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NASA NTRS2015

3D Photocatalytic Air Processor for Dramatic Reduction of Life Support Mass and Complexity

To dramatically reduce the cost and risk of CO2 management systems in future extended missions, we have conducted preliminary studies on the materials and device development for advanced "artificial photosynthesis" reaction systems termed the High Tortuosity PhotoElectroChemical (HTPEC) system. Our Phase I studies have demonstrated that HTPEC operates in much the same way a tree would function, namely directly contacting the cabin air with a photocatalyst in the presence of light and water (as humidity) to immediately conduct the process of CO2 reduction to O2 and useful, "tunable" carbon products. This eliminates many of the inefficiencies associated with current ISS CO2 management systems. We have laid the solid foundation for Phase II work to employ novel and efficient reactor geometries, lighting approaches, 3D manufacturing methods and in-house grown novel catalytic materials.The primary objective of the proposed work is to demonstrate the scientific and engineering foundation for light-activated, compact devices capable of converting CO2 to O2 and mission-relevant carbon compounds. The proposed HTPEC CO2 management system will demonstrate a novel pathway with high efficiency and reliability in a compact, lightweight reactor architecture. The proposed HTPEC air processing concept can be developed in multiple architectures, such as centralized processing as well as "artificial leaves" distributed throughout the cabin that utilize pre-existing cabin ventilation (wind). Additionally, HTPEC can be deployed with spectrally tunable collection channels for selectable product generation. HTPEC employs light as its only energy source to remove and convert waste CO2 using a non-toxic composite catalyst.We have demonstrated in the Phase I studies the production, tunability and robustness of the novel composite catalysts following the preliminary work in the Chen laboratory. Additionally, we have designed, fabricated and tested all components of HTPEC device with active materials, including flow modeling to optimize flow mixing and pressure drop as well as the production of ethylene and other larger hydrocarbons. To best determine how this technology could be implemented, we also performed system integration optimization and trade studies. This includes parameters such as mass, volume, power in relation to selected mission configurations, CO2 delivery methods and light source/delivery approaches.

Artificial Photosynthesis↗

NASA NTRS1976

Remote measurements of ambient air pollutants with a bistatic laser system

The ambient air pollutants ozone, nitric oxide, and ethylene have been monitored in the Pasadena area with a bistatic IR laser apparatus. These pollutants were measured with a differential absorption technique, using selected wavelengths in the 9.5-, 5.2-, and 10.5-micron regions, respectively. The transmitted laser radiation was detected using both direct and heterodyne detection techniques. In the direct detection case, cube corner retroreflectors provided the return, and the heterodyne detection responded to scattered radiation from various rough surfaces, ranging from 400 m to 1.9 km in distance from the apparatus. Significant departures from ambient background concentration levels were noticed in the region near a local freeway during periods of moderate and heavy traffic.

Menzies, R. T.↗

NASA NTRS1983

A survey of laser and selected optical systems for remote measurement of pollutant gas concentrations

Applications of the Differential Absorption Lidar (DIAL) technique to the remote sensing of pollutant gases are surveyed. In the DIAl technique, the differential absorption of two laser beams reflected back to a receiver from a target determines the concentration of the gas being studied. The types of instruments available are considered in detail: dye lidar (to measure nitrogen dioxide, sulfur dioxide, and ozone); carbon dioxide laser (for ozone, ethylene, ammonia, and hydrazine), helium-neon laser (for methane); hydrogen fluoride laser (for HF); and tunable diode laser (for nitric oxide and carbon monoxide). DIAL instruments are compared with other optical remote sensors such as Fourier-transform infrared spectrometers, correlation spectrometers (COSPEC and GASPEC), and grating spectrometers; and criteria for the selection of an appropriate gas measuring system are suggested. Laser and other optical remote sensors are found to be cost effective in many cases, despite the fact that they are more costly than point-monitoring systems.

