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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

The geological record of life 3500 Ma ago: Coping with the rigors of a young earth during late accretion

Thin cherty sedimentary layers within the volcanic portions of the 3,500 to 3,300 Ma-old Onverwacht and Fig Tree Groups, Barberton Greenstone belt, South Africa, and Warrawoona Group, eastern Pilbara Block, Western Australia, contain an abundant record of early Archean life. Five principal types of organic and probably biogenic remains and or structures can be identifed: stromatolites, stromatolite detritus, carbonaceous laminite or flat stromalite, carbonaceous detrital particles, and microfossils. Early Archean stromatolites were reported from both the Barberton and eastern Pilbara greenstone belts. Systematic studies are lacking, but two main morphological types of stromatolites appear to be represented by these occurrences. Morphology of the stromalites is described. Preserved early Archean stromatolites and carbonaceous matter appear to reflect communities of photosynthetic cyanobacteria inhabiting shallow, probably marine environments developed over the surfaces of low-relief, rapidly subsiding, simatic volcanic platforms. The overall environmental and tectonic conditions were those that probably prevailed at Earth's surface since the simatic crust and oceans formed sometime before 3,800 Ma. Recent studies also suggest that these early Archean sequences contain layers of debris formed by large-body impacts on early Earth. If so, then these early bacterial communities had developed strategies for coping with the disruptive effects of possibly globe-encircling high-temperature impact vapor clouds, dust blankets, and impact-generated tsunamis. It is probable that these early Archean biogenic materials represent organic communities that evolved long before the beginning of the preserved geological record and were well adapted to the rigors of life on a young, volcanically active Earth during late bombardment. These conditions may have had parallels on Mars during its early evolution.

Lowe, Donald R.↗
NASA NTRS1989

Temporal patterns of phytoplankton abundance in the North Atlantic

A time series of CZCS images is being developed to study phytoplankton distribution patterns in the North Atlantic. The goal of this study is to observe temporal variability in phytoplankton pigments and other organic particulates, and to infer from these patterns the potential flux of biogenic materials from the euphotic layer to the deep ocean. Early results of this project are presented in this paper. Specifically, the satellite data used were 13 monthly composited images of CZCS data for the North Atlantic from January 1979 to January 1980. Results are presented for seasonal patterns along the 20 deg W meridian.

Campbell, Janet W.↗
NASA NTRS2001

The Mars Microbeam Raman Spectrometer (MMRS)

The Mars Microbeam Raman Spectrometer can identify minerals in situ, determine rock types and textures, provide some mineral chemistry, detect organic and biogenic materials, and identify bound water. Additional information is contained in the original extended abstract.

Haskin, L. A.↗
NASA NTRS1996

SOFIA: The Next Airborne Observatory

SOFIA (Stratospheric Observatory for Infrared Astronomy) will be a telescope with 2.5 m effective aperture operating at altitudes of 12.5 to 13.7 km in a Boeing 747 aircraft. It will enable astronomers on board to make observations which are impossible from the ground at wavelengths between 0.3 microns and 1.5 mm. Diffraction-limited imaging will be possible at wavelengths beyond about 10 microns. SOFIA's mobility will assure all-sky coverage and access to transient events from anywhere in the world. Some of the science topics to be studied will be star and planet formation, origin and evolution of biogenic materials, comets and planetary atmospheres in the solar system, the interstellar media of other galaxies, and phenomena at our galactic center. The SOFIA concept is based on 21 years of experience with NASA's Kuiper Airborne Observatory (KAO), which has been retired to help fund the project. As with the KAO, state-of-the-art focal plane instruments and a vigorous educational outreach program will be features of this new airborne astronomy facility. A more intensive flight program, approximately 150 flights per year, will accommodate many more guest investigators however. Planned as a collaboration between the United States and Germany, SOFIA is scheduled to begin a 20 year operating lifetime in 2001.

Erickson, E. F.↗
NASA NTRS2003

Survey for Life-related Species During a Planetary Surface Exploration; System Type I - UV Stimulated Fluorescent Sensor

