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At least 37 records · Page 2

Hydrodynamics of bubble flow through a porous medium with applications to packed bed reactors

Gas-liquid flows through packed bed reactors (PBRs) are challenging to predict due to the tortuous flow paths that fluid interfaces must traverse. Experiments at the International Space Station showed that bubble and pulse flows are predominately observed under microgravity conditions, while the trickle and spray flows observed under terrestrial conditions are not present in microgravity. To understand the physics behind the former experiments, we simulate bubble flow through a PBR for different packing-particle-diameter-based Weber numbers and under different gravity conditions. We demonstrate different pore-scale mechanisms, such as capillary entrapment, buoyancy entrapment, and inertia-induced bubble displacement. Then, we perform a quantitative analysis by introducing new dynamic scales, dependent upon the evolving gas-liquid interfacial area, to understand the dynamic trade-offs between the inertia, capillary, and buoyancy forces on a bubble passing through a PBR. This analysis leads us to define new dimensionless Weber-like numbers that delineate bubble entrapment from bubble displacement.

Pranay P Nagrani↗

Magnetospheric particle composition experiment

Thin foils of aluminum and platinum were mounted on the exterior of the Skylab spacecraft where they were bombarded by particles that penetrate to the 400-km spacecraft altitude, including auroral particles precipitating from the earth magnetosphere. These foils have a high trapping efficiency for both charged and neutral particles above 1 keV and a decreasing but appreciable efficiency below that energy. Some sections of the foils were double layered to obtain an estimate of the energy of the entrapped particles. The foils were retrieved and returned for analysis in an ultrahigh-vacuum mass spectrometer. So far, the noble gas components of the entrapped particles have been analyzed in selected sections of two foils. Helium-4, helium-3, neon-20, and neon-22 have been detected.

Geiss, J.↗

Solar and terrestrial noble gases in magnetospheric precipitation

Metal-foil collectors were installed on the external structure of Skylab to entrap precipitating magnetospheric particles. The foils were retrieved, and the entrapped helium, neon, and argon were isotopically analyzed in a high-resolution mass spectrometer. Solar and terrestrial helium and neon and terrestrial argon were detected. As expected, the isotopic composition of neon and argon in the high atmosphere was found to be strongly fractionated. Special techniques were used to estimate the initial particle energy of He-3. The measured He-3 flux is consistent with the assumption that precipitating solar He-3 is the major source of terrestrial He-3.

Lind, D. L.↗

Observation of the O I ultraviolet intercombination emissions in the terrestrial dayglow

The first measurement of the 1173-A O I intercombination line in emission in the terrestrial dayglow was performed using the EUV-FUV spectrometer designed to be flown with the Astro-1 observatory. The atmospheric conditions and viewing geometry were such as to suppress nitrogen emission relative to those from atomic oxygen, permitting the identification and measurement of the weak O I 1173-A intercombination multiplet and the 1641-A line as well as the strong 989-A and 1304-A emissions. At lower altitudes, the 1173-A emission rate increased while the 989-A emission, from the same upper level, decreased. This behavior is consistent with the radiative entrapment model of Meier (1982) and the laboratory value of the 1173-A/989-A branching ratio measured by Morrison (1985). The 1641-A/1304-A emission ratio is also consistent with a radiative entrapment model.

Bowers, C. W.↗

Characteristics and carbon stable isotopes of fluids in the Southern Kerala granulites and their bearing on the source of CO2

Carbon dioxide-rich inclusions commonly occur in the banded charnockites and khondalites of southern Kerala as well as in the incipient charnockites formed by desiccation of gneisses along oriented zones. The combined high density fluid inclusion isochores and the range of thermometric estimates from mineral assemblages indicate entrapment pressures in the range of 5.4 to 6.1 Kbar. The CO2 equation of state barometry closely compares with the 5 plus or minus 1 Kbar estimate from mineral phases for the region. The isochores for the high density fluid inclusions in all the three rock types pass through the P-T domain recorded by phase equilibria, implying that carbon dioxide was the dominating ambient fluid species during peak metamorphic conditions. In order to constrain the source of fluids and to evaluate the mechanism of desiccation, researchers undertook detailed investigations of the carbon stable isotope composition of entrapped fluids. Researchers report here the results of preliminary studies in some of the classic localities in southern Kerala namely, Ponmudi, Kottavattom, Manali and Kadakamon.

