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Geothermal Heating, Convective Flow and Ice Thickness on Mars

Our 3D calculations suggest that hydrothermal circulation may occur in the martian regolith and may significantly thin the surface ice layer on Mars at some locations due to the upwelling of warm convecting fluids driven solely by background geothermal heating. Additional information is contained in the original extended abstract.

Rosenberg, N. D.↗

Application of remote sensing in South Dakota to provide accurate inventories of agricultural crops, enhance contrast in photographic products, monitor rangeland habitat loss, map Aspen, and prepare hydrogeologic surveys

The author has identified the following significant results. Digital analysis of LANDSAT CCT's indicated that two discrete spectral background zones occurred among the five soil zone. K-CLASS classification of corn revealed that accuracy increased when two background zones were used, compared to the classification of corn stratified by five soil zones. Selectively varying film type developer and development time produces higher contract in reprocessed imagery. Interpretation of rangeland and cropped land data from 1968 aerial photography and 1976 LANDSAT imagery indicated losses in rangeland habitat. Thermal imagery was useful in locating potential sources of sub-surface water and geothermal energy, estimating evapotranspiration, and inventorying the land.

Myers, V. I.↗

Noctis Landing: A Proposed Landing Site/Exploration Zone for Human Missions to the Surface of Mars

The proposed Noctis Landing Site/Exploration Zone (LS/EZ) is shown in Figure 1. Our preliminary study suggests that the proposed site meets all key Science and Resources (incl. Civil Engineering) requirements. The site is of significant interest, as the EZ not only offers a large number and wide range of regions of interest (ROIs) for short-term exploration, it is also located strategically at the crossroads between Tharsis and Valles Marineris, which are key for long-term exploration. The proposed site contains Regions of Interest (ROIs) that meet the following Science requirements: -­‐ Access to (1) deposits with a high preservation potential for evidence of past habitability and fossil biosignatures and (2) sites that are promising for present habitability. The site presents a wide variety of ROIs qith likely aqueous features and deposits, including sinous channels and valleys, slope gullies, lobate debris aprons, impact craters with lobate ejecta flows, and "bathtub ring" deposits. Neutron spectrometry also suggests hydrogen is present within the topmost 0.3 m or so of 4 to 10 wt% WEH (Water Equivalent Hydrogen). -­‐ Noachian and/or Hesperian rocks in a stratigraphic context that have a high likelihood of containing trapped atmospheric gases. Collapsed canyon rim material with preserved stratigraphy is abundantly present and accessible. -­‐ Exposures of at least two crustal units that have regional or global extents, that are suitable for radiometric dating, and that have relative ages that sample a significant range of martian geological time. Canyons floors in Ius Chasma, Tithonium Chasma, and plateau tops on Tharsis and in Sinai Planum offer access to distinct crustal units of regional extent. -­‐ Access to outcrops with linked morphological and/or geochemical signatures indicative of aqueous or groundwater/ mineral interactions. Iron and sulfur-bearing deposits on canyon floors in Noctis Labyrinthus, and in Ius Chasma (IC) and Tithonium Chasma (TC) offer many such outcrop options. -­‐ Identifiable stratigraphic contacts and cross-cutting relationships from which relative ages can be determined. In place and collapsed canyon walls in NL, TC, and IC offer such opportunities. -­‐ Other types of ROIs include access points to surrounding plateau top areas for longer term regional exploration. A key attribute of the proposed Noctic Landing site is its strategic location to allow the shortest possible surface excusions to Tharsis and Valles Marineris (VM). VM is the feature and region on Mars that exposes the longest record of Mars' geology and evolution through time. Tharsis is the region of Mars that has experienced the longest and most extensive volcanic history, and might still be volcanically active. Some of the youngest lava flows on Mars have been identified on the western flanks of the Tharsis Bulge, i.e., within driving range of future longrange (500 - 1000 km) pressurized rover traverses. The proposed site also contains ROIs that offer the following Resources (incl. Civil Engineering) characteristics: -­‐ Access to raw material that exhibits the potential to (1) be used as feedstock for water-generating in situ resource utilization (ISRU) processes and (2) yield significant quantities (greater than 100 MT) of water. The raw material is likely in the form of hydrated minerals, and possibly ice/regolith mix. The top of the raw material deposit is at the surface. -­‐ Access to a region where infrastructure can be emplaced or constructed. This region is less than 5 km from the LS and contains flat, stable terrain. The region exhibits evidence for an abundant source of loose regolith. Several deep pits in the area combined with the availability of sand suggests that some natural terrain features can be adapted for construction purposes. -­‐ Access to raw material that exhibits the potential to be used as metal feedstock for ISRU and construction purposes. Iron and sulfur-rich mineral surface deposits have been identified in CRISM data in many locations in this area. Noctis Landing is the lowest-altitude location on Mars that straddles both the Tharsis region (above average geothermal gradients) and Valles Marineris (minimal crustal thickness from surface (valley floor) to a subsurface liquid water table. Noctis Landing has the potential for being an ideal site for eventual deep drilling on Mars to access deep subsurface liquid water and potentially encountering extant life. Available data remains insufficient to fully qualify the Noctis Landing site. Additional remote sensing data (visible, Near and Mid-IR, and radar) and surface reconnaissance via a high-mobility robotic rover are recommended. In particular, it will be important to assess the trafficability of the site, and its potential for yielding water and metals as a resource. Access to plateau tops from the Noctis Landing site on the canyon floor should be demonstrated. Future exploration of the site would also be enhanced significantly by the availability of robotic (tele-operatable) surveying and sample-collecting drones. Testing of the use of such collaborative science and exploration technologies should be conducted at terrestrial sites such as the Haughton-Mars Project site on Devon Island, High Arctic, among others. Note: Noctis Landing is not an official Mars nomenclature name for this location. Because the area of the proposed LS/EZ had no name, and because it is close to Noctis Labyrinthus to the West while being distinct from it, the provisional name Noctis Landing is proposed. Noctis means night in Latin.

