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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Assessment of landscape-scale fluxes of carbon dioxide and methane in subtropical coastal wetlands of South Florida

Coastal wetlands play a significant role in the storage of “blue carbon,” indicating their importance in the carbon biogeochemistry in the coastal zone and in global climate change mitigation strategies. We present airborne eddy covariance observations of CO 2 and CH 2 fluxes collected in southern Florida as part of the NASA BlueFlux mission during April 2022, October 2022, February 2023, and April 2023. The flux data generated from this mission consists of over 100 flight hours and more than 6,000 km of horizontal distance over coastal saline and freshwater wetlands. We find that the spatial and temporal heterogeneity in CO 2 and CH 2 exchange is primarily influenced by season, vegetation type, ecosystem productivity, and soil inundation. The largest CO 2 uptake fluxes of more than 20 μmol m -2 s -1 were observed over mangroves during all deployments and over swamp forests during flights in April. The greatest CH 4 effluxes of more than 250 nmol m -2 s -1 were measured at the end of the wet season in October 2022 over freshwater marshes and swamp shrublands. Although the combined Everglades National Park and Big Cypress National Preserve region was a net sink for carbon, CH 4 emissions reduced the ecosystem carbon uptake capacity (net CO 2 exchange rates) by 11%–91%. Average total net carbon exchange rates during the flight periods were −4 to −0.2 g CO 2 -eq m -2 d -1 . Our results highlight the importance of preserving mangrove forests and point to potential avenues of further research for greenhouse gas mitigation strategies.

atmosphere↗

Ocean Carbon From Space: Current Status and Priorities for the Next Decade

The ocean plays a central role in modulating the Earth’s carbon cycle. Monitoring how the ocean carbon cycle is changing is fundamental to managing climate change. Satellite remote sensing is currently our best tool for viewing the ocean surface globally and systematically, at high spatial and temporal resolutions, and the past few decades have seen an exponential growth in studies utilising satellite data for ocean carbon research. Satellite-based observations must be combined with in-situ observations and models, to obtain a comprehensive view of ocean carbon pools and fluxes. To help prioritise future research in this area, a workshop was organised that assembled leading experts working on the topic, from around the world, including remote-sensing scientists, field scientists and modellers, with the goal to articulate a collective view of the current status of ocean carbon research, identify gaps in knowledge, and formulate a scientific roadmap for the next decade, with an emphasis on evaluating where satellite remote sensing may contribute. A total of 449 scientists and stakeholders participated (with balanced gender representation), from North and South America, Europe, Asia, Africa, and Oceania. Sessions targeted both inorganic and organic pools of carbon in the ocean, in both dissolved and particulate form, as well as major fluxes of carbon between reservoirs (e.g., primary production) and at interfaces (e.g., air-sea and land–ocean). Extreme events, blue carbon and carbon budgeting were also key topics discussed. Emerging priorities identified include: expanding the networks and quality of in-situ observations; improved satellite retrievals; improved uncertainty quantification; improved understanding of vertical distributions; integration with models; improved techniques to bridge spatial and temporal scales of the different data sources; and improved fundamental understanding of the ocean carbon cycle, and of the interactions among pools of carbon and light. We also report on priorities for the specific pools and fluxes studied, and highlight issues and concerns that arose during discussions, such as the need to consider the environmental impact of satellites or space activities; the role satellites can play in monitoring ocean carbon dioxide removal approaches; economic valuation of the satellite based information; to consider how satellites can contribute to monitoring cycles of other important climatically-relevant compounds and elements; to promote diversity and inclusivity in ocean carbon research; to bring together communities working on different aspects of planetary carbon; maximising use of international bodies; to follow an open science approach; to explore new and innovative ways to remotely monitor ocean carbon; and to harness quantum computing. Overall, this paper provides a comprehensive scientific roadmap for the next decade on how satellite remote sensing could help monitor the ocean carbon cycle, and its links to the other domains, such as terrestrial and atmosphere.

oceanography↗

Inundation and Sediment Supply Predict Annual but Not Centennial Carbon Accumulation in Tidal Wetlands Across Land‐Use Types

