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NASA NTRS2017

Characterization of Volatiles Loss from Soil Samples at Lunar Environments

Resource Prospector Integrated Thermal Vacuum Test Program A series of ground based dirty thermal vacuum tests are being conducted to better understand the subsurface sampling operations for RP Volatiles loss during sampling operations Hardware performance Sample removal and transfer Concept of operationsInstrumentation5 test campaigns over 5 years have been conducted with RP hardware with advancing hardware designs and additional RP subsystems Volatiles sampling 4 years Using flight-forward regolith sampling hardware, empirically determine volatile retention at lunar-relevant conditions Use data to improve theoretical predictions Determine driving variables for retention Bound water loss potential to define measurement uncertainties. The main goal of this talk is to introduce you to our approach to characterizing volatiles loss for RP. Introduce the facility and its capabilities Overview of the RP hardware used in integrated testing (most recent iteration) Summarize the test variables used thus farReview a sample of the results.

In Situ Resource Utilization↗
NASA NTRSDate not supplied

VIPER Mission Traverse Planning – Design, Strategies, and Dynamics

The Volatiles Investigation Polar Exploration Rover (VIPER) is a lunar polar volatiles prospecting mission developed through NASA’s Science Mission Directorate (SMD) Planetary Science Di-vision[1].VIPER is scheduled to land on Mons Mouton near the lunar South Pole in late 2024. VIPER’s primary mission goal is to characterize the distribution of water and volatiles across a range of thermal environments. This characterization aims to assist in understanding the origin of lunar polar volatiles and also help evaluate the In-Situ Resource Utilization (ISRU) potential of the lunar poles. The VIPER rover is a four-wheeled robotic vehicle weighing ~450 kg. It is solar-powered and teleoperated from Earth over a line-of-sight radio link. The rover can move at up to 20 cm/s on flat terrain. Accounting for commanding, localization, navigation, and obstacle-avoidance delays, however, the effective speed is closer to 1 cm/s. This effective speed is known as “Speed Made Good” (SMG), adopted from maritime culture, and kept as a key performance metric for VIPER oper-ations planning, execution, and evaluation. The mission duration is anticipated to be more than 90 Earth days and involves up to 20 km of driving. VIPER’s prospecting payload consists of spectrometers to detect volatiles and assess concentrations, context imagers, and a drill for sub-surface measurements down to one meter depth [2]. Mobility, combined with the prospecting and drill instrument suite, makes VIPER an analytically powerful resource mapper.

Volatiles Investigation Polar Exploration Rover (V↗
NASA NTRS1979

74001 drive tube - Siderophile elements match II B iron meteorite pattern

Eight siderophile elements, seven volatile elements, and U were determined in three samples from 74001 by radiochemical neutron activation analysis. The siderophile pattern closely corresponds to the addition of approximately 0.1% of II B iron meteorites, and the enrichment of nonsiderophile volatile elements seems to be derived from lunar sources with variation generally following Se content. In addition, in 74001 (predominantly black glass), moderately volatile elements (Ag, Zn) are more abundant than In, Cd, and particularly Bi, while in 74220 (mainly orange glass), Ag, Zn, In, and Cd are almost equally abundant, but Bi is as low as in 74001.

Morgan, J. W.↗
NASA NTRS1976

Lunar Science Conference, 7th, Houston, Tex., March 15-19, 1976, Proceedings. Volume 1 - Regolith studies. Volume 2 - Petrogenetic studies of mare and highland rocks. Volume 3 - The moon and other bodies

Attention is given to lunar core studies (multi-core, deep drill, and drive tube), surface soil studies (petrography and geochemistry, light and volatile element studies, and agglutinate related studies), and surfaces process studies. Also considered are mare basalts, with emphasis on mineralogy and petrology, chemical and isotopic studies, and constraints and models of basalt evolution, along with breccia and highland samples with attention given to geochronology, boulders and consortium studies and the formation of highland samples. Remote sensing and photogeology of the moon, crustal bombardment, physical properties of the moon, and comparative planetology are also discussed.