Lee, Pascal↗

Detectability of geothermal areas using Skylab X-5 data

The results are presented of a study which was undertaken to determine if data from a single near-noon pass of Skylab could be used to detect geothermal areas. The size and temperature requirements for a geothermally heated area to be seen by Skylab S-192 MSS X-5 thermal sensor were calculated. This sensor obtained thermal data with the highest spatial resolution of any nonmilitary satellite system. Only very large hot areas could be expected to be unambiguously recognized with a single data set from this instrument. The study area chosen was The Geysers geothermal field in Sonoma County, California, the only geothermal area of significant size scanned by Skylab. Unfortunately, 95% of the Skylab thermal channel data was acquired within 3 hours of local noon. For The Geysers area only daytime X-5 data were available. An analysis of the thermal channel data (10.2 to 12.5 um) revealed that ground temperatures determined by Skylab were normally distributed. No anomalous hot spots were apparent. Computer enhancement techniques were used to delineate the hottest 100 and 300 ground areas (pixel, 75 m by 75 m) within the study region. It was found that the Skylab MSS with the X-5 thermal detector does not have sufficient spatial resolution to locate unambiguously from daytime data any but the largest and hottest convectively created geothermal features, which in general are prominent enough to have been previously recognized.

Siegal, B. S.↗

Radar and infrared remote sensing of geothermal features at Pilgrim Springs, Alaska

High-altitude radar and thermal imagery collected by the NASA research aircraft WB57F were used to examine the structural setting and distribution of radiant temperatures of geothermal anomalies in the Pilgrim Springs, Alaska area. Like-polarized radar imagery with perpendicular look directions provides the best structural data for lineament analysis, although more than half the mapped lineaments are easily detectable on conventional aerial photography. Radiometer data and imagery from a thermal scanner were used to evaluate radiant surface temperatures, which ranged from 3 to 17 C. The evening imagery, which utilized density-slicing techniques, detected thermal anomalies associated with geothermal heat sources. The study indicates that high-altitude predawn thermal imagery may be able to locate relatively large areas of hot ground in site-specific studies in the vegetated Alaskan terrain. This imagery will probably not detect gentle lateral gradients.

Dean, K. G.↗

Landform Degradation and Slope Processes on Io: The Galileo View

The Galileo mission has revealed remarkable evidence of mass movement and landform degradation on Io. We recognize four major slope types observed on a number of intermediate resolution (250 m/pixel) images and several additional textures on very high resolution (10 m/pixel) images. Slopes and scarps on Io often show evidence of erosion, seen in the simplest form as alcove-carving slumps and slides at all scales. Many of the mass movement deposits on Io are probably mostly the consequence of block release and brittle slope failure. Sputtering plays no significant role. Sapping as envisioned by McCauley et al. remains viable. We speculate that alcove-lined canyons seen in one observation and lobed deposits seen along the bases of scarps in several locations may reflect the plastic deformation and 'glacial' flow of interstitial volatiles (e.g., SO2) heated by locally high geothermal energy to mobilize the volatile. The appearance of some slopes and near-slope surface textures seen in very high resolution images is consistent with erosion from sublimation-degradation. However, a suitable volatile (e.g., H2S) that can sublimate fast enough to alter Io's youthful surface has not been identified. Disaggregation from chemical decomposition of solid S2O and other polysulfur oxides may conceivably operate on Io. This mechanism could degrade landforms in a manner that resembles degradation from sublimation, and at a rate that can compete with resurfacing.

