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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Validation of theory-based models for the control of plasma currents in W7-X divertor plasmas

A theory-based model for the control of plasma currents for steady-state operation in W7-X is proposed and intended for model-based plasma control. The conceptual outline implies the strength of physics-based models: it offer approaches applicable to future conditions of fusion devices or next-step machines. The application at extrapolated settings is related to the validity range of the theory model. Therefore, the predictive power of theory-based control models could be larger than for data-driven approaches and limitations can be predicted from the validity range for the prediction of bootstrap currents in W7-X. The model predicts the L/R response when density or heating power is changed. The model is based on neoclassical bootstrap current calculations and validated for different discharge conditions. While the model was found to be broadly applicable for conducted electron-cyclotron-heated discharges in W7-X, limits were found for cases when the polarization of the electron cyclotron heating was changed from X2 to O2-heating. The validity assessment attempts to quantify the potential of the derived model for model-based control in the operational space (density, heating power) of W7-X.

neoclassical modelling↗

A History of Molecular Level Analysis of Natural Organic Matter by FTICR Mass Spectrometry and The Paradigm Shift in Organic Geochemistry

Natural organic matter (NOM) is a complex mixture of biogenic molecules resulting from the deposition and transformation of plant and animal matter. It has long been recognized that NOM plays an important role in many geological, geochemical, and environmental processes. Of particular concern is the fate of NOM in response to a warming climate in environments that have historically sequestered carbon (e.g., peatlands and swamps) but may transition to net carbon emitters. In this review, we will highlight developments in the application of high-field Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) in identifying the individual components of complex NOM mixtures, focusing primarily on the fraction that is dissolved in natural waters (dissolved organic matter or DOM). We will first provide some historical perspective on developments in FTICR technology that made molecular-level characterizations of DOM possible. In conclusion, a variety of applications of the technique will then be described, followed by our view of the future of high-field FTICR MS in carbon cycling research, including a particularly exciting metabolomic approach.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Broadening of microwave heating beams in the DIII-D tokamak by edge turbulence

Abstract We have demonstrated for the first time that turbulent plasma density fluctuations in the edge of the DIII-D tokamak are responsible for substantial broadening of an injected microwave beam by successful quantitative comparison between experimental observations and first principles 2D full-wave simulations. The broadening of the beam has important implications for control of tokamak discharges through localized electron cyclotron deposition needed for eliminating magnetohydrodynamic instabilities. This new predictive capability is mandatory to design & operate present & future tokamaks in such a way that microwave heating schemes achieve their intended objectives.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

SPRUCE FT-ICR MS, Bulk Chemistry, and Mass Loss from Litter Decomposition Study in Experimental Plots, Marcell Experimental Forest, Minnesota, 2015-2017

This dataset contains molecular, bulk chemical, and mass loss measurements from a litter decomposition study at the Spruce and Peatland Responses Under Changing Environments (SPRUCE) experimental site within the Marcell Experimental Forest in northern Minnesota, USA. This site is in a Sphagnum spp. ombrotrophic bog forest. Litterbags were deployed into the peat in September 2015 across three warming levels (+0, +4.5, and +9°C) under ambient and elevated carbon dioxide (CO₂ - +500 ppm) and retrieved after roughly 0.5, 1, and 2 years of field incubation (2015-09-23 to 2017-08-02). Litterbags containing six peatland litter types: black spruce needles (Picea mariana - SPL), spruce fine roots (SPR), Sphagnum angustifolium (ANG), Sphagnum magellanicum (MAG), Labrador tea leaves (Rhododendron groenlandicum - LTL), and Labrador tea roots (LTR). Molecular composition of water-soluble organic matter extracts was characterized using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) at 9.4 Tesla, operated in negative ion mode with electrospray ionization, providing molecular formula assignments and compound-class distributions across the decomposition time series. Bulk chemical characterization included elemental analysis (percent carbon, nitrogen, and phosphorus) and Fourier Transform Infrared Spectroscopy (FTIR) to quantify functional group composition. Litter mass loss was tracked gravimetrically at each retrieval interval, expressed as percent mass remaining relative to initial dry mass for each litter type and treatment combination. These data are valuable for understanding how vegetation shifts driven by increased atmospheric CO2 and temperature in peatlands alter litter inputs and organic matter stabilization trajectories, with implications for projecting and modeling peatland carbon cycling. This dataset contains two data files in comma-separated value (.csv) format. Additional metadata are provided: two data dictionaries and a file-level metadata file in comma separate (.csv) format and a user guide in PDF (*.pdf) format.

