Search NASA⌕ Search

SEARCH · Search NASA

Results for “bimodal”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Additive manufacturing enabled synergetic strengthening of bimodal reinforcing particles for aluminum matrix composites

An additive manufactured TiB 2 /Al-Cu-Mg-Ni composite with a minor amount of Sc was fabricated by laser powder bed fusion (LPBF). The composite shows a yield strength of ~370 MPa, almost doubling the strength of its wrought matrix counterpart, and an elongation of ~7 %. The superior mechanical properties are attributed to a unique micro-nano hierarchical microstructure, consisting of nanoscale and microscale TiB 2 particles dispersed in a matrix of fine aluminum grains (3 µm) together with intragranular intermetallic nanoparticles and nano-cellular networks (cell size 30 nm). The formation of the TiB 2 nanoparticles is the consequence of partial dissolution of the TiB 2 particulates and the enrichment of Sc in the newly formed nanoparticles. Remarkable strengthening effects are achieved by the bimodal TiB 2 particles, intermetallic nanoparticles and intragranular nano-cellular networks. Finally, this study provides new insights into the role of additive manufacturing in tailoring the microstructure of particulate reinforced metal matrix composites (MMCs) with advanced properties.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Bimodal particle distributions with increased thermal conductivity for solid particles as heat transfer media and storage materials

Solid particles are being considered in several high temperature thermal energy storage systems and as heat transfer media in a variety of advanced power generation systems, particularly in concentrated solar power plants. The downside of such an approach is the low overall heat transfer coefficients caused by the inherently low thermal conductivity values of the low-cost solid media when coupled to heat exchanger for the power cycle working fluid. Choosing the right particle size distribution, emittance, and material of the solid media can all make a substantial difference in packed bed thermal conductivity. Current research though exclusively focuses on continuous unimodal distributions of particles. Here, in this work, we propose the use of a binary particle system with a bimodal size distribution to significantly increase packed bed thermal conductivity by reducing packed bed porosity. This is the first study related to ceramic solid particle heat transfer that has considered the thermal conductivity of non-unimodal size distributions at room and elevated temperatures. The following study found that for the binary particle system using Carbo particles CP 16/30 – CP 70/140 where the large particle volume fraction was 50% there was an 17–47% increase in packed bed thermal conductivity when compared with a nearly unimodal particle size distribution of CP 16/30 between 50 and 300 °C. Two different porosity and effective thermal conductivity models were studied, with one providing better prediction of porosity but both effective thermal conductivity models providing less predictive capacity. Importantly this approach can have a substantial impact of thermal performance, with little to no impact on the particle cost.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Variations in proton transfer pathways and energetics on pristine and defect-rich quartz surfaces in water: Insights into the bimodal acidities of quartz

Hypothesis. Understanding the mechanisms of proton transfer on quartz surfaces in water is critical for a range of processes in geochemical, environmental, and materials sciences. The wide range of surface acidities (>9 pKa units) found on the ubiquitous mineral quartz is caused by the structural variations of surface silanol groups. Molecular scale simulations provide essential tools for elucidating the origin of site-specific surface acidities. Simulations. Here, we used density-functional tight-binding-based molecular dynamics combined with rare-event metadynamics simulations to probe the mechanisms of deprotonation reactions from ten representative surface silanol groups found on both pristine and defect-rich quartz (1 0 1) surfaces with Si vacancies. Findings. The results show that deprotonation is a highly dynamic process where both the surface hydroxyls and bridging oxygen atoms serve as the proton acceptors, in addition to water. Deprotonation of embedded silanols through intrasurface proton transfer exhibited lower pKa values with less H-bond participation and higher energy barriers, suggesting a new mechanism to explain the bimodal acidity observed on quartz surface. Defect sites, recently shown to comprise a significant portion of the quartz (1 0 1) surface, diversify the coordination and local H-bonding environments of the surface silanols, changing both the deprotonation pathways and energetics, leading to a wider range of pKa values (2.4 to 11.5) than that observed on pristine quartz surface (10.4 and 12.1).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Formation of a Large Cold Groundwater Mantle Helium Anomaly and High Temperature Geothermal Resources in Response to Bimodal Magmatism Near Roosevelt Hot Springs and Utah FORGE, Milford Valley, Southwest Utah

