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At least 37 records · Page 2

The Explosive Hazards of Icosahedral Carboranes and Dodecaborate with Common Oxidizers and Salts

Carboranes find use in a wide variety of applications ranging from specialty catalysts to medicinal uses. Certain functionalized carboranes are described as explosive materials, although their nonfunctionalized precursors are regarded as inherently stable and not explosive. Herein, we report new findings on the sensitization of nonfunctionalized 12-vertex ortho-, meta-, and para-carboranes as well as dodecaborate in physical mixtures with several common inorganic salts. These mixtures were evaluated for explosive properties with drop hammer impact tests, friction tests, and differential scanning calorimetry thermal gravimetric analysis (DSC-TGA). Results indicate explosive sensitization to mechanical stimuli for the nonfunctionalized carboranes tested with a wide variety of inorganic salts, especially oxidizers. Sensitization of these compounds has not previously been reported, and raising awareness to the broader scientific community on this matter is warranted, especially as several of the mixtures evaluated are more sensitive to mechanical stimuli than primary explosives such as lead azide or pentaerythritol tetranitrate.

36 MATERIALS SCIENCE

High-throughput dataset of impurity adsorption on common catalysts in biomass upgrading applications

Abstract An extensive dataset consisting of adsorption energies of pernicious impurities present in biomass upgrading processes on common catalysts and support materials has been generated. This work aims to inform catalyst and process development for the conversion of biomass-derived feedstocks to fuels and chemicals. A high-throughput workflow was developed to execute density functional theory calculations for a diverse set of atomic (Al, B, Ca, Cl, Fe, K, Mg, Mn, N, Na, P, S, Si, Zn) and molecular (COS, H 2 S, HCl, HCN, K 2 O, KCl, NH 3 ) species on 35 unique surfaces for transition-metal (Ag, Au, Co, Cu, Fe, Ir, Ni, Pd, Pt, Re, Rh, Ru) and metal-oxide (Al 2 O 3 , MgO, anatase-TiO 2 , rutile-TiO 2 , ZnO, ZrO 2 ) catalysts and supports. Approximately 3,000 unique adsorption geometries and corresponding adsorption energies were obtained.

09 BIOMASS FUELS

Personalized Tucker Decomposition: Modeling Commonality and Peculiarity on Tensor Data

In this paper, we propose a personalized Tucker decomposition (perTucker) to address the limitations of traditional tensor decomposition methods in capturing heterogeneity across different datasets. perTucker decomposes tensor data into shared global components and personalized local components. We introduce an order orthogonality assumption and develop a proximal gradient regularized block coordinate descent algorithm guaranteed to converge to a stationary point. The unique and common representations learned by perTucker reveal intrinsic statistical patterns in data and provide valuable information for a wide range of downstream analytics, including anomaly detection, source classification, and clustering. We demonstrate perTucker’s effectiveness through a simulation study and two case studies on solar flare detection and tonnage signal classification.

14 SOLAR ENERGY

Short-period post-common envelope binaries with Balmer emission from SDSS and LAMOST based on ZTF photometric data

ABSTRACT We present here 55 short-period post-common envelope binaries (PCEBs) containing a hot white dwarf (WD) and a low-mass main sequence (MS). Based on the photometric data from Zwicky Transient Facility survey data Release 19 (ZTF DR19), the light curves are analysed for about 200 WDMS binaries with emission line(s) identified from the Sloan Digital Sky Survey (SDSS) or the Large Sky Area Multi-Object Fibre Spectroscopic Telescope (LAMOST) spectra, in which 55 WDMS binaries are found to exhibit variability in their luminosities with a short period and are thus short-period binaries (i.e. PCEBs). In addition, it is found that the orbital periods of these PCEBs locate in a range from 2.2643 to 81.1526 h. However, only six short-period PCEBs are newly discovered and the orbital periods of 19 PCEBs are improved in this work. Meanwhile, it is found that three objects are newly discovered eclipsing PCEBs, and a object (i.e. SDSS J1541) might be the short-period PCEB with a late M-type star or a brown dwarf companion based on the analysis of its spectral energy distribution. At last, the mechanism(s) being responsible for the emission features in the spectra of these PCEBs are discussed, the emission features arising in their optical spectra might be caused by the stellar activity or an irradiated component owing to a hot WD companion because most of them contain a WD with an effective temperature higher than $\sim$10 000 K.