Despite growing interest in the contributions of tidal wetlands to natural climate solutions, data remain scarce on how land use affects their carbon accumulation rates (CAR). Additionally, environmental factors driving the large observed variability in CAR among sites are poorly understood. To address these knowledge gaps, we measured short-term (∼1 year) and long-term (∼100 years) CAR using feldspar marker horizons, 210 Pb profiles, and surface elevation tables from 39 sites in seven estuaries in Oregon and Washington, USA. Sites varied in wetland type (tidal marsh, tidal swamp, nontidal pasture), land-use history (reference, restored, and disturbed), and salinity (fresh to polyhaline). Across both timescales, CAR was lowest in disturbed pastures and highest in restored marshes, reflecting patterns in sediment accretion rates. Short-term CAR exceeded long-term CAR by approximately 50% on average and was only weakly correlated with long-term CAR, with differences among hydrogeomorphic setting. Short-term CAR was well predicted by summer inundation frequency and relative sediment load, together explaining 60% of variance, whereas long-term CAR was poorly predicted by contemporary environmental conditions. These findings highlight the importance of aligning predictor and response timescales when modeling blue carbon dynamics, and reinforce the climate mitigation potential of tidal wetland restoration.

land use and land cover change↗

Methane fluxes in tidal marshes of the conterminous United States

Abstract Methane (CH 4 ) is a potent greenhouse gas (GHG) with atmospheric concentrations that have nearly tripled since pre‐industrial times. Wetlands account for a large share of global CH 4 emissions, yet the magnitude and factors controlling CH 4 fluxes in tidal wetlands remain uncertain. We synthesized CH 4 flux data from 100 chamber and 9 eddy covariance (EC) sites across tidal marshes in the conterminous United States to assess controlling factors and improve predictions of CH 4 emissions. This effort included creating an open‐source database of chamber‐based GHG fluxes ( https://doi.org/10.25573/serc.14227085 ). Annual fluxes across chamber and EC sites averaged 26 ± 53 g CH 4 m −2 year −1 , with a median of 3.9 g CH 4 m −2 year −1 , and only 25% of sites exceeding 18 g CH 4 m −2 year −1 . The highest fluxes were observed at fresh‐oligohaline sites with daily maximum temperature normals (MATmax) above 25.6°C. These were followed by frequently inundated low and mid‐fresh‐oligohaline marshes with MATmax ≤25.6°C, and mesohaline sites with MATmax >19°C. Quantile regressions of paired chamber CH 4 flux and porewater biogeochemistry revealed that the 90th percentile of fluxes fell below 5 ± 3 nmol m −2 s −1 at sulfate concentrations >4.7 ± 0.6 mM, porewater salinity >21 ± 2 psu, or surface water salinity >15 ± 3 psu. Across sites, salinity was the dominant predictor of annual CH 4 fluxes, while within sites, temperature, gross primary productivity (GPP), and tidal height controlled variability at diel and seasonal scales. At the diel scale, GPP preceded temperature in importance for predicting CH 4 flux changes, while the opposite was observed at the seasonal scale. Water levels influenced the timing and pathway of diel CH 4 fluxes, with pulsed releases of stored CH 4 at low to rising tide. This study provides data and methods to improve tidal marsh CH 4 emission estimates, support blue carbon assessments, and refine national and global GHG inventories.

54 ENVIRONMENTAL SCIENCES↗

Microbial community dynamics and coexistence in a sulfide-driven phototrophic bloom

