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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Toward Fully 3D-Printed Two Degree of Freedom Acoustic Liners

An acoustic liner optimization tool is developed for designing two degree of freedom (2DOF) liners with high absorption over a wide range of frequencies and sound pressure levels (SPLs). Two additively manufactured 2DOF liners (one constant and one variable chamber depth) are designed and printed with an embedded perforate layer as the septum. A normal incidence impedance tube study is performed to directly compare impedance and absorption spectra to a more traditionally manufactured 2DOF liner with embedded mesh caps in phenolic honeycomb. Comparisons of test data to predictions are shown as well as SPL sensitivities for each acoustic liner. Broadband absorption is achieved with the 3D printed 2DOF liner containing constant chamber depths, although due to current limitations in printed embedded perforate hole size, not as broad as the traditional mesh cap liner. However, results also show that the 3D printed variable chamber depth sample is more comparable to the mesh cap liner absorption, demonstrating the viability of printed embedded perforates in novel concepts.

acoustic liner 2DOF two degree of freedom 3D print↗
DOE OSTI2021

Electronic Coherence and Coherent Dephasing in the Optical Control of Electrons in Graphene

Electronic coherence is of utmost importance for the access and control of quantum-mechanical solid-state properties. Using a purely electronic observable, the photocurrent, we measure a lower bound of the electronic coherence time of 22 ± 4 fs in graphene. The photocurrent is ideally suited to measure electronic coherence, as it is a direct result of coherent quantum-path interference, controlled by the delay between two ultrashort two-color laser pulses. The maximum delay for which interference between the population amplitude injected by the first pulse interferes with that generated by the second pulse determines the electronic coherence time. In particular, numerical simulations reveal that the experimental data yields a lower bound on the electronic coherence time, masked by coherent dephasing due to the broadband absorption in graphene. Overall, we expect that our results will significantly advance the understanding of coherent quantum control in solid-state systems ranging from excitation with weak fields to strongly driven systems.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Momentum-Space Observation of Optically Excited Nonthermal Electrons in Graphene with Persistent Pseudospin Polarization

The unique optical properties of graphene, with broadband absorption and ultrafast response, make it a critical component of optoelectronic and spintronic devices. Using time-resolved momentum microscopy with high data rate and high dynamic range, we report momentum-space measurements of electrons promoted to the graphene conduction band with visible light and their subsequent relaxation. Here, we observe a pronounced nonthermal distribution of nascent photoexcited electrons with lattice pseudospin polarization in remarkable agreement with results of simple tight-binding theory. By varying the excitation fluence, we vary the relative importance of electron-electron vs electron-phonon scattering in the relaxation of the initial distribution. Increasing the excitation fluence results in increased noncollinear electron-electron scattering and reduced pseudospin polarization, although up-scattered electrons retain a degree of polarization. These detailed momentum-resolved electron dynamics in graphene demonstrate the capabilities of high-performance time-resolved momentum microscopy in the study of 2D materials and can inform the design of graphene devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Broadband Infrared Carbon Nanotube Linear Photodetector Arrays

Carbon nanotubes (CNTs) possess exceptional optoelectronic properties, including broadband absorption and high absorption coefficients, making them promising candidates for photodetector applications. However, conventional designs often rely on single or aligned nanotubes, which restrict device scalability and require complex fabrication techniques. Here, in this work, we address these limitations by utilizing CNT-suspended solutions to fabricate large-area photodetectors based on CNT networks via vacuum filtration and direct laser scribing. CNT networks are uniformly formed onto low-thermal-conductance polymeric filter papers that serve as substrates and mitigate the need for suspended structures, reducing the fabrication complexity and cost. The CNT films are patterned into single devices and 49-pixel linear arrays by using a laser-cutting process, enabling scalable and cost-effective production. The resulting devices operate as bolometers and exhibit broad spectral sensitivity extending from visible to midwave infrared, showing stable operation at room temperature. We further demonstrate proof-of-concept IR imaging using linear arrays.