Grant, W. B.↗

NASA NTRS2008

Supersonic Combusting Jet Experiments for Code Development and Validation

Computational fluid dynamics (CFD) methods based on the Reynolds averaged Navier-Stokes (RANS) equations are extensively employed in the design of hypersonic airbreathing engines. A fundamental weakness in these methods is the accurate mathematical modeling of turbulence and turbulence-combustion interactions. This paper is one of a companion pair of papers which describe the use of the combined dual pump CARS and newly developed interferometric Rayleigh scattering optical system to acquire time-accurate turbulence and mixing data with which to aid calibration and verification of the current turbulence models. This test program consisted of a pilot laboratory-scale experiment used to develop the optical system and data acquisition techniques, and a significantly larger experiment to acquire the necessary turbulence data. The flow is an axially-symmetric, supersonic, combusting, free jet that provides good optical access, consisting of a central jet of hot "vitiated air" and a coflow jet of hydrogen or ethylene fuel. In this paper the development of both experiments is described. Facility and flow visualization data are presented for various types of flames, including the flames selected for detailed study with the CARS/Rayleigh optical techniques.

Cutler, Andrew D.↗

NASA NTRS1982

Microelectrophoresis of selected mineral particles

Particle mobilities of ilmenite, labradorite plagioclase, enstatite pyroxene, and olivine were measured with a Rank microelectrophoresis system to evaluate indicated mineral separability. Sodium bicarbonate buffer suspension media with and without additives (0.0001 M DTAB and 5 percent v/v ethylene glycol) were used to determine differential adsorption by mineral particles and modification of relative mobilities. Good separability between some minerals was indicated; additives did not enhance separability.

Herren, B. J.↗

NASA NTRS1991

Calculating Thermophysical Properties Of 12 Fluids

MIPROPS is set of computer programs giving thermophysical and transport properties of selected fluids. Calculates properties of fluids in both liquid and vapor states over wide range of temperatures and pressures. Fluids included: helium, hydrogen, nitrogen, oxygen, argon, nitrogen trifluoride, methane, ethylene, ethane, propane, isobutane, and normal butane. All programs except helium program incorporate same equation of state. Written in FORTRAN 77.

Cleghorn, T. F.↗

NASA NTRS1990

Hydrocarbon-fuel/combustion-chamber-liner materials compatibility

Results of material compatibility experiments using hydrocarbon fuels in contact with copper-based combustion chamber liner materials are presented. Mil-Spec RP-1, n- dodecane, propane, and methane fuels were tested in contact with OFHC, NASA-Z, and ZrCu coppers. Two distinct test methods were employed. Static tests, in which copper coupons were exposed to fuel for long durations at constant temperature and pressure, provided compatibility data in a precisely controlled environment. Dynamic tests, using the Aerojet Carbothermal Test Facility, provided fuel and copper compatibility data under realistic booster engine service conditions. Tests were conducted using very pure grades of each fuel and fuels to which a contaminant, e.g., ethylene or methyl mercaptan, was added to define the role played by fuel impurities. Conclusions are reached as to degradation mechanisms and effects, methods for the elimination of these mechanisms, selection of copper alloy combustion chamber liners, and hydrocarbon fuel purchase specifications.

Gage, Mark L.↗

NASA NTRS2003

Grease-Resistant O Rings for Joints in Solid Rocket Motors

There is a continuing effort to develop improved O rings for sealing joints in solid-fuel rocket motors. Following an approach based on the lessons learned in the explosion of the space shuttle Challenger, investigators have been seeking O-ring materials that exhibit adequate resilience for effective sealing over a broad temperature range: What are desired are O rings that expand far and fast enough to maintain seals, even when metal sealing surfaces at a joint move slightly away from each other shortly after ignition and the motor was exposed to cold weather before ignition. Other qualities desired of the improved O rings include adequate resistance to ablation by hot rocket gases and resistance to swelling when exposed to hydrocarbon-based greases used to protect some motor components against corrosion. Five rubber formulations two based on a fluorosilicone polymer and three based on copolymers of epichlorohydrin with ethylene oxide were tested as candidate O-ring materials. Of these, one of the epichlorohydrin/ethylene oxide formulations was found to offer the closest to the desired combination of properties and was selected for further evaluation.