Li, Lifang

Inverse Segmented Motor Drive Using Dual ANPC Inverters for Common-Mode Voltage and Neutral-Point Current Cancellation

This article proposes an inverse segmented motor drive (SgMD) utilizing dual active neutral point clamped (ANPC) inverters. In the proposed configuration, the neutral point current and common-mode (CM) voltage is topologically canceled, achieving zero total neutral point current and CM voltage under ideal conditions. Also, the zero total neutral point current minimizes the neutral point voltage imbalance in ANPC inverters. The mechanisms behind neutral point current and CM voltage cancellation in the proposed inverse SgMD are first introduced. The modifications to the motor windings for implementing the inverse SgMD are explained, showing that a standard motor can be readily adapted for the proposed configuration. A space vector modulation (SVM) scheme tailored for the proposed topology is presented, along with a carrier-based implementation. Simulation results validate that the proposed topology can achieve zero total CM voltage and neutral point current. It is also shown that the proposed inverse SgMD can reduce neutral point voltage fluctuation by about 90% and RMS current stress in the dc-link capacitors by about 43% compared to the conventional SgMD.

Lee, Sangwhee [ORNL] (ORCID:0000000335490057)

Evaluation of Common Thermoplastic Polymers in High-Pressure Cycling Hydrogen Under Ambient and Cold Environments as Applicable to the Hydrogen Infrastructure

Thermoplastic polymers are required to perform unfailingly under stringent conditions of changing pressures (35 MPa to 70 MPa) and temperatures (-40°C to +85°C) in storage and fueling operations. Although diffusivity in glassy polymers appear to be an order of magnitude lower than elastomers, polymer microstructural attributes such as degree of crystallinity and presence of polar and non-polar groups on the main chain with and without branching can play a substantial role in influencing their behaviors in hydrogen environments. In the work described here, the effect of high-pressure hydrogen cycling on PEEK, PTFE, PA11, HDPE, POM (and different commercial grades of these polymers) under ambient and cold (-40°C) conditions is addressed. Ex-situ characterization for polymer changes included density measurements for impact of hydrogen retention, hardness changes using nanoindentation, storage modulus and glass transition changes using dynamic mechanical and thermal analysis (DMTA), degree of crystallization with Differential Scanning Calorimetry (DSC) and tensile testing following ASTM D412. In other evaluations, solid-state nuclear magnetic resonance (NMR), attenuated total reflectance Fourier transform infra-red spectroscopy (ATRFTIR), X-ray diffraction (XRD), and X-ray CT results are presented. The overall impact of these evaluations is to establish a technical basis for the behaviors of common thermoplastics in cycling hydrogen environments under ambient and cold temperatures while establishing the relationship between polymer structure-based properties and hydrogen transport effects.

Menon, Nalini C.

Intraspecific variability in plant and soil chemical properties in a common garden plantation of the energy crop Populus

Optimizing crops for synergistic soil carbon (C) sequestration can enhance CO 2 removal in food and bioenergy production systems. Yet, in bioenergy systems, we lack an understanding of how intraspecies variation in plant traits correlates with variation in soil biogeochemistry. This knowledge gap is exacerbated by both the heterogeneity and difficulty of measuring belowground traits. Here, we provide initial observations of C and nutrients in soil and root and stem tissues from a common garden field site of diverse, natural variant, Populus trichocarpa genotypes—established for aboveground biomass-to-biofuels research. Our goal was to explore the value of such field sites for evaluating genotype-specific effects on soil C, which ultimately informs the potential for optimizing bioenergy systems for both aboveground productivity and belowground C storage. To do this, we investigated variation in chemical traits at the scale of individual trees and genotypes and we explored correlations among stem, root, and soil samples. We observed substantial variation in soil chemical properties at the scale of individual trees and specific genotypes. While correlations among elements were observed both within and among sample types (soil, stem, root), above-belowground correlations were generally poor. We did not observe genotype-specific patterns in soil C in the top 10 cm, but we did observe genotype associations with soil acid-base chemistry (soil pH and base cations) and bulk density. Finally, a specific phenotype of interest (high vs low lignin) was unrelated to soil biogeochemistry. Our pilot study supports the usefulness of decade-old, genetically-variable, Populus bioenergy field test plots for understanding plant genotype effects on soil properties. Finally, this study contributes to the advancement of sampling methods and baseline data for Populus systems in the Pacific Northwest, USA. Further species- and region-specific efforts will enhance C predictability across scales in bioenergy systems and, ultimately, accelerate the identification of genotypes that optimize yield and carbon storage.