IR imaging↗
DOE OSTI2022

Shape memory in self-adapting colloidal crystals

We report reconfigurable, mechanically responsive crystalline materials are central components in many sensing, soft robotic, and energy conversion and storage devices1,2,3,4. Crystalline materials can readily deform under various stimuli and the extent of recoverable deformation is highly dependent upon bond type1,2,5,6,7,8,9,10. Indeed, for structures held together via simple electrostatic interactions, minimal deformations are tolerated. By contrast, structures held together by molecular bonds can, in principle, sustain much larger deformations and more easily recover their original configurations. In this report we study the deformation properties of well-faceted colloidal crystals engineered with DNA. These crystals are large in size (greater than 100 µm) and have a body-centred cubic (bcc) structure with a high viscoelastic volume fraction (of more than 97%). Therefore, they can be compressed into irregular shapes with wrinkles and creases, and, notably, these deformed crystals, upon rehydration, assume their initial well-formed crystalline morphology and internal nanoscale order within seconds. For most crystals, such compression and deformation would lead to permanent, irreversible damage. The substantial structural changes to the colloidal crystals are accompanied by notable and reversible optical property changes. For example, whereas the original and structurally recovered crystals exhibit near-perfect (over 98%) broadband absorption in the ultraviolet–visible region, the deformed crystals exhibit significantly increased reflection (up to 50% of incident light at certain wavelengths), mainly because of increases in their refractive index and inhomogeneity.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Standoff detection of chemical plumes from high explosive open detonations using a swept-wavelength external cavity quantum cascade laser

A swept-wavelength external cavity quantum cascade laser (ECQCL) is used to perform standoff detection of combustion gases in a plume generated from an outdoor high-explosive (HE) open detonation. The swept-ECQCL system was located at a standoff distance of 830 m from a 41kg charge of LX-14(polymer-bonded high explosive) and was used to measure the infrared transmission/absorption through the post-detonation plume as it propagated through the beam path. The swept-ECQCL was operated continuously to record broadband absorption spectra at 200hz rate over a spectral range from 2050 to 2230 cm -1 (4.48 - 4.88 μm). Fitting of measured spectra was used to determine time-resolved column densities of CO, CO 2 , H 2 O, and N 2 O. Analysis of visible video imagery was used to provide timing correlations and to estimate plume dimensions, from which gas mixing ratios were estimated. Measured emission factors and modified combustion efficiency show good agreement with previously reported values.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Photophysical properties of zero-dimensional perovskites studied by PBE0 and GW+BSE methods

Due to the exceptional photophysical properties and great potential applications in solid state lighting, zero-dimensional halide perovskites with broadband emitting have recently attracted much attention. In this work, to reveal the origin of the broadband absorption and emission spectra of 0D (C 4 N 2 H 14 Br) 4 SnBr x I 6-x (x = 3), the ground state and exciton dynamics properties have been studied by hybrid PBE0 functional and the GW+BSE method. Different self-trapped excitons (STEs) are obtained, and their emission energies by PBE0 are consistent well with experimental data. By considering the vibrational broadening of emission, our calculated full width at half maximum of emission accords well with the experiment. The absorption of free exciton and STEs is also calculated by considering the quasiparticle and excitonic effect. Our results show that these light-induced trapped states can be observed by experiments, as confirmed in other similar systems by the femtosecond transient absorption spectra.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

High-precision monitoring of outgassing species in model extreme ultraviolet photoresists with a cavity ring-down spectrometer

Background Extreme ultraviolet (EUV) photoresists play a pivotal role in advancing nanopatterning technologies by balancing image quality and sensitivity. The outgassing behavior of photoresist thin films under EUV and deep ultraviolet (DUV) exposure reveals chemical details relevant to their performance. Aim Here, we focus on utilizing an analytical technique not previously used in photolithography, the tabletop cavity ring-down spectrometer, to investigate outgassing dynamics in EUV photoresists, enabling precise chemical identification and deeper insights into resist processing. Approach The spectrometer’s enhanced laser path length (∼ 20 km) and broadband absorption capabilities in the C–H overtone region allow for sensitive and temporally resolved detection of mixtures of outgassed species. Using a model resist comprising a polymer matrix with a photoacid generator and quencher, we analyzed the influence of time delays between exposure and post-exposure bake (PEB) as well as storage under varying environmental conditions. Results Suppression of isobutylene outgassing and thickness loss was observed with extended delays between exposure and PEB, potentially linked to water absorption and acid deactivation. The technique proved highly effective in distinguishing subtle chemical differences between processing stages. Conclusions Delay times and their environmental conditions, particularly humidity, reduce outgassing and thickness loss of photoresists during PEB, suggesting decreased acid-driven deprotection. This can potentially impact sensitivity, defectivity, and roughness of resist patterns, necessitating precise monitoring and control.

