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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Comparative evaluation of insulating properties of plasma-sprayed ceramic coatings

A simple method for evaluating the thermal insulating capability of ceramic coatings was devised. It is based on monitoring the temperature of the uncoated back surface of a thin superalloy disk while its front surface, coated with the ceramic material, is exposed to the high-temperature environment of an electric muffle furnace. The results obtained indicate that zirconia containing 8 wt% Y2O3 is a better thermal insulator than barium zirconate or calcium orthosilicate.

Zaplatynsky, I.↗

Microstructure and Friction-Wear Behavior of Multi-arc Ion Plating TiAlNC Ceramic Coating on WC-6%Co Substrate

Nanocomposite coating could be used for machining tools, which can be used for cutting, drilling, milling, whetting, profiling, honing and superfinishing of various materials with high productivity. In this work, the TiAlNC ceramic coating was prepared by multi-arc ion plating method on WC-6%Co substrate. The microstructure and morphology of the coating were observed by scanning electron microscopy and transmission electron microscopy. The phase and chemical composition of the coating were determined by x-ray diffraction and x-ray energy-dispersive spectroscopy, respectively. The adhesive force of the coating was measured by a scratch tester, at the same time the friction-wear behavior of the coating was studied. The results show that there were TiN and (Ti,Al)(N,C) two phases, and there was the coexistence of amorphous and nanocrystalline in the coating. The chemical composition of the coating was composed of 20 ± 9 at.% Ti, 16 ± 5 at.% Al, 39 ± 5 at.% N and 25 ± 10 at.% C. The thickness of the coating was about 4.5 μm. The average root mean square value of the surface roughness was 225 ± 16 nm. A critical force for coating failure in scratch testing was about 25 N. The friction coefficients of the substrate and the coating were 0.55 and 0.35, respectively. The ceramic coating could improve the wear resistance of the substrate.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Wear-Resistance Investigations on Ceramic Coatings for Lunar Dust Mitigation

Lunar dust has posed a major challenge to exploration efforts due to abrasion and impact. This work focuses on fundamental studies on ceramic coatings as candidates for enhanced resistance to impact and wear. As a first step, standard and modified approaches to the method of abrasion testing were explored for options to incorporate lunar regolith as wear media, the effects of which were presented for AL6061-T6 control samples. Following this, wear results for air plasma-sprayed (APS) alumina coatings were investigated due to their superior strength and surface hardness. In addition, APS 8 wt % yttria-stabilized zirconia (8YSZ) coatings were studied for their strength and martensitic transformation toughness. Measurements were made by assessing the mass loss, with a standard scale at various intervals. In addition, surface roughness was measured with a profilometer and features identified with a high-resolution microscope. The findings demonstrated that wear media has a distinct effect on the abrasion. The alumina coatings demonstrated improved wear over 8YSZ. However, the tailorability of 8YSZ makes it an attractive option to continue to modify as a wear-resistant coating to protect against lunar dust abrasion. The results of these measurements provide insight into the wear behavior of future directions in candidate ceramic coatings for the harsh lunar environment.

ceramic coatings↗

Wear-Resistance Investigations on Ceramic Coatings for Lunar Dust Mitigation

Lunar dust has posed a major challenge to exploration efforts due to abrasion and impact. This work focuses on fundamental studies on ceramic coatings as candidates for enhanced resistance to impact and wear. As a first step, standard and modified approaches to the method of abrasion testing were explored for options to incorporate lunar regolith as wear media, the effects of which were presented for AL6061-T6 control samples. Following this, wear results for air plasma-sprayed (APS) alumina coatings were investigated due to their superior strength and surface hardness. In addition, APS 8 wt % yttria-stabilized zirconia (8YSZ) coatings were studied for their strength and martensitic transformation toughness. Measurements were made by assessing the mass loss, with a standard scale at various intervals. In addition, surface roughness was measured with a profilometer and features identified with a high-resolution microscope. The findings demonstrated that wear media has a distinct effect on the abrasion. The alumina coatings demonstrated improved wear over 8YSZ. However, the tailorability of 8YSZ makes it an attractive option to continue to modify as a wear-resistant coating to protect against lunar dust abrasion. The results of these measurements provide insight into the wear behavior of future directions in candidate ceramic coatings for the harsh lunar environment.

