Search NASA⌕ Search

SEARCH · Search NASA

Results for “entrapment”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

Understanding MOF Gas Entrapment Through Modeling

Metal organic frameworks (MOF) were created for the capture of noble gases (NG). They were tested to see which would be the most efficient and selective. MOFs are synthetic materials that are used in a variety of purposes: gas separations, catalysis reactions, drug delivery, and gas storage. In a previous study, there was an extremely long retention time of NG within the Ca-MOF material. Between 30-65 % of the NG was never recovered even under vacuum and at 150 °C. An understanding of this retention at a fundamental level is needed for utilizing the MOF material in industry or other applications

Metal organic frameworks↗

Tailoring Mesopores and Nitrogen Groups of Carbon Nanofibers for Polysulfide Entrapment in Lithium–Sulfur Batteries

In the current work, we combined different physical and chemical modifications of carbon nanofibers through the creation of micro-, meso-, and macro-pores as well as the incorporation of nitrogen groups in cyclic polyacrylonitrile (CPAN) using gas-assisted electrospinning and air-controlled electrospray processes. We incorporated them into electrode and interlayer in Li–Sulfur batteries. First, we controlled pore size and distributions in mesoporous carbon fibers (mpCNF) via adding polymethyl methacrylate as a sacrificial polymer to the polyacrylonitrile carbon precursor, followed by varying activation conditions. Secondly, nitrogen groups were introduced via cyclization of PAN on mesoporous carbon nanofibers (mpCPAN). We compared the synergistic effects of all these features in cathode substrate and interlayer on the performance Li–Sulfur batteries and used various characterization tools to understand them. Our results revealed that coating CPAN on both mesoporous carbon cathode and interlayer greatly enhanced the rate capability and capacity retention, leading to the capacity of 1000 mAh/g at 2 C and 1200 mAh/g at 0.5 C with the capability retention of 88% after 100 cycles. The presence of nitrogen groups and mesopores in both cathodes and interlayers resulted in more effective polysulfide confinement and also show more promise for higher loading systems.

25 ENERGY STORAGE↗

Remote sensing analysis of water quality and the entrapment zone in the San Francisco Bay and delta

The author has identified the following significant results. Data from an ocean color scanner flown on a U-2 aircraft at 65,000 ft and from LANDSAT MSS were enhanced to identify biologically active areas of San Francisco Bay, and to determine the salinity, turbidity, chlorophylls, and suspended solids. The best fit regression models for mapping water quality parameters were based on bands 3, 5, 7, and 10. Comparision of the results indicate that chlorophyll concentrations can best be estimated by the OCS or MSS data. Salinity can best be estimated by OCS data; turbidity can best be estimated by LANDSAT data. Neither OCS nor MSS data provide reliable basis for estimating suspended solids. Aerial photography of the highest quality taken with either conventional color or infrared-sensitive color films was unable to locate the biologically active areas.

Colwell, R. N.↗

O I (7990 A) emission and radiative entrapment of auroral EUV

The auroral O I 7990-A multiplet intensity distribution has been observed by means of a 2-m grille spectrometer and a Fabry-Perot interferometer during 1977 and 1982, respectively, in Alaska. Grille spectrometer results indicate a nonstatistical distribution in the excited state, consistent with the preferential scattering of the O I 989-A EUV emission and in accord with recent radiative transfer calculations. A comparison of O I 7990-A intensities measured on the nightside with those from dayside magnetospheric cleft aurora shows a cascade contribution to the O I 8446-A line, and ultimately to the O I 1304-A transition, that depends on the altitude of the aurora. This is attributed to the greater radiative enhancement of O I 989-A at low altitude, and the correspondingly enhanced probability for branching from the 3 s-prime to the 3 p level in atomic O.

Christensen, A. B.↗

Capillary Liquid Acquisition Device Heat Entrapment

Cryogenic liquid acquisition devices (LADs) for space-based propulsion interface directly with the feed system, which can be a significant heat leak source. Further, the accumulation of thermal energy within LAD channels can lead to the loss of subcooled propellant conditions and result in feed system cavitation during propellant outflow. Therefore, the fundamental question addressed by this program was: To what degree is natural convection in a cryogenic liquid constrained by the capillary screen meshes envisioned for LADs? Testing was first conducted with water as the test fluid, followed by LN2 tests. In either case, the basic experimental approach was to heat the bottom of a cylindrical column of test fluid to establish stratification patterns measured by temperature sensors located above and below a horizontal screen barrier position. Experimentation was performed without barriers, with screens, and with a solid barrier. The two screen meshes tested were those typically used by LAD designers, 200x1400 and 325x2300, both with Twill Dutch Weave. Upon consideration of both the water and LN2 data, it was concluded that heat transfer across the screen meshes was dependent upon barrier thermal conductivity and that the capillary screen meshes were impervious to natural convection currents.

Bolshinskiy, L. G.↗

Cryogenic Capillary Screen Heat Entrapment

Cryogenic liquid acquisition devices (LADs) for space-based propulsion interface directly with the feed system, which can be a significant heat leak source. Further, the accumulation of thermal energy within LAD channels can lead to the loss of sub-cooled propellant conditions and result in feed system cavitation during propellant outflow. Therefore, the fundamental question addressed by this program was: "To what degree is natural convection in a cryogenic liquid constrained by the capillary screen meshes envisioned for LADs.?"Testing was first conducted with water as the test fluid, followed by LN2 tests. In either case, the basic experimental approach was to heat the bottom of a cylindrical column of test fluid to establish stratification patterns measured by temperature sensors located above and below a horizontal screen barrier position. Experimentation was performed without barriers, with screens, and with a solid barrier. The two screen meshes tested were those typically used by LAD designers, "200x1400" and "325x2300", both with Twill Dutch Weave. Upon consideration of both the water and LN2 data it was concluded that heat transfer across the screen meshes was dependent upon barrier thermal conductivity and that the capillary screen meshes were impervious to natural convection currents.

Bolshinskiy, L.G.↗