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From Astrochemistry to Astrobiology ...... and Back Again

Tremendous strides have been made in our understanding of interstellar material over the past twenty five years thanks to significant developments in observational infrared astronomy and laboratory astrophysics. Twenty five years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds generally ignored, and the notion of large, abundant, gas phase, carbon-rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of interstellar dust is reasonably well understood. In molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is reasonably well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. The first part of this talk will describe how infrared spectroscopic studies of interstellar space, combined with laboratory simulations and theoretical studies of PAHs and interstellar ices, have revealed the widespread presence of interstellar PAHs and the composition of interstellar precometary ices. The remainder of the presentation will focus on the photochemical evolution of these icy materials. Within a molecular cloud, and especially the presolar nebula, materials frozen into the ices are photoprocessed by ultraviolet light and more complex molecules are produced. As these materials are the building blocks of comets and related to carbonaceous micrometeorites, they are likely to be important sources of complex materials delivered to habitable planets and their composition may be related to the origin of life.

Allamandola, L. J.↗

On the Discrepancy Between the X-Ray and UV Absorption Measurements of O VI in the Local ISM

The total amount of Ovi present in the interstellar medium (ISM) obtained via absorption measurements in UV and X-ray spectra is currently in disagreement, with the latter being significantly larger (by a factor of 10 or more) than the former. Previous works have proposed that the blend of the Ovi K line (22.032 Ã) with the Oii K-L12 line (22.04 Ã) could account for the stronger absorption observed in the X-ray spectra. Here, we present a detailed study of the oxygen absorption in the local ISM, implementing our new model IGMabs which includes photoabsorption cross-sections of highly ionized species of abundant elements as well as turbulence broadening. By analysing high-resolution Chandra spectra of 13 low-mass X-ray binaries (LMXBs) and 29 extragalactic sources, we have estimated the column densities of Oi - Oiii and from Ovi - Oviii along multiple line-of-sights. We find that in most cases the Oii K-L12 line accounts for <30 per cent of the total Ovi K a + Oii K b. We conclude that the amount of Oii predicted by our model is still insufficient to explain the discrepancy between X-ray and UV measurements of Ovi column densities.

Gatuzz, Efrain↗

Computer simulation of dust grain evolution

The latest results are reported from a Monte Carlo code that is being developed at NASA Ames. The goal of this program, is to derive from the observed and presumed properties of the interstellar medium (ISM) the following information: (1) the size spectrum of interstellar dust; (2) the chemical structure of interstellar dust; (3) interstellar abundances; and (4) the lifetime of a dust grain in the ISM. Presently this study is restricted to refractory interstellar material, i.e., the formation and destruction of ices are not included in the program. The program is embedded in an analytic solution for the bulk chemical evolution of a two-phase interstellar medium in which stars are born in molecular clouds, but new nucleosynthesis products and stellar return are entered into a complementary intercloud medium. The well-mixed matter of each interstellar phase is repeatedly cycled stochastically through the complementary phase and back. Refractory dust is created by thermal condensation as stellar matter flows away from sites of nucleosynthesis such as novae and supernovae and/or from the matter returned from evolved intermediate stars. The history of each particle is traced by standard Monte Carlo techniques as it is sputtered and fragmented by supernova shock waves in the intercloud medium. It also accretes an amorphous mantle of gaseous refractory atoms when its local medium joins with the molecular cloud medium. Finally it encounters the possibility of astration (destruction by star formation) within the molecular clouds.

Liffman, K.↗

Gas and Cosmic-Ray Properties in the MBM 53, 54, and 55 Molecular Clouds and the Pegasus Loops Revealed by H i Line Profiles, Dust, and Gamma-Ray Data

In studying the interstellar medium (ISM) and Galactic cosmic rays (CRs), uncertainty of the interstellar gas density has always been an issue. To overcome this difficulty, we used a component decomposition of the 21 cm H i emission line and used the resulting gas maps in an analysis of γ-ray data obtained by the Fermi Large Area Telescope (LAT) for the MBM 53, 54, and 55 molecular clouds and the Pegasus loop. We decomposed the ISM gas into intermediate-velocity clouds, narrow-line and optically thick H i, broad-line and optically thin H i, CO-bright H 2 , and CO-dark H 2 using detailed correlations with the H i line profiles from the HI4PI survey, the Planck dust-emission model, and the Fermi-LAT γ-ray data. We found the fractions of the optical depth correction to the H i column density and CO-dark H 2 to be nearly equal. We fitted the CR spectra directly measured at/near the Earth and the measured γ-ray emissivity spectrum simultaneously. We obtained a spectral break in the interstellar proton spectrum at ~7 GeV, and found that the γ-ray emissivity normalization agrees with the AMS-02 proton spectrum within 10%, relaxing the tension with the CR spectra previously claimed.