The widely accepted minimum requirements for life on Earth include the presence of water and accessible sources of carbon. We assume that the same criteria must hold for putative life on past or present Mars. The evidence for CO2 and H2O at or near the Martian surface, carbon in Martian meteorites, aqueous alteration, and probable hydrothermal activity suggest that conditions conducive to the origin and evolution of life on Mars may have existed for long periods of time and may still obtain at present. Surface exploration on Mars that enables the direct detection of water in minerals and of organic carbon (including not just organic and biogenic materials but their degradation products such as kerogen-like hydrocarbons and graphitized carbon) that might be products or residues of biologic activity, is crucial. The search for evidence of life, past or present, will nevertheless be difficult. The lack of direct evidence for organic carbon and the low amounts of water found in the soils at the Viking sites demonstrated the difficulties. Recent results of GRS experiment of Odyssey mission indicated the existence of abundant water ice beneath the Mars surface. Mineralogical evidence for the presence of carbonate, sulfates, or clay minerals, products of weathering and aqueous deposition, have not been identified unambiguously on Mars. Rocks such as shales and, more particularly, limestones, which we associate with moist and benign environments on Earth, are evidently not abundant. Presumably, then, neither were the photosynthetic organisms that might have produced them. In addition, the harsh present environment on Mars (e.g., dryness, low temperatures, large temperature cycles, high level of UV light on the surface, frequent dust storms, etc.) can both destroy carbon- and water-bearing materials and hide them. Therefore, directly detecting life-related materials on Mars was likened to seeking and examining proverbial needles in haystacks. We argue that survey type instruments, that can frequently and quickly check a relatively large amount of material at many locations during a mission, are essential.

Wang, Alian↗
NASA NTRS2005

A Compact Instrument for Remote Raman and Fluorescence Measurements to a Radial Distance of 100 m

Compact remote spectroscopic instruments that could provide detailed information about mineralogy, organic and biomaterials on a planetary surface over a relatively large area are desirable for NASA s planetary exploration program. Ability to explore a large area on the planetary surfaces as well as in impact craters from a fixed location of a rover or lander will enhance the probability of selecting target rocks of high scientific contents as well as desirable sites in search of organic compounds and biomarkers on Mars and other planetary bodies. We have developed a combined remote inelastic scattering (Raman) and laser-induced fluorescence emission (LIFE) compact instrument capable of providing accurate information about minerals, organic and biogenic materials to a radial distance of 100 m. Here we present the Raman and LIFE (R-LIFE) data set.

Sharma, S. K.↗
NASA NTRS2005

Submillimeter Spectroscopy with SOFIA

Four submillimeter spectrometers are being developed for use on SOFIA, the Stratospheric Observatory for Infrared Astronomy. They will be nearly diffraction limited by SOFIA'S 2.5 m telescope, giving for example images of 8.5 arc seconds FWHM at 100 microns. The instruments are FlFI LS, an integral-field imaging grating spectrometer (MPE) covering 40-210 microns with ~150 km/s resolution; SAFIRE an imaging Fabry-Perot spectrometer covering 100-'650 microns with resolution ~200 km/s, and two heterodyne receivers with resolving powers up to ~0.03 km/s: GREAT covering bands from 158-187 um, 110-125, and 62-65 microns, and CASIMIR, operating from 150-264 and 508-588 microns. These instruments will enable a variety of studies including topics relating to the origins of stars, planets, and biogenic materials in the interstallar medium of our own and other galaxies. Opportunities for observing with these and the other SOFIA instruments will be available to general investigators. SOFIA is a joint project of NASA in the U.S. and DLR in Germany.

Erickson, E.↗
NASA NTRS2012

TPSAS-NF1676L-14292-DND

NASA Langley Research Center (LaRC) initiated the development of the miniature Raman-Fluorescence spectrograph and Lidar system with Langley investment funds. Later, a proposal called “Combined Raman, Fluorescence, and Lidar Multi-Sensor (RFLMS) Instrument Development Program” under NASA Mars Instrument Development Project (MIDP) was jointly proposed by University of Hawaii and NASA LaRC in 2008 and was selected for funding. Finally, Raman, Fluorescence, and Lidar prototype instrument has been integrated onto a rover system and demonstrated at NASA LaRC. Surface and atmospheric characterizations are performed with this prototype instrument from a robotic platform to investigate and identify the water, ice, and dry-ice at a 15 meter distance as well as conducting atmospheric aerosol and cloud distributions profiling. Recently acquired Raman spectra from water, ice, and dry-ice as well as atmospheric characterization results [refs. 1-2] are discussed in this study. The objective of this study is to develop a remote Raman-Fluorescence spectroscopy and Lidar multi-sensor instrument capable for investigation and identification of minerals, organics, and biogenic materials as well as conducting atmospheric studies of Mars, Moon, Asteroids/Comets, Europa, Titan, Venus, and other planets from rovers and landers.

