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Antarctic polymict eucrite Yamato 792769 and the cratering record on the HED parent body

Compared to most other Yamato polymict eucrites, Yamato Y792769 eucrite includes fewer and smaller eucritic clasts with homogenized pyroxenes, and its fine-grained matrix is shock-compacted and sintered. In this work, the relationships between the Antarctic eucrite Y792769, monomict eucrites, polymict eucrites, and isotopic ages are investigated, using results of Ar-39/Ar-40 method to date the time of the major thermal event on the Y792769 body and the Rb-Sr and Sm-Nd methods to determine whether relict older ages might have been preserved in some of the breccia materials. The Ar-39/Ar-40 time of the last thermal event which produced the Y792769 texture is 3.99 +/- 0.04 Ga. The complete resetting of the Ar-39/Ar-40 age is consistent with the texture of Y792769 observed in TEM, suggesting that shock compaction converted part of the matrix plagioclase to maskelynite. The Sm-Nd data give an age of 4.23 +/- 0.12 Ga, reflecting partial resetting of the Sm-Nd system during breccia formation. The 3.9 Ga Ar-39/Ar-40 age probably reflects a period of intense meteoroid bompardment which affected the entire inner solar system.

Bogard, D.↗

The thickness of eucritic crust in the HED parent body

Because cumulate eucrites are generally thought to be located at the lower part in eucritic crust on a diogenitic mantle in the HED parent body, the burial depth of cumulate eucrites gives information on the thickness of the eucritic crust. We estimated the burial depth and cooling rate of cumulate eucrites, Serra de Mage and Moore County on the basis of the width of augite lamellae and compositional gradients of Ca in pyroxenes by numerically solving the diffusion equation. We obtained the burial depth of the eucrites of 7-8 km and cooling rate of 0.00016-0.0002 degrees C/yr.

Miyamoto, M.↗

Petrology of Anomalous Eucrites

Most mafic achondrites can be broadly categorized as being "eucritic", that is, they are composed of a ferroan low-Ca clinopyroxene, high-Ca plagioclase and a silica phase. They are petrologically distinct from angritic basalts, which are composed of high-Ca, Al-Ti-rich clinopyroxene, Carich olivine, nearly pure anorthite and kirschsteinite, or from what might be called brachinitic basalts, which are composed of ferroan orthopyroxene and high-Ca clinopyroxene, intermediate-Ca plagioclase and ferroan olivine. Because of their similar mineralogy and composition, eucrite-like mafic achondrites formed on compositionally similar asteroids under similar conditions of temperature, pressure and oxygen fugacity. Some of them have distinctive isotopic compositions and petrologic characteristics that demonstrate formation on asteroids different from the parent of the HED clan (e.g., Ibitira, Northwest Africa (NWA) 011). Others show smaller oxygen isotopic distinctions but are otherwise petrologically and compositionally indistinguishable from basaltic eucrites (e.g., Pasamonte, Pecora Escarpment (PCA) 91007). The degree of uniformity in delta O-17 of eucrites and diogenites is one piece of evidence considered to favor of a magma-ocean scenario for their petrogenesis. Given that the O isotopic differences separating Pasamonte and PCA 91007 from other eucrites are small, and that there is an absence of other distinguishing characteristics, a legitimate question is: Did the HED parent asteroid fail to homogenize via a magma-ocean stage, thus explaining outliers like Pasamonte? We are initiating a program of study of anomalous eucrite-like achondrites as one part of our effort to seek a resolution of this issue. Here we present preliminary petrologic information on Asuka (A-) 881394, Elephant Moraine (EET) 87520 and EET 87542. We will have studied several more by conference time.

Mittlefehldt, D. W.↗

Petrology of Anomalous Eucrite QUE 94484

Most mafic achondrites are broadly "eucritic", being composed of ferroan low-Ca clinopyroxene, high-Ca plagioclase, a silica phase, ilmenite and accessory phases. Their characteristics indicate that eucrite-like basalts formed on asteroids of similar composition under similar petrologic conditions (T, P, fO2). Some eucrite-like basalts have isotopic compositions and petrologic characteristics consistent with formation on different parent asteroids (e.g., Ibitira, NWA 011). Others show small isotopic differences but no distinguishing petrological characteristics (e.g., Caldera, Pasamonte). We have begun a study of anomalous eucrite-like achondrites in an effort to seek resolution to the issues: Did the eucrite parent asteroid fail to homogenize via a magma-ocean stage, thus explaining outliers like Pasamonte? How many parent asteroids are represented by these basalts? Here we present preliminary petrologic information on anomalous basaltic eucrite QUE 94484.