ceramic coatings↗

Development of improved-durability plasma sprayed ceramic coatings for gas turbine engines

An investigation is reported of improving the durability of plasma sprayed ceramic coatings for the vane platforms in the JT9d turbofan engine. The program aims for reduced fuel consumption of commercial aircraft engines; the use of improved strain tolerant microstructures and control of the substrate temperature during coating application are being evaluated. The initial burner rig tests at temperatures up to 1010 C indicated that improvements in cyclic life greater than 20:1 over previous ceramic coatings were achieved. Three plasma sprayed coating systems applied to first stage vane platforms in the high pressure turbine were subjected to a 1000-cycle JT9D engine endurance test with only minor damage occurring to the coatings.

Sumner, I. E.↗

Cyclic stress analysis of ceramic coated gas turbine seals

Through the use of the Finite Element Method, the cyclic thermomechanical response of ceramic coated gas turbine parts is considered. The analysis includes temperature dependent elastic-plastic-creep material properties and cyclic thermal loads. To demonstrate the cyclic thermomechanical response, a ceramic coated outer gas path seal is studied. The analysis will estimate the significant residual stress field created by the cyclic thermal loads.

Padovan, Joe↗

Implantable devices having ceramic coating applied via an atomic layer deposition method

Substrates coated with films of a ceramic material such as aluminum oxides and titanium oxides are biocompatible, and can be used in a variety of applications in which they are implanted in a living body. The substrate is preferably a porous polymer, and may be biodegradable. An important application for the ceramic-coated substrates is as a tissue engineering scaffold for forming artificial tissue.

47 OTHER INSTRUMENTATION↗

Energetics of Reactions between Ceramic Coating Materials and their Binary Oxide Components with Silicate Melts

This paper summarizes our previous and current studies of using high-temperature calorimetry to investigate the energetics of reactions of ceramic coating materials (e.g., yttrium disilicate and 7-wt% yttria-stabilized zirconia) and their binary oxide components with silicate melts in the CaO–MgO–Al 2 O 3 –SiO 2 (CMAS) system. Such interactions are found to become stronger (more exothermic) with increasing difference in acid–base character between these materials and the melt. Our results suggest that the reactivity between the coating materials and the melt increases with decreasing thermodynamic stability (less exothermic enthalpy of formation from oxide components) of the coating material. They also suggest that ceramic coating materials made from binary oxides that have less exothermic enthalpies of solution and mixing are less susceptible to CMAS melt corrosion when in contact with an acidic, relatively polymerized, melt rich in SiO 2 . Thus, we propose that new coating material formulation and CMAS melt corrosion mitigation strategies should be optimized based on the energetic contributions of their binary oxide components.

CMAS↗

Extension of similarity test procedures to cooled engine components with insulating ceramic coatings

Material thermal conductivity was analyzed for its effect on the thermal performance of air cooled gas turbine components, both with and without a ceramic thermal-barrier material, tested at reduced temperatures and pressures. The analysis shows that neglecting the material thermal conductivity can contribute significant errors when metal-wall-temperature test data taken on a turbine vane are extrapolated to engine conditions. This error in metal temperature for an uncoated vane is of opposite sign from that for a ceramic-coated vane. A correction technique is developed for both ceramic-coated and uncoated components.

Gladden, H. J.↗

Inelastic high-temperature thermomechanical response of ceramic coated gas turbine seals

Through the use of a constrained Newton-Raphson time stepping finite element scheme, the inelastic thermomechanical response of ceramic coated gas turbine parts is considered. Due to the generality of the solution procedure developed, the combined thermoelastic-plastic-creep properties associated with ceramics is treated. This includes the handling of temperature-dependent elastic-plastic creep and thermal material properties. To illustrate the procedure, the thermomechanical response of ceramic coated outer gas path seals is considered. This includes the evaluation of time-dependent thermal ratcheting and its concomitant residual stress and strain fields.

Padovan, J.↗

High temperature thermomechanical analysis of ceramic coatings

This paper investigates the thermomechanical response of ceramically coated metal parts in elevated thermal environments. This is made possible through the development of an improved finite element algorithm that enables the efficient and stable solution of the inherently nonlinear elastic-creep (inelastic) type thermomechanical field equations associated with high temperature. Based on the improved algorithm, the results of several numerical experiments are presented. These illustrate the significant influence of inelastic behavior in generating residual stress fields.