Santosh, M.↗

Thermographic Analysis of Composite Cobonds on the X-33

The methods utilized to perform an infrared thermography inspection of the bondline of structural reinforcing caps on X-33 liquid hydrogen (LH2) tank during the manufacture are described in this presentation. A total of thirty-six caps were bonded to the tank using a wet cobond process with vacuum bagging and low temperature curing. The thermal map of each bondline was acquired through the vacuum bag by applying heat to the cap and then viewing it during cool down. Poorly bonded regions, or voids, were characterized by localized hot spots in the thermal image. These regions were marked on the tank by referring to a live thermal image, then hand massaged in an attempt to remove the entrapped air. The cap was then reinspected and, if it was determined that the entrapped air could not be removed, the cap was removed and the adhesive cleaned away before it cured. Measures were then taken to better match the surface of the cap to the tank and the process repeated. After the bondline had cured sufficiently to allow vacuum bag removal, a "flash heating" thermographic Investigation was performed to verify that the cap had bonded properly to the tank. Any regions that had opened up after the preliminary inspection were marked and filled by drilling small holes in the cap and injecting resin. A final inspection was then performed to ensure the quality of the bondline.

Russell, Samual S.↗

Particle Engulfment and Pushing By Solidifying Interfaces

The phenomenon of interaction of particles with solid-liquid interfaces (SLI) has been studied since the mid 1960's. While the original interest stemmed from geology applications (frost heaving in soil), researchers soon realized that fundamental understanding of particles behavior at solidifying interfaces might yield practical benefits in other fields, including metallurgy. In materials engineering the main issue is the location of particles with respect to grain boundaries at the end of solidification. Considerable experimental and theoretical research was lately focused on applications to metal matrix composites produced by casting or spray forming techniques, and on inclusion management in steel. Another application of particle SLI interaction is in the growing of Y1Ba2Cu3O(7-delta) (123) superconductor crystals from an undercooled liquid. The oxide melt contains Y2Ba1Cu1O5 (211) precipitates, which act as flux pinning sites. The experimental evidence on transparent organic materials, as well as the recent in situ observations on steel demonstrates that there exist a critical velocity of the planar SLI below which particles are pushed ahead of the interface, and above which particles are engulfment. The engulfment of a SiC particle in succinonitrile is exemplified. However, in most commercial alloys dendritic interfaces must be considered. Indeed, most data available on metallic alloys are on dendritic structures. The term engulfment is used to describe incorporation of a particle by a planar or cellular interface as a result of local interface perturbation, as opposed to entrapment that implies particle incorporation at cells or dendrites boundaries. During entrapment the particles are pushed in the intercellular or interdendritic regions and then captured when local solidification occurs. The physics of these two phenomena is fundamentally different.

Stefanescu, Doru M.↗

Mechanical signals in plant development: a new method for single cell studies

Cell division, which is critical to plant development and morphology, requires the orchestration of hundreds of intracellular processes. In the end, however, cells must make critical decisions, based on a discrete set of mechanical signals such as stress, strain, and shear, to divide in such a way that they will survive the mechanical loads generated by turgor pressure and cell enlargement within the growing tissues. Here we report on a method whereby tobacco protoplasts swirled into a 1.5% agarose entrapment medium will survive and divide. The application of a controlled mechanical load to agarose blocks containing protoplasts orients the primary division plane of the embedded cells. Photoelastic analysis of the agarose entrapment medium can identify the lines of principal stress within the agarose, confirming the hypothesis that cells divide either parallel or perpendicular to the principal stress tensors. The coincidence between the orientation of the new division wall and the orientation of the principal stress tensors suggests that the perception of mechanical stress is a characteristic of individual plant cells. The ability of a cell to determine a shear-free orientation for a new partition wall may be related to the applied load through the deformation of the matrix material. In an isotropic matrix a uniaxial load will produce a rotationally symmetric strain field, which will define a shear-free plane. Where high stress intensities combine with the loading geometry to produce multiaxial loads there will be no axis of rotational symmetry and hence no shear free plane. This suggests that two mechanisms may be orienting the division plane, one a mechanism that works in rotationally symmetrical fields, yielding divisions perpendicular to the compressive tensor, parallel to the long axis of the cell, and one in asymmetric fields, yielding divisions parallel to the short axis of the cell and the compressive tensor.

