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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Regional Geologic Cross Sections for Potential Storage and Containment Zones in the MRCSP Region

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO 2 ) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. Five geologic cross sections (labeled A through E) were constructed onshore across the parts of the MRCSP Region west of the Valley and Ridge Province, and one section (labeled F) was constructed beginning onshore in New Jersey and running eastward to offshore areas examined for carbon storage. Regional and local stratigraphic units were used in these cross sections to show current nomenclature as well as highlighting specific units/features pertinent to carbon capture, utilization and storage (CCUS) opportunities in the region. Each cross section uses 15 to 25 deep wells and other geologic information to illustrate the relative depth, thickness and location of rock units in the subsurface.

01 COAL, LIGNITE, AND PEAT↗

Regional Geologic Cross Sections for Potential Storage and Containment Zones in the MRCSP Region [plus Plates 1-6]

The regional characterization work conducted by the Geoteams during the MRCSP Phase III project period (2010 –2019) focused on the following tasks: (1) refinement of geologic seals/reservoir systems; (2) assessment of Atlantic Coastal Plain and offshore opportunities; (3) expanded assessments of oil and gas fields, particularly as they relate to enhanced recovery opportunities; (4) regional support for implementation of carbon capture utilization and storage (CCUS) in the partnership area; and (5) communication and data sharing. This report, entitled Regional Geology, has been prepared in association with (4), regional support for implementation of CCUS in the partnership area..

58 GEOSCIENCES↗

Evaluating the De Hoffmann-Teller Cross-Shock 2 Potential at Real Collisionless Shocks

Shock waves are common in the heliosphere and beyond. The collisionless nature of most astrophysical plasmas allows for the energy processed by shocks to be partitioned amongst particle sub-populations and electromagnetic fields via physical mechanisms that are not well understood. The electrostatic potential across such shocks is frame dependent. In a frame where the incident bulk velocity is parallel to the magnetic field, the deHoffmann-Teller frame, the potential is linked directly to the ambipolar electric field established by the electron pressure gradient. Thus measuring and understanding this potential solves the electron partition problem, and gives insight into other competing shock processes. Integrating measured electric fields in space is problematic since the measurements can have offsets that change with plasma conditions. The offsets, once integrated, can be as large or larger than the shock potential. Here we exploit the high-quality field and plasma measurements from NASA’s Magnetospheric Multiscale mission to attempt this calculation. We investigate recent adaptations of the deHoffmann-Teller frame transformation to include time variability, and conclude that in practice these face difficulties inherent in the 3D time-dependent nature of real shocks by comparison to 1D simulations. Potential estimates based on electron fluid and kinetic analyses provide the most robust measures of the deHoffmann-Teller potential, but with some care direct integration of the electric fields can be made to agree. These results suggest that it will be difficult to independently assess the role of other processes, such as scattering by shock turbulence, in accounting for the electron heating.

Steven J Schwartz↗

Analytic model of aurorally coupled magnetospheric and ionospheric electrostatic potentials

This paper describes modest but significant improvements on earlier studies of electrostatic potential structure in the auroral region, using the adiabatic auroral arc model. With certain simplifying assumptions, new analytic nonlinear solutions fully exhibiting the parametric dependence of potentials on magnetospheric (e.g., cross-tail potential) and ionospheric (e.g., recombination rate) parameters are found. No purely phenomenological parameters are introduced. The results are in reasonable agreement with observed average auroral potential drops, inverted-V scale sizes, and dissipation rates. The dissipation rate is quite comparable to tail energization and transport rates and should have a major effect on tail and magnetospheric dynamics. Various relations between the cross-tail potential and auroral parameters (e.g., total parallel currents and potential drops) are given which can be studied with existing data sets.

Cornwall, John M.↗

Analytic model of aurorally coupled magnetospheric and ionospheric electrostatic potentials

This paper describes modest but significant improvements on earlier studies of electrostatic potential structure in the auroral region using the adiabatic auroral arc model. This model has crucial nonlinearities (connected, for example. with aurorally produced ionization) which have hampered analysis; earlier work has either been linear, which I will show is a poor approximation or, if nonlinear, either numerical or too specialized to study parametric dependencies. With certain simplifying assumptions I find new analytic nonlinear solutions fully exhibiting the parametric dependence of potentials on magnetospheric (e.g.. cross-tail potential) and ionospheric (e.g., recombination rate) parameters. No purely phenomenological parameters are introduced. The results are in reasonable agreement with observed average auroral potential drops, inverted-V scale sizes, and dissipation rates. The dissipation rate is quite comparable to tail energization and transport rates and should have a major effect on tail and magnetospheric dynamics. This paper gives various relations between the cross-tail potential and auroral parameters (e.g., total parallel currents and potential drops) which can be studied with existing data sets.

