TOFMS) to quantitatively measure biomarkers for human space exploration. Virtues of the JHU/APL TOFMS technologies reside in the promise for a small (less than one cubic ft), lightweight (less than 5 kg), low-power (less than 50 watts), rugged device that can be used continuously with advanced signal processing diagnostics. To date, the JHU/APL program has demonstrated mass capability from under 100 to beyond 10,000 atomic mass units (amu) in a very small, low power prototype for biological analysis. Further, the electronic nature of the TOFMS output makes it ideal for rapid telemetry to earth for in-depth analysis by ground support teams.
Potember, Richard S.↗
Technology Demonstration Missions
Technology Demonstration Missions (TDM) is in its third year of execution, being initiated in 2010 and baselined in January of 2012. There are 11 projects that NASA Marshall Space Flight Center (MSFC) has contributed to or led: (1) Evolvable Cryogenics (eCryo): Cyrogenic Propellant Storage and Transfer Engineering Development Unit (EDU), a proof of manufacturability effort, used to enhance knowledge and technology related to handling cryogenic propellants, specifically liquid hydrogen. (2) Composites for Exploration Upper Stage (CEUS): Design, build, test, and address flight certification of a large composite shell suitable for the second stage of the Space Launch System (SLS). (3) Deep Space Atomic Clock (DSAC): Spaceflight to demo small, low-mass atomic clock that can provide unprecedented stability for deep space navigation. (4) Green Propellant Infusion Mission (GPIM): Demo of high-performance, green propellant propulsion system suitable for Evolved Expendable Launch Vehicle (EELV) Secondary Payload Adapter (ESPA)-class spacecraft. (5) Human Exploration Telerobotics (HET): Demonstrating how telerobotics, remote control of a variety of robotic systems, can take routine, highly repetitive, dangerous or long-duration tasks out of human hands. (6) Laser Communication Relay Demo (LCRD): Demo to advance optical communications technology toward infusion into deep space and near Earth operational systems, while growing the capabilities of industry sources. (7) Low Density Supersonic Decelerator (LDSD): Demo new supersonic inflatable decelerator and parachute technologies to enable Mars landings of larger payloads with greater precision at a wider range of altitudes. (8) Mars Science Laboratory (MSL) Entry Descent & Landing Instrumentation (MEDLI): Demo of embedded sensors embedded in the MSL heat shield, designed to record the heat and atmospheric pressure experienced during the spacecraft's high-speed, hot entry in the Martian atmosphere. (9) Solar Electric Propulsion (SEP): 50-kW class spacecraft that uses flexible blanket solar arrays for power generation and an electric propulsion system that delivers payload from low-Earth orbit to higher orbits. (10) Solar Sail Demonstration (SSD): Demo to validate sail deployment techniques for solar sails that are propelled by the pressure of sunlight. (11) Terrestrial HIAD Orbit Reentry (THOR): Demo of a 3.7-m Hypersonic Inflatable Aerodynamic Decelerator (HIAD) entry vehicle to test second generation aerothermal performance and modeling.
McDougal, John↗
Ion composition results during the International Cometary Explorer encounter with Giacobini-Zinner
The International Cometary Explorer spacecraft passed through the coma of comet Giacobini-Zinner about 7800 kilometers antisunward of the nucleus on September 11, 1985. The ion composition instrument was sensitive to ambient ions with mass-to-charge ratios in the ranges 1.4 to 3 atomic mass units per electron charge (amu/e) and 14 to 33 amu/e. Initial interpretation of the measurements indicates the presence of H2O(+), H3O(+), probably CO(+) and HCO(+), and ions in the mass range 23 to 24; possible candidates are Na(+) and Mg(+) and Mg(+). In addition to these heavy ions, measured over the velocity range 80 to 223 kilometers per second, the instruments measured He(2+) of solar wind origin over the range 237 to 463 kilometers per second. The heavy ions have a velocity distribution which indicates that they have been picked up by the motional electric field, whereas the light ions are steadily decelerated as the comet tail axis is approached. These results are in agreement with the picture of a comet primarily consisting of water ice, together with other material, that sublimes, streams away from the nucleus, becomes ionized, and interacts with the solar wind.
