Single-electron capture by multiply-charged carbon ions at energies below 40 keV
Single-electron capture by carbon ions from helium, neon, and argon at energies below 40 keV
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Single-electron capture by carbon ions from helium, neon, and argon at energies below 40 keV
Much of the uncertainty in predicting variations in greenhouse gases originates in the complex dynamics of the land ecosystem and the atmosphere. To reduce the uncertainties, it is useful to decouple the contributions of land carbon fluxes and atmospheric transport to atmospheric carbon variability. Here we isolate these contributions using a version of the NASA GEOS model that couples carbon, energy and water cycles between the land and the atmosphere. Our current study is a follow-on to a preliminary analysis that suggested that an extreme event (e.g., imposed drought) in a free running AGCM simulation affects atmospheric CO2 more through its impact on atmospheric transport than through a modification of land carbon fluxes. In order to more carefully isolate the effects of the land carbon variability and atmospheric transport variability on atmospheric CO2 variability, we conducted two coupled-AGCM simulations in replay mode, a mode that forces the model's evolution of weather to match that of the MERRA-2 reanalysis. In the control simulation, the land carbon fluxes and the atmospheric CO2 concentrations, as well as the meteorology, are simulated over 2001-2015. We compute the climatological seasonal cycles of net land carbon production from this control simulation and then prescribe, in a second simulation, these climatological carbon fluxes to the atmosphere in the same replay mode. By comparing the atmospheric CO2 variability produced in the two simulations, we fully isolate the part of this variability associated with land surface fluxes. Relative contributions of land flux variability and atmospheric transport variability to CO2 variability are quantified both on a regional basis and as a function of height into the atmosphere to support interpretation of both ground-based and satellite observations.
Recent satellite-based studies have revealed that the northern sub-Saharan African (NSSA) region has one of the highest biomass-burning rates per unit land area among all regions of the world. Because of the high concentration and frequency of fires in this region, with the associated abundance of heat release and gaseous and particulate smoke emissions, biomass-burning activity is believed to be a major driver of the regional carbon, energy, and water cycles. We acknowledge that the rainy season in the NSSA region is from April to September while biomass burning occurs mainly during the dry season (October to March). Nevertheless, these two phenomena are indirectly coupled to each other through a chain of complex processes and conditions, including land-cover and surface-albedo changes, the carbon cycle, evapotranspiration, drought, desertification, surface water runoff, ground water recharge, and variability in atmospheric composition, heating rates, and circulation. In this presentation, we will examine the theoretical linkages between these processes, discuss the preliminary results based on satellite data analysis, and provide an overview of plans for more integrated research to be conducted over the next few years.
The northern sub-Saharan African (NSSA) region, extending from the southern fringes of the Sahara to the Equator, and stretching west to east from the Atlantic to the Indian ocean coasts, plays a prominent role in the distribution of Saharan dust and other airborne matter around the region and to other parts of the world, the genesis of global atmospheric circulation, and the birth of such major (and often catastrophic) events as hurricanes. Therefore, this NSSA region represents a critical variable in the global climate change equation. Recent satellite-based studies have revealed that the NSSA region has one of the highest biomass-burning rates per unit land area among all regions of the world. Because of the high concentration and frequency of fires in this region, with the associated abundance of heat release and gaseous and particulate smoke emissions, biomass-burning activity is believed to be a major driver of the regional carbon, energy, and water cycles. We acknowledge that the rainy season in the NSSA region is from April to September while biomass burning occurs mainly during the dry season (October to March). Nevertheless, these two phenomena are indirectly coupled to each other through a chain of complex processes and conditions, including land-cover and surface-albedo changes, the carbon cycle, evapotranspiration, drought, desertification, surface water runoff, ground water recharge, and variability in atmospheric composition, heating rates, and circulation. In this presentation, we will examine the theoretical linkages between these processes, discuss the preliminary results based on satellite data analysis, and provide an overview of plans for more integrated research to be conducted over the next few years.