Extreme ultraviolet photoresists↗
DOE OSTI2025

High precision monitoring of outgassing species in model EUV photoresists with a cavity ring-down spectrometer

Extreme ultraviolet (EUV) photoresists play a pivotal role in advancing nanopatterning technologies by balancing image quality and sensitivity. The outgassing behavior of photoresist thin films under EUV and deep ultraviolet (DUV) exposure reveals chemical details relevant to their performance. This study focuses on utilizing an analytical technique not previously used in photolithography, the tabletop cavity ring-down spectrometer, to investigate outgassing dynamics in EUV photoresists, enabling precise chemical identification and deeper insights into resist processing. The spectrometer’s enhanced laser path length (~20 km) and broadband absorption capabilities in the CH overtone region allow for sensitive and temporally resolved detection of outgassed species. Using a model resist comprising a polymer matrix with a photoacid generator and quencher, we analyzed the influence of time delays between exposure and Post-Exposure Bake (PEB) as well as storage under varying environmental conditions. Suppression of isobutylene outgassing and thickness loss was observed with extended delays between exposure and PEB, potentially linked to water absorption and acid deactivation. The technique proved highly effective in distinguishing subtle chemical differences between processing stages. Delay times and their environmental conditions, particularly humidity, reduce outgassing and thickness loss of photoresists during PEB, suggesting decreased acid-driven deprotection. This can potentially impact sensitivity, defectivity, and roughness of resist patterns, necessitating precise monitoring and control.

Lüttgenau, Bernhard↗
NASA NTRS1984

Properties of the Upper Tropospheres of Uranus and Neptune Derived from Observations at Visible to Near-Infrared Wavelengths

Photons at wavelengths between 0.3 and 4.5 microns penetrate the atmospheres of Uranus and Neptune to pressures between about 0.01 bar and 10 bars. This pressure range brackets the radiative convective boundary in both atmospheres and is therefore designated upper troposphere. Physical processes which govern the transfer of radiation in Uranus's and Neptune's atmospheres at these wavelengths include Rayleigh/Raman scattering by hydrogen, scattering and broadband absorption by suspended aerosol particles and absorption in discrete bands and lines by methane and hydrogen. Consequently, tropospheric properties constrained by observations at these wavelengths include optical properties and distribution of aerosol particles, methane/hydrogen ratio, and ortho/para hydrogen ratio. Recent observations of Uranus and Neptune in this spectral range, are reviewed and compared with predictions based on models of the atmospheric structures. Significant results for Uranus include the presence of an opaque lower boundary to the visible atmosphere very near the level corresponding to 2 bars pressure, and consequently a methane/hydrogen ratio no less than 3 percent.

Bergstralh, J. T.↗
NASA NTRS1983

Kinetic modeling of an IBr solar pumped laser

The possibility of using an IBr laser as a solar-energy converter is examined theoretically, and reasons for its choice are given. Broadband absorption results in dissociation with the formation of excited metastable Br atoms, some of which then lase to the ground state Br. The ground state is depopulated by three-body recombination and, more importantly, by exchange reactions which more than compensate for the high quenching in heteronuclear halogen systems. Kinetic modeling indicates lasing is possible in the pulsed mode and possibly in the steady state with a cooled gas flow system. Temperature effects are discussed. The efficiency of the laser approaches 1.2 percent at optical thicknesses large enough for complete absorption of the photons.