Mittlefehldt, D. W.↗

Secondary Textures in Brecciated Basaltic Eucrite MIL 11290

Basaltic eucrites originate from the upper crust of their parent body, likely asteroid 4-Vesta. This largely intact protoplanet has undergone differentiation and therefore provides insights into early planetary processes. Radiogenic chronometers indicate rapid planetary differentiation within <10 Ma of solar system formation and a period of magmatism spanning as much as 50 million years. An extensive history of impacts prior to about 3.1 Ga significantly modified many materials derived from the eucrite parent body. Therefore, eucrites display diverse igneous to metamorphic textures formed by endogenous crustal processes and impacts. Their mineralogy is dominantly composed of plagioclase, pigeonite, and augite with minor to accessory phases including silica, ilmenite, spinel, Ca-phosphates, olivine, zircon, Ni-poor metal, and potassium feldspar. Although there are abundant achondrites originating from 4-Vesta, the geologic history of the body is not well understood. Better constraining the igneous textures and chemistry in basaltic eucrites are necessary to follow the magmatic evolution and impact history of this planetary body. This study characterizes the composition, textures, and age of a basaltic eucrite through techniques such as electron microscopy, geochemistry, and geochronology to add to our understanding of early planetary formation.

meteorite↗

Rb-Sr and Sm-Nd internal isochron ages of a subophitic basalt clast and a matrix sample from the Y75011 eucrite

Rb-Sr and Sm-Nd dating studies of the Yamato polymict eucrite Y75011, which contains several coarse-grained mesostasis-rich basaltic clasts with subophitic texture which are representative of pristine lavalike basalts extruded on the surface of the Howardite-Eucrite-Diogenite (HED) parent body, are reported. The results show that moderately evolved basaltic lavas were produced very early in the history of the HED parent body. Their preservation as clasts in the polymict eucrites suggests derivation from a different geological setting on the parent body than that occupied by the more thermally metamorphosed monomict eucrites. It is suggested that the preservation of pristine clasts in polymict eucrites may be due to their impact excavation to the surface of the parent body away from heat sources concentrated within impact craters.

Nyquist, L. E.↗

The Pasamonte unequilibrated eucrite: Pyroxene REE systematic and major-, minor-, and trace-element zoning

We are evaluating the trace-element concentrations in the pyroxenes of Pasamonte. Pasamonte is a characteristic member of the main group eucrites, and has recently been redescribed as a polymict eucrite. Our Pasamonte sample contained eucritic clasts with textures ranging from subophitic to moderately coarse-grained. This study concentrates on pyroxenes from an unequilibrated, coarse-grained eucrite clast. Major-, minor-, and trace-element analyses were measured for zoned pyroxenes in the eucritic clast of Pasamonte. The major- and minor-element zoning traverses were measured using the JEOL 733 electron probe with an Oxford-Link imaging/analysis system. Complemenatry trace elements were then measured for the core and rim of each of the grains by SIMS. The trace elements analyzed consisted of eight REE, Sr, Y, and Zr. These analyses were performed on a Cameca 4f ion probe. The results of the CI chondrite normalized (average CI trace-element analyses for several grains and the major- and minor-element zoning patterns from a single pyroxene grain are given. The Eu abundance in the cores of the pyroxenes represents the detection limit and therefore the (-Eu) anomaly is a minimum. Major- and minor-element patterns are typical for igneous zoning. Pyroxene cores are Mg enriched, whereas the rims are enriched in Fe and Ca. Also, Ti and Mn are found to increase, while Cr and Al generally decrease in core-to-rim traverses. The cores of the pyroxenes are more depleted in the Rare Earth Elements (REE) than the rims. Using the minor- and trace-element concentrations of bulk Pasamonte and the minor- and trace-element concentrations from the cores of the pyroxenes in Pasamonte measured in this study, we calculated partition coefficients between pyroxene and melt. This calculation assumes that bulk Pasamonte is representative of a melt composition.