Background: Lagoons are common along coastlines worldwide and are important for biogeochemical element cycling, coastal biodiversity, coastal erosion protection and blue carbon sequestration. These ecosystems are frequently disturbed by weather, tides, and human activities. Here, we investigated a shallow lagoon in New England. The brackish ecosystem releases hydrogen sulfide particularly upon physical disturbance, causing blooms of anoxygenic sulfur-oxidizing phototrophs. To study the habitat, microbial community structure, assembly and function we carried out in situ experiments investigating the bloom dynamics over time. Results: Phototrophic microbial mats and permanently or seasonally stratified water columns commonly contain multiple phototrophic lineages that coexist based on their light, oxygen and nutrient preferences. We describe similar coexistence patterns and ecological niches in estuarine planktonic blooms of phototrophs. The water column showed steep gradients of oxygen, pH, sulfate, sulfide, and salinity. The upper part of the bloom was dominated by aerobic phototrophic Cyanobacteria, the middle and lower parts by anoxygenic purple sulfur bacteria (Chromatiales) and green sulfur bacteria (Chlorobiales), respectively. We show stable coexistence of phototrophic lineages from five bacterial phyla and present metagenome-assembled genomes (MAGs) of two uncultured Chlorobaculum and Prosthecochloris species. In addition to genes involved in sulfur oxidation and photopigment biosynthesis the MAGs contained complete operons encoding for terminal oxidases. The metagenomes also contained numerous contigs affiliating with Microviridae viruses, potentially affecting Chlorobi. Our data suggest a short sulfur cycle within the bloom in which elemental sulfur produced by sulfide-oxidizing phototrophs is most likely reduced back to sulfide by Desulfuromonas sp. Conclusions: The release of sulfide creates a habitat selecting for anoxygenic sulfur-oxidizing phototrophs, which in turn create a niche for sulfur reducers. Strong syntrophism between these guilds apparently drives a short sulfur cycle that may explain the rapid development of the bloom. The fast growth and high biomass yield of Chlorobi-affiliated organisms implies that the studied lineages of green sulfur bacteria can thrive in hypoxic habitats. This oxygen tolerance is corroborated by oxidases found in MAGs of uncultured Chlorobi. The findings improve our understanding of the ecology and ecophysiology of anoxygenic phototrophs and their impact on the coupled biogeochemical cycles of sulfur and carbon.

59 BASIC BIOLOGICAL SCIENCES↗

Tailoring sub-3.3 Å ultramicropores in advanced carbon molecular sieve membranes for blue hydrogen production

Carbon molecular sieve (CMS) membranes prepared by carbonization of polymers containing strongly size-sieving ultramicropores are attractive for high-temperature gas separations. However, polymers need to be carbonized at extremely high temperatures (900° to 1200°C) to achieve sub-3.3 Å ultramicroporous channels for H 2 /CO 2 separation, which makes them brittle and impractical for industrial applications. Here, we demonstrate that polymers can be first doped with thermolabile cross-linkers before low-temperature carbonization to retain the polymer processability and achieve superior H 2 /CO 2 separation properties. Specifically, polybenzimidazole (PBI) is cross-linked with pyrophosphoric acid (PPA) via H bonding and proton transfer before carbonization at ≤600°C. The synergistic PPA doping and subsequent carbonization of PBI increase H 2 permeability from 27 to 140 Barrer and H 2 /CO 2 selectivity from 15 to 58 at 150°C, superior to state-of-the-art polymeric materials and surpassing Robeson’s upper bound. This study provides a facile and effective way to tailor subnanopore size and porosity in CMS membranes with desirable molecular sieving ability.

42 ENGINEERING↗

Lignin-Derived Magnetic Activated Carbons for Effective Methylene Blue Removal

Large-scale environmental remediation of polluted water requires an effective and recyclable adsorbent produced from an abundant, low-cost, and renewable feedstock via a simple processing procedure. In this work, we demonstrate that lignin-derived magnetic activated carbons (mACs) uniquely satisfy these five criteria for (i) high-performance adsorption, (ii) high regeneration efficiency, (iii) feedstock economic and environmental viability, (iv) single-step processing and (v) large-scale production. The mACs are synthesized via an efficient co-carbonization and activation with simultaneous impregnation of ferric sulfate. Here, the Langmuir model closely fits the adsorption of methylene blue (MB) by mACs within the temperature range of 298–323 K, where the adsorption capacity increases as temperature increases. This capacity increased from 55.0 mg g -1 to 220.2 mg g -1 with the presence of magnetic nanoparticles. In addition, the magnetite nanoparticles on the ACs surface significantly improve its recycling ability with the removal percentage above 95% after four cycles for 5:1 mAC.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