M Nurul Abedin↗
DOE OSTI2024

Tailoring Nanoporous Silica and Natural Straw Structural Insulation Composites

Nanoporous silica exhibits ultralow thermal conductivity as a result of its nanoscale pore size, high pore volume, and specific surface area. In this study, we report the self-assembled surfactant-templated synthesis of nanoporous silica, which is integrated with cellulose fibers derived from natural straw to manufacture high thermal insulation and mechanically robust nanocomposites. The nanocomposite shows a low thermal conductivity of 22.5 mW/(m·K), a compressive modulus of 0.93 MPa, and a hydrophobicity with a water contact angle of 125°. Moreover, we observed a marked reduction in water absorption capacity and a carbon footprint of 0.21 kg CO 2 equiv/kg. Here, this study provides a pathway toward the development of nanoporous structural insulation materials for energy-efficient building applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Tautomerism induces bending and twisting of biogenic crystals

Understanding and exploiting material flexibility through phenomena such as the bending and twisting of molecular crystals has been a subject of increased interest owing to the number of applications that benefit from these properties, such as optoelectronics, mechanophotonics, soft robotics, and smart sensors. Here, we report the growth of spontaneously bent and twisted ammonium urate crystals induced by the keto–enol tautomerism of the urate molecule. The major tautomer is native to biogenic crystals, whereas the minor tautomer functions as an effective crystal growth modifier to induce naturally bent and twisted ammonium urate crystals. We show that the degree of curvature can be tailored based on the judicious selection of growth conditions. A combination of state-of-the-art microscopy and spectroscopy techniques are used to characterize the origin of bending. Spatially resolved nano-electron diffraction and high-resolution electron microscopy of naturally bent crystals show nearly single crystallinity with local lattice deformations generated by a combination of screw and edge dislocations. These observations are consistent with photoinduced force microscopy and contact resonance atomic force microscopy, which confirmed spatially resolved changes in the intermolecular interactions and the mechanical properties throughout the cross-sectional and axial regions of bent crystals. A mechanism of bending involving the generation of regionally specific dislocations is proposed as an alternative to more commonly reported models. These findings highlight a unique characteristic of tautomeric crystals that may have broader implications for other biogenic materials.

Science & Technology - Other Topics↗
DOE OSTI2024

Surfactant templated biogenic nanoporous silica thermal insulation composite

Carbon-sequestration biogenic insulation materials offer a promising solution for sustainable and energy-efficient buildings. However, minimizing energy-intensive manufacturing processes and ensuring a uniform microstructure are essential to achieve widespread application. In this work, we introduce cetyltrimethylammonium bromide (CTAB) surfactant as both synthesis and dispersion template for nanoporous silica to create biogenic straw-based thermal insulation composites. As the amount of nanoporous silica increases to 72 wt%, the elastic insulation composite dried using the solvent exchange method exhibits a density of 0.058 g cm –3 , a thermal conductivity of 30.3 mW m –1 K –1 and a flexural modulus of 3.96 MPa, while demonstrating materials circularity and fire retardance. The use of CTAB surfactant effectively captures nanoporous silica, preventing its loss during manufacturing and enhancing the homogeneity and dispersion of the silica within the composite. In addition, the results show that the ethanol solvent exchange drying at ambient conditions provides the optimum thermal insulation performance with less energy consumption compared to freeze-drying.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Oxygenic Photosynthesis and the Oxidation State of Mars

The oxidation state of the Earth's surface is one of the most obvious indications of the effect of life on this planet. The surface of Mars is highly oxidized, as evidenced by its red color, but the connection to life is less apparent. Two possibilities can be considered. First, the oxidant may be photochemically produced in the atmosphere. In this case the fundamental source of O2 is the loss of H2 to space and the oxidant produced is H2O2. This oxidant would accumulate on the surface and thereby destroy any organic material and other reductants to some depth. Recent models suggest that diffusion limits this depth to a few meters. An alternative source of oxygen is biological oxygen production followed by sequestration of organic material in sediments - as on the Earth. In this case, the net oxidation of the surface was determined billions of years ago when Mars was a more habitable planet and oxidative conditions could persist to great depths, over 100 m. Below this must be a compensating layer of biogenic organic material. Insight into the nature of past sources of oxidation on Mars will require searching for organics in the martian subsurface and sediments.