NASA Discipline Number 40-50↗

Detection of microlesions induced by heavy ions using liposomes filled with fluorescent dye

In cells irradiation by heavy ions has been hypothesized to produce microlesions, regions of local damage. In cell membranes this damage is thought to manifest itself in the form of holes. The primary evidence for microlesions comes from morphological studies of cell membranes, but this evidence is still controversial, especially since holes also have been observed in membranes of normal, nonirradiated, cells. However, it is possible that damage not associated with histologically discernable disruptions may still occur. In order to resolve this issue, we developed a system for detecting microlesions based on liposomes filled with fluorescent dye. We hypothesized that if microlesions form in these liposomes as the result of irradiation, then the entrapped dye will leak out into the surrounding medium in a measurable way. Polypropylene vials containing suspensions of vesicles composed of either dipalmitoyl phosphatidylcholine, or a combination of egg phosphatidylcholine and cholesterol were irradiated at the Brookhaven National Laboratory using 56Fe ions at 1 GeV/amu. In several cases we obtained a significant loss of the entrapped dye above the background level. Our results suggest that holes may form in liposomes as the result of heavy ion irradiation, and that these holes are large enough to allow leakage of cell internal contents that are at least as large as a 1 nm diameter calcein molecule. c2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

Non-NASA Center↗

Operational Considerations for Oxygen Flammability Risks: Concentrated Oxygen Diffusion and Permeation Behaviors

Increased human spaceflight operations utilize oxygen concentrations that are frequently varied with use of concentrations up to 100 percent oxygen. Even after exiting a higher percentage oxygen environment, high oxygen concentrations can still be maintained due to material saturation and oxygen entrapment between barrier materials. This paper examines the material flammability concerns that arise from changing oxygen environments during spaceflight operations. We examine the time required for common spacecraft and spacesuit materials exposed to oxygen to return to reduced ignitability and flammability once removed from the increased concentration. Various common spacecraft materials were considered: spacecraft cabin environment foams, Extra Vehicular Mobility Unit materials and foams, Advanced Crew Escape Suit materials, and other materials of interest such as Cotton, Nomex^ HT90-40, and Tiburon Surgical Drape. This paper presents calculated diffusion coefficients derived from experimentally obtained oxygen transmission rates for the tested materials and the analytically derived times necessary for reduced flammability to be achieved based on NASA flammability criteria. Oxygen material saturation and entrapment scenarios are examined. Experimental verification data on oxygen diffusion in saturation scenarios are also presented and discussed. We examine how to use obtained data to address flammability concerns during operational planning to reduce the likelihood of fires while improving efficiency for procedures.

Harper, Susana↗

Application of Molecular Adsorber Coatings in Chamber A for the James Webb Space Telescope

As a coating made of highly porous zeolite materials, the Molecular Adsorber Coating (MAC) was developed to capture outgassed molecular contaminants, such as hydrocarbons and silicones. For spaceflight applications, the adsorptive capabilities of the coating can alleviate on-orbit outgassing concerns on or near sensitive surfaces and instruments within the spacecraft. Similarly, this sprayable paint technology has proven to be significantly beneficial for ground-based space applications, in particular, for vacuum chamber environments. This presentation describes the application of the MAC technology for the James Webb Space Telescope (JWST) at NASA Johnson Space Center (JSC). The coating was used as a mitigation tool to entrap outgassed contaminants, specifically silicone-based diffusion pump oil, from within JSCs cryogenic optical vacuum chamber test facility called Chamber A. This presentation summarizes the background, fabrication, installation, chemical analysis test results, and future plans for the MAC technology, which was effectively used to protect the JWST test equipment from vacuum chamber contamination. As a coating made of highly porous zeolite materials, the Molecular Adsorber Coating (MAC) was developed to capture outgassed molecular contaminants, such as hydrocarbons and silicones. For spaceflight applications, the adsorptive capabilities of the coating can alleviate on-orbit outgassing concerns on or near sensitive surfaces and instruments within the spacecraft. Similarly, this sprayable paint technology has proven to be significantly beneficial for ground-based space applications, in particular, for vacuum chamber environments. This presentation describes the application of the MAC technology for the James Webb Space Telescope (JWST) at NASA Johnson Space Center (JSC). The coating was used as a mitigation tool to entrap outgassed contaminants, specifically silicone-based diffusion pump oil, from within JSCs cryogenic optical vacuum chamber test facility called Chamber A. This presentation summarizes the background, fabrication, installation, chemical analysis test results, and future plans for the MAC technology, which was effectively used to protect the JWST test equipment from vacuum chamber contamination.