79 ASTRONOMY AND ASTROPHYSICS↗

Nitrogen X-ray absorption in the local ISM

Nitrogen is one of the most abundant metals in the interstellar medium (ISM), and thus it constitutes an excellent test to study a variety of astrophysical environments, ranging from nova to active galactic nuclei. We present a detailed analysis of the gaseous component of the N K-edge using high-resolution XMM–Newton spectra of 12 Galactic and 40 extragalactic sources. For each source, we have estimated column densities for N I, N II, N III, N V, N VI, and N VII ionic species, which trace the cold, warm, and hot phases of the local Galactic ISM. We have found that the cold-warm component column densities decrease with the Galactic latitude, while the hot component does not. Moreover, the cold column density distribution is in good agreement with UV measurements. This is the first detailed analysis of the nitrogen K-edge absorption due to ISM using high-resolution X-ray spectra.

Efrain Gatuzz↗

The Interstellar Medium

The Interstellar Medium (ISM) forms an integral part of the lifecycle of stars and the galaxy. Stars are formed by gravitational contraction of interstellar clouds. Over their life, stars return much of their mass to the ISM through winds and supernova explosions, resulting in a slow enrichment in heavy elements. Understanding the origin and evolution of the ISM is a key problem within astrophysics. The KAO has made many important contributions to studies of the interstellar medium both on the macro and on the micro scale. In this overview, I will concentrate on two breakthroughs in the last decade in which KAO observations have played a major role: (1) the importance of large Polycyclic Aromatic Hydrocarbon (PAH) molecules for the ISM (section 3) and (2) the study of Photodissociation Regions (PDRs) as an analog for the diffuse ISM at large (section 4). Appropriately, the micro and macro problem are intricately interwoven in these problems. Finally, section 5 reviews the origin of the (CII) emission observed by COBE.

Tielens, Alexander G. G. M.↗

Acceleration of cosmic rays in supernova-remnants

It is commonly accepted that supernova-explosions are the dominant source of cosmic rays up to an energy of 10 to the 14th power eV/nucleon. Moreover, these high energy particles provide a major contribution to the energy density of the interstellar medium (ISM) and should therefore be included in calculations of interstellar dynamic phenomena. For the following the first order Fermi mechanism in shock waves are considered to be the main acceleration mechanism. The influence of this process is twofold; first, if the process is efficient (and in fact this is the cas) it will modify the dynamics and evolution of a supernova-remnant (SNR), and secondly, the existence of a significant high energy component changes the overall picture of the ISM. The complexity of the underlying physics prevented detailed investigations of the full non-linear selfconsistent problem. For example, in the context of the energy balance of the ISM it has not been investigated how much energy of a SN-explosion can be transfered to cosmic rays in a time-dependent selfconsistent model. Nevertheless, a lot of progress was made on many aspects of the acceleration mechanism.

Dorfi, E. A.↗

Infrared Emission From Interstellar PAHs, New Probes of the Interstellar Medium

Tremendous strides have been made in the understanding of interstellar material over the past twenty years thanks to significant, parallel developments in two closely related areas: observational IR astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely unknown and the notion of abundant, gas phase, polycyclic aromatic hydrocarbons (PAHs) anywhere in the interstellar medium (ISM) considered impossible. Today the dust composition of the diffuse and dense ISM is reasonably well constrained and the spectroscopic case for interstellar PAHs, impossibly large molecules by early interstellar chemistry standards, is very strong. PAH spectral features are now being used as new probes of the ISM. PAH ionization states reflect the ionization balance of the medium while PAH size and structure reflect the energetic and chemical history of the medium. Aromatic carbon-rich materials ranging in size from PAHs and PAH nanoclusters, to sub-micron and micron-sized dust grains represent an important component of the ISM. These species: (1) dominate the heating and cooling of interstellar clouds via energetic photoelectron ejection and infrared (IR) emission; (2) moderate the ionization balance in photodissociation regions and molecular clouds; (3) moderate the composition of the gas phase and play an important role in determining the chemistry of the ISM; (4) contribute to the interstellar extinction in the near IR, visible, and UV spectral regions; and (5) convert UV, visible, and near-IR radiation to mid- and far-IR radiation in the ISM and, as such, are responsible for the well known, widespread family of mid-IR emission features with major components near 3.3, 6.2, 7.7, 8.6, and 11.3 microns.