Cornwall, J. M.↗

Cross-Polar Aircraft Trajectory Optimization and Potential Climate Impact

Cross-Polar routes offer new opportunities for air travel markets. Transpolar flights reduce travel times, fuel burns, and associated environmental emissions by flying direct paths between many North American and Asian cities. This study evaluates the potential benefits of flying wind-optimal polar routes and assessed their potential impact on climate change. An optimization algorithm is developed for transpolar flights to generate wind-optimal trajectories that minimize climate impact of aircraft, in terms of global warming potentials (relative to warming by one kg of CO2) of several types of emissions, while avoiding regions of airspace that facilitate persistent contrail formation. Estimations of global warming potential are incorporated into the objective function of the optimization algorithm to assess the climate impact of aircraft emissions discharged at a given location and altitude. The regions of airspace with very low ambient temperature and areas favorable to persistent contrail formation are modeled as undesirable regions that aircraft should avoid and are formulated as soft state constraints. The fuel burn and climate impact of cross-polar air traffic flying various types of trajectory including flightplan, great circle, wind-optimal, and contrail-avoidance are computed for 15 origin-destination pairs between major international airports in the U.S. and Asia. Wind-optimal routes reduce average fuel burn of flight plan routes by 4.4% on December 4, 2010 and 8.0% on August 7, 2010, respectively. The tradeoff between persistent contrail formation and additional global warming potential of aircraft emissions is investigated with and without altitude optimization. Without altitude optimization, the reduction in contrail travel times is gradual with increase in total fuel consumption. When altitude is optimized, a one percent increase in additional global warming potential, a climate impact equivalent to that of 4070kg and 4220kg CO2 emission, reduces 135 and 105 minutes persistent contrail formation per flight during a day with medium and high contrail formation, respectively.

Sridhar, Banavar↗

The repulsive 1 Sigma g/+/ He2 potential obtained from total cross sections

An improved apparatus for obtaining short-range molecular potentials is described. The setup is a refined version of that used by Jordan-Amdur and by Leonas. The ion source is provided with a mass analyzing magnet, the capacitance manometer in the scattering cell is calibrated with a McCleod gauge, and the detection unit substitutes a Channeltron multiplier for the thermopile. The measured ground-state He-He potential for radii between 0.49 and 1.56 A is approximately V(r) = 215 x exp(-3.95r) eV, which is 25% higher than the earlier experiments. The result is supported by molecular orbital and statistical model calculations.

Foreman, P. B.↗

Effective Potential Energies and Transport Cross Sections for Atom-Molecule Interactions of Nitrogen and Nitrogen

The potential energy surfaces for H2-N and N2-N interactions are calculated by accurate ab initio methods and applied to determine transport data. The results confirm that an effective potential energy for accurately determining transport properties can be calculated using a single orientation. A simple method is developed to determine the dispersion coefficients of effective potential energies Effective potential energies required for O2-O collisions are determ=ined. The H2-N, N2-N, O2-H, and O2-O collision integrals are calculated and tabulated for a large range of temperatures. The theoretical values of the N2-N and O2-O diffusion coefficients compare well with measured data available at room temperature.

Stallcop, James R.↗

Cross-Polar Aircraft Trajectory Optimization and the Potential Climate Impact

Cross-Polar routes offer new opportunities for air travel markets. Transpolar flights reduce travel times, fuel burns, and associated environmental emissions by flying direct paths between many North American and Asian cities. This study evaluates the potential benefits of flying wind-optimal polar routes and assessed their potential impact on climate change. An optimization algorithm is developed for transpolar flights to generate wind-optimal trajectories that minimize climate impact of aircraft, in terms of global warming potentials (relative to warming by one kg of CO2) of several types of emissions, while avoiding regions of airspace that facilitate persistent contrail formation. Estimations of global warming potential are incorporated into the objective function of the optimization algorithm to assess the climate impact of aircraft emissions discharged at a given location and altitude. The regions of airspace with very low ambient temperature and areas favorable to persistent contrail formation are modeled as undesirable regions that aircraft should avoid and are formulated as soft state constraints. The fuel burn and climate impact of cross-polar air traffic flying various types of trajectory including flight plan, great circle, wind-optimal, and contrail-avoidance are computed for 15 origin-destination pairs between major international airports in the U.S. and Asia. Wind-optimal routes reduce average fuel burn of flight plan routes by 4.4% on December 4, 2010 and 8.0% on August 7, 2010, respectively. The tradeoff between persistent contrail formation and additional global warming potential of aircraft emissions is investigated with and without altitude optimization. Without altitude optimization, the reduction in contrail travel times is gradual with increase in total fuel consumption. When altitude is optimized, a one percent increase in additional global warming potential, a climate impact equivalent to that of 4070kg and 4220kg CO2 emission, reduces 135 and 105 minutes persistent contrail formation per flight during a day with medium and high contrail formation, respectively.

