Time dependent signatures: Moisture content interpretation in well logging applications with a D-T neutron generator
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Instruments & Instrumentation↗
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Influence of water content on alkali metal chloride transport in cross-linked Poly(ethylene glycol) diacrylate.2. Ion diffusion
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catalysis (heterogeneous)↗
Effect of Mg Content in Melt-Spun Mn–Bi–Mg–Sb–In Alloys on the Structure and Properties of Field-Annealed Magnets
Mn-Bi alloys modified with Mg and other elements were recently developed into promising rare-earth-free permanent magnets through successive melt-spinning, warm compaction, and short magnetic-field annealing. This letter reports herein on the crystal structures, texture, and magnetic properties observed in Mn 50 Bi 49-x Mg x Sb 0.5 In 0.5 alloys (x = 0, 1.5, 3.0, 4.5) throughout these processing steps. The Mg substitution favors MnBi-based intermetallic phases over the Bi- and Mn-based solid solutions and the stable α intermetallic phase over the metastable β' intermetallic phase. Magnesium increases the c/a ratio of the α phase lattice parameters for all studied x values and it increases the degree of the field-annealing-induced texture for x ≤ 3. The effect of Mg on coercivity is explained as combination of a positive one via the α phase magnetocrystalline anisotropy and a negative one via the development of texture. The effect of the substitution on the maximum energy product additionally involves the decreasing density of the alloys; the optimum x is found to be ≈3. Additionally reported are the thermal properties of selected alloys. The mechanism of field-annealing effect on the coercivity is briefly discussed.
36 MATERIALS SCIENCE↗
Thermal Properties of Sodium Borosilicate Glasses as a Function of Sulfur Content
SO3 additions, up to 3.0 wt%, were systematically investigated for effects on the physical properties of sodium borosilicate glass melted in air, with a sulfur-free composition of 50SiO2-10Al2O3-12B2O3-21Na2O-7CaO (wt%). Solubility measurements, using electron microscopy chemical analysis, determined the maximum loading to be ~1.5 wt% SO3. It was found that sulfur (here as sulfate) in this glass increased the glass transition temperature, thermal diffusivity, heat capacity, and thermal conductivity, and decreased the mass density. Structural analysis, performed with Raman spectroscopy, indicated that the borosilicate network polymerized with sulfur additions, presumably due to Na2O being required to charge compensate the ionic SO42- additions, thus becoming unavailable to form non-bridging oxygen in the silicate network. It is postulated that this increased crosslinking of the borosilicate backbone lead to a structure with higher dimensionality and average bond energy. This increased the mean free paths and vibration frequency of the phonons, which resulted in the observed increase in thermal properties.
Thermal properties, Borosilicate glass, Sulfur sol↗
Water Contents of the Mantle Beneath the Rio Grande Rift: FTIR Analysis of Kilbourne Hole Peridotite Xenoliths
Although nominally anhydrous mantle minerals contain only trace amounts of water, they are the main reservoir of water in the mantle. Added up at the scale of the Earth's mantle, these trace amounts of water represent oceans worth in mass]. Mantle xenoliths from Kilbourne Hole in southern New Mexico are ideal to study mantle water distribution in a rift tectonic setting as they come from a recently‐erupted maar in the middle of the Rio Grande Rift. Eleven lherzolites, one harzburgite, and one dunite are being analyzed for water contents by FTIR. The xenoliths will also be analyzed for major and trace element composition, Fe3+/Summation (Fe) ratios, and characterized petrologically. Olivines exhibit variable water contents with less water at the rims compared to the cores. This is probably due to H loss during decompression and xenolith transport by the host magma. Mantle water contents appear to have been primarily preserved in the core of the olivines, based on diffusion modeling of the typically plateau-shaped water content profiles across these grains. Water concentrations are in equilibrium between clino- and orthopyroxene, but olivine concentrations are typically not in equilibrium with those of either pyroxene. Lherzolites analyzed so far have water contents of 2‐12 ppm H2O in olivines, 125‐165 ppm H2O in orthopyroxenes, and 328‐447 ppm H2O in clinopyroxenes. These water contents are similar to, but with a narrower range, than those for the respective minerals in other continental peridotite xenoliths. The lherzolites have bulk-rock (BR) Al2O3 contents that range between 3.17 and 3.78 wt%, indicating similar degrees of partial melting, which could explain the narrow range of their pyroxene water contents. Primitive mantle normalized rare earth element (REE) profiles of the bulk lherzolites vary from light REE depleted to flat, with no significant differences between, nor relation to, their mineral water contents. Consequently, the metasomatic agents that enriched LREEs in these lherzolites were most likely water-poor. The harzburgite and the dunite have lower weight percent Al2O3 compared to the lherzolites (2.11% and 0.34% respectively) indicating higher degrees of melting. Their olivine water contents, however, are similar to those of the lherzolites. Moreover, no correlations are observed between pyroxene water contents and indices of melting or metasomatism between the lherzolite group, the harzburgite, and the dunite, although the latter has the lowest pyroxene water contents. More samples will be analyzed to determine if the water contents are controlled by melting, metasomatism, or a combination of the two in the Kilbourne Hole mantle.