Padovan, J.↗

Aerodynamic performance of a ceramic-coated core turbine vane tested with cold air in a two-dimensional cascade

The aerodynamic performance of a core turbine vane with a ceramic coating was investigated experimentally in a two-dimensional cascade of 10 vanes. The vane was first tested with a rough coating and then retested after the coating had been smoothed. The test fluid was atmospheric air. The cascade tests covered a range of pressure ratios corresponding to ideal exit critical velocity ratios of 0.6 to 0.95. The principal measurements were cross-channel surveys of exit total pressure, static pressure, and flow angle. The results presented include exit survey results and overall performance in terms of flow angle, weight flow, and kinetic energy loss. The performance of the ceramic-coated vanes is compared with the performance of an uncoated vane having a similar profile.

Stabe, R. G.↗

Development of improved-durability plasma sprayed ceramic coatings for gas turbine engines

As part of a NASA program to reduce fuel consumption of current commercial aircraft engines, methods were investigated for improving the durability of plasma sprayed ceramic coatings for use on vane platforms in the JT9D turbofan engine. Increased durability concepts under evaluation include use of improved strain tolerant microstructures and control of the substrate temperature during coating application. Initial burner rig tests conducted at temperatures of 1010 C (1850 F) indicate that improvements in cyclic life greater than 20:1 over previous ceramic coating systems were achieved. Three plasma sprayed coating systems applied to first stage vane platforms in the high pressure turbine were subjected to a 100-cycle JT9D engine endurance test with only minor damage occurring to the coatings.

Sumner, I. E.↗

Single-drop impact damage prediction for low density, coated ceramic materials

A technique utilizing finite element analysis, liquid impact kinematics, and momentum theory is described and compared to single-drop impact test data performed on various configurations of coated ceramic material. The method correlates well with test data and is useful in predicting the single-drop impact damage velocity threshold for low-density, coated ceramic materials.

Mustelier, D.↗

Thermal and flow analysis of a convection air-cooled ceramic coated porous metal concept for turbine vanes

The heat transfer and pressure drop through turbine vanes made of a sintered, porous metal coated with a thin layer of ceramic and convection cooled by spanwise flow of cooling air were analyzed. The analysis was made to determine the feasibility of using this concept for cooling very small turbines, primarily for short duration applications such as in missile engines. The analysis was made for gas conditions of approximately 10 and 40 atm and 1644 K and with turbine vanes made of felt type porous metals with relative densities from 0.2 to 0.6 and ceramic coating thicknesses of 0.076 to 0.254 mm.

Stepka, F. S.↗

Thermal and flow analysis of a convection, air-cooled ceramic coated porous metal concept for turbine vanes

Analysis was made of the heat transfer and pressure drop through turbine vanes made of a sintered, porous metal coated with a thin layer of ceramic and convection cooled by spanwise flow of cooling air. The analysis was made to determine the feasibility of using this concept for cooling very small turbines, primarily for short duration applications such as in missile engines. The analysis was made for gas conditions of approximately 10 and 40 atm and 1644 K and with turbine vanes made of felt-type porous metals with relative densities from 0.2 and 0.6 and ceramic coating thicknesses of 0.076 to 0.254 mm.

Stepka, F. S.↗

Status Report on Ion Irradiation Study of Ceramic Coating in Suppressing Fuel/Cladding Chemical Interaction

Advanced cladding is critical for the development of advanced nuclear reactors with enhanced performance in radiation tolerance and neutron transparency. It will ensure adequate thermal conductivity and mechanical stability of cladding base material, corrosion resistance and high temperature coolant compatibility of cladding surface. Finally, it provides chemical stability in the cladding inner wall against fuel/cladding chemical interaction (FCCI). An innovative cladding with a three-layer structure (i.e., a treated surface, a base material, and a treated inner-wall) promises to meet all the listed requirements. The initial work on innovative researching and developing these cladding materials seeks to demonstrate the effectiveness of a thin ceramic coating in suppressing FCCI through ion-irradiation. It consists of a study of Ce/TiN/Fe diffusion couples. This report provides an update on the status of ceramic-coating preparation and the testing of diffusion couple samples, the design of an ion-irradiation experiment, and characterization of the microstructure of a legacy-coupon sample coated with 1 µm of TiN and irradiated with 5 MeV Fe ions to 200 dpa at 500°C.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