Merrill, R. B.↗
NASA NTRS2015

Evolution of H2O, CO, and CO2 Production in Comet C/2009 P1 Garradd During the 2011-2012 Apparition

We present analysis of high spectral resolution NIR spectra of CO and H2O in Comet C/2009 P1 (Garradd) taken during its 2011-2012 apparition with the CSHELL instrument on NASA's Infrared Telescope Facility (IRTF). We also present analysis of observations of atomic oxygen in Comet Garradd obtained with the ARCES echelle spectrometer mounted on the ARC 3.5-m telescope at Apache Point Observatory and the Tull Coude spectrograph on the Harlan J. Smith 2.7-m telescope at McDonald Observatory. The observations of atomic oxygen serve as a proxy for H2O and CO2. We confirm the high CO abundance in Comet Garradd and the asymmetry in the CO/H2O ratio with respect to perihelion reported by previous studies. From the oxygen observations, we infer that the CO2/H2O ratio decreased as the comet moved towards the Sun, which is expected based on current sublimation models. We also infer that the CO2/H2O ratio was higher pre-perihelion than post-perihelion. We observe evidence for the icy grain source of H2O reported by several studies pre-perihelion, and argue that this source is significantly less abundant post-perihelion. Since H2O, CO2, and CO are the primary ices in comets, they drive the activity. We use our measurements of these important volatiles in an attempt to explain the evolution of Garradd's activity over the apparition.

Comets↗
NASA NTRSDate not supplied

Investigating Pyroclastic Volcanism in the Taurus-Littrow Valley (TLV) Using the Station 3 Double Drive Tube 73001-73002

Well over 100 pyroclastic deposits have been identified on the Moon. Eruptive processes such as represented by these deposits transported endogenous volatiles from the Moon’s mantle to its surface. Debris from pyroclastic deposits has been identified in all Apollo and Luna samples. The high-Ti pyroclastic de- posit sampled at Shorty Crater by the Station 4 double drive tube (74001-74002) is our best sampling of these types of deposits. Samples 78500 and 78526, NAC images of fissures in the Sculptured Hills, ash identified in 70001-7, and other green volcanic glass indicate that very low-Ti basalt (VLT) erup- tions also occurred in TLV. The double drive tube core being investigated by the ANGSA initiative provides an- other view of TLV pyroclastic eruptions. The regolith in 73001-73002 and the regolith breccias therein have nu- merous pyroclastic beads. Some individual regolith brec- cia fragments have abundant pyroclastic beads (>50 in a polished surface). In this work, we address the following questions. Do these glass beads overlap in composition with those sampled elsewhere in the TLV or do they rec- ord another episode of pyroclastic eruption? Are the magmas associated with pyroclastic eruptions petroge- netically related to the crystalline mare basalts in the TLV? Finally, is the volatile record of the pyroclastic eruptions better preserved in the newly opened and spe- cially contained Station 3 double drive tube core?

C.K. Shearer↗
NASA NTRS2017

Inconsistent Regolith Thermal Control of Hydrogen Distributions at the Moons South Pole

Introduction: For over fifty years, intense interest has focused on determining if, where, and how much hydrogen (H) may be found near the Moons poles [1]. Driving the ongoing interest has been the critical role that H volatiles must play as a resource for human missions [2]. Now, with several lines of evidence consistently indicating that H concentrations are enhanced in some permanently shadowed regions (PSRs), plus the possibility of diurnally-dependent volatile H concentrations [3-8], investigations are shifting towards understanding the sources of H and factors that govern concentrations. For the last seven-plus years, the Lunar Reconnaissance Orbiter (LRO) has collected an unparalleled temporal and spatial record of geophysical factors that may govern the Moons H distribution [9]. XXXX

Moon↗
NASA NTRS2017

Application of the Core Flight System to a Lunar Rover

Resource Prospector (RP) is a lunar mission sponsored by NASAs Advanced Exploration Systems (AES) division, that aims to study in-situ resource utilization (ISRU) feasibility and technologies on the surface of the moon. The RP missions lunar surface segment includes a rover equipped with with a suite of instruments specifically designed to measure and map volatiles both at the surface and in the subsurface. Of particular interest is the quantity and state of volatiles in permanently shadowed regions. To conduct the mission, ground system operators will remotely drive the rover, directing it to waypoints along the surface in order to achieve measurement objectives. At selected locations, an onboard drill will be deployed to collect material and obtain direct measurements of the subsurface constituents. RP is currently planned for launch in 2022. RP is managed at NASA Ames Research Center. The RP Rover is being designed and developed by NASA Johnson Space Center (JSC) in partnership with NASA Ames. NASA Kennedy Space Center (KSC) is responsible for the Honeybee drilling system and science payload.In order to better understand the technical challenges and demonstrate capability, in 2015 the RP project developed a rover testbed (known as RP15). In this mission in a year, a rover was designed, developed, and outfitted with science instruments and a drill. The rover was operated from a remote operations center, and operated in an outdoor lunar rock yard at Johnson space center. The study was a resounding success meeting all objectives. The RP Rover software architecture and development processes were based on the successful Lunar Atmosphere and Dust Environment Explorer spacecraft. This architecture is built on the Core Flight System software and an interface to MatlabSimulink auto-generated software components known as the Simulink Interface Layer (SIL). The application of this lunar satellite inspired framework worked well for the rover application, and is currently being planned for the mission. This presentation provides an overview of the architecture and processes, and describes some of the changes and challenges for the rover application.

