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Building and Breaking Carbon Composites with REACTER

Carbon composites have become indispensable for aerospace and other high-performance applications, and a detailed picture of their morphology and failure mechanisms remains difficult to obtain through experiment. REACTER is a versatile computational modeling tool for atomistic molecular dynamics designed to model chemical reactions at the speed and length scales of classical force fields.1 In this work, several recent features of REACTER were applied to the creation and subsequent mechanical testing of two classes of carbon composites, carbon-fiber reinforced polymers (CFRP) and carbon nanotube (CNT) composites. Carbon fiber core morphologies were created by the method of Desai et al.,2 but using the advanced reaction constraints framework of REACTER, their proposed multistep procedure was reduced to a single uninterrupted molecular dynamics simulation. The carbon fiber filler was embedded into a polymer matrix by simulated in situ polymerization of several thermosetting resins, including bismaleimide and polyarylacetylene, to obtain the final CFRP model. To generate the second class of carbon composite, CNT networks were grown dynamically using the new ‘create atoms’ feature of REACTER, and similarly infiltrated with resin to obtain CNT composites. The resulting models were compared directly to experiment using simulated high resolution transmission electron microscopy and x-ray diffraction. Failure mechanisms were elucidated by simulating mechanically induced bond breaking, as characterized by third-order DFT-based tight-binding (DFTB3) simulations, via a reaction constraint on the total potential energy of the involved atoms.

Molecular Dynamics↗

NASA NTRS1991

High frequency scattering by a smooth coated cylinder simulated with generalized impedance boundary conditions

Rigorous uniform geometrical theory of diffraction (UGTD) diffraction coefficients are presented for a coated convex cylinder simulated with generalized impedance boundary conditions. In particular, ray solutions are obtained which remain valid in the transition region and reduce uniformly to those in the deep lit and shadow regions. These involve new transition functions in place of the usual Fock-type integrals, characteristic to the impedance cylinder. A uniform asymptotic solution is also presented for observations in the close vicinity of the cylinder. As usual, the diffraction coefficients for the convex cylinder are obtained via a generalization of the corresponding ones for the circular cylinder.

Syed, Hasnain H.↗

NASA NTRS2006

Effects of diffraction and static wavefront errors on high-contrast imaging from the Thirty Meter Telescope

High-contrast imaging, particularly direct detection of extrasolar planets, is a major science driver for the next generation of extremely large telescopes such as the segmented Thirty Meter Telescope. This goal requires more than merely diffraction-limited imaging, but also attention to residual scattered light from wavefront errors and diffraction effects at the contrast level of 10-8-10-9. Using a wave-optics simulation of adaptive optics and a diffraction suppression system we investigate diffraction from the segmentation geometry, intersegment gaps, obscuration by the secondary mirror and its supports. We find that the large obscurations pose a greater challenge than the much smaller segment gaps. In addition the impact of wavefront errors from the primary mirror, including segment alignment and figure errors, are analyzed. Segment-to-segment reflectivity variations and residual segment figure error will be the dominant error contributors from the primary mirror. Strategies to mitigate these errors are discussed.

segmented mirrors↗

NASA NTRS2019

Innovative Compact Coronagraph Approach for Balloon-Borne Investigation of Temperature and Speed of Electrons in the Corona (BITSE)

We are developing an innovative compact coronagraph for studying the physical conditions in the solar wind acceleration region. This paper presents the new development of the compact coronagraph for the investigation of temperature and speed of electrons in the solar corona. The proposed compact coronagraph is a one stage externally occulted coronagraph without internal occulter or Lyot stop mask. The key of the new idea is to set the inner field cutoff at the External Occulter (EO) much smaller than the specified inner field cutoff. A second occulter on the surface of the detector array removes the remaining diffraction. The occulter on the detector surface functions similar to an internal occulter with the Inner Field of View Cutoff (IFoVC) exactly the same as specified. For BITSE, the desired inner field cutoff is 3 R, but the cutoff at EO is only 1.5 R☉. The diffraction analysis shows that in the sensor plane, the diffraction intensity at the 3 R☉ is not sensitive to the EO cutoff, either at 1.5 R☉ or close to 3 R☉. The advantage of having a smaller EO cutoff is that the vignetting decreased for the Field of View (FoV) near 3 R☉, therefore, the signal increases. Meanwhile, the diffraction of Point Spread Function is much less in the radial direction, which not only increases the image quality around 3 R☉, but also increases the encircled energy and signal to noise ratio. In other words, the data is useful right at 3 R☉! The BITSE optical design and diffraction analysis will be presented in detail. The simulation shows the signal to noise ratio obtained from the diffraction and vignetting data enables corona temperature and speed measurement.