Pun, A.↗

Ar-39 - Ar-40 Dating of Unusual Eucrite NWA-011: Is it from Vesta?

Basaltic meteorite NWA-011 is similar to eucrites in many aspects, but its oxygen isotopic composition lies far off the oxygen fractionation line defined by eucrites. It was suggested that NWA011 may have derived from a different parent body from that of eucrites, which are thought to derive from the asteroid Vesta. Some other eucrites also show small anomalous oxygen compositions. This suggests that for all eucrites to derive from Vesta, it must be compositionally inhomogeneous. Some workers have speculated whether early, large impactors on Vesta might have contributed the anomalous oxygen.

Bogard, D. D.↗

Evidence for Subsolidus Metasomatism in the Eucrite Parent Body

The eucrite parent body (4Vesta) was continuously and rapidy resurfaced by basaltic lavas that formed the non-cumulate eucrites. Ophitic and variolitic textures have been preserved even though eucrites exhibit varying degrees of equilibration based on the extent of thermal metamorphism. Types range from least metamorphosed (type 1) to most metamorphosed (type 7) based in part on the interpretation of textures and compositional zoning profiles within pigeonitic pyroxenes. To provide constraints on the source and duration of the heating event responsible for metamorphism we have investigated primary and secondary textural and compositional relations in noncumulate eucrites with emphasis on subsolidus textures developed in pyroxenes. We have studied examples of most metamorphic types including Pasamonte (type 2) Stannern (4), Nuevo Laredo (4), Juvinas (5), Lakangaon (5), Millbillillie (6), Palo Blanco Creek (7), Jonzac (7), Haraiya (7), along with the cumulate eucrites Moama and Moore County.

McCallum, I. Stewart↗

Comparisons of Mineralogy Between Cumulate Eucrites and Lunar Meteorites Possibly from the Farside Anorsothitic Crust

Anorthosites composed of nearly pure anorthite (PAN) at many locations in the farside highlands have been observed by the Kaguya multiband imager and spectral profiler [1]. Mineralogical studies of lunar meteorites of the Dhofar 489 group [2,3] and Yamato (Y-) 86032 [4], all possibly from the farside highlands, showed some aspects of the farside crust. Nyquist et al. [5] performed Sm-Nd and Ar-Ar studies of pristine ferroan anorthosites (FANs) of the returned Apollo samples and of Dhofar 908 and 489, and discussed implications for lunar crustal history. Nyquist et al. [6] reported initial results of a combined mineralogical/chronological study of the Yamato (Y-) 980318 cumulate eucrite with a conventional Sm-Nd age of 4567 24 Ma and suggested that all eucrites, including cumulate eucrites, crystallized from parental magmas within a short interval following differentiation of their parent body, and most eucrites participated in an event or events in the time interval ~4400- 4560 Ma in which many isotopic systems were partially reset. During the foregoing studies, we recognized that variations in mineralogy and chronology of lunar anorthosites are more complex than those of the crustal materials of the HED parent body. In this study, we compared the mineralogies and reflectance spectra of the cumulate eucrites, Y-980433 and 980318, to those of the Dhofar 307 lunar meteorite of the Dhofar 489 group [2]. Here we consider information from these samples to gain a better understanding of the feldspathic farside highlands and the Vesta-like body.

Takeda, H.↗

Volatile Concentrations and H-Isotope Composition of Unequilibrated Eucrites

Eucrites are among the oldest and best studied asteroidal basalts (1). They represent magmatism that occurred on their parent asteroid, likely 4-Vesta, starting at ~ 4563 Ma and continuing for approx. 30 Myr. Two hypotheses are debated for the genesis of eucrites, a magma ocean model (2), and a mantle partial melting model. In general, volatiles (H, C, F, Cl) have been ignored for eucrites and 4-Vesta, but solubility of wt% levels of H2O are possible at Vestan interior PT conditions. Targeted measurements on samples could aid our understanding considerably. Recent studies have found evidence of volatile elements in eucrites, but quantifying the abundance of volatiles remains problematic (6). Volatile elements have a disproportionately large effect on melt properties and phase stability, relative to their low abundance. The source of volatile elements can be elucidated by examining the hydrogen isotope ratio (D/H), as different H reservoirs have drastically different H isotope compositions. Recent studies of apatite in eucrites have shown that the D/H of 4-Vesta matches that of Earth and carbonaceous chondrites, however, the D/H of apatites may not represent the D/H of a primitive 4-Vesta melt due to the possibility of degassing prior to the crystallization of apatite. Therefore, the D/H of early crystallizing phases must be measured to determine if the D/H of 4-Vesta is equal to that of the Earth and carbonaceous chondrites.