One hundred priority questions for advancing seagrass conservation in Europe

Societal Impact Statement Seagrass ecosystems are of fundamental importance to our planet and wellbeing. Seagrasses are marine flowering plants, which engineer ecosystems that provide a multitude of ecosystem services, for example, blue foods and carbon sequestration. Seagrass ecosystems have largely been degraded across much of their global range. There is now increasing interest in the conservation and restoration of these systems, particularly in the context of the climate emergency and the biodiversity crisis. The collation of 100 questions from experts across Europe could, if answered, improve our ability to conserve and restore these systems by facilitating a fundamental shift in the success of such work. Summary Seagrass meadows provide numerous ecosystem services including biodiversity, coastal protection, and carbon sequestration. In Europe, seagrasses can be found in shallow sheltered waters along coastlines, in estuaries & lagoons, and around islands, but their distribution has declined. Factors such as poor water quality, coastal modification, mechanical damage, overfishing, land‐sea interactions, climate change and disease have reduced the coverage of Europe’s seagrasses necessitating their recovery. Research, monitoring and conservation efforts on seagrass ecosystems in Europe are mostly uncoordinated and biased towards certain species and regions, resulting in inadequate delivery of critical information for their management. Here, we aim to identify the 100 priority questions, that if addressed would strongly advance seagrass monitoring, research and conservation in Europe. Using a Delphi method, researchers, practitioners, and policymakers with seagrass experience from across Europe and with diverse seagrass expertise participated in the process that involved the formulation of research questions, a voting process and an online workshop to identify the final list of the 100 questions. The final list of questions covers areas across nine themes: Biodiversity & Ecology; Ecosystem services; Blue carbon; Fishery support; Drivers, Threats, Resilience & Response; Monitoring & Assessment; Conservation & Restoration; Governance, Policy & Management; and Communication. Answering these questions will fill current knowledge gaps and place European seagrass onto a positive trajectory of recovery.

Nordlund, Lina Mtwana↗

Sea Level-Driven Marsh Migration Results in Rapid Net Loss of Carbon

Sea level rise alters coastal carbon cycling by driving the rapid migration of coastal ecosystems, salinization of freshwater systems, and replacement of terrestrial forests with tidal wetlands. Wetland soils accumulate carbon (C) at faster rates than terrestrial soils, implying that sea level rise may lead to enhanced carbon accumulation. Here, we show that carbon stored in tree biomass greatly exceeds carbon stored in adjacent marsh soils so that marsh migration reduces total carbon stocks by ~50% in less than 100 years. Continued marsh soil carbon accumulation may eventually offset forest carbon loss, but we estimate that the time for replacement is similar to estimates of marsh survival (i.e., centuries), which suggests that forest C may never be replaced. These findings reveal a critical C source not included in coastal C budgets driven by migrating ecosystems and rapidly shifting allocations between carbon stored in soils and biomass.

58 GEOSCIENCES↗

Methods for Measuring Carbon Dioxide Uptake and Permanence: Review and Implications for Macroalgae Aquaculture

Carbon dioxide removal (CDR) is gaining recognition as a necessary action in addition to emissions reduction to prevent some of the worst effects of climate change. Macroalgae aquaculture has been identified as a potential CDR strategy and significant research investments have been made in this area. This article reviews current methods for monitoring carbon to assess the potential for application in the context of macroalgae aquaculture as a CDR strategy. In total, 382 papers were included in the review and categorized by carbon uptake methods, carbon permanence methods, and comprehensive frameworks for assessing carbon capture. While methods for measuring carbon uptake are well established, methods to assess the permanence of carbon in the natural life cycle of macroalgae and in products following harvest are lacking. To achieve the full benefit of macroalgae cultivation as a climate solution, monitoring, reporting, and verification standards and improved methods for assessing carbon uptake and permanence need to be developed.

59 BASIC BIOLOGICAL SCIENCES↗

Measuring Mangrove Carbon Loss and Gain in Deltas

Demand for mangrove forest resources has led to a steady decline in mangrove area over the past century. Land conversions in the form of agriculture, aquaculture and urbanization account for much of the deforestation of mangrove wetlands. However, natural processes at the transition zone between land and ocean can also rapidly change mangrove spread. In this study, we applied a robust field-based carbon inventory and new structural and temporal remote sensing techniques to quantify the magnitude and change of mangrove carbon stocks in major deltas across Africa and Asia. From 2000–2016, approximately 1.6% (12 270 ha) of the total mangrove area within these deltas disappeared, primarily through erosion and conversion to agriculture. However, the rapid expansion of mangroves in some regions during this same period resulted in new forests that were taller and more carbon-dense than the deforested areas. Because of the rapid vertical growth rates and horizontal expansion, new mangrove forests were able to offset the total carbon losses of 5 332 843 Mg C by 44%. Each hectare of new mangrove forest accounted for ∼84% to ∼160% of the aboveground carbon for each hectare of mangrove forest lost, regardless of the net change in mangrove area. Our study highlights the significance of the natural dynamics of erosion and sedimentation on carbon loss and sequestration potential for mangroves over time. Areas of naturally regenerating mangroves will have a much larger carbon sequestration potential if the rate of mangrove deforestation of taller forests is curbed.