decomposition↗

Final Design of Vacuum Pumping Systems for the Material Plasma Exposure eXperiment

The Material Plasma Exposure eXperiment (MPEX) vacuum pumping system is responsible for creating prototypic conditions in the plasma material interaction chamber that mimic those in a fusion reactor divertor region. Additionally, the vacuum system needs to minimize the pressure in the plasma heating region to improve the coupling of the electron cyclotron heating and ion cyclotron heating to the plasma, minimizing waste heat exhausted to high heat flux components. Here, the final design of the system has been sized to comply with the vacuum pump operating environment and to reduce the number of unique pumps required while meeting performance requirements. Bounding cases with and without the plasma present have been developed in the pumping analysis, and an initial calculation has been performed based on the plasma pumping identified in Proto-MPEX operation though this result will remain unverified until MPEX operation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Data and scripts associated with a manuscript investigating dissolved organic matter and microbial community linkages across seven globally distributed rivers

This data package is associated with the publication “Meta-metabolome ecology reveals that geochemistry and microbial functional potential are linked to organic matter development across seven rivers” submitted to Science of the Total Environment. This data package includes the data necessary to replicate the analyses presented within the manuscript to investigate dissolved organic matter (DOM) development across broad spatial distances and within divergent biomes. Specifically, we included the Fourier transform ion cyclotron mass spectrometry (FTICR-MS) data, geochemistry data, annotated metagenomic data, and results from ecological null modeling analyses in this data package. Additionally, we included the scripts necessary to generate the figures from the manuscript. Complete metagenomic data associated with this data package can be found at the National Center for Biotechnology (NCBI) under Bioproject PRJNA946291. This dataset consists of (1) four folders; (2) a file-level metadata (flmd) file; (3) a data dictionary (dd) file; (4) a factor sheet describing samples; and (5) a readme. The FTICR Data folder contains (1) the processed Fourier transform ion cyclotron mass spectrometry (FTICR-MS) data; (2) a transformation-weighted characteristics dendrogram generated from the FTICR-MS data; and (3) the script used to generate all FTICR-MS related figures. The Geochemical Data folder contains (1) the single geochemistry data file and (2) the R script responsible for generating associated figures. The Metagenomic Data folder contains (1) annotation information across different levels; (2) carbohydrate active enzyme (CAZyme) information from the dbCAN database (Yin et al., 2012); (3) phylogenetic tree data (FASTAs, alignments, and tree file); and (4) the scripts necessary to analyze all of these data and generate figures. The Null Modeling Data folder contains (1) data generated during null modeling for each river and all rivers combined and (2) the R scripts necessary to process the data. All files are .csv, .pdf, .tsv, .tre, .faa, .afa, .tree, or .R.

54 ENVIRONMENTAL SCIENCES↗

Simultaneous measurement of organic scintillator response to carbon and proton recoils

Organic scintillators are widely used for neutron detection in both basic nuclear physics and applications. While the proton light yield of organic scintillators has been extensively studied, measurements of the light yield from neutron interactions with carbon nuclei are scarce. Demonstrate a new approach for the simultaneous measurement of the proton and carbon light yield of organic scintillators. Provide new carbon light yield data for the EJ-309 liquid and EJ-204 plastic organic scintillators. A 33-MeV 2 H + beam from the 88-Inch Cyclotron at Lawrence Berkeley National Laboratory was impinged upon a 3-mm-thick Be target to produce a high-flux, broad-spectrum neutron beam. The double time-of-flight technique was extended to simultaneously measure the proton and carbon light yields of the organic scintillators, wherein the light output associated with the recoil particle was determined using np and nC elastic scattering kinematics. The proton and carbon light yield relations of the EJ-309 liquid and EJ-204 plastic organic scintillators were measured over a recoil energy range of approximately 0.3 to 1 MeV and 2 to 5 MeV, respectively, for EJ-309, and 0.2 to 0.5 MeV and 1 to 4 MeV, respectively, for EJ-204. Furthermore, these data provide new insight into the ionization quenching effect in organic scintillators and key input for simulation of the response of organic scintillators for both basic science and a broad range of applications.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Quasilinear theory of Brillouin resonances in rotating magnetized plasmas