Sarafian, Adam R.↗

Thermodynamic and Diffusion Model Estimates on Metamorphic Temperatures and Timescales for Basaltic Eucrite GRA 98098

Introduction: HED meteorites are thought to rep-resent igneous rocks from Vesta’s basaltic crust and preserve evidence of early crustal metamorphism. Determining the temperatures and timescales of thermal metamorphism is important for reconstructing crustal evolution in the early solar system. Here, we study basaltic eucrite Graves Nunataks (GRA) 98098, which has been identified as a highly metamorphosed eucrite [1]. We present new estimates on metamorphic temperatures determined via thermodynamic modeling as well as the initial results from diffusion models constraining timescales of thermal metamorphism. Sample Description: GRA 98098 is an unbrecciated eucrite with a granoblastic plagioclase and pyroxene mineralogy. Millimeter to cm-long lathes of tridymite cross-cut and poikilitically enclose plagioclase and pyroxene [1,this work]. Pyroxene grains have exsolved into Ca-rich (~Wo38En29Fs33) and Ca-poor (~Wo4.5En36Fs59.5) lamellae. Both unzoned and zoned plagioclase grains are observed. Unzoned plagioclase grains are found solely with tridymite laths. These grains have ~An92 compositions. The cores of the zoned plagioclase grains have the same composition and thin, relatively sodic rims (~An67), (Fig. 1). The bulk sample is unusually enriched in highly in-compatible elements and has one of the most fractionated REE patterns reported [1]. Maximum metamorphic temperatures of 985±78°C have been estimated using two-pyroxene thermometry [2]. Methods: Thermodynamic modeling. Thermodynamic models were constructed using the software Perple_X, which employs a Gibbs free energy minimization in order to determine the most stable phase assemblage for a given bulk rock composition [3]. Bulk composition was calculated using mineral com-positions acquired via EMPA (this study) and the observed abundancies present in the thin section. Two bulk compositions were estimated; 1) includes all phases present in the thin section, (assumes that all phases are present during metamorphism), 2) excludes tridymite from the bulk calculation (assumes that tridymite was not present during metamorphism). In order to determine whether metamorphic equilibria was achieved and estimate temperatures of metamorphism, we compared measured pyroxene compositions with thermodynamically predicted compositions [4, Fig. 2]. Diffusion Modeling. Several time-temperature de-pendent diffusion profiles were calculated in order to determine the best match for XAn chemical profiles observed at the edges of the zoned plagioclase (Fig. 3). We assumed that the start condition was a stepwise gradient at the plagioclase/pyroxene interface. We also assumed an average diffusion coefficient (D) and a constant temperature using the equation in [5]. D was determined for two temperatures (T = 1060ºC; near eucrite solidus [6] and T = 985ºC; metamorphism reported in [4]) and then XAn was calculated as a function of distance from plagioclase core to rim using an error function solution to Fick’s second law. Results: Thermodynamic model results are summarized in Fig. 2. For a bulk composition that includes all phases in the thin section, pyroxene endmember compositions plot in the following temperature ranges: Fs ~660-860ºC, En~1000ºC & 1150ºC, and Wo~760-900ºC (Fig. 2a). For a bulk composition that excludes tridymite from the peak metamorphic assemblage (i.e., the bulk composition minus the contribution from tridymite), a temperature range could not be determined for the Fs component of pyroxene. For Wo, T~760-900ºC and En, T~1000ºC & 1150ºC (Fig. 2b). Fig. 3 summarizes the diffusion model results. For T = 1060°C & 985°C, the most appropriate time interval was estimated based on which diffusion curve most matched (solid lines, Fig. 3) the EMPA data. For T = 1060°C, the best looking match was t = 500 ka. For T = 985°C, the best match was t = 7 Ma. Discussion and future work: Temperature estimates from thermodynamic models are not conclusive because the temperature ranges determined for pyroxene endmember stability do not overlap (colored fields in Fig. 2), thus implying that there is disequilibrium between pyroxene crystals and the bulk composition considered [4]. Thus, additional exploration is needed to define a metamorphically equilibrated do-main that accurately records peak temperature. The utility of defining metamorphically equilibrated do-mains to improve the accuracy and level of detail elucidated regarding the petrogenetic history of metamorphose samples has been demonstrated previously [4,7]. We suggest that in the case of Fig. 2a, the thin section composition is not representative of the length scales over which metamorphic equilibrium was achieve and in the case of Fig. 2b, the assumption that tridymite was not present during metamorphism was incorrect. However, results from thermodynamic models can provide insight into the relative timing of mineral and compositional textures. For example from texture alone, it is unclear whether tridymite was igneous in origin and represents the last bits of melt in a crystallizing magma chamber, or if it formed during (and possibly initiated) open system thermal metamorphism. The latter could be consistent with a partial melt hypothesis [8,9] while the former implies that simple fractional crystallization can yield the textures present in GRA 98098. The lack of coincidence be-tween pyroxene endmember compositions in Fig. 2b suggest that the bulk composition minus tridymite was not the assemblage in equilibrium with the pyroxene, suggesting that tridymite was present during metamorphism and formed during igneous crystallization. We conclude that the development of the Na-rich plagioclase rims likely occurred during or immediately after peak thermal metamorphism, because eucrites of similar metamorphic grade and texture have unzoned plagioclase (~An92) [2,4,8], and Na zoning is only observed in the plagioclase not included in the tridymite. This suggests that the zoning formed after tridymite formation, and therefore after igneous crystallization. Thus, the timescales calculated via diffusion modeling possibly represent the time interval over which thermal metamorphism occurred. Cooling rates approximated for the Vestan crust predict that the crust cooled below 300°C around 35-40 Ma after formation[10]. This is consistent with our modeling results that predict formation of the Na rich plagioclase rims occurring at higher temperatures over a period of 0.5 to 7 Ma years. Future work. Additional thermodynamic modeling work will focus on selecting an equilibrated bulk rock domain in which to elucidate metamorphic conditions. Diffusion models currently provide a minimum time-scale, since diffusion slows down as the system cools. Future work with will focus on integrating cooling into the diffusion models and constraining the depth at which thermal metamorphism occurs because it could be used to determine whether the range of time-scales calculated for thermal metamorphism are consistent with the geologic environment.