CFS↗
NASA NTRS2017

Application of CFS to a Lunar Rover: Resource Prospector (RP)

Resource Prospector (RP) is a lunar mission sponsored by NASA's Advanced Exploration Systems (AES) division, that aims to study in-situ resource utilization (ISRU) feasibility and technologies on the surface of the moon. The RP mission's lunar surface segment includes a rover equipped with with a suite of instruments specifically designed to measure and map volatiles both at the surface and in the subsurface. Of particular interest is the quantity and state of volatiles in permanently shadowed regions. To conduct the mission, ground system operators will remotely drive the rover, directing it to waypoints along the surface in order to achieve measurement objectives. At selected locations, an onboard drill will be deployed to collect material and obtain direct measurements of the subsurface constituents. RP is currently planned for launch in 2022. RP is managed at NASA Ames Research Center. The RP Rover is being designed and developed by NASA Johnson Space Center (JSC) in partnership with NASA Ames. NASA Kennedy Space Center (KSC) is responsible for the Honeybee drilling system and science payload. In order to better understand the technical challenges and demonstrate capability, in 2015 the RP project developed a rover testbed (known as RP15). In this mission in a year, a rover was designed, developed, and outfitted with science instruments and a drill. The rover was operated from a remote operations center, and operated in an outdoor lunar rock yard at Johnson space center. The study was a resounding success meeting all objectives. The RP Rover software architecture and development processes were based on the successful Lunar Atmosphere and Dust Environment Explorer spacecraft. This architecture is built on the Core Flight System software and an interface to Matlab/Simulink auto-generated software components known as the Simulink Interface Layer (SIL). The application of this lunar satellite inspired framework worked well for the rover application, and is currently being planned for the mission. This presentation provides an overview of the architecture and processes, and describes some of the changes and challenges for the rover application.

RP↗
NASA NTRS2024

Variations in Apatite F, Cl, and OH Abundances in Primitive Achondrites: Evidence of Fractional Melting?

The apatite group minerals [Ca 5 (PO 4 ) 3 (F,Cl,OH)] are some of the primary mineralogical reservoirs for phosphorus on Earth and a common phosphate mineral within a broad range of extraterrestrial samples. Naturally occurring apatite hosts F, Cl, and OH as essential structural constituents, and all three make up the apatite endmembers fluorapatite, chlorapatite, and hydroxylapatite, respectively. Although apatite is one of the most common phosphate minerals in meteorites and rocks from Earth, it typically occurs at minor to trace abundances. Apatite has been widely used as a mineralogical tool to probe the interiors of both differentiated and undifferentiated parent bodies for information about volatiles; however, little work has been done on apatite F, Cl, and OH abundances of apatite from primitive achondrite meteorites. There are broad differences between apatite X -site chemistry in chondrite parent bodies (typically F-poor) compared to apatite from basaltic rocks from many achondrite parent bodies (Cl-poor, apart from Mars). These differences could indicate that planetary differentiation processes, namely melting, play an important role in the evolution of apatite X -site chemistry. In fact, some ordinary chondrite meteorites that exhibit evidence of minor impact melting have apatite with X -site compositions that are much more F-rich than typical chondrite apatite. McCubbin et al., hypothesized that the F-rich compositions of the apatite in ordinary chondrites affected by impact melting could be the result of apatite partially melting, driving the residual apatite to more F-rich compositions; however, they also indicated that degassing of the more volatile Cl and H may also contribute to the F-enrichment. To further test the partial melting hypothesis, we investigate the F, Cl, and OH (by difference) abundances of apatite from primitive achondrite parent bodies given that they are thought to come from partially differentiated parent bodies that represent residues after partial melting. Consequently, their apatites could provide valuable insights into the effects of melting on apatite X -site chemistry. In this study, we report F and Cl abundances of apatite from a broad array of primitive achondrite meteorites, and we develop a model for apatite fractional melting using known apatite-melt partitioning relationships. Together, we use these results to further elucidate the role of melting on apatite X -site compositions.