Harvey, Albert R.↗

NASA NTRS1986

Demixing of aqueous polymer two-phase systems in low gravity

When polymers such as dextran and poly(ethylene glycol) are mixed in aqueous solution biphasic systems often form. On Earth the emulsion formed by mixing the phases rapidly demixes because of phase density differences. Biological materials can be purified by selective partitioning between the phases. In the case of cells and other particulates the efficiency of these separations appears to be somewhat compromised by the demixing process. To modify this process and to evaluate the potential of two-phase partitioning in space, experiments on the effects of gravity on phase emulsion demixing were undertaken. The behavior of phase systems with essentially identical phase densities was studied at one-g and during low-g parabolic aircraft maneuvers. The results indicate the demixing can occur rather rapidly in space, although more slowly than on Earth. The demixing process was examined from a theoretical standpoint by applying the theory of Ostwald ripening. This theory predicts demizing rates many orders of magnitude lower than observed. Other possible demixing mechanisms are considered.

Bamberger, S.↗

NASA NTRS1999

Thermal Control Replacement Materials Evaluated for Durability and Selected for the Hubble Space Telescope

During the Hubble Space Telescope (HST) second servicing mission, astronauts noticed that the outer layer of the multilayer insulation (MLI) was cracked in many locations around the telescope. The insulation s outer layer is composed of 5-mil (0.127 mm) Teflon FEP (DuPont; fluorinated ethylene propylene) with vapor-deposited aluminum (VDA) on the backside. The MLI blankets, which are used on over 80 percent of the external surface of the telescope, provide passive thermal control for equipment. Two large cracks were observed on the light shield directly above the high gain antenna. The upper light shield crack propagated from a cut placed in the blanket during installation around a handrail standoff. Two cracks propagated almost normal to each other, with the outer layer curling tightly as the cracks propagated. A second much larger vertical crack had started to curl and lift away from the telescope, as seen in the figure. MLI on the equipment bays was cracked extensively also, and in some areas it had pulled away from the bay. Continued degradation of the equipment bay insulation would potentially cause limited observations because of housekeeping boxes; for example, the data interface unit could overheat during some portions of the year, in certain sun angles.

deGroh, Kim K.↗

NASA NTRS1982

A review of acetylene, ethylene and ethane molecular spectroscopy for planetary applications

Spectroscopic work in acetylene, ethylene and ethane, are of particular interest since the Voyager IRIS observations of Jupiter. Acetylene and ethane but not ethylene were observed in the Jovian spectrum. Two fundamental bands of the observed gases are used to determine the spatial distribution of these hydrocarbons on Jupiter and to illuminate the photochemistry of these species. The 100 to 1000 cm region is discussed and selected examples of current laboratory work are given.

Maguire, W. C.↗

NASA NTRS1993

ASRM Case Insulation development

The ASRM Case Insulation Program used design of experiments to develop a high performance case insulation. The program traded-off more than thirty properties in areas of ablation performance, material properties, processibility, bonding/aging. Kevlar pulp was found to be the most significant factor. The low-molecular weight ethylene propylene diene monomer, EPDM was the second most significant factor. The curative was the third most significant factor. The tackifier was the fourth most significant factor. The stripwinding process for applying the insulation onto the case inner surfaces was also studied. The parameters selected for experiment were extruder speed, upper roller temperature and extruder nozzle temperature. The extrudability results showed that non-Kevlar filled formulations displayed optimum edges but poor thickness continuity. High Kevlar filled formulations displayed optimum thickness continuity but poor strip edge ratings.

Tam, W. F. S.↗

NASA NTRS2001

Use of GC/MS and Microtome Techniques as Methods to Evaluate ODC Free Cleaner Diffusion and Evaporation in Insulation and Phenolic Case Material