Moore, Jeffrey M.↗

Polar Lunar Regions: Exploiting Natural and Augmented Thermal Environments

In polar regions of the Moon, some areas within craters are permanently shadowed from solar illumination and can reach temperatures of 100 K or less. These regions could serve as cold traps, capturing ice and other volatile compounds. These potential ice stores have many applications for lunar exploration. Within double-shaded craters, even colder regions exist, with temperatures never exceeding 50 K in many cases. Observed temperatures suggest that these regions could enable equivalent liquid nitrogen cryogenic functions. These permanently shaded polar craters also offer unprecedented high-vacuum cryogenic environments, which in their current state could support cryogenic applications. Besides ice stores, the unique conditions at the lunar poles harbor an environment that provides an opportunity to reduce the power, weight, and total mass that needs to be carried from the Earth to the Moon for lunar exploration and research. Reducing the heat flux of geothermal, black body radiation can have significant impacts on the achievable temperature. With a few manmade augmentations, permanently shaded craters located near the lunar poles achieve temperatures even lower than those that naturally exist. Our analysis reveals that lightweight thermal shielding within shaded craters could create an environment several Kelvin above absolute zero. The temperature ranges of both naturally shaded and thermally augmented craters could enable the long-term storage of most gases, low-temperature superconductors for large magnetic fields, devices and advanced high-speed computing instruments. Augmenting thermal conditions in these craters could then be used as a basis for the development of an advanced thermal management architecture that would support a wide variety of cryogenically based applications. Lunar exploration and habitation capabilities would significantly benefit if permanently shaded craters, augmented with thermal shielding, were used to facilitate the operation of near absolute zero instruments, including a wide variety of cryogenically based propulsion, energy, communication, sensing, and computing devices. The required burden of carrying massive life-supporting components from the Earth to the Moon for lunar exploration and research potentially could be reduced.

Ryan, Robert E.↗

The Lawrence Berkeley Laboratory geothermal program in northern Nevada

The Lawrence Berkeley Laboratory's geothermal program began with consideration of regions where fluids in the temperature range of 150 to 230 C may be economically accessible. Three valleys, located in an area of high regional heat flow in north central Nevada, were selected for geological, geophysical, and geochemical field studies. The objective of these ongoing field activities is to select a site for a 10-MW demonstration plant. Field activities (which started in September 1973) are described. A parallel effort has been directed toward the conceptual design of a 10-MW isobutane binary plant which is planned for construction at the selected site. Design details of the plant are described. Project schedule with milestones is shown together with a cost summary of the project.

Mirk, K. F.↗

Icelandic geothermal activity and the mercury of the Greenland icecap.

Aerometric studies concerning the level of atmospheric mercury were conducted at a number of sites in Iceland during June and July 1972. Samples from widely separated locations yielded Hg concentrations well above the range commonly cited for unpolluted air. Atmospheric mercury may be introduced in part by degassing fluid magmas. However, the release from fine ash could also serve as a vehicle. It is pointed out that from the mid-17th century to the present, Iceland has recorded nearly 50 volcanic eruptions.

Siegel, B. Z.↗

Structural and lithologic study of northern coast ranges and Sacramento Valley, California

The author has identified the following significant results. Analysis of ERTS-1 imagery of the Northern California Coast Ranges has disclosed a potential relation between a heretofore unrecognized fracture system and known deposits of mercury and geothermally active areas in the Coast Range and between oil and gas fields in the Sacramento Valley. Three potentially important systems of linear elements within the Coast Ranges, detected on ERTS-1 imagery, may represent fault systems or zones of shearing because topographic offset and stratigraph disruption can be seen along one or two of the lineations. One of the systems in subparallel to the San Andreas fault and is confined to the Pacific Coastal Belt. Another set is confined to the central core of the Coast Ranges. The third set of linear features (Valley System) has not heretofore been recognized. Some of the known mercury deposits and geothermally active areas near Clear Lake, in the Coast Ranges, are along the Valley System or at the intersection of the Central and Valley Systems. The plotted locations of some of the oil and gas fields in the Sacramento Valley are associated with the Valley and/or Central Systems. If these relations prove reliable, the ERTS-1 imagery may prove to be an extremely useful exploration tool.