Harries, W. L.↗
NASA NTRS1990

Sensitivity of surface radiative fluxes to meteorological parameter errors

A parameterized radiative transfer model is employed to estimate longwave fluxes, while shortwave fluxes are estimated with a broadband absorption and scattering technique. Meteorological parameters of surface radiative fluxes are the profiles of temperature and cloud cover, ozone, water vapor and aerosols. A sensitivity study is presented to estimate the magnitudes of biases in the computed fluxes resulting from the biases in the satellite meteorological data.

Ritchey, Nancy A.↗
NASA NTRS1995

Laser-Induced Photochromic Centers in Ce(3+):La2Be2O5

Intense 355-nm excitation of the lowest 4f to 5d transition of Ce(3+):La2Be2O5 leads to a brownish coloration of the crystal due to the formation of stable photochromic centers. These centers are characterized by a broadband absorption spectrum that spans the 220-840 nm spectral range. Since they can be readily bleached by optical excitation into their absorption band, the centers are photochromic. They are produced by a two-step photoionization of Ce(3+) ions followed by attachment of the detached electrons at trapping sites in the crystal. The dependence of the number of centers on laser intensity and length of exposure have been measured, and the kinetics of growth have been studied.

Cheung, Y. M.↗
NASA NTRS1999

High Temperature Acoustic Liner Technology

This paper describes work currently in progress at Langley on liner concepts that employ structures that may be suitable for broadband exhaust noise attenuation in high speed flow environments and at elevated temperatures characteristic of HSCT applications. Because such liners will need to provide about 10 dB suppression over a 2 to 3 octave frequency range, conventional single-degree-of-freedom resonant structures will not suffice. Bulk absorbers have the needed broadband absorption characteristic; however, at lower frequencies they tend to be inefficient.

Parrott, Tony L.↗
NASA NTRS1995

Vibrational Energy Coupling in Expanding N2/O2/NO Admixtures

Recent direct measurements of N2 and O2 vibrational populations in expansions of synthetic air show a closer coupling of the vibrational energies than indicated by adapting earlier experimental results from shock compressions to the nozzle expansion problem. An important difference between the shock wave and nozzle flow problems is the presence of NO in significant amounts throughout the relaxation in the case of a nozzle flow. This may account for the stronger coupling since NO is well suited to promote vibrational energy exchange. The results of a series of experiments and analysis examining vibrational energy coupling in expansions of admixtures approximating air are reported. N2 and O2 vibrational populations are determined by a single-pulse spontaneous Raman scattering technique. NO vibrational populations are determined by broadband absorption by the NO(y) system. The resulting data permit the role of NO in promoting vibrational energy coupling to be better understood, and are used to evaluate models of vibrational energy exchange for application to expanding flows.

Gilmore, John O.↗
NASA NTRSDate not supplied

Evaluation of Variable-Depth Liners with Slotted Cores

An initial evaluation of variable-depth, slotted-core liners fabricated with conventional, flightworthy com-ponents is presented. Liners with two distinct chamber lengths provide significant broadband absorption and their impedances are, to first order, predictable with the NASA impedance prediction code. These liners employ film caps embedded in alternating chambers to provide a near-rigid boundary condition. This enables improved control of the liner design process. A number of additively-manufactured, bent-chamber liners are also investigated to explore the e˙ects of the bend on the liner impedance. The liner impedance is negligibly a˙ected by changes to the partition width, but is significantly a˙ected by changes to the slot height. This o˙ers an option for achieving low-frequency sound absorption with relatively thin liners.

acoustic↗
NASA NTRSDate not supplied

Evaluation of Variable-Depth Liners with Slotted Cores

An initial evaluation of variable-depth, slotted-core liners fabricated with conventional, flightworthy components is presented. Liners with two distinct chamber lengths provide significant broadband absorption and their impedances are, to first order, predictable with the NASA impedance prediction code. These liners employ film caps embedded in alternating chambers to provide a near-rigid boundary condition. This enables improved control of the liner design process. A number of additively-manufactured, bent-chamber liners are also investigated to explore the effects of the bend on the liner impedance. The liner impedance is negligibly affected by changes to the partition width, but is significantly affected by changes to the slot height. This offers an option for achieving low-frequency sound absorption with relatively thin liners.

acoustic↗