F M McCubbin↗
NASA NTRSDate not supplied

Large Scale Volcanism: An Explanation for the Heat-death of Venus-like Worlds

Large scale volcanism has played a critical role in the long-term habitability of Earth and possibly Venus. Large Igneous Provinces (LIPs) are in fact the cause of most major extinction events in Earth’s history, contrary to the popular belief about the devastation from large bolides. We examine the timing of Large Igneous Provinces (LIPs) through Earth’s history [1] to estimate the likelihood of nearly simultaneous events that could drive a planet into an extreme moist or runaway greenhouse, quenching subductive plate tectonics. Such events would end volatile cycling and may have driven Venus from a cool temperate state into the heat-death we see today. Using the Earth's LIP record [1] we have found that LIP events are distributed randomly throughout the past 3 billion years. A conservative estimate of the rate of LIPs in a random history statistically the same as Earth’s, pairs and triplets of LIPs closer in time than 0.1-1 million years are likely. This simultaneity threshold is significant to the extent that it is less than the time over which environmental effects have been shown to persist, for example in the Siberian Traps record [2,3]. With the recent mission selections of VERITAS and EnVision it may be possible for their high resolution radar maps to distinguish LIPs in the surface record we can see today on Venus.

Large Igneous Provinces↗
NASA NTRS1992

High-temperature mass spectrometric degassing of enstatite chondrites - Implications for pyroclastic volcanism on the aubrite parent body

The volatile contents of a number of enstatite chondrite falls of different chemical groups (EH; EL) and petrologic types (EH3-5; EL6) were investigated in order to find evidence of explosive pyroclastic volcanism, supporting the mechanism proposed by Wilson and Keil (1991) to explain the lack of aubritic basalts in aubrites. It is shown that abundant volatiles are likely to have been released upon partial melting of enstatite chondritelike precursor materials of aubrites, enough to drive pyroclastic volcanic eruptions which would explain the lack of aubritic basalts.

Muenow, David W.↗
NASA NTRS1997

Observational Search for Cometary Aging Processes

The scientific objectives of this study were (i) to search for physical differences in the behavior of the dynamically new comets (those which are entering the solar system for the first time from the Oort cloud) and the periodic comets, and (ii) to interpret these differences, if any, in terms of the physical and chemical nature of the comets and the evolutionary histories of the two comet groups. Because outer solar system comets may be direct remnants of the planetary formation processes, it is clear that the understanding of both the physical characteristics of these bodies at the edge of the planet forming zone and of their activity at large heliocentric distances, r, will ultimately provide constraints on the planetary formation process both in our Solar System and in extra-solar planetary systems. A combination of new solar system models which suggest that the protoplanetary disk was relatively massive and as a consequence comets could form at large distances from the sun (e.g. from the Uranus-Neptune region to the vicinity of the Kuiper belt), observations of activity in comets at large r, and laboratory experiments on low temperature volatile condensation, are dramatically changing our understanding of the chemical'and physical conditions in the early solar nebula. In order to understand the physical processes driving the apparent large r activity, and to address the question of possible physical and chemical differences between periodic, non-periodic and Oort comets, the PI has been undertaking a long-term study of the behavior of a significant sample of these comets (approximately 50) over a wide range of r to watch the development, disappearance and changing morphology of the dust coma. The ultimate goal is to search for systematic physical differences between the comet classes by modelling the coma growth in terms of volatile-driven activity. The systematic observations for this have been ongoing since 1986, and have been obtained over the course of approximately 300 nights using the telescopes on Mauna Kea, Kitt Peak, Cerro Tololo, the European Southern Observatory, and several other large aperture facilities. A greater than 2 TB database of broad band comet images has been obtained which follows the systematic development and fading of the cometary coma for the comets in the database. The results to date, indicate that there is a substantial difference in the brightness and the amount of dust as a function of r between the two comet classes. In addition to this major finding, the program has been responsible for several exciting discoveries, including: the P/Halley outburst at r = 14.3 AU, the discovery of Chiron's coma and modelling and observations of the gravitationally bound component, observational evidence that activity continues out beyond r = 17 AU for many dynamically new comets

Meech, Karen J.↗
NASA NTRS1981

Volcanic eruptions on Io

Nine eruption plumes which were observed during the Voyager 1 encounter with Io are discussed. During the Voyager 2 encounter, four months later, eight of the eruptions were still active although the largest became inactive sometime between the two encounters. Plumes range in height from 60 to over 300 km with corresponding ejection velocities of 0.5 to 1.0 km/s and plume sources are located on several plains and consist of fissures or calderas. The shape and brightness distribution together with the pattern of the surface deposition on a plume 3 is simulated by a ballistic model with a constant ejection velocity of 0.5 km/s and ejection angles which vary from 0-55 deg. The distribution of active and recent eruptions is concentrated in the equatorial regions and indicates that volcanic activity is more frequent and intense in the equatorial regions than in the polar regions. Due to the geologic setting of certain plume sources and large reservoirs of volatiles required for the active eruptions, it is concluded that sulfur volcanism rather than silicate volcanism is the most likely driving mechanism for the eruption plumes.