J S Gorce↗

Terrestrial Ages and Pairing of Howardites, Eucrites and Diogenites From the Miller Range Icefields, Antarctica

In the past 45 years, the US Antarctic Meteorite (ANSMET) program has recovered more than 22,000 meteorites from more than 50 individual meteorite stranding areas. Although the Antarctic meteorite collection is dominated by ordinary chondrites which represent 80-90% of the recovered samples, it also contains many achondrites, including howardites, eucrites and diogenites, which are collectively known as HED meteorites. A challenge for the Antarctic meteorite collection is to identify paired fragments that belong to the same fall. Eight ANSMET field sea-sons at the Miller Range Icefields (MIL), a series of blue ice fields about 40 km long and 10-20 km wide, have yielded more than 3000 meteorites including 56 HEDs. At least three possible pairing groups (with 3-10 members each) were initially identified among the MIL diogenites and one each among the howardites and eucrites. Since many HED meteorites are heterogeneous breccias, pairing identifications based on cm-sized samples is difficult and other independent evidence is needed to verify these proposed pairings, as was shown for several Antarctic howardite pairing-groups. Here we re-examine pairings of HED’s from the Miller Range Icefields, using multiple lines of evidence, including texture/petrography, chemical composition, cosmogenic radionuclides and find locations. Due to the heterogeneous nature of HED meteorites, we will not only consider pairings strictly among the three HED groups, but will also consider pairing of howardites with brecciated eucrites or brecciated diogenites if the cosmogenic nuclides, texture and chemical compositions support this. The concentrations of cosmogenic radionuclides in meteorites are a function of the cosmic-ray exposure (CRE) age, shielding conditions (size and irradiation depth), chemical composition, as well the terrestrial age of the meteorite sample. Since the production rates of cosmogenic nuclides as a function of meteoroid size, depth and composition are well understood [6], their measured concentrations can be used to determine which meteorites belong to the same fall even if the chemical composition of the samples show significant variations. We selected 28 of the 56 HED samples from the MIL collection, including 12 diogenites, 8 howardites and 8 brecciated eucrites to investigate pairing relationships.

