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At least 37 records · Page 2

Nonlinear wave propagation using three different finite difference schemes (category 2 application)

Three common finite difference schemes are used to examine the computation of one-dimensional nonlinear wave propagation. The schemes are studied for their responses to numerical parameters such as time step selection, boundary condition implementation, and discretization of governing equations. The performance of the schemes is compared and various numerical phenomena peculiar to each is discussed.

Pope, D. Stuart

Impact of differences in the solar irradiance spectrum on surface reflectance retrieval with different radiative transfer codes

Surface reflectance retrieval from imaging spectrometer data as acquired with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) has become important for quantitative analysis. In order to calculate surface reflectance from remotely measured radiance, radiative transfer codes such as 5S and MODTRAN2 play an increasing role for removal of scattering and absorption effects of the atmosphere. Accurate knowledge of the exo-atmospheric solar irradiance (E(sub 0)) spectrum at the spectral resolution of the sensor is important for this purpose. The present study investigates the impact of differences in the solar irradiance function, as implemented in a modified version of 5S (M5S), 6S, and MODTRAN2, and as proposed by Green and Gao, on the surface reflectance retrieved from AVIRIS data. Reflectance measured in situ is used as a basis of comparison.

Staenz, K.

The power of lanthanides: same composition, but different lanthanides leading to different interesting materials properties, from magnetocalorics to molecular magnets and phosphors

Commonly accepted design concepts for ionic liquids (ILs) state that the constituting ions must be large and carry low, well-dispersed charges. A series of ILs based of pentadeca charged ILs with pentanuclear linear {Ln 5 } units ([Ln 5 (C 2 H 5 -C 3 H 3 N 2 -CH 2 COO) 16 (H 2 O) 8 ](Tf 2 N) 15 (C 3 H 3 N 2 = imidazolium moiety, Tf 2 N = bis(trifluoromethanesulfonyl)amide) with Ln = Er, Ho, Tm) demonstrates that these criteria are not absolute. Highly charged ions can also support IL formation, provided they are sufficiently large. Expanding the series of these unconventional, record pentadeca charged with new lanthanide representatives, led to the discovery of additional unprecedented properties for ILs: The Gd compound exhibits a strong magnetocaloric effect (MCE) in the liquid state with a maximum magnetic entropy change of −ΔS M = −11 J⋅kg −1 ⋅K −1 at 2 K for Δμ 0 H = 7 T. Albeit the Dy representative shows slow magnetic relaxation, the relaxation times are not favorable for practical application as a molecular magnet. Lastly, for both the Gd and the Y compound, phosphorescence in the seconds time scale is observed, which is, to the best of our knowledge, the longest ever reported for an IL.

Ionic Liquids

Data for KETCHUP: Parameterizing of Large-Scale Kinetic Models Using Multiple Datasets with Different Reference States

Repository for Kinetic Estimation Tool Capturing Heterogeneous Datasets Using Pyomo (KETCHUP), a flexible parameter estimation tool that leverages a primal-dual interior-point algorithm to solve a nonlinear programming (NLP) problem that identifies a set of parameters capable of recapitulating the steady-state fluxes and concentrations in wild-type and perturbed metabolic networks. KETCHUP can use K-FIT [2] input files. Example K-FIT input files are located in the K-FIT repository at https://github.com/maranasgroup/K-FIT.

Metabolomics

Investigation of the level difference between sound pressure and sound intensity in an aircraft cabin under different fuselage conditions

Problems in using two-microphone sound-intensity (SI) measurements to measure structural transmission losses are investigated in experiments involving light-aircraft fuselage panels and windows. Both sound pressure (SP) and SI are measured near the passenger and door windows and panels of a single-engine aircraft and with these barriers removed, and the effect of increasing interior acoustic absorption and blocking flanking transmission paths is also tested. The results are presented graphically, and the SP measurements are used to indicate frequency ranges in which the two-microphone technique significantly underestimates SI. It is inferred that flanking paths and interior reverberation must be effectively suppressed in order to obtain accurate transmission-loss measurements.

Atwal, M. S.

Thermal power transfer system using applied potential difference to sustain operating pressure difference

A thermal power transfer system using a phase change liquid gas fluid in a closed loop configuration has a heat exchanger member connected to a gas conduit for inputting thermal energy into the fluid. The pressure in the gas conduit is higher than a liquid conduit that is connected to a heat exchanger member for outputting thermal energy. A solid electrolyte member acts as a barrier between the gas conduit and the liquid conduit adjacent to a solid electrolyte member. The solid electrolyte member has the capacity of transmitting ions of a fluid through the electrolyte member. The ions can be recombined with electrons with the assistance of a porous electrode. An electrical field is applied across the solid electrolyte member to force the ions of the fluid from a lower pressure liquid conduit to the higher pressure gas conduit.