Because of the 1990 Clean Air Act Amendment (CAAA) many chlorinated solvents used in the aerospace industry are being phased out. Replacement of the ODC (ozone-depleting chemicals) with less volatile, non-ozone depleting cleaners has been extensively studied over the past seven years at Thiokol Propulsion, a Division of Cordant Technologies, Inc. The down selection of ODC replacement cleaners has been based on several factors including the diffusion evaporation of the cleaners in selected substrates. Methodologies were developed to evaluate the cleaner content in substrates. Methods of cutting thin slices of material (microtoming) were combined with GC/MS (gas chromatography/mass spectroscopy) analysis. Substrates evaluated in this study include potential solid rocket motor materials: ASNBR (asbestos-filled nitrile butadiene rubber) and CFEPDM (carbon-filled ethylene propylene dimonomer) insulation and glass (GCP), carbon (CCP) and silica (SCP) cloth phenolic substrates with fibers either parallel (0 deg) or perpendicular (90 deg) to the surface. Residue profiles indicate both cleaner and substrate composition affect the diffusion and subsequent evaporation of the cleaner from the substrate surface.

Biegert, L. L.↗

NASA NTRS1986

Fluorescent indicator dyes for calcium ions

The present invention discloses a new class of highly fluorescent indicator dyes that are specific for calcium ions. The new fluorescent indicator dyes combine a stilbene-type fluorophore with a tetracarboxylate parent Ca.sup.2+ chelating compound having the octacoordinate pattern of liganding groups characteristic of EGTA and BAPTA. Preferred forms contain extra heterocyclic bridges to reinforce the ethylenic bond of the stilbene and to reduce hydrophobicity. Compared to their widely used predecessor, quin2, the new dyes offer up to thirty-fold brighter fluorescence, major changes in wavelength (not just intensity) upon Ca.sup.2+ binding, slightly lower affinities for Ca.sup.2+, slightly longer wavelengths of excitation, and considerably improved selectivity for Ca.sup.2+ over other divalent cations. These properties, particularly the wavelength sensitivity to Ca.sup.2+, make the dyes useful indicators for many intracellular applications, especially in single cells, adherent cell layers, or bulk tissues. The present invention also discloses an improved method for synthesizing alpha-acyloxyalkyl bromides wherein the bromides so synthesized are free of contaminating bis(1-bromoalkyl)ether. The improved method is exemplified herein in the synthesis of acetoxymethyl bromide, a compound useful in preparing the acetoxymethyl esters disclosed herein as novel Ca.sup.2+ specific fluorescent indicators.

Tsien, Roger Y.↗

NASA NTRS2000

Non-Asbestos Insulation Testing Using a Plasma Torch

Insulation obsolescence issues are a major concern for the Reusable Solid Rocket Motor (RSRM). As old sources of raw materials disappear, new sources must be found and qualified. No simple, inexpensive test presently exists for predicting the erosion performance of a candidate insulation in the full-scale motor, Large motor tests cost million of dollars and therefore can only be used on a few very select candidates. There is a need for a simple, low cost method of screening insulation performance that can simulate some of the different erosion environments found in the RSRM. This paper describes a series of erosion tests on two different non-asbestos insulation formulations, a KEVLAR(registered) fiber-filled and a carbon fiber-filled insulation containing Ethylene-Propylene-Diene Monomer (EPDM) rubber as the binder. The test instrument was a plasma torch device. The two main variables investigated were heat flux and alumina particle impingement concentration. Statistical analysis revealed that the two different formulations had very different responses to the main variable. The results of this work indicate that there may be fundamental differences in how these insulation formulations perform in the motor operating environment. The plasma torch appears to offer a low-cost means of obtaining a fundamental understanding of insulation response to critical factors in a series of statistically designed experiments.

