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At least 37 records · Page 2

High-temperature thermodynamics.

High temperature thermodynamics requiring species and phases identification, crystal structures, molecular geometries and vibrational, rotational and electronic energy levels and equilibrium constants

Margrave, J. L.↗

Absorption of a laser light pulse in a dense plasma.

An experimental study of the absorption of a laser light pulse in a transient, high-density, high-temperature plasma is presented. The plasma is generated around a metallic anode tip by a fast capacitive discharge occurring in vacuum. The amount of transmitted light is measured for plasmas made of different metallic ions in the regions of the discharge of high electronic density. Variation of the transmission during the laser pulse is also recorded. Plasma electrons are considered responsible for the very high absorption observed.

Mehlman-Balloffet, G.↗

High-temperature mass spectrometry - Vaporization of group 4-B metal carbides

The high temperature vaporization of the metal-carbon systems TiC, ZrC, HfC, and ThC was studied by the Knudsen effusion - mass spectrometric method. For each system the metal dicarbide and tetracarbide molecular species were identified in the gas phase. Relative ion currents of the carbides and metals were measured as a function of temperature. Second- and third-law methods were used to determine enthalpies. Maximum values were established for the dissociation energies of the metal monocarbide molecules TiC, ZrC, HfC, and ThC. Thermodynamic functions used in the calculations are discussed in terms of assumed molecular structures and electronic contributions to the partition functions. The trends shown by the dissociation energies of the carbides of Group 4B are compared with those of neighboring groups and discussed in relation to the corresponding oxides and chemical bonding. The high temperature molecular beam inlet system and double focusing mass spectrometer are described.

Stearns, C. A.↗

Temperature, stress, and annealing effects on the luminescence from electron-irradiated silicon

Low-temperature photoluminescence spectra are presented for Si crystals which have been irradiated with high-energy electrons. Studies of isochronal annealing, stress effects, and the temperature dependences of the luminescence are used to discuss the nature of the luminescent transitions and the properties of defects. Two dominant bands present after room-temperature anneal of irradiated material are discussed, and correlations of the properties of these bands are made with known Si defects. A band between 0.8 and 1.0 eV has properties which are related to those of the divacancy, and a band between 0.6 and 0.8 eV has properties related to those of the Si-G15(K) center. Additional peaks appear in the luminescence after high-temperature anneal; the influence of impurities and the effects of annealing of these lines are discussed.

Jones, C. E.↗

The NATA code: Theory and analysis, volume 1

A computer program for calculating quasi-one-dimensional gas flow in axisymmetric and two-dimensional nozzles and rectangular channels is presented. Flow is assumed to start from a state of thermochemical equilibrium at a high temperature in an upstream reservoir. The program provides solutions based on frozen chemistry, chemical equilibrium, and nonequilibrium flow with finite reaction rates. Electronic nonequilibrium effects can be included using a two-temperature model. An approximate laminar boundary layer calculation is given for the shear and heat flux on the nozzle wall. Boundary layer displacement effects on the inviscid flow are considered also. Chemical equilibrium and transport property calculations are provided by subroutines. The code contains precoded thermochemical, chemical kinetic, and transport cross section data for high-temperature air, CO2-N2-Ar mixtures, helium, and argon. It provides calculations of the stagnation conditions on axisymmetric or two-dimensional models, and of the conditions on the flat surface of a blunt wedge. The primary purpose of the code is to describe the flow conditions and test conditions in electric arc heated wind tunnels.

Bade, W. L.↗

A review of chromium, molybdenum, and tungsten alloys

The mechanical properties of chromium, molybdenum, and tungsten alloys are reviewed with particular emphasis on high-temperature strength and low-temperature ductility. Precipitate strengthening is highly effective at 0.4 to 0.8 times the melting temperature in these metals, with HfC being most effective in tungsten and molybdenum, and Ta(B,C) most effective in chromium. Low-temperature ductility can be improved by alloying to promote rhenium ductilizing or solution softening. The low-temperature mechanical properties of these alloys appear related to electronic interactions rather than to the usual metallurgical considerations.

Klopp, W. D.↗

An upper limit on interstellar C IV in the spectrum of gamma-2 Velorum

An upper limit on the column density of C IV along the line of sight to gamma-2 Vel is derived from upper limits placed on the equivalent widths of the interstellar C IV doublet with rest wavelengths at 1548.20 A and 1550.77 A. A lower limit of 250,000 K is calculated for the electron temperature of O VI emitting regions by combining the C IV results with a measurement of the column density of interstellar O VI for the same star and using calculations for the relative ionization of some abundant elements as a function of electron temperature in a low-density plasma. Since gamma-2 Vel is in the central part of the Gum Nebula, the high temperature suggested by these results is shown to support the idea that a high-temperature phase of the interstellar medium, possibly maintained by supernova explosions, may exist.-

Lengyel-Frey, D.↗

Iron line emission from a high-temperature plasma in Cassiopeia A

The letter reports a measurement of the X-ray spectrum of Cas A with a proportional counter on board OSO-8. The high-energy data (greater than 7 keV) are found to agree equally well with a power law having a number index of about 4.5 and with a thermal spectrum having kT of about 3.9 keV. A narrow iron line predicted by the thermal model is also observed; this line is centered at about 6.67 keV and has an equivalent width of approximately 1270 eV. The low-energy data (below 6 keV) are not fully accounted for by the above thermal spectrum, but are fitted well by an additional low-temperature thermal component with kT not exceeding 0.7 keV and an atomic hydrogen column density of approximately 10 to the 22nd power per sq cm. The iron abundance in the plasma at an electron temperature of 40 keV is estimated from the observed line-to-continuum ratio, and it is shown that a normal cosmic iron abundance is adequate to explain the observation.