Both spin and orbital angular momentum can be exchanged between a rotating wave and a rotating magnetized plasma. Through resonances the spin and orbital angular momentum of the wave can be coupled to both the cyclotron rotation and the drift rotation of the particles. It is, however, shown that the Landau and cyclotron resonance conditions which classically describe resonant energy–momentum exchange between waves and particles are no longer valid in a rotating magnetized plasma column. In this case a new resonance condition which involves a resonant matching between the wave frequency, the cyclotron frequency modified by inertial effects and the harmonics of the guiding centre rotation is identified. A new quasilinear equation describing orbital and spin angular momentum exchanges through these new Brillouin resonances is then derived, and used to expose the wave-driven radial current responsible for angular momentum absorption.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Upgrades to the ion cyclotron emission diagnostic on the DIII-D tokamak

The ion cyclotron emission diagnostic on the DIII-D tokamak comprises seven single-turn loops that measure high-frequency (1–100 MHz) magnetic field fluctuations that are often excited by energetic particles in the plasma. The raw voltage signals induced in the loops in response to these fluctuations travel through a series of cables, isolation transformer DC blocks, low-pass filters, and finally a digitizer before being analyzed in frequency space. The diagnostic has been recently upgraded, most notably to include four additional graphite tile loops and a new eight-channel digitizer. The previous three loops are all on the low-field side of the tokamak. The measurement capabilities of the system have been expanded by the addition of a new horizontally oriented loop on the low-field side, an additional toroidal loop on the low-field side, and two toroidal loops on the high-field side. These loops will be used to provide approximate mode polarization, improved toroidal mode number calculations, and information on modes in inward-shifted plasmas, respectively.

47 OTHER INSTRUMENTATION↗

Coupled Biotic-Abiotic Processes Control Biogeochemical Cycling of Dissolved Organic Matter in the Columbia River Hyporheic Zone

A critical component of assessing the impacts of climate change on watershed ecosystems involves understanding the role that dissolved organic matter (DOM) plays in driving whole ecosystem metabolism. The hyporheic zone—a biogeochemical control point where ground water and river water mix—is characterized by high DOM turnover and microbial activity and is responsible for a large fraction of lotic respiration. Yet, the dynamic nature of this ecotone provides a challenging but important environment to parse out different DOM influences on watershed function and net carbon and nutrient fluxes. We used high-resolution Fourier-transform ion cyclotron resonance mass spectrometry to provide a detailed molecular characterization of DOM and its transformation pathways in the Columbia river watershed. Samples were collected from ground water (adjacent unconfined aquifer underlying the Hanford 300 Area), Columbia river water, and its hyporheic zone. The hyporheic zone was sampled at five locations to capture spatial heterogeneity within the hyporheic zone. Our results revealed that abiotic transformation pathways (e.g., carboxylation), potentially driven by abiotic factors such as sunlight, in both the ground water and river water are likely influencing DOM availability to the hyporheic zone, which could then be coupled with biotic processes for enhanced microbial activity. The ground water profile revealed high rates of N and S transformations via abiotic reactions. The river profile showed enhanced abiotic photodegradation of lignin-like molecules that subsequently entered the hyporheic zone as low molecular weight, more degraded compounds. While the compounds in river water were in part bio-unavailable, some were further shown to increase rates of microbial respiration. Together, river water and ground water enhance microbial activity within the hyporheic zone, regardless of river stage, as shown by elevated putative amino-acid transformations and the abundance of amino-sugar and protein-like compounds. This enhanced microbial activity is further dependent on the composition of ground water and river water inputs. Our results further suggest that abiotic controls on DOM should be incorporated into predictive modeling for understanding watershed dynamics, especially as climate variability and land use could affect light exposure and changes to ground water essential elements, both shown to impact the Columbia river hyporheic zone.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Real-time steerable frequency-stepped Doppler backscattering (DBS) system for local helicon wave electric field measurements on the DIII-D tokamak