Bhandari, Pradeep

NADH oxidase activity (NOX) and enlargement of HeLa cells oscillate with two different temperature-compensated period lengths of 22 and 24 minutes corresponding to different NOX forms

NOX proteins are cell surface-associated and growth-related hydroquinone (NADH) oxidases with protein disulfide-thiol interchange activity. A defining characteristic of NOX proteins is that the two enzymatic activities alternate to generate a regular period length of about 24 min. HeLa cells exhibit at least two forms of NOX. One is tumor-associated (tNOX) and is inhibited by putative quinone site inhibitors (e.g., capsaicin or the antitumor sulfonylurea, LY181984). Another is constitutive (CNOX) and refractory to inhibition. The periodic alternation of activities and drug sensitivity of the NADH oxidase activity observed with intact HeLa cells was retained in isolated plasma membranes and with the solubilized and partially purified enzyme. At least two activities were present. One had a period length of 24 min and the other had a period length of 22 min. The lengths of both the 22 and the 24 min periods were temperature compensated (approximately the same when measured at 17, 27 or 37 degrees C) whereas the rate of NADH oxidation approximately doubled with each 10 degrees C rise in temperature. The rate of increase in cell area of HeLa cells when measured by video-enhanced light microscopy also exhibited a complex period of oscillations reflective of both 22 and 24 min period lengths. The findings demonstrate the presence of a novel oscillating NOX activity at the surface of cancer cells with a period length of 22 min in addition to the constitutive NOX of non-cancer cells and tissues with a period length of 24 min.

Non-NASA Center

Magnetic Reconnection in Different Environments: Similarities and Differences

Depending on the specific situation, magnetic reconnection may involve symmetric or asymmetric inflow regions. Asymmetric reconnection applies, for example, to reconnection at the Earth's magnetopause, whereas reconnection in the nightside magnetotail tends to involve more symmetric geometries. A combination of review and new results pertaining to magnetic reconnection is being presented. The focus is on three aspects: A basic, MHD-based, analysis of the role magnetic reconnection plays in the transport of energy, followed by an analysis of a kinetic model of time dependent reconnection in a symmetric current sheet, similar to what is typically being encountered in the magnetotail of the Earth. The third element is a review of recent results pertaining to the orientation of the reconnection line in asymmetric geometries, which are typical for the magnetopause of the Earth, as well as likely to occur at other planets.

Reconnection

T2M Forecasts at Subseasonal Leads: Do Different Soil Moisture Initial States Have Different Impacts?

Soil moisture (W) helps control evapotranspiration (ET), and ET variations can in turn have a distinct impact on 2-m air temperature (T2M), given that increases in evaporative cooling encourage reduced temperatures. Soil moisture is accordingly linked to T2M, and realistic soil moisture initialization has, in previous studies, been shown to improve the skill of subseasonal T2M forecasts. The relationship between soil moisture and evapotranspiration, however, is distinctly nonlinear, with ET tending to increase with soil moisture in drier conditions and to be insensitive to soil moisture variations in wetter conditions. Here, through an extensive analysis of subseasonal forecasts produced with a state-of-the-art seasonal forecast system, this nonlinearity is shown to imprint itself on T2M forecast error in the conterminous United States in two unique ways: (i) the T2M forecast bias (relative to independent observations) induced by a negative precipitation bias tends to be larger for dry initializations, and (ii) on average, the unbiased root-mean-square error (ubRMSE) tends to be larger for dry initializations. Such findings can aid in the identification of forecasts of opportunity; taken a step further, they suggest a pathway for improving bias correction and uncertainty estimation in subseasonal T2M forecasts by conditioning each on initial soil moisture state.

2-meter Temperature

Understanding The Top-Of-Atmosphere Fluxes Difference Between Aerocom Phase III Models And The CERES Product: Clear-Sky Perspective

The Clouds and the Earth’s Radiant Energy System (CERES) project produces a long-term global climate data record (CDR) that can be used to detect decadal changes in the Earth’s radiation budget (ERB) from the surface to the top-of-atmosphere (TOA). The CERES Energy Balanced and Filled (EBAF) product includes monthly mean shortwave (SW), longwave (LW), and net TOA all-sky and clear-sky radiative fluxes over 1-degree latitude by 1-degree longitude regions. The EBAF SW and LW fluxes are adjusted within their uncertainties to be consistent with the heat storage in the Earth-atmosphere system (Johnson et al. 2016). EBAF also provides a gap-free monthly mean clear-sky flux map by inferring clear-sky fluxes from both CERES and MODIS measurements (Loeb et al. 2018). In this study, we compare the TOA clear-sky fluxes from Aerocom phase III output with those from the CERES EBAF products. Flux differences over the ocean are generally smaller than over the land, and the magnitude of the differences shows seasonal and regional dependency. To understand the flux differences, aerosol optical depths (AOD) from the Aerocom models are compared with the satellite retrievals from MODIS and MISR. Over the ocean, the AOD differences and the flux differences show consistent regional features, indicating that the differences between models and observations are robust as the CERES EBAF clear-sky SW fluxes and MODIS/MISR AODs are determined independently. However, very little resemblance is found between the AOD and flux differences over the land. To further understand the cause of the flux differences over the land, we compare the land surface albedo from MODIS with the albedo from the models and find consistency in regional albedo differences and flux differences. Monthly regional radiative kernels of AOD and surface albedo derived using the MERRA-2 reanalysis data (Thorsen et al. 2020) are applied to AOD and surface albedo differences between models and observations. For most of the models, the AOD and surface albedo differences can explain most of the flux differences between models and CERES EBAF. The EOS era satellites have provided 20 years of carefully calibrated and validated observations that are suitable for trend analysis. Both the MODIS AOD and CERES EBAF clear-sky SW flux show decreasing trends over the coastal regions of eastern China and the eastern United States due to the emission control policies enforced in both countries, and an increasing trend off the coast of India. The AOD and clear-sky SW flux trends are less consistent over land, as the surface albedo changes complicate the clear-sky SW flux trend. The AOD and clear-sky SW flux trends from the Oslo model HIST run are also examined. However, none of the aforementioned regional trends are found in the model results.

Wenying Su