Hartman, Hyman↗
NASA NTRS1987

A preliminary study of a Mars penetrator system for subsurface exobiological exploration

The earth seems to stand alone among the planets of the solar system in that its surface, atmosphere, and hydrosphere provide an environment conducive to the maintenance of life. At one time, Mars was also considered to have the potential to harbor life. However, the absence of detectable organic molecules at the two Viking landing sites and the absence of liquid water anywhere on the surface seems to indicate that life is not present on Mars now. There are, however, many indications that the surface of Mars was less hostile in the distant past and the possibility that life may have existed on primordial Mars or that prebiotic chemistry may have occurred can not be excluded. The search for the organic evidence of this prebiotic or biotic activity will require a subsurface study of possible sediments at several sites. The purpose of this paper is to propose and describe a device termed a penetrator to emplant the required instrumentation beneath the surface (2-4 m) at likely sites to search for the evidence of biogenic organic material. The paper examines, in detail, the rationale for the scientific activity, any issues of technical feasibility, and describes the associated system requirements.

Swenson, Byron L.↗
DOE OSTI2024

Comparative clumped isotope temperature relationships in freshwater carbonates

Lacustrine, riverine and spring carbonates represent archives of terrestrial climates and their geochemistry has been used to study palaeoenvironments. Clumped isotope thermometry is an emerging tool that has been applied to freshwater carbonates. Limited work has been done to evaluate comparative relationships between clumped isotopes and temperature in different types of modern freshwater carbonates. This study assembles an extensive calibration data set with 135 samples of modern freshwater carbonates from 96 sites and constrains the relationship between independent observations of water temperature and the clumped isotopic composition of carbonates (denoted by Δ 47 ), including new measurements, and recalculates published data in accordance with current community-defined standard values. For temperature reconstruction, the study reports a composite freshwater calibration and material-specific calibrations for biogenic carbonates (freshwater gastropods and bivalves), fine-grained carbonate (e.g. micrites), biologically mediated carbonates (microbialites and tufas) and travertines. Material-specific calibration trends show a convergence of slopes that are in agreement with recently published syntheses, but statistically significant differences in intercepts occur between some materials (e.g. some biogenics, fine-grained carbonates). These differences may arise due to unresolved seasonal biases, kinetic isotope effects and/or varying degrees of biological influence. The impact of different calibrations is shown through application to new data for glacial and deglacial age travertines from Austria and published data sets. While material-specific calibrations may yield more accurate results for biogenic and fine-grained carbonate samples, the use of material-specific and the composite freshwater calibrations generally produces values within 1.0–1.5°C of each other, and typically fall within calibration uncertainty given limitations of precision.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Direct evidence for eoarchean iron metabolism?

Metasedimentary rocks from Isua, West Greenland (> 3,700 million years old) contain carbonaceous compounds, compatible with a biogenic origin. The metamorphic mineral assemblage with garnet and quartz intergrowths contains layers of carbonaceous inclusions contiguous with carbon–rich sedimentary beds in the host rock. Previous studies on Isua rocks focused on testing the biogenic origin of the carbonaceous material, but here we searched for evidence which could provide new insights into the nature of the life that generated this carbonaceous material. We studied material trapped in inclusions armoured within quartz grains inside garnet porphyroblasts by non–destructive ptychographic X–ray nanotomography (PXCT). The 3D electron density maps generated by PXCT were correlated with maps from X–ray fluorescence tomography and micro–Raman spectroscopy. We found that the material trapped inside inclusions in the quartz grains consist of disordered carbon material encasing domains of iron–rich carbonaceous material. These results corroborate earlier claims for biogenic origins and are compatible with relics of metamorphosed biological material originally containing high iron/carbon ratios, comparable to ratios found in most extant organisms. Finally, these iron–rich domains represent the oldest evidence for organic iron complexes in the geologic record and are consistent with Fe–isotopic evidence for metabolic iron fractionation in > 3,700 Ma Isua banded iron formation.

58 GEOSCIENCES↗
DOE OSTI2020

Clumped 13 CH 2 D and 12 CHD 2 compositions of methyl groups from wood and synthetic monomers: Methods, experimental and theoretical calibrations, and initial results