A new frequency-stepped Doppler backscattering (DBS) system has been integrated into a real-time steerable electron cyclotron heating launcher system to simultaneously probe local background turbulence (f < 10 MHz) and high-frequency (20–550 MHz) density fluctuations in the DIII-D tokamak. The launcher allows for 2D steering (horizontally and vertically) over wide angular ranges to optimize probe location and wavenumber response. The vertical steering can be optimized during a discharge in real time. The new DBS system employs a programmable frequency synthesizer with adjustable dwell time as a source to launch either O or X-mode polarized millimeter waves. This system can step in real-time over the entire E-band frequency range (60–90 GHz). This combination of capabilities allows for the diagnosis of the complex internal spatial structure of high power (>200 kW) helicon waves (476 MHz) injected from an external antenna during helicon current drive experiments in DIII-D. Broadband density fluctuations around the helicon frequency are observed during real-time scans of measurement location and wavenumber during these experiments. Analysis indicates that these broadband high-frequency fluctuations are a result of backscattering of the DBS millimeter-wave probe beam from plasma turbulence modulated by the helicon wave. It is observed that background turbulence is effectively locally “tagged” with the helicon wave electric field, forming images of the turbulent spectrum in the overall density fluctuation spectrum that appear as high-frequency sidebands of the turbulence. These observations of background turbulence and high-frequency fluctuations open up the possibility of monitoring local helicon wave amplitude by comparing the high-frequency signal amplitude to the simultaneously measured background turbulence. In combination with the real-time measurement location and wavenumber scanning capabilities (offered by real-time frequency-stepping and steering), this allows rapid determination of the spatial distribution of the helicon wave power during steady-state plasma operation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Soil microbiome resilience to short-term (30 days, 90 days) and long-term (1000 days) drought

This dataset contains data used for the paper "Drought duration does not impact soil microbiome resilience". The Related References will be updated with a full citation when available. Increasing global droughts exert large but poorly understood effects on the microbial communities and ecology of soil. Microbial communities generally show resilience and return to pre-drought conditions when short-term droughted soils are rewet; soils exposed to long-term drought, however, often show a lag upon rewetting, after which microbial communities may or may not return to their pre-stressed conditions. Though short-term droughts have been widely studied, long-term drought manipulation experiments remain rare, especially those that compare microbial response to short-term and long-term drought in tandem. We conducted a 1000-day drought simulation in controlled laboratory conditions with soil cores collected from a tidal freshwater ecosystem in Washington state, USA, and subsequently exposed them to rewetting for two weeks. We also included short-term (30-day and 90-day) drought and rewet treatments to directly compare microbial community and organic matter responses across drought durations. We found distinct microbial taxa belonging to Firmicutes and Actinobacteria enriched after the 1000-day drought, but not after the short-term droughts. While we hypothesized that the microbial community would recover from a short-term drought after rewetting to resemble pre-drought conditions, our results revealed community dissimilarities between rewet and pre-drought conditions across all drought durations. These findings suggest unique microbial life history strategies within certain microbial phyla that make them successful colonizers during an extended drought period, and the influence of environmental and physiological context on microbial responses to rewetting. The 16SrRNA gene amplicon dataset contains processed DNA sequences in the form of an ASV table with raw unrarefied read counts and representative sequences in .fasta format as described in the ESS-DIVE amplicon sequence reporting format (https://ess-dive.gitbook.io/amplicon-sequencing-reporting-format/instructions). The Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) dataset consists of processed files containing presence absence data of molecular formulae and molecular characterization of FTICR resolved peaks. The Nuclear Magnetic Resonance (NMR) dataset contains files relevant to NMR spectra and peaks. A sample key file and a sample metadata file is included for the FTICR/NMR and 16S dataset respectively.