Threshold energy and sunlight photodetachment measurements on negative carbon dioxide ions, using a 2.5 kw light pressure xenon lamp, show that: (1) Electron affinity of CO3(+) is larger than 2.7 e.V. and that an isomeric form of CO3(+) is likely an error; (2) The photodetachment cross section of CO3(-) will roughly be like a step function across the range of 4250 to 2500A, having its threshold energy at 4250A; (3) Sunlight photodetachment rate for CO3(-) is probably much smaller than elsewhere reported; and (4) The probability of having photodetached electrons re-attach to form negative ions is less than 1%. Mass identifying drift tube tests confirm that the slower ion is CO3(-), formed through the O(-) + 2CO2 yields CO3(-) + CO2 reaction.
The Earth Observing System (EOS), the centerpiece of NASA's Earth science program, is a suite of spacecraft and interdisciplinary science investigations dedicated to advancing our understanding of global change. The flagship EOS satellite, Terra (formerly EOS AM-1), scheduled for launch in July 1999, will provide key measurements of the physical and radiative properties of clouds; air-land and air-sea exchanges of energy, carbon, and water; trace gases; and volcanoes. Flying in formation with Terra, Landsat 7 will make global high spatial resolution measurements of land surface and surrounding coastal regions. Other upcoming EOS missions and instruments include QuikSCAT, to collect sea surface wind data; the Stratospheric Gas and Aerosol Experiment (SAGE III), to create global profiles of key atmospheric gases; and the Active Cavity Radiometer Irradiance Monitors (ACRIM) to measure the energy output of the Sun. The second of the major, multi-instrument EOS platforms, PM-1, is scheduled for launch in 2000. Interdisciplinary research projects sponsored by EOS use specific Earth science data sets for a broader investigation into the function of Earth systems. Current EOS research spans a wide range of sciences, including atmospheric chemistry, hydrology, land use, and marine ecosystems. The EOS program has been managed since 1990 by the Goddard Space Flight Center in Greenbelt, Md., for NASA's Office of Earth Science in Washington, D. C. Additional information on the program can be found on the EOS Project Science Office Web site (http://eospso.gsfc.nasa.gov).
The land surface is a critical part of the earth system as processes related to water, carbon, energy and nitrogen cycling have important implications for climate forcing, air quality, water availability and seasonal atmospheric forecasting. Despite advances in land surface modeling, land surface model performance is often limited because of errors related to initial and boundary conditions, model structure, and parameters. Data assimilation (DA) techniques combined with an expanding network of earth system observations present an opportunity to reduce these errors and improve simulations. Here, we emphasize the implementation of tools and approaches to overcome challenges related to land DA to constrain carbon and water cycling. In particular, we discuss the implementation of adaptive inflation to modify ensemble spread in response to time-varying networks of gridded observations. We also discuss methods to generate ensemble spread through boundary condition (meteorology) forcing that can be applied to site-level applications. Next, we describe the application of vertical localization upon surface soil moisture observations, and forward operators specifically designed for the assimilation of snow and solar-induced fluorescence observations. Finally, we discuss the potential benefit of a quantile conserving filter used to update bounded quantities (state or parameter values).
The land surface is a critical part of the earth system as processes related to water, carbon, energy and nitrogen cycling have important implications for climate forcing, air quality, water availability and seasonal atmospheric forecasting. Despite advances in land surface modeling, land surface model performance is often limited because of errors related to initial and boundary conditions, model structure, and parameters. Data assimilation (DA) techniques combined with an expanding network of earth system observations present an opportunity to reduce these errors and improve simulations. Here we apply an Ensemble Kalman Filter DA system as part of the Data Assimilation Research Testbed to a variety of land surface simulations. First, we describe the use of remotely sensed biomass observations to provide improved simulations of plant phenology, carbon and water cycling for regions highly sensitive to climate change (Western US, China, and Arctic). We discuss approaches to account for systemic biases between models and observations, including the use of spatially-varying adaptive ensemble inflation as an alternative approach to re-scaling soil moisture observations. Finally, we discuss a strategy to incorporate complementary observations (snow water equivalent, solar-induced fluorescence) to better constrain the representation of carbon and water cycling across complex terrain.