54 ENVIRONMENTAL SCIENCES

The study of high-frequency pick-ups for electron beam position measurements in the AWAKE common beamline

The common beamline of the AWAKE experiment at CERN involves the co-propagation of two particle beams: protons with 48 nC bunch charge and 250 ps bunch length, and electrons with up to 600 pC bunch charge and approximately 4 ps bunch length. The existing operational beam position monitors at AWAKE cannot measure the electron bunches whilst the more-intense proton bunches are present, due to their low operating frequency. In order to try to address this challenge, two different types of high-frequency pick-ups were studied, a conical-shaped button pick-up and a Cherenkov diffraction radiation-based pick-up designed to operate at around 30 GHz. Both devices were installed at AWAKE and were connected to two identical read-out systems designed by TRIUMF. This contribution presents and discusses the results obtained from beam-based measurements during the current experimental year.

43 PARTICLE ACCELERATORS

Application of aerosol-ice nucleating particle closure to establish the leading parameters governing ice crystal number concentration under commonly observed mixed-phase cloud conditions

This is the final technical report for DOE DE-SC0021034 award entitled “Application of aerosol-ice nucleating particle closure to establish the leading parameters governing ice crystal number concentration under commonly observed mixed-phase cloud conditions”. The overarching objective of this project was to gain a predictive understanding of the processes that lead from aerosols to ice-nucleating particles (INPs) to ice crystal number concentrations (ICNCs) in stratiform mixed-phase clouds where supercooled water droplets and ice crystals coexist, and to inform climate model parameterizations. During this four-year project we addressed the three main research goals of this objective: 1) Study the aerosol-INP link; 2) Develop an aerosol-cloud column model (AC-1D); and 3) Study the INP-ICNC link. Those activities significantly advanced our predictive understanding of how to represent INPs in could models and its implications on ice crystal number concentrations. The results have been published in five peer-reviewed publications with three more in review and preparation. It allowed for collaboration resulting in additional fourteen peer-reviewed publications that are concerned with the objective of this research project. This research has been communicated to the scientific community at national and international meetings and conferences by numerous talks, seminars, and posters including fifteen invited presentations. This project allowed training of four graduate students and one postdoctoral research associate resulting in one M.S. thesis and advancement to Ph.D. candidacy.

54 ENVIRONMENTAL SCIENCES

Restoring Homes After Wildfires, Interviews with Practitioners about Common Cleanup Approaches and Knowledge Gaps

This document summarizes the key themes from our interviews with 10 remediation companies regarding common approaches used to remove odor and contaminants from homes impacted by fire and smoke damage Remediation companies are in agreement that thorough cleaning is the first step. Cleaning and removing contaminants from homes impacted by wildfires may be sufficient to eliminate smoke odor, which is the most important step when it comes to reducing exposure to any residues that may pose health risks to residents. Remediation companies differ in their approaches to addressing odors, such as using ozone generators, hydroxyl generators, chlorine dioxide treatment, thermal fogging and applying sealants. Their opinions of what works and why differs. There is little consensus on efficacy, safety, or application protocols. For example, some view ozone very favorably, while others would prefer using other methods. The influence of insurance companies in their coverage for some methods but not others also impact the decision about the approaches used. Remediation companies differ in their view on laboratory testing for contaminants, which may be partly influenced by insurance companies as well.

99 GENERAL AND MISCELLANEOUS

Blueprint: Open Worldwide Application Security Project Top 10 Common Weakness Enumerations for Electric Vehicle Supply Equipment

This report categorizes the top 10 security weaknesses in electric vehicle supply equipment (EVSE) using a similar approach by the Open Worldwide Application Security Project (OWASP) Top 10, and it describes example exploitations, methods for prevention, and related common weakness enumerations (CWEs) for each category. The weaknesses listed in this report could lead to security issues or vulnerabilities in EVSE if they are exploited by an attacker to compromise the confidentiality, integrity, or availability of a system. This report also recommends EVSE industry best practices and remediations for the identified weaknesses to use as guidelines for their secure products and systems.

33 ADVANCED PROPULSION SYSTEMS

Geothermal Heat Pump Case Study: Norton Commons, Kentucky

Geothermal heat pumps can be great alternatives to air conditioners and furnaces, and require less electricity to run. This case study focuses on Norton Commons, Kentucky and is part of a series: https://www.energy.gov/eere/geothermal/geothermal-heat-pump-case-studies.

case study

Navigating Common Electric Vehicle and Charging Infrastructure Concerns

Increasing knowledge about electric vehicles (EVs) can increase Tribal member comfort level with the technology, leading to increased EV adoption. This fact sheet lists common EV and charging infrastructure concerns and provides information to help address these hurdles during engagement with Tribal communities.