Abstract A large mantle helium anomaly and separate domains of high heat flow are the predominant manifestations of bimodal magmatic activity in the Milford valley. The mantle helium anomaly (1.9–2.6 R/Ra) covers 270 km 2 and is subdivided into two separated domains: a cold shallow groundwater regime and high temperature hydrothermal activity. The zone of anomalous heat flow covers >100 km 2 and is also subdivided into two adjacent domains, comprising hydrothermal activity at Roosevelt Hot Springs (RHS) (3–7 W/m 2 ) and conductive heat flow (100–180 mW/m 2 ). While the transfer of heat and mantle helium at RHS are coupled, heat and helium transfer are decoupled in the adjacent cold groundwater regime to the west. Both the mantle helium and geothermal anomalies are attributed to recent mafic‐felsic magmatic intrusions of >400 km 3 , however, the absence of volcanic eruptions <500,000 years indicates magmas stall before rising to shallow crustal level <10 km depth. Deep level magmatism produces a felsic composition melt, which is inferred to be responsible for the widespread and near uniform range of diluted mantle helium values. A thick and impermeable mass of crystalline granitic basement rock at the mid‐crustal level divides the ascent of mantle helium into separate flow paths. It may also impede the rise of buoyant magma trapping thermal energy that facilitates partial melting, slow cooling, and development of a thick thermal aureole. Partitioning of convective and conductive thermal regimes and independent flow paths supplying deeply derived helium characterize the development of a large long‐lived magma‐related geothermal system.

Geochemistry & Geophysics↗
DOE OSTI2020

Determining population densities in bimodal micellar solutions using contrast-variation small angle neutron scattering

Self-assembly of amphiphilic polymers in water is of fundamental and practical importance. Significant amounts of free unimers and associated micellar aggregates often coexist over a wide range of phase regions. The thermodynamic and kinetic properties of the microphase separation are closely related to the relative population density of unimers and micelles. Although the scattering technique has been employed to identify the structure of micellar aggregates as well as their time-evolution, the determination of the population ratio of micelles to unimers remains a challenging problem due to their difference in scattering power. In this work, using small-angle neutron scattering (SANS), we present a comprehensive structural study of amphiphilic n-dodecyl-PNIPAm polymers, which shows a bimodal size distribution in water. By adjusting the deuterium/hydrogen ratio of water, the intra-micellar polymer and water distributions are obtained from the SANS spectra. The micellar size and number density are further determined, and the population densities of micelles and unimers are calculated to quantitatively address the degree of micellization at different temperatures. Our method can be used to provide an in-depth insight into the solution properties of microphase separation, which are present in many amphiphilic systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

A Bimodal Diagnostic Cloud Fraction Parameterization. Part I: Motivating Analysis and Scheme Description

Cloud fraction parameterizations are beneficial to regional, convection-permitting numerical weather prediction. For its operational regional midlatitude forecasts, the Met Office uses a diagnostic cloud fraction scheme that relies on a unimodal, symmetric subgrid saturation-departure distribution. This scheme has been shown before to underestimate cloud cover and hence an empirically based bias correction is used operationally to improve performance. This first of a series of two papers proposes a new diagnostic cloud scheme as a more physically based alternative to the operational bias correction. The new cloud scheme identifies entrainment zones associated with strong temperature inversions. Additionally, for model grid boxes located in this entrainment zone, collocated moist and dry Gaussian modes are used to represent the subgrid conditions. The mean and width of the Gaussian modes, inferred from the turbulent characteristics, are then used to diagnose cloud water content and cloud fraction. It is shown that the new scheme diagnoses enhanced cloud cover for a given gridbox mean humidity, similar to the current operational approach. It does so, however, in a physically meaningful way. Using observed aircraft data and ground-based retrievals over the southern Great Plains in the United States, it is shown that the new scheme improves the relation between cloud fraction, relative humidity, and liquid water content. An emergent property of the scheme is its ability to infer skewed and bimodal distributions from the large-scale state that qualitatively compare well against observations. A detailed evaluation and resolution sensitivity study will follow in Part II.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