Schaffer, Lillian A.↗
Simultaneous Ice Water Content Measurements at Multiple Locations on the NASA DC-8 Aircraft during the 2018 HIWC RADAR Flight Campaign
Ice water content measurements were made simultaneously at three locations on the NASA DC-8 in natural, glaciated conditions during the 2018 High Ice Water Content RADAR flight campaign. The purpose of these measurements was to further evaluate efficiency factors of hot-wire total water content probes in glaciated conditions and investigate the enhancement of ice crystal concentrations near fuselage surfaces due to flow field inertial effects, and ice crystals impacting the nose, breaking up, and flowing downstream. The total water content measurements were made using either Science Engineering Associates Ice Crystal Detectors or Robust Probes. Three common sensors were mounted on an underwing canister considered to be in near free-flow conditions, a standoff from a fuselage window, and the nose of the fuselage near the pitot probes. The Ice Crystal Detector total water content sensor and Robust Probe sensor collection and retention efficiencies were evaluated through comparisons with the underwing Ice Crystal Detector and Robust Probe measurements to the IKP2 isokinetic evaporator probe, which provided the reference ice water content measurement. Local ice water content at the nose position was evaluated by comparing ratios of the nose and underwing ice crystal detectors to the IKP2. Local ice water content at the window-standoff location was also evaluated by comparing total water content sensor measurements from the window ice crystal detector to the measurements made with the underwing and nose Ice Crystal Detectors The key findings were: 1) the Ice Crystal Detector total water content sensor ice water content efficiency factor was similar to previous estimates, but reduced with increased ice crystal median mass diameter; 2) the ice water content at the fuselage nose location near the DC-8 pitot probes was approximately 2.5 times the freestream values – although this estimate is affected by a higher probe efficiency factor due to smaller particles in the debris cloud from impacts upstream of the probe; and 3) the ice water content at the 17” standoff from the port window varied from about 50% to 3 times freestream values in a complicated manner. Similar measurement locations are not uncommon on cloud research aircraft, where ice particle measurements may be subject to similar uncertainties.
Aircraft Icing↗
Simultaneous Ice Water Content Measurements at Multiple Locations on the NASA DC-8 Aircraft during the 2018 HIWC RADAR Flight Campaign
Ice water content measurements were made simultaneously at three locations on the NASA DC-8 in natural, glaciated conditions during the 2018 High Ice Water Content RADAR flight campaign. The purpose of these measurements was to further evaluate efficiency factors of hot-wire total water content probes in glaciated conditions and investigate the enhancement of ice crystal concentrations near fuselage surfaces due to flow field inertial effects, and ice crystals impacting the nose, breaking up, and flowing downstream. The total water content measurements were made using either Science Engineering Associates Ice Crystal Detectors or Robust Probes. Three common sensors were mounted on an underwing canister considered to be in near free-flow conditions, a standoff from a fuselage window, and the nose of the fuselage near the pitot probes. The Ice Crystal Detector total water content sensor and Robust Probe sensor collection and retention efficiencies were evaluated through comparisons with the underwing Ice Crystal Detector and Robust Probe measurements to the IKP2 isokinetic evaporator probe, which provided the reference ice water content measurement. Local ice water content at the nose position was evaluated by comparing ratios of the nose and underwing ice crystal detectors to the IKP2. Local ice water content at the window-standoff location was also evaluated by comparing total water content sensor measurements from the window ice crystal detector to the measurements made with the underwing and nose Ice Crystal Detectors The key findings were: 1) the Ice Crystal Detector total water content sensor ice water content efficiency factor was similar to previous estimates, but reduced with increased ice crystal median mass diameter; 2) the ice water content at the fuselage nose location near the DC-8 pitot probes was approximately 2.5 times the freestream values – although this estimate is affected by a higher probe efficiency factor due to smaller particles in the debris cloud from impacts upstream of the probe; and 3) the ice water content at the 17” standoff from the port window varied from about 50% to 3 times freestream values in a complicated manner. Similar measurement locations are not uncommon on cloud research aircraft, where ice particle measurements may be subject to similar uncertainties.