Recent advances in the ability to predict climate anomalies at sub-seasonal to seasonal (S2S) timescales allow us to explore the possibility of forecasting carbon flux anomalies. Although carbon flux forecasting is a relatively new concept, it is potentially beneficial as it can help us better understand global and regional land-atmosphere carbon feedbacks associated with climate variations and can provide guidance for future field mission design. Here we evaluate the skill of forecasted terrestrial carbon anomalies generated from meteorological anomalies produced with the NASA Global Modeling and Assimilation Office (GMAO) S2S forecast system. We focus here on three representative time periods (the most recent 2015-2016 El Nino, 2011 La Nina, and 2014 as a neutral year), with each corresponding 9-month forecast comprising four ensemble members initialized in the preceding December. The meteorological variables produced by the GMAO forecast system were bias-corrected using a climatology derived from the Modern Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) before being used to drive a suite of offline simulations with the NASA Catchment-CN terrestrial biosphere model, a model that computes water-energy-carbon dynamics. Forecasts are evaluated by comparing against satellite-driven estimates of gross primary production (GPP) and inverse model estimates of net carbon flux that incorporate satellite carbon dioxide measurements. We find that the restrospectively predicted carbon fluxes in the tropics reasonably reproduce the signs and magnitudes of the observed anomalies between the 2015-2016 El Nino and the 2011 La Nina for both net flux and GPP. For instance, for the El Nino period, the magnitude of the forecasted negative GPP anomaly in the South American tropics (which undergoes anomalously warm and dry conditions) agrees with the observed GPP anomaly at leads of up to three or four months. Overall, this study demonstrates potential skill in the forecast of biospheric carbon fluxes a few months in advance, a capability that could contribute to attribution studies focusing on carbon flux variations and support innovative observation strategies in the future.
In terms of the space cities occupy, urbanization appears as a minor land transformation. However, it permanently modifies land's ecological functions, altering its carbon, energy, and water fluxes. It is therefore necessary to develop a land cover characterization at fine spatial and temporal scales to capture urbanization's effects on surface fluxes. We develop a series of biophysical vegetation parameters such as the fraction of photosynthetically active radiation, leaf area index, vegetation greenness fraction, and roughness length over the continental US using MODIS and Landsat products for 2001. A 13-class land cover map was developed at a climate modeling grid (CMG) merging the 500mMODIS land cover and the 30m impervious surface area from the National Land Cover Database. The landscape subgrid heterogeneity was preserved using fractions of each class from the 500 m and 30 m into the CMG. Biophysical parameters were computed using the 8-day composite Normalized Difference Vegetation Index produced by the North American Carbon Program. In addition to urban impact assessments, this dataset is useful for the computation of surface fluxes in land, vegetation, and urban models and is expected to be widely used in different land cover and land use change applications.
The surface water and energy balances can be coupled or uncoupled depending on whether the evaporation regime is water-limited or energy-limited. As the landscape loses soil moisture during drydowns, a transition between the regimes may occur, which signifies a nonlinear change in water-energy-carbon coupling. Regions that switch often between these two regimes, that is, are dominated by neither regime, are particularly vulnerable to climate variability and change. To robustly identify these tipping points, we identify drydown events based on global soil moisture data sets from remote sensing. The event identification does not rely on precipitation information and is robust with respect to measurement noise. Then, the soil moisture thresholds delineating the evaporation regime transitions are determined by Sequential Monte Carlo Sampling and a two-stage parametrization strategy. Based on the estimated soil moisture thresholds across the globe, we estimate observation-based water availability indices which quantify the nonlinear controls of soil moisture on evaporation. This framework is tested and applied globally using Soil Moisture Active Passive soil moisture retrievals. Combined with a new tippling-point metric that describes the frequency of evaporation regime transitions, we identify regions that switch often between different evaporation regimes at the global scale. Given unit shifts in soil moisture, these regions will experience the most change in how their surface water and energy are coupled.