Rich, E. I.↗

Geophysical investigations of a geothermal anomaly at Wadi Ghadir, eastern Egypt

During regional heat flow studies a geothermal anomaly was discovered approximately 2 km from the Red Sea coast at Wadi Ghadir, in the Red Sea Hills of Eastern Egypt. A temperature gradient of 55 C/km was measured in a 150 m drillhole at this location, indicating a heat flow of approximately 175 mw/sqm, approximately four times the regional background heat flow for Egypt. Gravity and magnetic data were collected along Wadi Ghadir, and combined with offshore gravity data, to investigate the source of the thermal anomaly. Magnetic anomalies in the profile do not coincide with the thermal anomaly, but were observed to correlate with outcrops of basic rocks. Other regional heat flow and gravity data indicate that the transition from continental to oceanic type lithosphere occurs close to the Red Sea margin, and that the regional thermal anomaly is possibly related to the formation of the Red Sea.

Morgan, P.↗

The distribution of ground ice on Mars

A wealth of geologic evidence indicates that subsurface water ice has played an important role in the evolution of Martian landforms. Theoretical models of the stability of ground ice show that in the near-surface regolith ice is currently stable at latitudes poleward of about +/- 40 deg and below a depth of a few centimeters to a meter, with some variations with longitude. If ice is not previously present at a particular location where it is stable, atmospheric water will diffuse into the regolith and condense as ice, driven by the annual subsurface thermal oscillations. The lower boundary of this ice deposit is found to occur at a depth (typically a few meters) where the annual thermal oscillations give way to the geothermal gradient. In the equatorial regions near-surface ice is currently not stable, resulting in the sublimation of any existing ice and subsequent loss to the atmosphere. However, subliming ice might be maintained at a steady-state depth, where diffusion and loss to the atmosphere are balanced by resupply from a possible deeper source of water (either deeper, not yet depleted, ice deposits or ground water). This depth is typically a few tens to hundreds of meters and depends primarily on the surface temperature and the nature of the geothermal gradient, being deeper for a higher surface temperature and a lower geothermal gradient. Such an equatorial deposit is characterized by the regolith ice content being low nearer the surface and increasing with depth in the deposit. Oscillations in the orbit will affect this picture of ground ice in two ways: by causing periodic changes in the pattern of near-surface stability and by producing subsurface thermal waves that may be capable of driving water ice deeper into the regolith.

Mellon, M. T.↗

First Results of the Expedition to the Highest Lake on Earth: Studying a Martian Paleolake in Bolivia and the Survival Strategies Developed by Living Organisms

Between October 16th and November 9th 2002, the first NASA Ames DDF Licancabur multidisciplinary expedition initiated the investigation of the biology and environment for life in the highest lake on Earth located at the summit of the Licancabur volcano (6017 m/20,056 ft) at the boundary of Chile and Bolivia. The low oxygen, low atmospheric pressure, high-UV radiation, average temperature, volcano-tectonic and hydrothermal environment make the site a close analog to Martian paleolakes 3.5 billion years ago. The overall goal of the project is to understand through a series of high altitude scientific expeditions what strategies life is using to defend itself against killer-level UV radiation and environmental extreme conditions at this altitude. Several other lakes are located at 4300 m at the foot of the Licancabur volcano (hereafter named laguna Blanca and Laguna Verde). They were also investigated using identical experiments and methods as for the summit lake in order to compare the results and better understand the evolution of survival strategies at transitioning elevations. The lagunas are geothermally heated and many springs provide water at various temperatures. Sources of heat are also suspected for the summit lake as its surface water temperature was measured during the successful ascent at +6 C in a -9 C ambient crater environment (with a wind chill factor of -25 C with a wind blowing almost constantly). Results of this project are expected to provide critical keys to help searching and identifying potential sites for life (extant/extinct) on Mars and developing instruments, experiments and technologies for future missions.