o Aircraft Icing↗
Simultaneous Ice Water Content Measurements at Multiple Locations on the NASA DC-8 Aircraft during the 2018 HIWC RADAR Flight Campaign
Ice water content measurements were made simultaneously at three locations on the NASA DC-8 in natural, glaciated conditions during the 2018 High Ice Water Content RADAR flight campaign. The purpose of these measurements was to further evaluate efficiency factors of hot-wire total water content probes in glaciated conditions and investigate the enhancement of ice crystal concentrations near fuselage surfaces due to flow field inertial effects, and ice crystals impacting the nose, breaking up, and flowing downstream. The total water content measurements were made using either Science Engineering Associates Ice Crystal Detectors or Robust Probes. Three common sensors were mounted on an underwing canister considered to be in near free-flow conditions, a standoff from a fuselage window, and the nose of the fuselage near the pitot probes. The Ice Crystal Detector concave total water content sensor and Robust Probe sensor collection and retention efficiencies were evaluated through comparisons with the underwing Ice Crystal Detector and Robust Probe measurements to the Isokinetic Probe version 2 (IKP2), which provided the reference ice water content measurement. Local ice water content at the nose position was evaluated by comparing ratios of the nose and underwing ice crystal detectors to the IKP2. Local ice water content at the window-standoff location was also evaluated by comparing total water content sensor measurements from the window probes to the measurements made with the underwing and nose probes. The key findings were: (1) the Ice Crystal Detector concave water content sensor efficiency factor to glaciated conditions was similar to previous estimates, but reduced with increased ice crystal median mass diameter; (2) the ice water content at the fuselage nose location near the DC-8 pitot probes was approximately 2.5 times the freestream values—although this estimate is affected by a higher probe efficiency factor due to smaller particles in the debris cloud from impacts upstream of the probe; and (3) the ice water content at the 17 in. standoff from the port window varied from about 50 percent to nearly three times freestream values in a complicated manner. Similar measurement locations are not uncommon on cloud research aircraft, where ice particle measurements may be subject to similar uncertainties.
Aircraft Icing↗
Organic carbon content and turnover time in relation to pedogenic iron and aluminum in four temperate forest soils sampled in 2007
Soil organic carbon (SOC) can be stabilized via association with iron (Fe) and aluminum (Al) minerals. Fe and Al can be strong predictors of SOC storage and turnover in soils with relatively high extractable metals content and moderately acidic to circumneutral pH. Here we test whether pedogenic Fe and Al influence SOC content and turnover in soils with low Fe and Al content and acidic pH. In soils from four sites spanning three soil orders, we quantified the amount of Fe and Al in operationally-defined poorly crystalline and organically-complexed phases using selective chemical dissolution applied to the soil fraction containing mineral-associated carbon. We evaluated the correlations of Fe and Al concentrations, mean annual precipitation (MAP), mean annual temperature (MAT), and pH with SOC content and 14C-based turnover times. We found that poorly crystalline Fe and Al content predicted SOC turnover times (p < 0.0001) consistent with findings of previous studies, while organically-complexed Fe and Al content was a better predictor of SOC concentration (p < 0.0001). Greater site-level MAP (p < 0.0001) and colder site-level MAT (p < 0.0001) were correlated with longer SOC turnover times but were not correlated with SOC content. Our results suggest that poorly crystalline Fe and Al effectively slow the turnover of SOC in these acidic soils, even when their combined content in the soil is less than 2% by mass. However, in the strongly acidic Spodosol, organo-metal complexes tended to be less stable resulting in a more actively cycling mineral-associated SOC pool. We characterized mineralogy and carbon content in soils from four forested sites in the eastern deciduous forest zone that span three soil orders. Using selective chemical dissolution applied to the soil fraction containing mineral-associated carbon, we quantified the amount of Fe and Al in operationally-defined poorly crystalline and organically-complexed phases, and correlated these with previously published SOC content and 14C-based turnover times (McFarlane et al. 2013). This dataset comprises site characterization undertaken in 2007 (.png) and subsequent soil analyses (.csv containing C, Fe, Al, 14C-derived TurnoverTime) concluded in 2010.