A Bimodal Diagnostic Cloud Fraction Parameterization. Part II: Evaluation and Resolution Sensitivity

A wide range of approaches exists to account for subgrid cloud variability in regional simulations of the atmosphere. This paper addresses the following questions: 1) Is there still benefit in representing subgrid variability of cloud in convection-permitting simulations? 2) What is the sensitivity to the cloud fraction parameterization complexity? 3) Are current cloud fraction parameterizations scale-aware across convection-permitting resolutions? These questions are addressed for regional simulations of a 6-week observation campaign in the U.S. southern Great Plains. Particular attention is given to a new diagnostic cloud fraction scheme with a bimodal subgrid saturation-departure PDF, described in Part I. The model evaluation is performed using ground-based remote sensing synergies, satellite-based retrievals, and surface observations. It is shown that not using a cloud fraction parameterization results in underestimated cloud frequency and water content, even for stratocumulus. The use of a cloud fraction parameterization does not guarantee improved cloud property simulations, however. Diagnostic and prognostic cloud schemes with a symmetric subgrid saturation-departure PDF underestimate cloud fraction and cloud optical thickness, and hence overestimate surface shortwave radiation. These schemes require empirical bias-correction techniques to improve the cloud cover. The new cloud fraction parameterization, introduced in Part I, improves cloud cover, liquid water content, cloud-base height, optical thickness, and surface radiation compared to schemes reliant on a symmetric PDF. Furthermore, cloud parameterizations using turbulence-based, rather than prescribed constant subgrid variances, are shown to be more scale-aware across convection-permitting resolutions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

The Bimodal Absorption System Imaging Campaign (BASIC). I. A Dual Population of Low-metallicity Absorbers at z < 1

The bimodal absorption system imaging campaign (BASIC) aims to characterize the galaxy environments of a sample of 36 H I-selected partial Lyman limit systems (pLLSs) and Lyman limit systems (LLSs) in 23 QSO fields at z ≲ 1. These pLLSs/LLSs provide a unique sample of absorbers with unbiased and well-constrained metallicities, allowing us to explore the origins of metal-rich and low-metallicity circumgalactic medium (CGM) at z < 1. Here we present Keck/KCWI and Very Large Telescope/MUSE observations of 11 of these QSO fields (19 pLLSs) that we combine with Hubble Space Telescope/Advanced Camera for Surveys imaging to identify and characterize the absorber-associated galaxies at 0.16 ≲ z ≲ 0.84. We find 23 unique absorber-associated galaxies, with an average of one associated galaxy per absorber. For seven absorbers, all with <10% solar metallicities, we find no associated galaxies with logM * ≳ 9.0 within ρ/R vir and |Δv|/v esc ≤ 1.5 with respect to the absorber. We do not find any strong correlations between the metallicities or H I column densities of the gas and most of the galaxy properties, except for the stellar mass of the galaxies: the low-metallicity ([X/H] ≤ –1.4) systems have a probability of $0.39_{–0.15}^{+0.16}$ for having a host galaxy with logM * ≥ 9.0 within ρ/R vir ≤ 1.5, while the higher metallicity absorbers have a probability of $0.78_{–0.13}^{+0.10}$. This implies metal-enriched pLLSs/LLSs at z < 1 are typically associated with the CGM of galaxies with logM * > 9.0, whereas low-metallicity pLLSs/LLSs are found in more diverse locations, with one population arising in the CGM of galaxies and another more broadly distributed in overdense regions of the universe. Using absorbers not associated with galaxies, we estimate the unweighted geometric mean metallicity of the intergalactic medium to be [X/H] ≲ –2.1 at z < 1, which is lower than previously estimated.

79 ASTRONOMY AND ASTROPHYSICS↗