1000-day drought↗

Response Surface Methodology As a New Approach for Finding Optimal MALDI Matrix Spraying Parameters for Mass Spectrometry Imaging

Automated spraying devices have become ubiquitous in laboratories employing matrixassisted laser desorption/ionization mass spectrometry imaging (MALDI-MSI), in part because they permit control of a number of matrix application parameters that can easily be reproduced for intra- and interlaboratory studies. Determining the optimal parameters for MALDI matrix application, such as temperature, flow rate, spraying velocity, number of spraying cycles, and solvent composition for matrix application, is critical for obtaining high-quality MALDI-MSI data. However, there are no established approaches for optimizing these multiple parameters simultaneously. Instead optimization is performed iteratively (i.e., one parameter at a time), which is time consuming and can lead to overall non-optimal settings. In this report, we demonstrate the use a novel experimental design and the response surface methodology to optimize five parameters of MALDI matrix application using a robotic sprayer. Thirtytwo combinations of MALDI matrix spraying conditions were tested, which allowed us to elucidate relationships between each of the application parameters as determined by MALDI-MS (specifically, using a 15 Tesla Fourier transform ion cyclotron resonance mass spectrometer). As such, we were able to determine the optimal automated spraying parameters that minimized signal de-localization and enabled high MALDI sensitivity. We envision this optimization strategy can be utilized for other MALDI-MSI applications, tissue types, and matrix application approaches.

60 APPLIED LIFE SCIENCES↗

The real-time data processing and acquisition system for Project 8 Phase II

In Phase II of the Project 8 neutrino mass experiment, electrons from the decays of tritium or 83 m Kr are detected via their ≈ 26GHz cyclotron radiation while contained within a circular waveguide. The signal from a given electron is characterized as a brief chirp, lasting ≲ 10ms and changing in frequency by ≲ 1MHz/ms. To detect these signals, the Project 8 collaboration developed a Data Acquisition (DAQ) system tailored to the signal properties. The DAQ is responsible for simultaneously selecting up to three 100MHz-wide frequency windows to study, detect, and trigger on likely signals from different electron kinetic energies, and for writing the relevant data to disk. We describe the Phase II DAQ system in detail and address how the system was used for data-taking operations.

Ashtari Esfahani, A. [Washington U., Seattle; Shar↗

Cause and impact of low-frequency chirping modes in DIII-D hybrid discharges

Significant variations in MHD activity and fast-ion transport are observed in the DIIID high-beta, steady-state hybrid discharges with a mixture of Electron Cyclotron (EC) waves and Neutral Beam Injection (NBI). When Electron Cyclotron Heating (ECH) or Current Drive (ECCD) is applied, Alfven Eigenmodes (AEs) are usually suppressed and replaced by low-frequency bursting modes. The analysis of a recently compiled database of hybrid discharges suggests that the change of the fast-ion pressure especially the perpendicular pressure is the main factor responsible for the instability transition. The lower ratio of fast-ion injection speed v inj to Alfven speed v alfven and slight drop of safety factor q min during ECCD may also facilitate the transition. The database shows that AEs mainly occur when the fast-ion fraction P f /P total is less than 0.53 and v inj /v alfven is greater than 0.50, while low-frequency bursting modes appear in the opposite regime. In this research, P f and P total are the central fast-ion pressure from classical prediction and total plasma pressure, respectively. The reason why the instability transition correlates with P f /P total and v inj /v alfven is that they can significantly modify the drive of low-frequency bursting modes and AEs. The explanation is supported by the observation that low-frequency bursting modes are rarely seen in the hybrids with NBI only, with EC waves and counter-NBI, or with high plasma density. A careful check of the low-frequency bursting modes suggests that they are mainly chirping (neoclassical) tearing modes [referred to as chirping (N)TM], i.e. the mode frequency firstly jumps up from the steady (N)TM frequency, then chirps down, and finally returns to the steady (N)TM frequency. Sometimes, the (N)TMs are fully stabilized and replaced with pure fishbones. Lastly, the resonance condition calculation and ’Kick’ model simulations suggest that (N)TMs and fishbones can interact through modification of the fast ion distribution in phase space, which influences the drive.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The real-time data processing and acquisition system for Project 8 Phase II