Hudgins, D. M.↗

Interstellar and Planetary Analogs in the Laboratory

We present and discuss the unique capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to investigate the interaction of ionizing radiation (UV, charged particles) with molecular species (neutral molecules, radicals and ions) and carbonaceous grains in the Solar System and in the Interstellar Medium (ISM). COSmIC stands for Cosmic Simulation Chamber, a laboratory chamber where interstellar and planetary analogs are generated, processed and analyzed. It is composed of a pulsed discharge nozzle (PDN) expansion that generates a free jet supersonic expansion in a plasma cavity coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a cavity ring down spectroscopy (CRDS) system for photonic detection and a Reflectron time-of-flight mass spectrometer (ReTOF-MS) for mass detection. This setup allows the study of molecules, ions and solids under the low temperature and high vacuum conditions that are required to simulate some interstellar, circumstellar and planetary physical environments providing new fundamental insights on the molecular level into the processes that are critical to the chemistry in the ISM, circumstellar and planet forming regions, and on icy objects in the Solar System. Recent laboratory results that were obtained using COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid particles from their gas-phase molecular precursors in environments as varied as circumstellar outflow and planetary atmospheres.

Salama, Farid↗

A multiparametric analysis of the Einstein sample of early-type galaxies. 1: Luminosity and ISM parameters

We have conducted bivariate and multivariate statistical analysis of data measuring the luminosity and interstellar medium of the Einstein sample of early-type galaxies (presented by Fabbiano, Kim, & Trinchieri 1992). We find a strong nonlinear correlation between L(sub B) and L(sub X), with a power-law slope of 1.8 +/- 0.1, steepening to 2.0 +/- if we do not consider the Local Group dwarf galaxies M32 and NGC 205. Considering only galaxies with log L(sub X) less than or equal to 40.5, we instead find a slope of 1.0 +/- 0.2 (with or without the Local Group dwarfs). Although E and S0 galaxies have consistent slopes for their L(sub B)-L(sub X) relationships, the mean values of the distribution functions of both L(sub X) and L(sub X)/L(sub B) for the S0 galaxies are lower than those for the E galaxies at the 2.8 sigma and 3.5 sigma levels, respectively. We find clear evidence for a correlation between L(sub X) and the X-ray color C(sub 21), defined by Kim, Fabbiano, & Trinchieri (1992b), which indicates that X-ray luminosity is correlated with the spectral shape below 1 keV in the sense that low-L(sub X) systems have relatively large contributions from a soft component compared with high-L(sub X) systems. We find evidence from our analysis of the 12 micron IRAS data for our sample that our S0 sample has excess 12 micron emission compared with the E sample, scaled by their optical luminosities. This may be due to emission from dust heated in star-forming regions in S0 disks. This interpretation is reinforced by the existence of a strong L(sub 12)-L(sub 100) correlation for our S0 sample that is not found for the E galaxies, and by an analysis of optical-IR colors. We find steep slopes for power-law relationships between radio luminosity and optical, X-ray, and far-IR (FIR) properties. This last point argues that the presence of an FIR-emitting interstellar medium (ISM) in early-type galaxies is coupled to their ability to generate nonthermal radio continuum, as previously argued by, e.g., Walsh et al. (1989). We also find that, for a given L(sub 100), galaxies with larger L(sub X)/L(sub B) tend to be stronger nonthermal radio sources, as originally suggested by Kim & Fabbiano (1990). We note that, while L(sub B) is most strongly correlated with L(sub 6), the total radio luminosity, both L(sub X) and L(sub X)/L(sub B) are more strongly correlated with L(sub 6 CO), the core radio luminosity. These points support the argument (proposed by Fabbiano, Gioia, & Trinchieri 1989) that radio cores in early-type galaxies are fueled by the hot ISM.