Gong, Qian↗

NASA NTRS2019

Innovative Compact Coronagraph Approach for Balloon-Borne Investigation of Temperature and Speed of Electrons in the Corona (BITSE)

Gong, Qian↗

NASA NTRS2015

Simulation and Measurement of Stray Light in the CLASP

We are planning an international rocket experiment Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP) is (2015 planned) that Lyman Alpha line polarization spectroscopic observations from the sun. The purpose of this experiment, detected with high accuracy of the linear polarization of the Ly􀉲 lines to 0.1% by using a Hanle effect is to measure the magnetic field of the chromosphere-transition layer directly. For total flux of the sun visible light overwhelmingly larger and about 200 000 times the Ly􀉲 line wavelength region, also hinder to 0.1% of the polarization photometric accuracy achieved in the stray light of slight visible light. Therefore we were first carried out using the illumination design analysis software called stray light simulation CLASP Light Tools. Feature of this simulation, using optical design file (ZEMAX format) and structural design file (STEP format), to reproduce realistic CLASP as possible to calculate machine is that it was stray study. And, at the stage in the actual equipment that made the provisional set of CLASP, actually put sunlight into CLASP using coelostat of National Astronomical Observatory of Japan, was subjected to measurement of stray light (San test). Pattern was not observed in the simulation is observed in the stray light measurement results need arise that measures. However, thanks to the stray light measurement and simulation was performed by adding, it was found this pattern is due to the diffracted light at the slit. Currently, the simulation results is where you have taken steps to reference. In this presentation, we report the stray light simulation and stray light measurement results that we have implemented

CLASP↗

NASA NTRS2010

SUB 1-Millimeter Size Fresnel Micro Spectrometer

An ultra-small micro spectrometer with less than 1mm diameter was constructed using Fresnel diffraction. The fabricated spectrometer has a diameter of 750 nmicrometers and a focal length of 2.4 mm at 533nm wavelength. The micro spectrometer was built with a simple negative zone plate that has an opaque center with an ecliptic shadow to remove the zero-order direct beam to the aperture slit. Unlike conventional approaches, the detailed optical calculation indicates that the ideal spectral resolution and resolving power do not depend on the miniaturized size but only on the total number of rings. We calculated 2D and 3D photon distribution around the aperture slit and confirmed that improved micro-spectrometers below 1mm size can be built with Fresnel diffraction. The comparison between mathematical simulation and measured data demonstrates the theoretical resolution, measured performance, misalignment effect, and improvement for the sub-1mm Fresnel micro-spectrometer. We suggest the utilization of an array of micro spectrometers for tunable multi-spectral imaging in the ultra violet range.

Park, Yeonjoon↗

NASA NTRS2012

Nanostructure Secondary-Mirror Apodizing Mask for Transmitter Signal Suppression in a Duplex Telescope