In Phase II of the Project 8 neutrino mass experiment, electrons from the decays of tritium or 83m Kr are detected via their ≈26 GHz cyclotron radiation while contained within a circular waveguide. The signal from a given electron is characterized as a brief chirp, lasting ≲10 ms and changing in frequency by ≲1 MHz/ms. To detect these signals, the Project 8 collaboration developed a Data Acquisition (DAQ) system tailored to the signal properties. The DAQ is responsible for simultaneously selecting up to three 100 MHz-wide frequency windows to study, detect, and trigger on likely signals from different electron kinetic energies, and for writing the relevant data to disk. Finally, we describe the Phase II DAQ system in detail and address how the system was used for data-taking operations.

Data acquisition↗

Resolving ECRH deposition broadening due to edge turbulence in DIII-D

Microwave heat pulse propagation experiments have demonstrated a correlation between millimeter-scale turbulence and deposition profile broadening of electron cyclotron (EC) waves on the DIII-D tokamak. In a set of discharges in DIII-D, a variation in edge density fluctuations on the mm-scale is associated with 40%–150% broader deposition profiles, expressed in terms of normalized minor radius, as compared with equilibrium ray tracing. The 1D power profile is determined from transport analysis of the electron temperature response to EC power modulation using perturbative analysis with a square wave power modulation at 20–70 Hz, producing a series of Fourier harmonics that are fit collectively to resolve transport. Fitting an integrated heat flux expressed in the Fourier basis of the modulation to diffusive, convective, and coupled transport terms in a linear model can resolve the broadened EC deposition width from the power perturbation to resolve a broadening in each case. The best fit degree of beam broadening observed scales approximately linearly with the Doppler backscattering measured fluctuation level in the steep gradient region. Quantifying the effect of edge fluctuation broadening on EC current drive power needs of future devices will require 3D full-wave codes that can be validated on the current generation of machines. These DIII-D experiments provide a quantitative measure of fluctuation effects and a dataset to benchmark full-wave simulations that can model and eventually predict nonlinear effects neglected by 1D equilibrium beam and ray tracing.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Characterization of SOL profiles and turbulence in ICRF-heated plasmas in EAST

Scrape-off layer (SOL) profiles and turbulence in ion cyclotron range of frequency (ICRF)-heated plasmas are investigated by the reciprocating probe diagnostic system (FRPs) and gas puff imaging (GPI) diagnostic in EAST. A radio-frequency (RF) sheath potential reaching up to 100 V is identified proximate to the ICRF antennas. Notably, the amplitude of this RF sheath potential escalates in response to rising ICRF power and inversely with plasma density. When a RF sheath is present in the far SOL, a pronounced density ‘shoulder’ forms in front of the ICRF antennas, while the ‘shoulder’ fade away as the antenna and associated RF sheath shift outwards. A strong E r shear is revealed by measurements from both FRPs and GPI. Analysis of the poloidal wave number-frequency spectrum reveals suppression of high-frequency turbulence in the far SOL due to the RF sheath. This effect is manifested in the reduced autocorrelation time τ c and reduced average blob size δ blob of the SOL plasma. Intriguingly, the poloidal propagation direction of the low-frequency turbulence reverses from the electron to the ion diamagnetic drift direction at the RF sheath location. A surge of tungsten impurity is potentially attributed to the heightened interaction between the SOL plasmas and the wall material. Shifting the ICRF antennas outward, to alleviate heat spots, results in the relocation of the RF sheath to the shaded region of the main limiter. This shift amplifies the radial velocity of blobs in the far SOL and concurrently diminishes the SOL density when compared to conditions without ICRF injection. The properties of ion saturation current fluctuations are consistent with the stochastic model predictions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