54 ENVIRONMENTAL SCIENCES↗
Measurement of leaf relative water content by infrared reflectance
From basic considerations and Beer's law, a leaf water content index incorporating reflectances of wavelengths from 0.76 to 0.90 microns and from 1.55 to 1.75 microns was developed that relates leaf reflectance to leaf relative water content. For the leaf succulent, Agave deserti, the leaf water content index was not significantly different from the relative water content for either individual leaves or an entire plant. Also, the relative water contents of intact plants of Encelia farinosa and Hilaria rigida in the field were estimated by the leaf water content index; variations in the proportion of living to dead leaf area could cause large errors in the estimate of relative water content. Thus, the leaf water content index may be able to estimate average relative water content of canopies when TM4 and TM5 are measured at a known relative water content and fraction of dead leaf material.
Hunt, E. Raymond, Jr.↗
Quantifying CTFE content in FK-800 using ATR-FTIR and time to peak crystallization
The chlorotrifluoroethylene (CTFE) content in vinylidene fluoride (VDF)-CTFE copolymers greatly influences the chemical and physical properties and ultimately determines the application. The copolymer known as FK-800 has a VDF:CTFE ratio of ~1:3 and is used almost exclusively as the binder in the insensitive high explosive (HE) formulation PBX 9502. Due to the dangerous nature of HE work and the effect CTFE content variations have, the ability to quickly and easily quantify CTFE content is of interest. Two techniques, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) and time to peak crystallization measured by heat flow calorimetry, were evaluated here as potential means for quantifying CTFE content. Based on the certificate of analyses (COAs), FK-800 lots with varied CTFE content encompassing the range historically used in HE applications were used as standards for both methodologies. For FTIR, a linear regression was performed on the peak area of the C-Cl IR stretch and the CTFE content; the methodology was then demonstrated on four samples, two lots of unadulterated material and material recovered from two HE samples. The calculated CTFE content and COAs were in good agreement for all four samples. Heat flow calorimetry revealed the relationship between time to peak crystallization and CTFE content was best fit by a power regression; the methodology was then tested on two different FK-800 lots. Only one sample showed good agreement between the calculated CTFE content and the COA. This discrepancy indicates the method developed is not suitable for quantifying CTFE, but provides valuable insight regarding the crystallization behavior of VDF-CTFE copolymers.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Water content and the conversion of phytochrome regulation of lettuce dormancy
In an effort to determine which biological reactions can occur in relation to the water content of seeds, the regulation of lettuce seed dormancy by red and far red light was determined at various hydration levels. Far red light had an inhibiting effect on germination for seeds at all moisture contents from 4 to 32% water. Germination was progressively stimulated by red light as seed hydration increased from 8 to 15%, and reached a maximum at moisture contents above 18%. Red light was ineffective at moisture contents below 8%. Seeds that had been stimulated by red light and subsequently dried lost the enhanced germinability if stored at moisture contents above 8%. The contrast between the presumed photoconversion of phytochrome far red-absorbing (Pfr) to (Pr) occurring at any moisture content and the reverse reaction occurring only if the seed moisture content is greater than 8% may be explained on the basis of the existence of unstable intermediates in the Pr to Pfr conversion. Our results suggest that the initial photoreaction involved in phytochrome conversion is relatively independent of water content, while the subsequent partial reactions become increasingly facilitated as water content increases from 8 to 18%.