Eskridge, Paul B.↗

Observations of Carbon Isotopic Fractionation in Interstellar Formaldehyde

Primitive Solar System materials (e.g. chondrites. IDPs, the Stardust sample) show large variations in isotopic composition of the major volatiles (H, C, N, and O ) even within samples, witnessing to various degrees of processing in the protosolar nebula. For ex~ ample. the very pronounced D enhancements observed in IDPs [I] . are only generated in the cold. dense component of the interstellar medium (ISM), or protoplanetary disks, through ion-molecule reactions in the presence of interstellar dust. If this isotopic anomaly has an interstellar origin, this leaves open the possibility for preservation of other isotopic signatures throughout the form ation of the Solar System. The most common form of carbon in the ISM is CO molecules, and there are two potential sources of C-13 fractionation in this reservoir: low temperature chemistry and selective photodissociation. While gas-phase chemistry in cold interstellar clouds preferentially incorporates C-13 into CO [2], the effect of self-shielding in the presence of UV radiation instead leads to a relative enhancement of the more abundant isotopologue, 12CO. Solar System organic material exhibit rather small fluctuations in delta C-13 as compared to delta N-15 and delta D [3][1], the reason for which is still unclear. However, the fact that both C-13 depleted and enhanced material exists could indicate an interstellar origin where the two fractionation processes have both played a part. Formaldehyde (H2CO) is observed in the gas-phase in a wide range of interstellar environments, as well as in cometary comae. It is proposed as an important reactant in the formation of more complex organic molecules in the heated environments around young stars, and formaldehyde polymers have been suggested as the common origin of chondritic insoluable organic matter (IOM) and cometary refractory organic solids [4]. The relatively high gas-phase abundance of H2CO observed in molecular clouds (10(exp- 9) - 10(exp- 8) relative to H2) makes it feasible to observe its less common isotopologues. As a step in our investigation of C-13 fractionation patterns in the ISM, we here present comparisons between observations of the C-13 fraction in formaldehyde, and chemical fractionation models.

Wirstrom, E. S.↗

Metamorphism of cosmic dust: Processing from circumstellar outflows to the cometary regolith

Metamorphism of refractory particles continues in the interstellar medium (ISM) where the driving forces are sputtering by cosmic ray particles, annealing by high energy photons, and grain destruction in supernova generated shocks. Studies of the depletion of the elements from the gas phase of the interstellar medium tell us that if grain destruction occurs with high efficiency in the ISM, then there must be some mechanism by which grains can be formed in the ISM. Most grains in a cloud which collapses to form a star will be destroyed; many of the surviving grains will be severely processed. Grains in the outermost regions of the nebula may survive relatively unchanged by thermal processing or hydration. It is these grains which one hopes to find in comets. However, only those grains encased in ice at low temperature can be considered pristine since a considerable degree of hydrous alteration might occur in a cometary regolith if the comet enters the inner solar system. The physical, chemical and isotopic properties of a refractory grain at each stage of its life cycle will be discussed.

Nuth, Joseph A., III↗

Metamorphism of Cosmic Dust: Processing from Circumstellar Outflows to the Cometary Regolith

Nucleation is a non-equilibrium process: the products of this process are seldom the most thermodynamically stable condensates but are instead those which form fastest. It should therefore not be surprising that grains formed in a circumstellar outflow will undergo some degree of metamorphism if they are annealed or are exposed to a chemically active reagent. Metamorphism of refractory particles continues in the interstellar medium (ISM) where the driving forces are sputtering by cosmic ray particles, annealing by high energy photons and grain destruction in supernova generated shocks. Studies of the depletion of the elements from the gas phase of the interstellar medium tell us that if grain destruction occurs with high efficiency in the ISM, then there must be some mechanism by which grains can be formed in the ISM. Various workers have shown that refractory mantles could form on refractory cores by radiation processing of organic ices. A similar process may operate to produce refractory inorganic mantles on grain cores which survived the supernova shocks. Most grains in a cloud which collapses to form a star will be destroyed; many of the surviving grains will be severely processed. Grains in the outermost regions of the nebula may survive relatively unchanged by thermal processing or hydration. It is these grains which we hope to find in comets. However, only those grains encased in ice at low temperature can be considered pristine since a considerable degree of hydrous alteration might occur in a cometary regolith if the comet enters the inner solar system. Some discussion of the physical, chemical and isotopic properties of a refractory grain at each stage of its life cycle will be attempted based on the limited laboratory data available to date. Suggestions will be made concerning the types of experimental data which are needed in order to better understand the processing history of cosmic dust.