A document discusses a nanostructure apodizing mask, made of multi-walled carbon nanotubes, that is applied to the centers (or in and around the holes) of the secondary mirrors of telescopes that are used to interferometrically measure the strain of space-time in response to gravitational waves. The shape of this ultra-black mask can be adjusted to provide a smooth transition to the clear aperture of the secondary mirror to minimize diffracted light. Carbon nanotubes grown on silicon are a viable telescope mirror substrate, and can absorb significantly more light than other black treatments. The hemispherical reflectance of multi-walled carbon nanotubes grown at GSFC is approximately 3 to 10 times better than a standard aerospace paint used for stray light control. At the LISA (Laser Interferometer Space Antenna) wavelength of 1 micron, the advantage over paint is a factor of 10. Primarily, in the center of the secondary mirror (in the region of central obscuration, where no received light is lost) a black mask is applied to absorb transmitted light that could be reflected back into the receiver. In the LISA telescope, this is in the center couple of millimeters. The shape of this absorber is critical to suppress diffraction at the edge. By using the correct shape, the stray light can be reduced by approximately 10 to the 9 orders of magnitude versus no center mask. The effect of the nanotubes has been simulated in a stray-light model. The effect of the apodizing mask has been simulated in a near-field diffraction model. Specifications are geometry-dependent, but the baseline design for the LISA telescope has been modeled as well. The coatings are somewhat fragile, but work is continuing to enhance adhesion.

Hagopian, John↗

NASA NTRS1985

Microwave holography of large reflector antennas - Simulation algorithms

The performance of large reflector antennas can be improved by identifying the location and amount of their surface distortions and correcting them. To determine the accuracy of the constructed surface profiles, simulation studies are used to incorporate both the effects of systematic and random distortions, particularly the effects of the displaced surface panels. In this paper, different simulation models are investigated, emphasizing a model based on the vector diffraction analysis of a curved reflector with displaced panels. The simulated far-field patterns are then used to reconstruct the location and amount of displacement of the surface panels by employing a fast Fourier transform/iterative procedure. The sensitivity of the microwave holography technique based on the number of far-field sampled points, level of distortions, polarizations, illumination tapers, etc., is also examined.

Rahmat-Samii, Y.↗

NASA NTRS1974

Variable beamwidth monopulse feed for Tracking and Data Relay Satellite (TDRS)

The Tracking and Data Relay Satellite with a set of circularly-polarized, amplitude-sensing monopulse patterns suitable for acquiring and tracking user spacecraft at Ku-band (15.0 GHz) is discussed. The possibility of increasing the less than 0.4-degree half-power beamwidth of the data beam to almost 1.0 degree during the acquisition phase is predicated on the use of feeds situated in the first bright-ring of the Airy diffraction structure. A complex-vector simulation equivalent to the Kirchhoff-Kottler or Franz formulations is used to compute transmitted and received field information for a dual-reflector (Cassegrain) antenna configuration in a three-dimensional space.

Schmidt, R. F.↗

NASA NTRS1989

Near Zone: Basic scattering code user's manual with space station applications

The Electromagnetic Code - Basic Scattering Code, Version 3, is a user oriented computer code to analyze near and far zone patterns of antennas in the presence of scattering structures, to provide coupling between antennas in a complex environment, and to determine radiation hazard calculations at UHF and above. The analysis is based on uniform asymptotic techniques formulated in terms of the Uniform Geometrical Theory of Diffraction (UTD). Complicated structures can be simulated by arbitrarily oriented flat plates and an infinite ground plane that can be perfectly conducting or dielectric. Also, perfectly conducting finite elliptic cylinder, elliptic cone frustum sections, and finite composite ellipsoids can be used to model the superstructure of a ship, the body of a truck, and airplane, a satellite, etc. This manual gives special consideration to space station modeling applications. This is a user manual designed to give an overall view of the operation of the computer code, to instruct a user in how to model structures, and to show the validity of the code by comparing various computed results against measured and alternative calculations such as method of moments whenever available.

Marhefka, R. J.↗

NASA NTRS1992

Electromagnetic scattering by coated convex surfaces and wedges simulated by approximate boundary conditions