Strom, R. G.↗
NASA NTRS2010

Radiation-Hardened Solid-State Drive

A method is provided for a radiationhardened (rad-hard) solid-state drive for space mission memory applications by combining rad-hard and commercial off-the-shelf (COTS) non-volatile memories (NVMs) into a hybrid architecture. The architecture is controlled by a rad-hard ASIC (application specific integrated circuit) or a FPGA (field programmable gate array). Specific error handling and data management protocols are developed for use in a rad-hard environment. The rad-hard memories are smaller in overall memory density, but are used to control and manage radiation-induced errors in the main, and much larger density, non-rad-hard COTS memory devices. Small amounts of rad-hard memory are used as error buffers and temporary caches for radiation-induced errors in the large COTS memories. The rad-hard ASIC/FPGA implements a variety of error-handling protocols to manage these radiation-induced errors. The large COTS memory is triplicated for protection, and CRC-based counters are calculated for sub-areas in each COTS NVM array. These counters are stored in the rad-hard non-volatile memory. Through monitoring, rewriting, regeneration, triplication, and long-term storage, radiation-induced errors in the large NV memory are managed. The rad-hard ASIC/FPGA also interfaces with the external computer buses.

Sheldon, Douglas J.↗
NASA NTRSDate not supplied

Bessel Tube to Capture Lunar Volatiles

Current arts to create linear motion or acceleration of fine particles and molecules into devices such as mass spectrometers and vacuum pumps rely on the pressure difference created by a pinhole or mechanical processes. However, in an environment of vacuum, these approaches do not create such a pressure differential to drive and move fine particles and molecules. In some cases, electrostatic or magnetic processes may work to create the desired motion. A cylindrical harmonic of electric field, which is widely used in electron accelerators, offers a unique capability to capture and induce a linear motion of molecules and particles when electrically charged. Generally, lunar volatiles are electrostatically charged. The idea to capture and collect the lunar volatiles by creating a drift axis of motion using a cylindrical harmonic field has led to the development of a device concept, called a Bessel Tube. The Bessel Tube concept ingests fine particles, gaseous atoms, and gaseous molecules and guides them along an extraction tube for collection, separation, and analysis. The Bessel Tube concept for lunar volatile collection is discussed.

Bessel Tube↗
NASA NTRS2002

The Laboratory Production of Complex Organic Molecules in Simulated Interstellar Ices

Much of the volatiles in interstellar dense clouds exist in ices surrounding dust grains. Their low temperatures preclude most chemical reactions, but ionizing radiation can drive reactions that produce a suite of new species, many of which are complex organics. The Astrochemistry Lab at NASA-Ames studies the UV radiation processing of interstellar ice analogs to better identify the resulting products and establish links between interstellar chemistry, the organics in meteorites, and the origin of life on Earth. Once identified, the spectral properties of the products can be quantified to assist with the search for these species in space. Of particular interest are findings that UV irradiation of interstellar ice analogs produces molecules of importance in current living organisms, including quiriones, amphiphiles, and amino acids. Quinones play a variety of roles including electron transport and are used by all organisms. Studies show that quinones should be made wherever polycyclic aromatic hydrocarbons are irradiated in interstellar ices (Bernstein et al. 2001). Amphiphiles are also made when mixed molecular ices are irradiated. These amphiphiles self-assemble into membrane-walled vesicles when put in liquid water (Dworkin et al. 2001). Ice irradiation can also produce (Bernstein et al. 2002) and destroy amino acids (Ehrenfreund et al. 2001). Many of the same processes thought to make organics in space should yield products highly enriched in deuterium (D) (Sandford et al. 2001). The high D/H ratios in some interstellar species, and the knowledge that many of the organics in primitive meteorites are D-enriched, suggests that such linkages do exist. By using D as a tracer, we expect to learn more about the different chemical processes occurring in space and their relative importance in the production of different organic compounds and delivery to planetary surfaces.

Dworkin, Jason P.↗