Nuth, Joseph A., III↗

Relative Sputtering Rates of FeS, MgS, and Mg Silicates: Implications for ISM Gas Phase Depletions of Rock-Forming Elements

Astronomical measurements of S abundances in the diffuse interstellar medium (ISM) indicate ionized S is a dominant species with little (< 5%) S residing in grains (e.g. Jenkins 2009). This is an enigmatic result, given that abundant Fe-sulfide grains are observed in dust around pre- and post-main sequence stars and are also observed as major components of primitive meteoritic and cometary samples. These disparate observations suggest that the lifetime of sulfide grains in the ISM is short because of destruction processes. Our previous work has shown that FeS and MgS retain their crystallinity and do not amorphize during radiation processing, whereas enstatite and forsterite are readily amorphized. We have extended this study to measure the relative sputtering rates of FeS and MgS compared to enstatite and forsterite. Irradiation of FeS with 4 keV He+ results in preferential sputtering of S and the formation of a thin 2-3 nm, compact Fe metal layer that armors the surface. The zone of S loss extends to a depth of ~8-10 nm below the exposed surface. Despite this S loss, the FeS retains its crystallinity and shows no sign of incipient amorphization. Irradiation of FeS with 5kV Ga+ in a focused ion beam (FIB) instrument resulted in preferential sputtering of S and the formation of a 5-8-nm thick surface layer of nanophase Fe metal. X-ray mapping shows that the zone of S sputtering extends to a depth of nearly 20 nm, but there is no evidence for FeS amorphization, consistent with our previous work. The irradiation experiments show that the relative sputtering rate of FeS and MgS are much higher than olivine or enstatite. Sputtering experiments utilizing 30 kV and 5 kV Ga ions in the FIB produced volume loss in troilite that was ~4X greater than in enstatite or forsterite. The sputter yield under these conditions is such that for every Si atom sputtered from enstatite, ~14 S atoms are sputtered from FeS. We have performed similar sputtering experiments on Fe-bearing niningerite (MgS) and co-existing enstatite from the ALH 84170 EH3 chondrite. MgS also sputters much more rapidly than enstatite with a relative Si:S sputter yield of 1:8. For MgS, sulfur is highly depleted at the surface and the S-depletion zone extends to a depth of ~15 nm (using 5 kV Ga+). There is a corresponding zone of Mg and especially Fe enrichment that extends from 5 to ~10 nm below the surface, respectively. The dominant grain destruction mechanism in the ISM is sputtering from passage of supernova-generated shock waves. This process also results in the amorphization of crystalline silicates in the ISM. Our results indicate that FeS and MgS grains produced in evolved stars and injected into the ISM will be destroyed more rapidly than crystalline silicates. This process may account for the lack of significant depletion of S from the gas phase in the ISM. However, rare nanophase FeS grains occur as inclusions in circumstellar amorphous silicate grains found in comet dust particles analyzed in the laboratory. These results show that a finite amount of S in the ISM is sequestered in solid grains.

SPUTTERING RATES↗

Studies of interstellar vibrationally-excited molecules

Several molecules thus far have been detected in the ISM in vibrationally-excited states, including H2, SiO, HC3N, and CH3CN. In order for vibrational-excitation to occur, these species must be present in unusually hot and dense gas and/or where strong infrared radiation is present. In order to do a more thorough investigation of vibrational excitation in the interstellar medium (ISM), studies were done of several mm-wave transitions originating in excited vibrational modes of HCN, an abundant interstellar molecule. Vibrationally-excited HCN was recently detected toward Orion-KL and IRC+10216, using a 12 meter antenna. The J=3-2 rotational transitions were detected in the molecule's lowest vibrational state, the bending mode, which is split into two separate levels, due to l-type doubling. This bending mode lies 1025K above ground state, with an Einstein A coefficient of 3.6/s. The J=3-2 line mode of HCN, which lies 2050K above ground state, was also observed toward IRC+10216, and subsequently in Orion-KL. Further measurements of vibrationally-excited HCN were done using a 14 meter telescope, which include the observations of the (0,1,0) and (0,2,0) modes towards Orion-KL, via their J=3-2 transitions at 265-267 GHz. The spectrum of the J=3-2 line in Orion taken with the 14 meter telescope, is shown, along with a map, which indicates that emission from vibrationally-excited HCN arises from a region probably smaller than the 14 meter telescope's 20 arcsec beam.