33 ADVANCED PROPULSION SYSTEMS

Toxicity of Common Fluoropolymers and PFAS on C. Elegans and an Innovative Strategy to Promote in Situ Remediation - 26128

Per- and polyfluoroalkyl substances (PFAS) are a broad class of synthetic chemicals used in a variety of modern technologies and consumer products. PFAS have an alkyl backbone with all or most of the hydrogen (H) atoms replaced with fluorine (F) atoms. PFAS generally fall into one of two categories, they can be non-polymeric with relatively low molecular weights, or long-chain polymers. PFAS are a diverse group of organic compounds that can be solids, liquids, dispersions, or gases. Their mobility and toxicity are influenced by their chain lengths and functional groups. Non-polymeric PFAS are common building blocks for the manufacturing of fluoropolymers. Non-polymeric PFAS are known to be mobile in the environment and some are considered contaminants of emerging concern. Polymeric PFAS, or fluoropolymers, are typically thought to be of low concern, however few systematic investigations into their toxicity have been completed. PFAS, including fluoropolymers and microplastics, have been found in pristine environments and animals located far from site of origin including the arctic and deep ocean.

Jacobs, Stephanie [Savannah River National Laborat

University of Maryland Eastern Shore Common Garden

Located at the University of Maryland Eastern Shore, an HBCU (Historically Black Colleges and Universities), this data set is composed of the geographic coordinates of four transgenic Populus tremula x alba INRA 717-IB4 lines (CHX20, XBAT35, EXO70, DIR18) as well as a wild type (WT), and Empty vector (EV)). Our site is monitored by an ATOMS 41 weather station, which collects solar radiation, air temperature, vapor and atmospheric pressure, precipitation, and other weather variables. We will assess a suite of variables reflecting growth and performance, focusing on root allocation and soil carbon sequestration.

CBI, Populus, common garden, transgenic

Speciation of Transition Metal Dissolution in Electrolyte from Common Cathode Materials

Significant capacity loss has been observed across extended cycling of lithium-ion batteries cycled to high potential. One of the sources of capacity fade is transition metal dissolution from the cathode active material, ion migration through the electrolyte, and deposition on the solid-electrolyte interphase on the anode. While much research has been conducted on the oxidation state of the transition metal in the cathode active material or deposited on the anode, there have been limited investigations of the oxidation state of the transition metal ions dissolved in the electrolyte. Here, in this work, X-ray absorption spectroscopy has been performed on electrolytes extracted from cells built with four different cathode active materials (LiMn 2 O 4 (LMO), LiNi 0.5 Mn 1.5 O 4 (LNMO), LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811), and (x Li 2 MnO 3 *(1-x) LiNi a Mn b Co c O 2 , with a+b+c=1) (LMRNMC)) that were cycled at either high or standard potentials to determine the oxidation state of Mn and Ni in solution. Inductively coupled plasma-mass spectrometry has been performed on the anodes from these cells to determine the concentration of deposited transition metal ions. While transition metal ions were found dissolved in all electrolytes, the oxidation state(s) of Mn and Ni were determined to be dependent on the cathode material and independent of cycling potential.

25 ENERGY STORAGE

Evaluation of common trap types for capturing wild pigs

Abstract Wild pigs ( Sus scrofa ) are one of the most ecologically harmful invasive vertebrates globally. Due to their negative impacts, wild pig populations are managed via trapping, yet studies investigating various trap designs have been limited in duration, location, and number of trappers. Using data from professional trappers across the southeastern U.S., we evaluated the performance of 3 wild pig trap types (corral, drop, passive net), and the effect of forage season (barren, green‐up, masting) on trapping success. Specifically, we compared trap effectiveness (estimated proportion of targeted wild pigs caught per capture event), trap night effort (number of days to first catch), and the amount of bait and time used per individual take over the lifetime of each trap location across the 3 trap types and forage seasons. Across >850 capture events by 31 trappers, all 3 trap types evaluated were effective at capturing entire social groups of wild pigs. Few differences were observed among trap types, although drop traps in masting season captured a greater estimated proportion of wild pigs per capture event compared to other trap type‐season combinations. Our data also revealed that passive net traps required slightly more bait/wild pig captured than drop traps but there was no difference in the time/wild pig captured among traps. Our findings demonstrate that when operated by wildlife professionals, multiple designs of wild pig traps can be effective at removing targeted groups of wild pigs. Further, our results offer insights regarding the performance of wild pig trap types across seasons that can be used to inform wild pig trapping programs.

Taylor, Charles R. [Warnell School of Forestry and