Methyl groups are found in numerous biogenic and synthetic materials including geologically preserved materials such as wood. The carbon and hydrogen isotope compositions of methyl groups are used as tracers in biogeochemical cycles, as paleothermometers, and to determine the hydrogen isotopic composition of ancient rain. Here we present analyses of resolved 13 C–D ( 13 CH 2 D) and D–D ( 12 CHD 2 ) clumped isotope compositions of methyl groups as new variables for the study of methyl groups in the present and past. We first present chemical methods to extract, purify, and derivatize methyl groups from methoxyl (R–O–CH 3 ) groups as CH 3 F and CH 3 Cl, and high-resolution mass spectrometric techniques to determine the clumped isotope compositions of these species. We achieve precisions for 13 C–D clumping of ±0.25‰ and D–D clumping of ±2.5‰. We anchor our clumped isotopic measurements to a thermodynamic reference frame by first calculating the theoretical temperature dependences of 13 C–D and D–D clumping in CH 3 Cl, then placing our measurements onto this reference frame through experimental internal isotopic equilibration of CH 3 Cl at 200 °C. Finally, we provide and analyze an initial dataset of clumped 13 C–D and D–D compositions of methyl groups from various commercial/synthetic monomers and environmental woods. We observe ranges in clumped isotope compositions of ~11‰ in 13 C–D and ~48‰ in D–D, and systematic differences within these ranges between methyl groups from commercial monomers and wood. Specifically, commercial clumped 13 C–D compositions are between 0 and 3‰, which correspond to apparent equilibrium temperatures between 170 °C and the infinite temperature limit. In contrast, the clumped 13 C–D compositions of wood methoxyl groups are distinctively high (9.50–11.25‰) and 3–6‰ higher than would be expected if formed in internal isotopic equilibrium at Earth-surface temperatures. Commercial/synthetic methyl and wood methoxyl clumped D–D compositions are also distinct: -5 to +13‰ in commercial monomers vs. -35 to -8‰ in wood—such negative values cannot result from formation in isotopic equilibrium and require kinetic processes to have occurred. Overall, these results indicate that wood methoxyl groups are formed out of isotopic equilibrium and that clumped isotope compositions of methyl groups may be useful tracers of methyl group sources and sinks in the environment. For instance, isotopic clumping in methyl groups may be useful for understanding controls on isotopic clumping in methane produced by methylotrophic methanogens.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

High resolution chronology of late Cretaceous-early Tertiary events determined from 21,000 yr orbital-climatic cycles in marine sediments

A number of South Atlantic sites cored by the Deep Sea Drilling Project (DSDP) recovered late Cretaceous and early Tertiary sediments with alternating light-dark, high-low carbonate content. The sedimentary oscillations were turned into time series by digitizing color photographs of core segments at a resolution of about 5 points/cm. Spectral analysis of these records indicates prominent periodicity at 25 to 35 cm in the Cretaceous intervals, and about 15 cm in the early Tertiary sediments. The absolute period of the cycles that is determined from paleomagnetic calibration at two sites is 20,000 to 25,000 yr, and almost certainly corresponds to the period of the earth's precessional cycle. These sequences therefore contain an internal chronometer to measure events across the K/T extinction boundary at this scale of resolution. The orbital metronome was used to address several related questions: the position of the K/T boundary within magnetic chron 29R, the fluxes of biogenic and detrital material to the deep sea immediately before and after the K/T event, the duration of the Sr anomaly, and the level of background climatic variability in the latest Cretaceous time. The carbonate/color cycles that were analyzed contain primary records of ocean carbonate productivity and chemistry, as evidenced by bioturbational mixing of adjacent beds and the weak lithification of the rhythmic sequences. It was concluded that sedimentary sequences that contain orbital cyclicity are capable of providing resolution of dramatic events in earth history with much greater precision than obtainable through radiometric methods. The data show no evidence for a gradual climatic deterioration prior to the K/T extinction event, and argue for a geologically rapid revolution at this horizon.

Herbert, Timothy D.↗
NASA NTRS2006

Chemical Mapping of Proterozoic Organic Matter at Sub-Micron Spatial Resolution

We have used a NanoSIMS ion microprobe to map sub-micron-scale distributions of carbon, nitrogen, sulfur, silicon, and oxygen in organic microfossils and laminae from the approximately 0.85 Ga Bitter Springs Formation of Australia. The data provide clues about the original chemistry of the microfossils, the silicification process, and biosignatures of specific microorganisms and microbial communities. Chemical maps of fossil unicells and filaments reveal distinct wall-and sheath-like structures enriched in C, N and S, consistent with their accepted biological origin. Surprisingly, organic laminae, previously considered to be amorphous, also exhibit filamentous and apparently compressed spheroidal structures defined by strong enrichments in C, N and S. By analogy to data from the well-preserved microfossils, these structures are interpreted as being of biological origin, most likely representing densely packed remnants of microbial mats. Because the preponderance of organic matter in Precambrian sediments is similarly "amorphous," our findings open a large body of generally neglected material to in situ structural, chemical, and isotopic study. Our results also offer new criteria for assessing biogenicity of problematic kerogenous materials and thus can be applied to assessments of poorly preserved or fragmentary organic residues in early Archean sediments and any that might occur in meteorites or other extraterrestrial samples.

Oehler, Dorothy Z.↗