Electron Scattering by Hydrogen Molecules at 10 Ev with Excitation of Nuclear Motion
Born approximation to calculate electron scattering by hydrogen molecules
Kuppermann, A.↗
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Reaction of hydrogen atomic ions with hydrogen molecules - Experiment, ab initio theory and a conceptual model
Ab initio calculations on trajectories and nonadiabatic transitions in reactions of hydrogen atomic ions with hydrogen molecules
Krenos, J.↗
Hydrogen molecules in interstellar space
The most important results obtained from Copernicus satellite observations of ultraviolet H2 absorption features are summarized. The properties of the hydrogen molecule are described along with the radiative processes in which it can be involved. Techniques and equipment used in observing H2 absorption features from space are reviewed. The results are discussed in terms of the fraction of hydrogen in molecular form, rotational excitation of H2, physical conditions within interstellar gas clouds, and approaching clouds characterized by high excitation and negative radial velocity. It is shown that: (1) an appreciable fraction of the hydrogen in denser and thicker clouds is molecular, (2) at least some of the interstellar clouds are far from pressure equilibrium, (3) the approaching clouds are apparently dense thick sheets moving toward the sun as viewed in the local standard of rest, (4) these clouds are probably shock waves produced in the interstellar gas by old supernova remnants or expanding H II regions, and (5) the abundances relative to H of such elements as O, Mg, Si, and Cl in these clouds are nearly equal to the solar values, which is in contrast to the depletions observed in many other interstellar clouds.
Spitzer, L.↗
Intermediate energy proton stopping power for hydrogen molecules and monoatomic helium gas
Stopping power in the intermediate energy region (100 keV to 1 MeV) was investigated, based on the work of Lindhard and Winther, and on the local plasma model. The theory is applied to calculate stopping power of hydrogen molecules and helium gas for protons of energy ranging from 100 keV to 2.5 MeV. Agreement with the experimental data is found to be within 10 percent.
Xu, Y. J.↗
Intermediate energy proton stopping power for hydrogen molecules and monoatomic helium gas
Stopping power in the intermediate energy region (100 keV to 1 MeV) was investigated, based on the work of Lindhard and Winther, and on the local plasma model. The theory is applied to calculate stopping power of hydrogen molecules and helium gas for protons of energy ranging from 100 keV to 2.5 MeV. Agreement with the experimental data is found to be within 10 percent. Previously announced in STAR as N84-16955
Xu, Y. J.↗
Differential cross section for the reactive scattering of deuterium atoms by hydrogen molecules - Cross sections for the excitation of Na/3 2P/ by collisions with internally excited molecular hydrogen, deuterium and nitrogen
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Krause, H. F.↗
Hydrogen molecules and chains in a superstrong magnetic field
The electronic structures of hydrogen polymolecules H(n) (n = 2,3,4,...) is studied in a superstrong magnetic field (B greater than about 10 exp 12 G) typically found on the surface of a neutron star. Simple analytical scaling relations for several limiting cases (e.g., large n, high B field) are derived. The binding energies of H(n) molecules are numerically calculated for various magnetic-field strengths. For a given magnetic-field strength, the binding energy per atom in the H(n) molecules is found to approach a constant value as n increases. For typical field strengths of interest, energy saturation is essentially achieved once n exceeds 3 to 4. Also considered is the structure of negative H ions in a high magnetic field. For B about 10 exp 12 G, the dissociation energy of an atom in a hydrogen chain and the ionization potential of H(-) are smaller than the ionization potential of neutral atomic hydrogen.
Lai, Dong↗
Abundance of metastable hydrogen molecules in the interstellar medium.
Equilibrium population of ground and metastable states of molecular hydrogen in interstellar medium
HYDROGEN↗
Red Fluorescent Line Emission from Hydrogen Molecules in Diffuse Molecular Clouds
We have modeled the fluorescent pumping of electronic and vibrational emissions of molecular hydrogen (H2) within diffuse molecular clouds that are illuminated by ultraviolet continuum radiation. Fluorescent line intensities are predicted for transitions at ultraviolet, infrared, and red visible wavelengths as functions of the gas density, the visual extinction through the cloud, and the intensity of the incident UV continuum radiation. The observed intensity in each fluorescent transition is roughly proportional to the integrated rate of H2 photodissociation along the line of sight. Although the most luminous fluorescent emissions detectable from ground-based observatories lie at near-infrared wavelengths, we argue that the lower sky brightness at visible wavelengths makes the red fluorescent transitions a particularly sensitive probe. Fabry-Perot spectrographs of the type that have been designed to observe very faint diffuse Ha emissions are soon expected to yield sensitivities that will be adequate to detect H2 vibrational emissions from molecular clouds that are exposed to ultraviolet radiation no stronger than the mean radiation field within the Galaxy. Observations of red H2 fluorescent emission together with cospatial 21 cm H I observations could serve as a valuable probe of the gas density in diffuse molecular clouds.
Neufeld, David A.↗
Stripping in collisions between hydrogen molecules below 500 eV.
Measurement of the cross section of stripping the mass 2 and 4 isotopes from molecular hydrogen in their parent gases at kinetic energies between 50 and 500 eV. The angular dependence of the ions is found to be highly peaked in the forward direction, at energies above 100 eV. Plotted vs incident velocity, the cross sections for H2 and D2 approached the same value at the highest velocities and did diverge toward lower velocities. The behavior of the cross sections is found to be consistent with a theoretical model suggested by Demkov and Komarov (1968).