Asymptotic/high-frequency solutions are developed for analyzing the non-specular scattering mechanisms associated with coated convex surfaces and edges simulated by approximate boundary conditions. In particular, the standard impedance boundary conditions (SIBC's) and the second order generalized impedance boundary conditions (GIBC's) are employed for a characterization of the edge diffraction, creeping wave, and surface diffracted wave contributions. To study the creeping wave and surface diffracted wave mechanisms, rigorous UTD (uniform geometrical theory of diffraction) diffraction coefficients are developed for a convex coated cylinder simulated with SIBC's and GIBC's. The ray solutions obtained remain valid in the transition region and reduce uniformly to those in the deep lit and shadow regions. A uniform asymptotic solution is also presented for observations in the close vicinity of the cylinder. The diffraction coefficient for a convex cylinder are obtained via a generalization of the corresponding ones of the circular cylinder. To validate the asymptotic/high-frequency solution, integral equations are derived for both E and H-polarization and solved numerically using the method of moments. Results are presented for a single and three layered coated convex cylinder. Some insights are also provided on the accuracy of the employed GIBC's versus SIBC's for application to curved surfaces. To characterize the scattering by impedance wedges illuminated at skew incidence, diffraction coefficients are derived from an approximate solution of the governing functional difference equations. This solution exactly recovers the known ones for an impedance half plane or an arbitrary wedge at normal incidence, and to validate it for other wedge angles, a moment method code was used. Finally, to test the usefulness of the approximate skew incidence impedance wedge diffraction coefficient for three dimensional structures, equivalent currents are derived in the context of the physical theory of diffraction (PTD) for a finite length impedance wedge of arbitrary internal angles. These are incorporated in a standard general purpose PTD code and results are presented for a number of different impedance structures.

Syed, H. H.↗

NASA NTRS1997

Chemical and Thermal Analysis

Work during the past three years has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-Ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted changes in the molecular weight distribution and the increased crosslinking of the Coflon material using Gel Permeation Chromatographic Analysis. Again these changes may result in variations in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, and Differential Scanning Calorimetry. We investigated a plethora of aged samples of both Tefzel and Coflon that were forwarded from MERL. Pressurized tests were performed on powdered PVDF in a modified Fluid A, which we will call A-2. In this case the ethylene diamine concentration was increased to 3 percent in methanol. Coflon pipe sections and powdered Coflon were exposed in pressure cells at 1700 psi at three separate test temperatures.

Bulluck, J. W.↗

NASA NTRS1996

Chemical and Thermal Analysis

Work has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-Ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted changes in the molecular weight distribution of the Coflon material using a dual detector Gel Permeation Analysis. Again these changes may result in variation in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-Ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, Thermogravimetric Analysis, and Differential Scanning Calorimetry. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. Pressurized tests were performed in a modified Fluid G, which we will call G2. In this case the ethylene diamine concentration was increased to 3 percent in methanol. Coflon pipe sections and powdered Coflon were exposed in pressure cells at 1700 psi at three separate test temperatures, 70 C, 110 C, and 130 C. The primary purpose of the pressure tests in Fluid G2 was to further elucidate the aging mechanism of PVDF degradation.

Bulluck, J. W.↗

NASA NTRS1996

International Research Project on the Effects of Chemical Ageing of Polymers on Performance Properties: Chemical and Thermal Analysis

Work during the past six months has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted small changes in the molecular weight distribution. Again these changes may result in variations in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, Ultra- Violet Scanning Analysis, GC/Mass Spectrometry, Differential Scanning Calorimetry and Thermomechanical Analysis. In the ultra-violet analysis we noted the presence of an absorption band indicative of triene formation. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. We also cast films at SWT and subjected these films to a refluxing methanol 1% ethylene diamine solution. An updated literature search was conducted using Dialog and DROLLS to identify any new papers that may have been published in the open literature since the start of this project. The updated literature search and abstracts are contained in the Appendix section of this report.

Bulluck, J. W.↗

NASA NTRS1994

Numerical Simulations of Self-Focused Pulses Using the Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that are currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Kerr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations. Abstract of a proposed paper for presentation at the meeting NONLINEAR OPTICS: Materials, Fundamentals, and Applications, Hyatt Regency Waikaloa, Waikaloa, Hawaii, July 24-29, 1994, Cosponsored by IEEE/Lasers and Electro-Optics Society and Optical Society of America

Goorjian, Peter M.↗

NASA NTRS1994

Numerical Simulations of Light Bullets, Using the Full Vector, Time Dependent, Nonlinear Maxwell Equations

Goorjian, Peter M.↗

NASA NTRS1995

Numerical Simulations of Light Bullets, Using The Full Vector, Time Dependent, Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that we currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Karr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations.

Goorjian, Peter M.↗