Ogilvie, K. W.↗
The heavy ion analyser PICCA for the comet Halley fly-by with Giotto
The heavy ion analyzer RPA2-PICCA is designed to identify the composition and distribution of thermal positive ions in the coma of the comet Halley. The instrument is an electrostatic analyzer which takes advantage of the large relative flyby velocity and the fact that the ions in the inner coma should have low temperatures and be predominantly singly charged. Thus, the energy/charged measurements can be directly related to the mass distribution of the ions. Mass identification will be provided in the range from 10 to 203 amu (atomic mass units) with a mass resolution of either 0.4 amu or 1 amu, dependent on the ion mass.
Korth, A.↗
Theory of collision effects on line shapes using a quantum mechanical description of the atomic center of mass motion - Application to lasers
Quantum mechanical treatment of atomic center of mass motion in theory of collision effects on line shapes
Berman, P. R.↗
Organic Matter in Extraterrestrial Water-Bearing Salt Crystals
Introduction: Direct samples of early Solar System fluids are present in two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans (1998) [H5] and Zag [H3-6]), which were found to contain brine-bearing halite (NaCl) crystals that have been added to the regolith of an S-type asteroid following asteroidal metamorphism [1, 2]. The brine-bearing halite grains were proposed to be formed on an icy C-type asteroids (possibly Ceres), and transferred to an S-type asteroid via cryovolcanic event(s) [3]. A unique aspect of these halites is that they contain abundant organic rich solid inclusions hosted within the halites alongside the water inclusions. Methods: We analyzed in detail the compositions of the organic solids and the amino acid content of the halite crystals with two-step laser desorption/laser ionization mass spectrometry (L(sup 2) MS), Raman spectroscopy, X-ray absorption near edge structure (XANES), nanoscale secondary ion mass spectrometry (NanoSIMS), and ultra-performance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry (UPLC-FD/QToF-MS). Results and Discussion: The L(sup 2) MS results show signatures of low-mass polyaromatic hydro-carbons (PAHs) indicated by sequences of peaks separated by 14 atomic mass units (amu) due to successive addition of methylene (CH2) groups to the PAH skeletons [4]. Raman spectra of the micron-sized solid inclusions of the halites indicate the presence of abundant and highly variable organic matter that include a mixture of short-chain aliphatic compounds and macromolecular carbon. C-XANES analysis identified C-rich areas with peaks at 285.0 eV (aromatic C=C) and 286.6 eV (vinyl-keto C=O). However, there is no 1s-sigma* exciton peak (291.7 eV) that is indicative of the development of graphene structure [5], which suggests the organics were synthesized cold. Na-noSIMS analyses show C-rich and N-rich areas that exhibit similar isotopic values with that of the IOM in the unweathered CR chondrites and less metamorphosed meteorites [6], and are moderately enriched in N-15 (delta N-15 = 106.1-164.5 per mille). The total amino acid distribution and abundance of the Zag matrix (approximately 1,940 parts per billion [ppb]) is comparable to other ordinary chondrites (60-3,330 ppb) [7, 8]. While the Zag matrix is gamma-ABA and EACA-deficient, the halite is shown to exhibit an opposite trend and is almost depleted in amino acids. The striking difference in the amino acid contents between the halite and matrix indicates their separate synthetic origins. Conclusion: Abundant, primitive, and highly-diverse N-15-rich organic compounds were detected in brine-water bearing halite crystals that were synthesized on a cryovolcanically-active asteroid. Our study suggests that the asteroidal parent body where the halite precipitated, potentially Ceres, is a host to abundance large variety organic precursors. Insoluble organic matter and amino acids can be synthesized from similar organic precusors under hydrous conditions [9].We envision that similar organic synthetic processes could have occurred on Ceres that synthesized organic solids as well as biologically relevant molecules.
Chan, Q. H. S.↗