canopy height↗

Atmospheric CO 2 Emissions and Ocean Acidification From Bottom-Trawling

Trawling the seafloor can disturb carbon that took millennia to accumulate, but the fate of that carbon and its impact on climate and ecosystems remains unknown. Using satellite-inferred fishing events and carbon cycle models, we find that 55-60% of trawling-induced aqueous CO 2 is released to the atmosphere over 7-9 years. Using recent estimates of bottom trawling’s impact on sedimentary carbon, we found that between 1996-2020 trawling could have released, at the global scale, up to 0.34-0.37 Pg CO 2 yr -1 to the atmosphere, and locally altered water pH in some semi-enclosed and heavy trawled seas. Our results suggest that the management of bottom-trawling efforts could be an important climate solution.

climate mitigation↗

Metabolic Profiling Reveals Biochemical Pathways Responsible for Eelgrass Response to Elevated CO2 and Temperature

Abstract As CO 2 levels in Earth’s atmosphere and oceans steadily rise, varying organismal responses may produce ecological losers and winners. Increased ocean CO 2 can enhance seagrass productivity and thermal tolerance, providing some compensation for climate warming. However, the metabolic shifts driving the positive response to elevated CO 2 by these important ecosystem engineers remain unknown. We analyzed whole-plant performance and metabolic profiles of two geographically distinct eelgrass ( Zostera marina L.) populations in response to CO 2 enrichment. In addition to enhancing overall plant size, growth and survival, CO 2 enrichment increased the abundance of Calvin Cycle and nitrogen assimilation metabolites while suppressing the abundance of stress-related metabolites. Overall metabolome differences between populations suggest that some eelgrass phenotypes may be better suited than others to cope with an increasingly hot and sour sea. Our results suggest that seagrass populations will respond variably, but overall positively, to increasing CO 2 concentrations, generating negative feedbacks to climate change.

59 BASIC BIOLOGICAL SCIENCES↗

Impacts of Hurricane Disturbance on Water Quality across the Aquatic Continuum of a Blackwater River to Estuary Complex

Hurricanes cause landscape-scale disturbances that affect biogeochemical cycling and water quality in coastal ecosystems. During Hurricane Irma’s passage through northern Florida, water movements driven by wind velocities up to 105 km h-1 caused a salinity peak in an estuary/blackwater river complex. Water quality was monitored across the 15 km site to detect the magnitude and duration of disturbance. Saline water intruded 15 km inland into a freshwater portion of the river that peaked at a salinity of 2 psu. Due to the volume of precipitation from the hurricane, significant runoff of freshwater and dissolved organic matter (DOM) caused a decrease in salinity, dissolved oxygen (DO), and Chlorophyll-a concentrations while increasing turbidity and fluorescent dissolved organic matter (fDOM). The disturbance caused rapid changes observed by in-situ water quality monitors over a 3-week period, but some effects persisted for longer periods as shown by 3-month weekly water sampling. This disturbance caused shifts in DOM loading, altered salinity dynamics, and reshaped landscapes due to wind and wave surge both in upland marsh and downstream estuary. Hurricane disturbance temporarily and abruptly alters the aquatic continuum, and observations of system response can help us understand the mechanisms associated with ecosystem resilience and recovery.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of New Opportunities for Marine Energy To Power the Blue Economy: Green Hydrogen and Marine Carbon Dioxide Removal

This report examines the intersection of marine energy and the sectors of green hydrogen and marine Carbon Dioxide Removal, taking into account potential synergies, market maturity, barriers, policy enablers, and sustainability perspectives. Through desk research and interviews with a diverse range of subject matter experts from academia, government, industry, venture capital, and non-profit sectors, these emergent sectors were identified as the most promising new opportunities for marine energy integration beyond those explored in the 2019 Powering the Blue Economy Report. The findings presented are the combined result of desk research and information gathered through these interviews.

13 HYDRO ENERGY↗