Ng, Hok K.↗

Electrostatic potential jump across fast-mode collisionless shocks

The electrostatic potential jump across fast-mode collisionless shocks is examined by comparing published observations, hybrid simulations, and a simple model, in order to better characterize its dependence on the various shock parameters. In all three, it is assumed that the electrons can be described by an isotropic power-law equation of state. The observations show that the cross-shock potential jump correlates well with the shock strength but shows very little correlation with other shock parameters. Assuming that the electrons obey an isotropic power law equation of state, the correlation of the potential jump with the shock strength follows naturally from the increased shock compression and an apparent dependence of the power law exponent on the Mach number which the observations indicate. It is found that including a Mach number dependence for the power law exponent in the electron equation of state in the simple model produces a potential jump which better fits the observations. On the basis of the simulation results and theoretical estimates of the cross-shock potential, it is discussed how the cross-shock potential might be expected to depend on the other shock parameters.

Mandt, M. E.↗

Efficient and reversible electron bifurcation with either normal or inverted potentials at the bifurcating cofactor

A longstanding mystery surrounding electron bifurcation is the significance of inverted (or “crossed”) reduction potentials of the two-electron bifurcating cofactor. Using a many-electron open-system kinetic model, we show that reversible and efficient electron bifurcation is possible without inverted reduction potentials at the bifurcating site if the absolute value of the difference between first and second reduction potentials of the bifurcating species is sufficiently large (on the scale of the redox-potential span of the high- and low-potential branches). Surprisingly, the case with strong, normally ordered potentials at the bifurcating cofactor can produce electron bifurcation that is just as effective as the case with strongly inverted potentials. Lastly, this finding amplifies the puzzle surrounding the recruitment of inverted potentials in the few well-characterized bifurcating systems of nature and suggests that electron bifurcating cofactors without strongly inverted potentials may yet be discovered.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A theoretical F region study of ion compositional and temperature variations in response to magnetospheric storm inputs

The response of the high-latitude F region to magnetospheric storm inputs is modelled. During the 'storm', the spatial extent of the auroral oval, the intensity of the precipitating auroral electron energy flux, and the plasma convection pattern were varied with time. During the storm growth phase, the auroral oval expanded, the precipitating electron energy flux increased, and the magnetospheric convection pattern changed from a symmetric two-cell pattern with a 20 kV cross-tail potential to an asymmetric two-cell pattern with a total cross-tail potential of 90 kV. During the storm, there were significant changes in the ion temperature, ion composition, and molecular/atomic ion transition height. The storm time asymmetric convection pattern produced an ion temperature hot spot at the location of the dusk convection cell that contained significantly enhanced NO(+) densities. During the storm recovery phase, the decay of these densities closely followed the decrease in the plasma convection speed.

Sojka, J. J.↗

Potential curves for Na2/+/ and resonance charge transfer cross sections.

A mode potential method, applied earlier to the positively charged diatomic lithium molecule Li2(+), is used to calculate the six lowest potential energy curves of Na2(+). Charge transfer cross sections are calculated for Li(+) on Li and for Na(+) on Na and found to be in reasonable agreement with experiment.

Bottcher, C.↗

Impact of the electron density and temperature gradient on drift-wave turbulence in the Large Plasma Device

In this paper we present an experimental study of edge turbulence in the Large Plasma Device at UCLA. We utilize a scan of discharge power and prefill pressure (neutral density) to show experimentally that turbulent density fluctuations decrease with decreasing density gradient, as predicted for resistive drift-wave turbulence (RDWT). As expected for RDWT, we observe that the cross-phase between the density and potential fluctuations is close to 0. Moreover, the addition of an electron temperature gradient leads to a reduction in the amplitude of the density fluctuations, as expected for RDWT. However, counter to theoretical expectations, we find that the potential fluctuations do not follow the same trends as the density fluctuations for changes either in density gradients or the addition of a temperature gradient. The disconnect between the density and potential fluctuations is connected to changes in the parallel flows as a result of differences in the prefill pressure, i.e. neutral density. Further analysis of the density and potential fluctuation spectra show that the electron temperature gradient reduces the low frequency fluctuations up to $10 \,{\rm kHz}$ and the introduction of a temperature gradient leads to an unexpected ${\sim }{\rm \pi}$ shift of the density–potential cross-phase at ${\sim }10\,{\rm kHz}$ , while maintaining the typical resistive drift-wave cross-phase at lower frequencies. These experiments partly confirm existing knowledge on resistive drift-wave turbulence, but also introduce new observations that indicate a need for dedicated nonlinear three-dimensional turbulence simulations that include neutrals.

Physics↗