Morgan, R. E.↗

NASA NTRS2009

Fluoroester Co-Solvents for Low-Temperature Li+ Cells

Electrolytes comprising LiPF6 dissolved in alkyl carbonate/fluoroester mixtures have been found to afford improved low-temperature performance and greater high-temperature resilience in rechargeable lithium-ion electrochemical cells. These and other electrolytes comprising lithium salts dissolved mixtures of esters have been studied in continuing research directed toward extending the lower limit of operating temperatures of such cells. This research at earlier stages, and the underlying physical and chemical principles, were reported in numerous previous NASA Tech Briefs articles. The purpose of the present focus on high-temperature resilience in addition to low-temperature performance is to address issues posed by the flammability of the esters and, at temperatures near the upper end (about 55 C) of their intended operating temperature range, by their high chemical reactivity. As used here, high-temperature resilience signifies, loosely, a desired combination of low flammability of an electrolyte mixture and the ability of a cell that contains the mixture to sustain a relatively small loss of reversible charge/discharge capacity during storage in the fully charged condition at high temperature. The selection of fluoroesters for study as candidate electrolyte solvent components to increase high-temperature resilience was prompted in part by the observation that like other halogenated compounds, fluoroesters have low flammability. The fluoroesters investigated in this study include trifluoroethyl butyrate (TFEB), ethyl trifluoroacetate (ETFA), trifluoroethyl acetate (TFEA), and methyl pentafluoropropionate (MPFP). Solvent mixtures were prepared by mixing these fluoroesters with two other esters: ethylene carbonate (EC) and ethyl methyl carbonate (EMC).

Smart, Marshall↗

NASA NTRS2024

Reliable and Efficient Electrochemical Recovery of O 2 from Metabolic CO 2 at the International Space Station (ISS)

Maximum O 2 recovery from metabolic carbon dioxide (CO 2 ) is desired for future long-duration missions beyond Low Earth Orbit (LEO). The O 2 recovery for the Environmental Control and Life Support System (ECLSS) at the International Space Station (ISS), presently limited to 50% (Sabatier), must be highly reliable and efficient and recover a minimum of 75% oxygen (O 2 ) from metabolic CO 2 . An alternative technology development effort currently underway at NASA Marshall Space Flight Center (MSFC) via a Microfluidic Electrochemical Reactor (MFECR) approach has the potential to increase O 2 recovery significantly and reduce the complexity of the ECLSS O 2 recovery at the ISS as it would replace three pieces, the CO 2 Reduction Assembly (CRA) (Sabatier reactor), the Oxygen Generation Assembly (OGA), and the Plasma Pyrolysis Assembly (PPA). The MFECR's electrochemical process generates ethylene (C 2 H 4 ) and carbon moxide (CO) instead of methane (CH 4 ) (Sabatier) as a byproduct, eliminating the need for further dehydrogenation through the PPA. As in the OGA, the MFECR's electrochemical process generates O 2 and hydrogen (H 2 ) from the water electrolysis process. MSFC and the University of Texas in Arlington (UTA) have jointly designed and fabricated an MFECR's single cell that operates at ambient conditions and utilizes a proprietary catalysis highly selective on reducing CO 2 to C 2 H 4 and CO at the cathode. This MFECR's single cell consists of gas diffusion layers at the cathode and anode for respective intake of CO 2 and output of O 2 from the catalytic layer. This approach is expected to substantially improve the ISS ECLSS sustainability and reduce power and weight requirements as the MFECR would replace three units currently installed in the ISS. In this paper, the authors discuss the outcome of preliminary tests, the current development, and the evaluation efforts on different alternatives for the cathode and the anode configurations, the setup of the MFECR at an engineering development unit (EDU) scale, and the O 2 recovery performance, and evaluation efforts on different alternatives on not only the configuration and setup of the MFECR at an Engineering Design Unit (EDU) scale but also the selection of component materials.

Jesus A Dominguez↗

NASA NTRS1985

A consideration of atomic oxygen interactions with space station

A computer model is developed in order to calculate fluence for a generalized spacecraft in orbital flight based on mass spectrometer and incoherent scatter (MSIS) measurements of ambient density. The calculations are used to identify criteria for the selection of materials for the construction of an LEO Space Station. The model is generalized such that the surfaces for study can be oriented in any direction with respect to: a body coordinate system fixed to the spacecraft (E surfaces); and a solar inertial coordinate system. A parametric study was performed in order to evaluate the effects of altitude, inclination, and solar activity on atomic oxygen fluence. Values are obtained for samples of Mylar, Kevlar, Kapton, Tedlar, Teflon and sulfone, as well as for some ethylene polymers. The range of values for material reactivities is from 360 microns for ram-facing surfaces to 200 microns for solar power surfaces during each cycle of solar activity. The possibility of improving reactivity by employing certain chemical coatings is also discussed.

Leger, L. J.↗