Pravdo, S. H.↗

A high-temperature wideband pressure transducer

A condenser microphone AM carrier system, which has been developed to measure pressure fluctuations at elevated temperatures, consists of the following components: a condenser microphone designed for operation at elevated temperatures; existing carrier electronics developed under two previous research grants but adapted to meet present requirements; a 6 m cable operating as a half-wavelength transmission line between the microphone and carrier electronics; and a voltage-controlled oscillator used in a feedback loop for automatic tuning control. Both theoretical and practical aspects of the development program are considered. The three predominant effects of temperature changes are changes in the membrane-backplate gap, membrane tension, and air viscosity. The microphone is designed so that changes in gap and membrane tension tend to have compensating effects upon the microphone sensitivity.

Zuckerwar, A. J.↗

Is the common definition of the Mie-Grueneisen equation of state inconsistent

Anharmonic models are used to describe the high temperatures and the electronic effects characteristic of shock wave phenomena and planetary interiors. It is found that a generalized Grueneisen function dependent on temperature and volume is necessary for the self-consistent application of the Mie-Grueneisen equation at the physical conditions encountered in shock wave phenomena or in the interior of planets. It is noted that at temperatures of a few thousand degrees Kelvin, by deriving the function in terms of anharmonic lattice dynamics, the difference between gamma and gamma(th) is of the same order of a magnitude as gamma. This leads to the conclusions that (1) gamma is not a function of temperature and (2) gamma?gamma(th) does not explain either the equation of state of planetary interiors or high-temperature shock wave phenomena.

Mulargia, F.↗

Multiple loop activations and continuous energy release in the solar flare of June 15, 1973

The spatial and temporal evolution of the high-temperature plasma in the solar flare of June 15, 1973, is studied using XUV spectroheliograms and X-ray filtergrams obtained from Skylab. The analysis focuses on the changing forms and brightness of Fe XXIII 263-A and Fe XXIV 255-A images. Temperatures and emission measures computed for different times during the flare are compared with those derived from Solrad-9 flux data, the electron temperature in the bright compact core of the Fe XXIV image is determined, and a coronal origin is suggested for this bright core. The observational evidence shows that the overall flare event involved a number of different preexisting loops and arches which were activated in succession. The activation and heating are found to have persisted well past the end of the burst phase, implying that the energy release did not end when the impulsive phase was over. The overall development of the flare is summarized on the basis of the observed order of appearance of the loops.

Widing, K. G.↗

Helium /3/ rich solar flares

Several aspects of a solar flare model that emphasizes evidence for the formation of current filaments as mechanisms of field dissipation are discussed. The origin of flare magnetic fields is considered, along with the thermal distribution, electron density, and high-energy X ray emission of flares. It is suggested that the extreme He-3 enrichment in some solar flares is due to spallation and the subsequent confinement of spallation products in a high-temperature high-density plasma associated with the magnetic instability that produces the flare. A current filament is assumed to produce the spallation and maintain the temperature that yields the high-energy X-ray spectrum and depletes the isotopes D, Li, Be, and B, as observed.

Colgate, S. A.↗

X-15 conditioning and pressurization system

The cooling system for the X-15 airplane incorporates insulation partial protection against high-temperature effects plus liquid and gaseous nitrogen to control specifically environmental and equipment temperatures. Electronic-equipment cooling represents the largest load; however, other items to be considered are the pressure-suit ventilation, aerodynamic-heating effects, sensor-head cooling, and windshield antifogging. A review of various types of cooling systems indicates that an expendable, stored, cooling system is the most efficient for short-duration missions. This paper presents a description including a simplified schematic diagram of the subject system. (author)

Bouman, C P↗

Characterization of Ternary NiTiPt High-Temperature Shape Memory Alloys

Pt additions substituted for Ni in NiTi alloys are known to increase the transformation temperature of the alloy but only at fairly high Pt levels. However, until now only ternary compositions with a very specific stoichiometry, Ni50-xPtxTi50, have been investigated and then only to very limited extent. In order to learn about this potential high-temperature shape memory alloy system, a series of over twenty alloys along and on either side of a line of constant stoichiometry between NiTi and TiPt were arc melted, homogenized, and characterized in terms of their microstructure, transformation temperatures, and hardness. The resulting microstructures were examined by scanning electron microscopy and the phase compositions quantified by energy dispersive spectroscopy."Stoichiometric" compositions along a line of constant stoichiometry between NiTi to TiPt were essentially single phase but by any deviations from a stoichiometry of (Ni,Pt)50Ti50 resulted in the presence of at least two different intermetallic phases, depending on the overall composition of the alloy. Essentially all alloys, whether single or two-phase, still under went a martensitic transformation. It was found that the transformation temperatures were depressed with initial Pt additions but at levels greater than 10 at.% the transformation temperature increased linearly with Pt content. Also, the transformation temperatures were relatively insensitive to alloy stoichiometry within the range of alloys examined. Finally, the dependence of hardness on Pt content for a series of Ni50-xPtxTi50 alloys showed solution softening at low Pt levels, while hardening was observed in ternary alloys containing more than about 10 at.% Pt. On either side of these "stoichiometric" compositions, hardness was also found to increase significantly.

Rios, Orlando↗