Peterson, R. K.↗
Collision integrals for isotopic hydrogen molecules.
The study was undertaken to determine the effects of reduced mass and differences in asymmetry on the collision integrals and thermal diffusion factors of isotopic hydrogen systems. Each system selected for study consisted of two diatoms, one in the j = 0 rotation state and the other in the j = 1 state. The molecules interacted with a Lennard-Jones type potential modified to include angular terms. A set of cross sections and collision integrals were obtained for each system.
Brown, N. J.↗
Electrostatic Hellmann-Feynman theorem applied to long-range interatomic forces - The hydrogen molecule.
The use of the electrostatic Hellmann-Feynman theorem for the calculation of the leading term in the 1/R expansion of the force of interaction between two well-separated hydrogen atoms is discussed. Previous work has suggested that whereas this term is determined wholly by the first-order wavefunction when calculated by perturbation theory, the use of the Hellmann-Feynman theorem apparently requires the wavefunction through second order. It is shown how the two results may be reconciled and that the Hellmann-Feynman theorem may be reformulated in such a way that only the first-order wavefunction is required.
Steiner, E.↗
Accurate perturbation-variation treatment of the hydrogen molecule.
Rayleigh-Schroedinger perturbation-variation treatment of electron repulsion in H molecule ground state to determine energies, noting series convergence
Brown, W. B.↗
Photo-ionization of the hydrogen molecule.
H molecule photoionization, using one center wave function with polarized orbital approximation to obtain oscillator strengths in 700 to 300 angstrom range
Khare, S. P.↗
Detection of energetic hydrogen molecules in Jupiter's magnetosphere by Voyager 2 - Evidence for an ionospheric plasma source
The discovery of energetic (approximately 1 MeV/nuc) H3 and H2 molecules in Jupiter's magnetosphere is reported. The data, obtained with the LECP instrument on Voyager 2, showed these molecules to be present throughout the magnetosphere and as far as 180 Jupiter radii from the planet, in the 'magnetospheric wind' region. Although the relative abundances of H3 and H2 do not show a monotonic trend with distance from Jupiter, the intervals of highest abundance were found in the outer magnetosphere. As an example, in the radial range 51-56 Jupiter radii, of the dayside magnetosphere, the abundances of H3 and H2 (0.60-0.95 MeV/nuc) were about 20 and 13-25% that of He, respectively, and the He abundance was about 1-2% that of H. Since H3(+) is expected to be an important constituent of Jupiter's ionosphere, the data provide strong evidence that, in addition to Io, the ionosphere may be an important local plasma source for the Jovian energetic particles. The measurements reported may represent the first detection in nature of molecules at energies as high as 1 MeV/nucleon.
Hamilton, D. C.↗
A theoretical prediction of hydrogen molecule dissociation-recombination rates including an accurate treatment of internal state nonequilibrium effects
The dissociation and recombination of H2 over the temperature range 1000-5000 K are calculated in a nonempirical manner. The computation procedure involves the calculation of the state-to-state energy transfer rate coefficients, the solution of the 349 coupled equations which form the master equation, and the determination of the phenomenological rate coefficients. The nonempirical results presented here are in good agreement with experimental data at 1000 and 3000 K.
Schwenke, David W.↗
Radiative shocks and hydrogen molecules in pregalactic gas - The effects of postshock radiation
Previous calculations of radiative shocks in pregalactic gas are generalized and substantially improved. The hydrodynamical conservations are solved, along with the rate equations for nonequilibrium ionization, recombination, and molecule formation, and the equation of radiative transfer, for steady-state shocks in a gas of primordial compositions. This calculation self-consistently includes the effects of the diffuse postshock emission as well as a possible external radiation flux on the postshock flow and the preshock ionization levels. A previous result is confirmed that the shocked gas cools faster than it can recombine and, as a result, is able to form an H2 concentration as high as 0.003 via the formation of H(-) and H2(+) intermediaries due to the enhanced nonequilibrium ionization fraction at 10,000 K. It is shown that, as the level of the external radiation flux is increased, the formation of and cooling by H2 molecules can be inhibited and delayed. The detailed radiation spectra and ionizing photon number fluxes emergent from these shocks are presented.
Kang, Hyesung↗
Hydrogen Molecules in SN 1987A
The observations of CO and SiO in the infrared spectrum of SN 1987A clearly indicate that molecules can form in the debris of a supernova explosion. Since H2 is not easily observable we compute its abundance theoretically. For conditions typical of the inner (v less than 2500 km/s) envelope of SN 1987A, the fraction of H that is in molecular form rises to approx. 1% by t approx. 800 days. For t less than 500 days the formation is dominated by the gas-phase reactions H + H(+) yields H2(+) + hv; H2(+) + H yields H2 + H(+). Thereafter, the formation is dominated by the reactions H + e yields H(-) + hv; H(-) + H yields H2 + e. At early times the H(-) may absorb approx. 10%-30% of visible photons, contributing to the apparent paucity of H alpha emission. For t greater than 1000 days the abundance of H2 'freezes out' due to the slowing of all reactions. The opacity of the supernova envelope in the range 912 less than lambda less than or approx. equal to 1400 A (the upper limit depending on temperature) is dominated by resonance scattering in the Lyman and Werner bands of H2. The resulting fluorescence emission bands of H2 in the range 1150 less than lambda less than 1650 A may be observable in the UV spectra of supernovae at late times.
Culhane, Michael↗