Ziurys, L. M.↗

SILCC – VII. Gas kinematics and multiphase outflows of the simulated ISM at high gas surface densities

ABSTRACT We present magnetohydrodynamic (MHD) simulations of the star-forming multiphase interstellar medium (ISM) in stratified galactic patches with gas surface densities Σgas = 10, 30, 50, and 100 $\mathrm{M_\odot \, pc^{-2}}$. The silcc project simulation framework accounts for non-equilibrium thermal and chemical processes in the warm and cold ISM. The sink-based star formation and feedback model includes stellar winds, hydrogen-ionizing UV radiation, core-collapse supernovae, and cosmic ray (CR) injection and diffusion. The simulations follow the observed relation between Σgas and the star formation rate surface density ΣSFR. CRs qualitatively change the outflow phase structure. Without CRs, the outflows transition from a two-phase (warm and hot at 1 kpc) to a single-phase (hot at 2 kpc) structure. With CRs, the outflow always has three phases (cold, warm, and hot), dominated in mass by the warm phase. The impact of CRs on mass loading decreases for higher Σgas and the mass loading factors of the CR-supported outflows are of order unity independent of ΣSFR. Similar to observations, vertical velocity dispersions of the warm ionized medium (WIM) and the cold neutral medium (CNM) correlate with the star formation rate as $\sigma _\mathrm{z} \propto \Sigma _\mathrm{SFR}^a$, with a ∼ 0.20. In the absence of stellar feedback, we find no correlation. The velocity dispersion of the WIM is a factor ∼2.2 higher than that of the CNM, in agreement with local observations. For $\Sigma _\mathrm{SFR} \gtrsim 1.5 \times 10^{-2}\, \mathrm{M}_\odot \, \mathrm{yr}^{-1}\, \mathrm{kpc}^{-2}$ the WIM motions become supersonic.

Astronomy & Astrophysics↗

Diagnosis of 3D magnetic field and mode composition in MHD turbulence with Y -parameter

ABSTRACT Magnetic fields are crucial in numerous astrophysical processes within the interstellar medium (ISM). However, the detailed determination of magnetic field geometry is notoriously challenging. Based on the modern magnetohydrodynamic (MHD) turbulence theory, we introduce a novel statistical technique, the ‘Y-parameter’, to decipher the magnetic field inclination in the ISM and identify dominant turbulence modes. The Y-parameter, calculated as the ratio of anisotropies of different Stokes parameter combinations, displays contrasting trends with the mean-field inclination angle in Alfvénic and compressible turbulence modes. A Y-parameter value around 1.5 ± 0.5 provide a statistical boundary to determine the dominant MHD turbulence modes. We have discovered specific correlations between the Y-parameter value and the inclination angle that unveil the dominant turbulence mode. This methodology, when applied to future radio polarization surveys such as LOFAR and SKA, promises to significantly enhance our knowledge of 3D magnetic field in the ISM and improve our understanding of interstellar turbulence.

79 ASTRONOMY AND ASTROPHYSICS↗

On the Origin of GEMS

GEMS (glass with embedded metal and sulfides) are a major component of anhydrous interplanetary dust particles (IDPs) their physical and chemical characteristics show marked similarities to contemporary interstellar dust. Recent oxygen isotopic measurements confirm that at least a small fraction (less than 5%) of GEMS are demonstrably presolar, while the remainder have ratios that are indistinguishable from solar values. GEMS with solar oxygen isotopic compositions either (1) had their isotopic compositions homogenized through processing in the interstellar medium (ISM), or (2) formed in the early solar system. Isotopic homogenization necessarily implies chemical homogenization, so (interstellar) GEMS compositions should reflect the average composition of dust in the local ISM. We performed a systematic examination of the bulk chemistry of GEMS in primitive IDPs in order to test this hypothesis.

Keller, L. P.↗