Chlorophylls absorb photosynthetically active radiation and thus function as vital pigments for photosynthesis, which makes leaf chlorophyll content (C(sub ab) useful for monitoring vegetation productivity and an important indicator of the overall plant physiological condition. This study investigates the utility of integrating remotely sensed estimates of C(sub ab) into a thermal-based Two-Source Energy Balance (TSEB) model that estimates land-surface CO2 and energy fluxes using an analytical, light-use-efficiency (LUE) based model of canopy resistance. The LUE model component computes canopy-scale carbon assimilation and transpiration fluxes and incorporates LUE modifications from a nominal (species-dependent) value (LUE(sub n)) in response to short term variations in environmental conditions, However LUE(sub n) may need adjustment on a daily timescale to accommodate changes in plant phenology, physiological condition and nutrient status. Day to day variations in LUE(sub n) were assessed for a heterogeneous corn crop field in Maryland, U,S.A. through model calibration with eddy covariance CO2 flux tower observations. The optimized daily LUE(sub n) values were then compared to estimates of C(sub ab) integrated from gridded maps of chlorophyll content weighted over the tower flux source area. The time continuous maps of daily C(sub ab) over the study field were generated by focusing in-situ measurements with retrievals generated with an integrated radiative transfer modeling tool (accurate to within +/-10%) using at-sensor radiances in green, red and near-infrared wavelengths acquired with an aircraft imaging system. The resultant daily changes in C(sub ab) within the tower flux source area generally correlated well with corresponding changes in daily calibrated LUE(sub n) derived from the tower flux data, and hourly water, energy and carbon flux estimation accuracies from TSEB were significantly improved when using C(sub ab) for delineating spatio-temporal variations in LUE(sub n). The results demonstrate the synergy between thermal infrared and shortwave reflective wavebands in producing valuable remote sensing data for operational monitoring of carbon and water fluxes.
The BOReal Ecosystem-Atmosphere Study Tower Flux-2 (BOREAS TF-2) team collected energy, carbon dioxide, water vapor, and momentum flux data above the canopy and in profiles through the canopy, along with meteorological data at the BOREAS Southern Study Area-Old Aspen (SSA-OA) site. Above-canopy measurements began in early February and ran through mid-September of 1994. Measurements were collected over a longer period of 1994 than most BOREAS flux sites. Daily precipitation data from several gauges were also collected. The data are available in tabular ASCII files.
The BOReal Ecosystem-Atmosphere Study Tower Flux (BOREAS TF-4) team collected energy, carbon dioxide, and water vapor flux data at the BOREAS Southern Study Area-Young Jack Pine (SSA-YJP) site during the growing season of 1994. In addition, meteorological data were collected both above and within the canopy. The data are available in tabular ASCII files.
The BOREAS TF-1 team collected energy, carbon dioxide, and momentum flux data above the canopy along with meteorological and soils data at the BOREAS SSA-OA site from mid-April to the end of the year for 1996. The data are available in tabular ASCII files.
The BOREAS TF-9 team collected energy, carbon dioxide, and water vapor flux data at the BOREAS SSA-OBS site during the growing season of 1994 and most of the year for 1996. From the winter of 1995 to 1996, soil temperature data were also collected and provided. The data are available in tabular ASCII files.
The BOREAS TF-1 team collected energy, carbon dioxide, and momentum flux data under the canopy along with meteorological and soils data at the BOREAS SSA-OA site from mid-October to mid-November of 1993 and throughout all of 1994. The data are available in tabular ASCII files.
The BOREAS TF-11 team collected energy, carbon dioxide, and methane flux data at the BOREAS SSA-Fen site during the growing seasons of 1994 and 1995. The data are available in tabular ASCII files.