Non-NASA Center↗
Estimation of the oxalate content of foods and daily oxalate intake
BACKGROUND: The amount of oxalate ingested may be an important risk factor in the development of idiopathic calcium oxalate nephrolithiasis. Reliable food tables listing the oxalate content of foods are currently not available. The aim of this research was to develop an accurate and reliable method to measure the food content of oxalate. METHODS: Capillary electrophoresis (CE) and ion chromatography (IC) were compared as direct techniques for the estimation of the oxalate content of foods. Foods were thoroughly homogenized in acid, heat extracted, and clarified by centrifugation and filtration before dilution in water for analysis. Five individuals consuming self-selected diets maintained food records for three days to determine their mean daily oxalate intakes. RESULTS: Both techniques were capable of adequately measuring the oxalate in foods with a significant oxalate content. With foods of very low oxalate content (<1.8 mg/100 g), IC was more reliable than CE. The mean daily intake of oxalate by the five individuals tested was 152 +/- 83 mg, ranging from 44 to 352 mg/day. CONCLUSIONS: CE appears to be the method of choice over IC for estimating the oxalate content of foods with a medium (>10 mg/100 g) to high oxalate content due to a faster analysis time and lower running costs, whereas IC may be better suited for the analysis of foods with a low oxalate content. Accurate estimates of the oxalate content of foods should permit the role of dietary oxalate in urinary oxalate excretion and stone formation to be clarified. Other factors, apart from the amount of oxalate ingested, appear to exert a major influence over the amount of oxalate excreted in the urine.
NASA Discipline Regulatory Physiology↗
Protonospheric columnar electron content determination. II - Observations
The results of over 300 hours of measurements of the quantity I sub w - the difference between total columnar electron content, derived from the differential phase-path data, and Faraday electron content - is presented. The interpretation of the measurements in terms of protonospheric content is discussed in the light of a previous analysis which demonstrates that good protonospheric content measurements can only be obtained under certain geometries of observations unless information on the shape and height of the ionospheric layer is available. A strong correlation between I sub w and the ionospheric content is observed in most of the Arecibo data, because they were collected under unfavorable conditions. The Stanford data, on the other hand, yield good measurements of the protonospheric content. The May 1969 observations show a strong depletion of protonospheric content during a magnetic storm and its subsequent recovery. This is in general agreement with flux tube content behavior observed by the whistler technique during similar conditions.
Almeida, O. G.↗
A scheme for parameterizing ice-cloud water content in general circulation models
The optical properties of ice clouds are a primary issue for climate and climate change. Evaluating these optical properties in three-dimensional models for studying climate will require a method to calculate the ice water content of such clouds. A procedure is developed to parameterize ice water content as a function of large-scale meteorological characteristics for use in circulation models in which the ice water content is not calculated by means of a three-dimensional prognostic equation for condensed water. The technique identifies large-scale flows in which ice clouds exist and calculates their ice water content by reconstructing the trajectory associated with cloud formation. As the cloud forms, its ice content changes both by deposition of ice from water vapor and by ice removal by sedimentation. The sedimentation process is found to modify significantly the ice water content expected from deposition alone. Ice water contents predicted by the parameterization are compared with aircraft observations collected in the middle latitudes and the tropics, and show reasonable agreement over four orders-of-magnitude of ice water content. A parameterization for the sublimation of ice crystals settling into ice-subsaturated environments is also presented.