molecular contamination↗

Trace Element Abundances of Olivine-Hosted Melt Inclusions in Shergottites Northwest Africa 7397 and Robert Massif 04262

Olivine-hosted melt inclusions (MIs) may retain trapped parent magma compositions as well as record progressive differentiation while magmas crystallize and ascend towards the surface [1,2 and references therein]. Major element compositions of the MIs, especially Fe and Mg, can be affected by post-entrapment re-equilibration with their host olivine [1,2]. Therefore, Fe/Mg ratio correction is required to obtain MI bulk compositions following equilibrium with their host olivine. Partition coefficients of most of the trace elements in olivine are very low (i.e. DOL/melt<0.001). Thus, ratios of trace elements of olivine-hosted MIs are unlikely to be affected by post-entrapment re-equilibration and no correction is necessary [2]. Hence, tracking trace element behavior in MIs may constrain the composition of the parent magma and its evolution yielding insights on magma differentiation of shergottites. However, analyzing MIs for chemical compositions is a challenging task due to their low abundances and small sizes. Using a highly sensitive and precise micro-beam technique is essential to examine olivine-hosted MIs in order to measure trace element abundances. For this purpose, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is an excellent tool due to its wide range of laser spot sizes (1-150 μm), ability to obtain raster analysis (several mm2) and lower detection limits (0.1 ppb) [3].

Ferdous, J.↗

Meteoritic Carbonates - The Key to Sampling Extraterrestrial Fluids?

Fluid inclusions are naturally occurring mineral features that preserve trapped fluid phases inside a solid phase. These cavities exist as a closed system, recording the environmental conditions present during entrapment – both physical and chemical. As a result, fluid inclusions are great candidates for directly studying past fluid activity on extraterrestrial bodies within the Solar System. On Earth, fluid inclusions are abundant as they occur within numerous host minerals. They are a powerful tool for accurately and directly understanding the driving processes in various geological environments. In contrast, extraterrestrial fluid inclusions have only been positively identified on three separate occasions within host materials ranging from ordinary chondrites to C/B-type asteroid mission return samples. The possibility of directly studying the fluids involved in aqueous alteration and accurately constraining their heliocentric distances drives the hunt for these elusive capsules. Our goals are to locate new fluid inclusion candidates (hereon referred to as candidates) and assess whether fluid inclusions are a common feature within meteoritic carbonates and why they may have eluded detection for so long. We also aim to characterize the host grain’s mineralogical properties and assess the potentially preferential conditions for fluid entrapment on the asteroid parent body.

P A B Krizan↗

Non-Geometric Hazard Detection for a Mars Microrover

Non-geometric hazards (i.e., those which cannot be characterized solely by their shape, but instead are related to mechanical properties such as strength and friction) may pose a significant risk to planetary rovers. This paper describes a means for an articulated vehicle to detect sinkage and slippage in such material so as to prevent entrapment and to correct for dead-reckoning errors.

hazards↗

Reducing bubbles in glass coatings improves electrical breakdown strength

Helium reduces bubbles in glass coatings of accelerator grids for ion thrustors. Fusing the coating in a helium atmosphere creates helium bubbles in the glass. In an argon atmosphere, entrapped helium diffuses out of the glass and the bubbles collapse. The resultant coating has a substantially enhanced electrical breakdown strength.

Banks, B.↗

Thermal radiation shields for piping in vacuum environments

System of thermal radiation shielding reduces radiant heat transfer in vacuum installations containing piping which carries working fluids. Method employs successive layers of spacers and rolled metal shields which are easily installed or removed, expedites efficient removal of entrapped gases, and adapts easily to small pipings.

Spagnuolo, A. C.↗