howardite↗

The meteorite-asteroid connection - The infrared spectra of eucrites, shergottites, and Vesta

Infrared reflectance spectra have been obtained for the meteorites Shergotty and Allan Hills (ALHA) 77005, a unique achondrite apparently related to the shergottites. Comparisons with the reflectance spectra of eucrites and asteroid 4 Vesta indicate that the surface of Vesta is covered with eucrite-like basalts and that, if shergottite-like basalts are present on the surface of Vesta, they must be a minor rock type. The paradox that both the eucrite and shergottite parent bodies should presently exist is examined. The preferred solution is that both eucrites and shergottites are derived from Vesta, and that this asteroid is compositionally and isotopically heterogeneous; however, other possible solutions cannot be ruled out.

Feierberg, M. A.↗

Comparison of Yamato and Victoria Land polymict eucrites - A view from mineralogical and isotopic studies

New interior samples of four Yamato polymict eucrites (Y74159, Y74450, Y75011, and Y75015) have been studied by electron microprobe, transmission electron microscope, and X-ray diffraction techniques, and compared with several samples of the Victoria Land polymict eucrites. These same samples have been analysed using Rb-Sr and Nd-Sm isotopic systematics. Several grains of inverted pigeonite, with blebby augite similar to those in Binda and Moama, have been identified in all four Yamato eucrites. Coarse-grained meso-stasis-rich subophitic basalts, which contain Mg-rich pigeonite (with Fe-rich olivine veinlets) zoned outward to a subcalcic ferroaugite rims, have also been found. These unique clasts were not found in ALH76005, 77302, 78040, 7858, and 78165 and EET eucrites. The tight grouping of Rb/Sr and Sm/Nd ratos, and similar modal compositions of the Yamato group indicate that they are most likely to be pieces from a single fall, and distinct from the ALH and EET groups. However, the Yamato, Allan Hills, and Elephant Moraine groups may sample a few distinct magmas or similar but different source regions on the same parent body.

Takeda, H.↗

The polymict eucrites

Previous studies of the newly classified polymict basaltic meteorites, the polymict eucrites (PE), are reviewed to synthesize their significance in extraterrestrial volcanism investigations. The PE breccias contain mafic clasts of euritic or basalt materials in different proportions than found in howardites. Comparisons are made of the eucrite suites in PEs, howardites, eucrites, cumulative eucrites and diogenites. The PEs and the howardites are found to be part of a continuum of basaltic achondrite polymict breccia. The basaltic clasts cooled rapidly at the surface of the PEs and are accompanied by larger-cooling deep crustal materials. Some PEs are regolith breccias that have been exposed to the solar wind, which affected the rare gas contents. It is suggested that the more-than-38 specimens found in Antarctica represent only six or eight different meteorites.

Delaney, J. S.↗

Composition and origin of Nuevo Laredo Trend eucrites

The new bulk-rock analyses reported for the ALHA81001, Lakangaon and Nuevo Laredo eucritic meteorites indicate that the first of these resembles Ibitira in possessing lower Na concentrations than any other eucrite, while the other two are the lowest-Mg/Fe of all eucrites. The present data and those seen in the literature suggest that most of the ostensible Main Group eucrites actually belong to the Nuevo Laredo Trend, which is characterized by limited variations of incompatible element contents despite considerable variations in Mg/(Mg+Fe) ratio and V content.

Warren, Paul H.↗

Be-10 and Al-26 contents of eucrites - Implications for production rates and exposure ages

This paper presents the Be-10 contents of 20 and the Al-26 contents of nine eucrites. Most have Be-10 production rates between 16 and 26 dpm/kg. The average value of 21.8 dpm/kg agrees to within 10 percent with the value expected and does not support the suggestion that the eucrites received an unusually low flux of cosmic rays during the last few million years. Measured Be-10 and Al-26 contents are consistent with semiempirical calculations of nuclear production rates. The Al-26 contents provide a basis for computing shielding-corrected Ar-38 exposure ages of eucrites which show little evidence for clustering. Relatively more eucrites than diogenites are younger than 20 Ma.

Aylmer, D.↗