Heymsfield, Andrew J.↗
Ice Particle Impact on Cloud Water Content Instrumentation
Determining the total amount of water contained in an icing cloud necessitates the measurement of both the liquid droplets and ice particles. One commonly accepted method for measuring cloud water content utilizes a hot wire sensing element, which is maintained at a constant temperature. In this approach, the cloud water content is equated with the power required to keep the sense element at a constant temperature. This method inherently assumes that impinging cloud particles remain on the sensing element surface long enough to be evaporated. In the case of ice particles, this assumption requires that the particles do not bounce off the surface after impact. Recent tests aimed at characterizing ice particle impact on a thermally heated wing section, have raised questions about the validity of this assumption. Ice particles were observed to bounce off the heated wing section a very high percentage of the time. This result could have implications for Total Water Content sensors which are designed to capture ice particles, and thus do not account for bouncing or breakup of ice particles. Based on these results, a test was conducted to investigate ice particle impact on the sensing elements of the following hot-wire cloud water content probes: (1) Nevzorov Total Water Content (TWC)/Liquid Water Content (LWC) probe, (2) Science Engineering Associates TWC probe, and (3) Particle Measuring Systems King probe. Close-up video imaging was used to study ice particle impact on the sensing element of each probe. The measured water content from each probe was also determined for each cloud condition. This paper will present results from this investigation and attempt to evaluate the significance of ice particle impact on hot-wire cloud water content measurements.
Emery, Edward F.↗
Spatially Averaged Ice Contents of Ice-Wedge Polygon Cross-Sections to 3-m Depth, July 2013, Utqiagvik, Alaska
This dataset contains spatially averaged estimates of ice content (volume percent) for two-dimensional cross-sectional profiles (from trough center to trough center to a depth of 3 meters) of low- and flat-centered ice-wedge polygons (three of each type) located near Utqiagvik, Alaska. A combination of soil pits, trenches, and cores were used to describe, sample, and map the cross-section stratigraphy of soil horizons and ice wedges for each polygon at 6 depth intervals. Observed soil horizons were assigned to four types with increasing amounts of organic components (mineral, mineral/organic, organic/mineral, and organic). The average ice contents of each soil horizon type below the permafrost boundary and wedge ice were weighted by their cross-sectional area fractions to calculate spatially averaged estimates of ice content for each polygon. In the active layer, spatially averaged estimates of volumetric water contents were similarly determined and reported here as “ice” content to enable estimates of the soil’s structurally competent porosity and excess ice in permafrost layers. In this dataset, the file AK13_ice_contents.csv includes cross-sectional area fractions and spatially averaged ice contents for soil layers and horizon types at the six depth intervals. The file AK13_permafrost_ice_fractions.csv contains the calculated partitioning of ice contents into pore ice and excess ice fractions for the three permafrost-dominated depth intervals. In addition, there is a data dictionary file for each of these data files and a file-level metadata file. These data were generated by the Department of Energy’s Soil Carbon Response to Environmental Change Scientific Focus Area and were used as inputs to model simulations examining the consequences of thaw-affected subsidence and microtopography change on active layer thickness of low-relief polygonal tundra landscapes in a warming Arctic.
54 ENVIRONMENTAL SCIENCES↗
Fast and Non-Destructive Determination of Water Content in Ionic Liquids at Varying Temperatures by Raman Spectroscopy and Multivariate Regression Analysis
Imidazolium acetate ionic liquids (ILs) have been utilized as promising solvents in many applications that involve varying water content and temperature. These experimental variables affect the anion-cation intermolecular interactions, which in turn influence the performance of the ILs in these applications. Here, this paper shows Raman spectroscopy can be used as an operando method to measure water content in IL solvents when simultaneous temperature changes may occur. The Raman spectra of 1-alkyl-3-methylimidazolium acetate ILs (alkyl chain length n = 2, 4, 6, 8) with varying water content (from 0.028 to 0.899 water mole fraction) and temperature (from 78.1 K to 423.1 K) were measured. Increasing the water content or decreasing the temperature of the tested ILs weakens the anion-cation intermolecular interactions. The water content of these ILs can be quantified even in conditions when the temperature is changing using Raman spectroscopy combined with multivariate regression analysis, including principal component regression (PCR), partial-least-squares regression (PLSR), and artificial neural networks (ANNs). The ANN model combined with partial-least-squares (PLS) achieves the highest prediction accuracy of water content in ILs at varying temperatures (RMSECV = 0.017, R 2 CV = 99.1%, RMSEP = 0.019, R 2 P = 98.8%, RPD = 8.93). Raman spectroscopy provides a potential fast non-destructive operando method to monitor the water content of ILs even in applications when the temperature may be simultaneously altered; this information can lead to the optimized use of these ILs in many applications.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