Cabrol, N. A.↗

Attempt at correlating Italian long lineaments from LANDSAT-1 satellite images with some geological phenomena. Possible use in geothermal energy research

By utilizing the images from the LANDSAT-1, in the spectral band 0.8-1.1 microns (near infrared), a photomosaic was obtained of Italian territory. From this mosaic the field of long lineaments was drawn, corresponding to fractures of the earth crust more than 100 km long. The relationship between lineaments, hot springs, volcanic areas, and earthquake epicenters is verified. There is a clear connection between long lineaments and hot springs: 78% of the springs are located on one or more lineaments, and the existence of hot lineaments was observed. A slightly weaker, but still significant, connection exists between the Pliocene-Quaternary volcanic areas and long lineaments. The relationship between earthquakes and long lineaments can only be verified in some cases. The lineaments which can be related to earthquakes have little or no connection with the other phenomena.

Barbier, E.↗

Heat flow and thermal processes in the Jornada delMuerto, New Mexico

Most heat flow data in rifts are uncertain largely because of hydrologic disturbances in regions of extensive fracturing. Estimates of heat flow in deep petroleum tests within a large basin of the Rio Grande rift, which has suffered little syn-rift fracturing, may begin to provide clearer insight into the relationships between high heat flow and crustal thinning processes. The Jornada del Muerto is a large basin located in the Rio Grande rift of south central New Mexico. The region of interest within the Jornada del Muerto is centered about 30 km east of the town of Truth or Consequences, and is approximately 60 km north-south by 30 km east-west. High heat flows are estimated for the region. Values increase from about 90 mWm(-2) in the northern part of the study area to about 125 mWm(-2) in the southern part. These high heat flows are rather enigmatic because in the immediate vicinities of the sites there is little evidence of Cenozoic volcanism or syn-rift extensional tectonics. It is suggested that the geothermal anomaly in the southern Jornada del Muerto (approx. 125 to approx. 95 mWm(-2) results from some type of mass movement-heat transfer mechanism operating in the crust just below the elastic layer. This conclusion is consistent with the geologic and geophysical data which describe a thin crust, apparently devoid of features indicative of extensional-tectonics in the upper part of the lastic crust.

Reiter, M.↗

Ultramafic Terranes and Associated Springs as Analogs for Mars and Early Earth

Putative extinct or extant Martian organisms, like their terrestrial counterparts, must adopt metabolic strategies based on the environments in which they live. In order for organisms to derive metabolic energy from the natural environment (Martian or terrestrial), a state of thermodynamic disequilibrium must exist. The most widespread environment of chemical disequilibrium on present-day Earth results from the interaction of mafic rocks of the ocean crust with liquid water. Such environments were even more pervasive and important on the Archean Earth due to increased geothermal heat flow and the absence of widespread continental crust formation. The composition of the lower crust and upper mantle of the Earth is essentially the-same as that of Mars, and the early histories of these two planets are similar. It follows that a knowledge of the mineralogy, water-rock chemistry and microbial ecology of Earth's oceanic crust could be of great value in devising a search strategy for evidence of past or present life on Mars. In some tectonic regimes, cross-sections of lower oceanic crust and upper mantle are exposed on land as so-called "ophiolite suites." Such is the case in the state of California (USA) as a result of its location adjacent to active plate margins. These mafic and ultramafic rocks contain numerous springs that offer an easily accessible field laboratory for studying water/rock interactions and the microbial communities that are supported by the resulting geochemical energy. A preliminary screen of Archaean biodiversity was conducted in a cold spring located in a presently serpentinizing ultramafic terrane. PCR and phylogenetic analysis of partial 16s rRNA, sequences were performed on water and sediment samples. Archaea of recent phylogenetic origin were detected with sequences nearly identical to those of organisms living in ultra-high pH lakes of Africa.

Blake, David↗

The Origin of Carbon-bearing Volatiles in Surprise Valley Hot Springs in the Great Basin: Carbon Isotope aud Water Chemistry Characterizations

There are numerous hydrothermal fields within the Great Basin of North America, some of which have been exploited for geothermal resources. With methane and other carbon-bearing compounds being observed, in some cases with high concentrations, however, their origins and formation conditions remain unknown. Thus, studying hydrothermal springs in this area provides us an opportunity to expand our knowledge of subsurface (bio)chemical processes that generate organic compounds in hydrothermal systems, and aid in future development and exploration of potential energy resources as well. While isotope measurement has long been used for recognition of their origins, there are several secondary processes that may generate variations in isotopic compositions: oxidation, re-equilibration of methane and other alkanes with CO2, mixing with compounds of other sources, etc. Therefore, in addition to isotopic analysis, other evidence, including water chemistry and rock compositions, are necessary to identify volatile compounds of different sources. Surprise Valley Hot Springs (SVHS, 41º32'N, 120º5'W), located in a typical basin and range province valley in northeastern California, is a terrestrial hydrothermal spring system of the Great Basin. Previous geophysical studies indicated the presence of clay-rich volcanic and sedimentary rocks of Tertiary age beneath the lava flows in late Tertiary and Quaternary. Water and gas samples were collected for a variety of chemical and isotope composition analyses, including in-situ pH, alkalinity, conductivity, oxidation reduction potential (ORP), major and trace elements, and C and H isotope measurements. Fluids issuing from SVHS can be classified as Na-(Cl)-SO4 type, with the major cation and anion being Na+ and SO4 2-, respectively. Thermodynamic calculation using ORP and major element data indicated that sulfate is the most dominant sulfur species, which is consistent with anion analysis results. Aquifer temperatures at depth estimated by both dissolved SiO2 and Na-K-Ca geothermometers are in the range of 125.0 to 135.4 oC, and higher than the values measured at orifices (77.3 to 90.0 oC). CO2 and homologs of straight chain alkanes (C1-C5) were identified in gas samples. Carbon isotope values of alkanes increase with carbon numbers. The 13C fractionation between CO2 and dissolved inorganic carbon suggests they are out of carbon isotope equilibrium. The hypothesis regarding the formation of carbon-bearing compounds in SVHS may involve two processes: 1) Under high heat flow conditions which are caused by regional faulting and crustal extension, original high molecular weight organic compounds (kerogens) in clay-rich rocks decomposed to generate methane and other alkane homologs. 2) The SVHS area is associated with outflow structures, and distant from the heat source. Anaerobic oxidation of methane (AOM) with sulfate at shallow depth (< 90 oC) is suggested as being responsible for the generation of CO2 in SVHS.

Fu, Qi↗

The Origin of Carbon-bearing Volatiles in Surprise Valley Hot Springs in the Great Basin: Carbon Isotope and Water Chemistry Characterizations

There are numerous hydrothermal fields within the Great Basin of North America, some of which have been exploited for geothermal resources. With methane and other carbon-bearing compounds being observed, in some cases with high concentrations, however, their origins and formation conditions remain unknown. Thus, studying hydrothermal springs in this area provides us an opportunity to expand our knowledge of subsurface (bio)chemical processes that generate organic compounds in hydrothermal systems, and aid in future development and exploration of potential energy resources as well. While isotope measurement has long been used for recognition of their origins, there are several secondary processes that may generate variations in isotopic compositions: oxidation, re-equilibration of methane and other alkanes with CO2, mixing with compounds of other sources, etc. Therefore, in addition to isotopic analysis, other evidence, including water chemistry and rock compositions, are necessary to identify volatile compounds of different sources. Surprise Valley Hot Springs (SVHS, 41 deg 32'N, 120 deg 5'W), located in a typical basin and range province valley in northeastern California, is a terrestrial hydrothermal spring system of the Great Basin. Previous geophysical studies indicated the presence of clay-rich volcanic and sedimentary rocks of Tertiary age beneath the lava flows in late Tertiary and Quaternary. Water and gas samples were collected for a variety of chemical and isotope composition analyses, including in-situ pH, alkalinity, conductivity, oxidation reduction potential (ORP), major and trace elements, and C and H isotope measurements. Fluids issuing from SVHS can be classified as Na-(Cl)-SO4 type, with the major cation and anion being Na+ and SO4(2-), respectively. Thermodynamic calculation using ORP and major element data indicated that sulfate is the most dominant sulfur species, which is consistent with anion analysis results. Aquifer temperatures at depth estimated by both dissolved SiO2 and Na-K-Ca geothermometers are in the range of 125.0 to 135.4 C, and higher than the values measured at orifices (77.3 to 90.0 C). CO2 and homologs of straight chain alkanes (C1-C5) were identified in gas samples. Carbon isotope values of alkanes increase with carbon numbers. The C-13 fractionation between CO2 and dissolved inorganic carbon suggests they are out of carbon isotope equilibrium. The hypothesis regarding the formation of carbon-bearing compounds in SVHS may involve two processes: 1) Under high heat flow conditions which are caused by regional faulting and crustal extension, original high molecular weight organic compounds (kerogens) in clay-rich rocks decomposed to generate methane and other alkane homologs. 2) The SVHS area is associated with outflow structures, and distant from the heat source. Anaerobic oxidation of methane (AOM) with sulfate at shallow depth (< 90 C) is suggested as being responsible for the generation of CO2 in SVHS.

Fu, Qi↗